• Journal of Korean Society for Atmospheric Environment
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• 제21권E3호
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• pp.75-85
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• 2005

A mathematical sensitivity analysis of the flow-through dynamic flux chamber technique, which has been utilized usually for various trace gas flux measurement from soil and water surface, was performed in an effort to provide physical and mathematical understandings of parameters essential for the NO flux calculation. The mass balance equation including chemical reactions was analytically solved for the soil NO flux under the steady state condition. The equilibrium concentration inside the chamber, $C_{eq}$, was found to be determined mainly by the balance between the soil flux and dilution of the gas concentration inside the chamber by introducing the ambient air. Surface deposition NO occurs inside the chamber when the $C_{eq}$ is greater than the ambient NO concentration ($C_{0}$) introducing to the chamber; NO emission from the soil occurs when the $C_{eq}$ is less than the ambient NO concentration. A sensitivity analysis of the significance of the chemical reactions of NO with the reactive species (i.e. $HO_{2},/CH_{3}O_{2},/O_{3}$) on the NO flux from soils was performed. The result of the analysis suggests that the NO flux calculated in the absence of chemical reactions and wall loss could be in error ranges from 40 to $85\%$ to the total flux.

• 한국농림기상학회지
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• 제9권3호
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• pp.170-178
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• 2007

지난 수 세기 동안 온실기체와 기타 화학적으로 중요한 미량기체들이 급격하게 증가하였다. 이러한 주요기체가 기후 변화에 미치는 영향을 이해하기 위해서는 각 기체들의 흡원과 발원을 규명하고, 생물권과 대기권 사이에서 발생하는 생물 기원 기체 플럭스들을 특성화하며, 주요 기체를 조절하는 프로세스들을 이해해야 한다. 본 논문에서는 야외 실험을 위한 실용적 방법인 enclosure 기반의 관측법을 소개한다. 특히, 토양표면에서 방출되는 일산화질소 플럭스에 대한 enclosure내에서의 질량수지 방정식과 flow-through dynamic 플럭스 챔버 기법의 민감도를 제시하고 flow-through dynamic 플럭스 챔버 방법의 물리적인 시스템과 이론을 소개한다. 또한 챔버 벽에서 발생하는 일산화질소의 손실을 고려하므로써 새로운 플럭스 계산식을 소개하였고 그 계산식의 불확실성을 논의하였다.

• 한국환경보건학회지
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• 제36권1호
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• pp.33-43
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• 2010

Atmospheric ammonia is a very important constituent of the environment because it is the dominant alkaline gaseous species present in the atmosphere. Ammonia is known to affect ecosystems at relatively low concentration. In this study flux profiles of ammonia emitted from the cattle housing were evaluated using a dynamic flux chamber (DFC). We have developed the emission factor of $NH_3$ from the cattle housing. Analysis of ammonia flux variation was made with respect to such variables as manure surface temperature, pH, and ammonium concentration. Ammonia flux has been measured up to summer in 2007 at calf and cattle housing. In the fall, average ammonia flux from calf and cattle housing was estimated as 1.406 (${\pm}0.947$) and 1.534 ((${\pm}0.956$) $mg\;m^2\;min^1$, respectively. In the winter, average ammonia flux was estimated 1.060 ((${\pm}0.569$) from the calf housing and 1.216 ((${\pm}0.655$) $mg\;m^2\;min^1$ from the cattle housing. The correlation coefficient (R=0.732) between ammonia flux and manure surface ammonium concentration exhibited stronger relationship than manure surface pH and temperature. In the fall, ammonia emission factor from calf and cattle housing was estimated as 3.94 ((${\pm}2.66$) and 11.41 ((${\pm}5.86$) kg-$NH_3$ animal$^1\;yr^1$, respectively. In the winter, ammonia average flux was estimated as 2.89 ((${\pm}1.59$) from the calf housing and 6.51 ((${\pm}3.67$) kg-$NH_3$ animal$^1\;yr^1$ from the cattle housing.

• 환경영향평가
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• 제14권5호
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• pp.263-273
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• 2005

In this study, the major emission procedures and emission characteristics were identified at the site of sewage treatment plant which is one of the major sources of ammonia. At the same time the emission factors and emission rates were estimated. In order to calculate the emission flux, we used a Dynamic Flux Chamber(DFC), which is found to be a proper sampling devise for area sources such as sewage treatment plant. It was found that the most stable sampling condition was when the stirrer's speed of DFC was 120RPM, and it would be the best time to take a sample 60 minutes later after setting the chamber. The relatively higher flux was shown in Autumn compared to summer and winter. Annual ammonia emission rates procedures were calculated as $906.32{\mu}g/activity-ton$, $1,114.72{\mu}g/activity-ton$ and $437.53{\mu}g/activity-ton$ each at the primary settling basin, aeration basin and the final settling basin, respectively. The ammonia emission rate the highest at in the aeration basin according to this test. This results was due to that the surface of aeration basin or the final settling basin is relatively wider than the primary settling basin.

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2010년도 춘계학술대회 논문집
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• pp.263-264
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• 2010

• 한국대기환경학회지
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• 제22권5호
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• pp.701-711
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• 2006

Sewage treatment plants located near to large cities emit extremely higher concentration of odorous materials. This study evaluated flux profiles of ammonia emitted from the water surface of sewage treatment plants using a dynamic flux chamber. Also, an ammonia overall mass transfer coefficient and a mass transfer model was developed in order to estimate fluxes of ammonia using environment parameters and the flux from the sewage treatment plants. The developed mass transfer model was evaluated through a fitness analysis. Comparison modeled flux applying empirical overall mass transfer coefficients of ammonia and measured ammonia flux show a high linearity with 0.977. The flux ratio of 1.282 demonstrated highly statistical fitness, also. Modeled flux using the mass transfer model was compared with measured flux. In result, it indicated that empirical overall mass transfer coefficients were similar to measured flux. The mass transfer model using the empirical overall mass transfer coefficient developed in this study was proved to be an easy and effective method to make accurate and precise predictions for ammonia flux discharged from sewage treatment plants.

• 한국항공우주학회지
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• 제31권2호
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• pp.72-79
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• 2003

고체 추진제의 소화를 위한 연소실 압력 강하시 금속입자들에 의한 복사열전달에 동적소화에 미치는 영향을 알아보았다. AP:Binder의 화학반응으로 발생하는 전도열 플럭스를 구하기 위해 화염모델을 사용하였으며, 금속입자들에 복사열 플럭스를 구하기 위해 연소흐름 모델을 사용하였다. 연소실은 크기가 무한대인 경우와 노즐에 의해 제한된 형태 두 가지를 선택하여 계산을 수행하였다. 계산에 사용된 추진제 조성을 AP:Al:CTPB=76:10:14이며 최종압력 이후, 총 열 플럭스 중 복사열 플럭스가 차지하는 비중은 5~6%정도로 나타났다. 연소실 크기가 무한대인 경우, 복사열전달을 고려한 경우의 임계 압력강하율이 복하열을 고려하지 않은 경우보다 45% 크게 나타났다. 이는 복사열전달이 동적소화에 큰 영향을 미치는 것을 보여주는 것이다.

• 한국농림기상학회지
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• 제5권2호
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• pp.94-100
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• 2003

토양으로부터의 $CO_2$ 방출은 생태계의 탄소 순환에 중요한 위치를 차지한다. 주요 생태계의 순 $CO_2$ 교환과 일차 생산량 등을 정확히 산출하려면 군락 $CO_2$ 플럭스와 더불어 토양 $CO_2$ 플럭스의 관측이 함께 이루어져야 한다. 본 논문에서는 닫힌 역학 챔버 시스템을 활용한 토양 이산화탄소 플럭스의 관측 방법을 간략히 검토하고, 한반도 주요 생태계에 구축된 한국 타워 플럭스 관측 지역망(KoFlux)의 거점 관측소에서 예비 관측된 결과와 서로 다른 관측 시스템간의 상호비교 결과를 보고하고자 한다.

• 한국대기환경학회지
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• 제30권6호
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• pp.531-537
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• 2014

Terrestrial vegetation has been known as a main source of biogenic volatile organic compounds (BVOCs). Isoprene and monoterpene among the BVOCs are most abundant species emitted by forests, and have a significant impact on atmospheric chemistry. Abundancy of these species could lead to an increase or decrease in the production of natural tropospheric ozone in forests, depending on the nitric oxide (NO) concentration. Soil is the most significant source of natural NO. Understanding of NO emission from forest soil could be critical in evaluation of air quality in the forest area. Flux-gradient similarity theory (FGST) was applied for practical use to estimate forest soil NO emission at Mt. Taewha where is available micro-meteorological data near surface monitoring from flux tower. NO fluxes calculated by FGST were compared to flux results by flow-through dynamic chamber (FDC) measurement. Surface NO emission trends were shown between two different techniques, however their magnitudes were found to be different. NO emissions measured from FDC technique were relatively higher than those from theoretical results. Daily mean NO emissions resulted from FGST during Aug. 13, 14 and 15 were $0.28{\pm}8.45$, $2.17{\pm}15.55$, and $-3.18{\pm}13.65{\mu}gm^{-2}hr^{-1}$, respectively, while results from FDC were $2.26{\pm}1.44$, $5.11{\pm}3.85$, and $2.23{\pm}6.45{\mu}gm^{-2}hr^{-1}$. Trends of daily means were shown in similar pattern, which NO emissions were increasing during late afternoon ($r^2$=0.04). These emission trends could be because soil temperature and moisture influence importantly soil microbiology.

• 대한환경공학회지
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• 제38권10호
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• pp.535-542
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• 2016

플럭스 챔버법은 비용효율적인 표면 발산량의 측정방법으로 다양한 연구 분야에 널리 이용되어 왔다. 플럭스 챔버법은 운용 방식에 따라 기울기 방식을 이용한 닫힌 챔버법(SFC)과 평형 농도 방식을 이용한 열린 챔버법(DFC)으로 분류할 수 있는데, SFC 방식은 장비가 간단하고 운용이 쉬운 반면, 직선성에 대한 불확실한 가정으로 인하여 플럭스 산정 값이 가변적인 단점이 있다. 한편, DFC 방식은 더 많은 특정 기기가 필요하지만, 어떤 애매모호함이 없이 일정한 값을 산정할 수 있다. 따라서 본 연구는 작고 조밀한 키트를 이용하여 DFC를 자체 제작하였다. 자체 제작한 DFC는 30분 이내에 평형상태에 도달하였고, 측정 초기의 불충분한 혼합을 제외하면 시료 균질도가 5% 미만이고, 회수율이 90% 이상으로 우수하였다. 이 개선된 DFC의 상대확장불확도는 7.37%로 평가되었는데, 이는 주로 통제되지 않은 유입가스에 기인한다. 연구 결과는 대규모 매립지에서 소형의 측정 키트를 이용한, 개선된 DFC 방식이 신뢰성이 높은 자료를 효과적으로 축적할 수 있음을 보여준다.