• Macromolecular Research
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• v.12 no.4
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• pp.422-426
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• 2004

Solid polymer electrolytes based on poly(ethylene glycol)-polyurethane (PEG-PU) complexed with LiClO$_4$ salt have been prepared by the solvent casting method. A PEG-PU material (PEG:4,4'-diphenylmethane diisocyanate: l,4-butanediol = 1:2:1) was synthesized through a typical two-step condensation reaction. We investigated the effects of the salt concentration on the ionic conductivity ($\sigma$) and the glass transition temperature (T$_{g}$ ) of the complex electrolytes by using alternating current impedance spectroscopy, differential scanning calorimetry, and dynamic mechanical thermal analysis. The measured values of both $\sigma$ and T$_{g}$ exhibited similar tendencies in that they had maxima within the range studied, probably because of two opposite effects, i.e., the increased number of carrier ions and the decreased chain mobility (or increased T$_{g}$ ) caused by the increase in the salt concentration. The highest conductivity, on the order of 2.43 ${\times}$ 10$^{6}$ S$cm^{-1}$ /, was obtained at an [O]/[Li$^{+}$] ratio of ca. 16 (0.92 ㏖ salt per kg of matrix polymer).

• Structural Engineering and Mechanics
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• v.76 no.2
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• pp.163-173
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• 2020

As a vehicle moves on multiple equal-span beams at constant speed, the running vehicle would be subjected to repetitive excitations from the beam vibrations under it. Once the exciting frequency caused by the vibrating beams coincides with any of the vehicle's frequencies, resonance would take place on the vehicle. A similar resonance phenomenon occurs on a beam subject to sequential moving loads with identical axle-intervals. To reduce both resonant phenomena of a vehicle moving on guideway girders, this study proposed an additional feedback controller based the condensed virtual dynamic absorber (C-VDA) scheme. This condensation scheme has the following advantages: (1) the feedback tuning gains required to adapt the control currents or voltages are directly obtained from the tuning forces of the VDA; (2) the condensed VDA scheme does not need additional DoFs of the absorber to control the vibration of the maglev-vehicle/guideway system. By decomposing the maglev vehicle-guideway coupling system into two sub-systems (the moving vehicle and the supporting girders), an incremental-iterative procedure associated with the Newmark method is presented to solve the two sets of sub-system equations. From the present studies, the proposed C-VDA scheme is a feasible approach to suppress the interaction response for a maglev vehicle in resonance moving on a series of guideway girders.

• Macromolecular Research
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• v.12 no.4
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• pp.384-390
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• 2004

Single-walled carbon nanotubes (SWNTs) have been chemically modified through the formation of carboxylic acid functionalities or by grafting octadecylamine and polystyrene onto them. We purified SWNTs with nitric acid to remove some remaining catalysts and amorphous carbon materials. After purification, we broke the carbon nanotubes and shortened their lengths by using a 3:1 mixture of concentrated sulfuric acid and nitric acid. During these purification and cutting processes, carboxylic acid units formed at the open ends of the SWNTs. Octa-decylamine and amino-terminated polystyrene were grafted onto the cut SWNTs by condensation reactions between the amine and carboxylic acid units. The cut SWNTs did not disperse in organic solvents, but the octadecylamine-grafted and polystyrene-grafted SWNTs dispersed well in dichloromethane and aromatic solvents (e.g., benzene, toluene). Composites were prepared by mixing polystyrene with the octadecylamine-grafted or polystyrene-grafted SWNTs. Each composite had a higher dynamic storage modulus than that of a pristine polystyrene. The composites exhibited enhanced storage moduli, complex viscosities, and unusual non-terminal behavior when compared with a monodisperse polystyrene matrix because of the good dispersion of carbon nanotubes in the polystyrene matrix.

• Journal of Environmental Science International
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• v.21 no.10
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• pp.1195-1202
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• 2012

The purpose of this work is to study the adsorption and desorption characteristics of acetone vapor and toluene vapor from adsorption tower in the VOCs recovery device. The six kinds of activated carbon with different pore structures were used and the adsorption and desorption characteristics were compared according to pore structure, desorption temperature, and adsorption method, respectively. Adsorption capacity of acetone vapor and toluene vapor by batch method was higher than that by dynamic method. Especially, activated carbon with medium-sized or large pores had more difference in adsorption capacity according to adsorption methods as a result of gradually condensation of vapors on relatively mesopore and large pores. Activated carbons with relatively large pores and relatively small saturated adsorption capacity had excellent desorption ability.

• Computational Structural Engineering
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• v.10 no.4
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• pp.117-130
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• 1997

In this paper, a modified 10-node equivalent solid element(MQM10 element), which has smallest degrees of freedom among 3-dimensional solid elements accounting bending deformation as well as extensional and shear deformations of isotropic plates, is proposed. The proposed MQM10 element exhibits stiffer bending stiffness due to the reduction of degrees of freedom from 20-node element or Q11 element. As an effective way to correct the relative stiffness stiffening phenomenon, the modification equation of Gauss sampling points is proposed. The quantity of modification is a function of Poisson's ratio. The effectiveness of MQM10 element is tested by applying it to several examples. It is noted that the results of static and free vibration analysis of isotropic plates using MQM10 elements show a good agreement with those using 20-node element.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.20 no.4
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• pp.1320-1332
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• 1996

In the present study, we consider modified 5-node equivalent solid element which has smallest degree of freedom among 2-dimensional solid elements accounting bending deformation as well as extensional and shear deformations, We shall investigate static and dynamic characteristics of this element, which is very effective in thin beam, thick beam, large displacement problems, beam of variable thickness, and asymmetrically stepped beam, etc., as well as relatively simple problems of beam. The degree of freedom of this element is 10, which is smaller than 18 of 9-node element, 16 of 8-node elemtns, 12 of modified 6-node element and Q6 element. Therefore, this element is expected to broaden the effective range of application of the solid elements in the bending problems further.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.31 no.2 s.257
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• pp.221-230
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• 2007

An iterated improved reduced system (IIRS) procedure combined with sub-structuring scheme for nonclassically damped structural systems is presented. For dynamic analysis of such systems, complex eigenproperties are required to incorporate properly the nonclassical damping effect. In complex structural systems, the equations of motion are written in the state space from. Thus, the number of degrees of freedom of the new equations of motion and the size of the associated eigenvalue problem required to obtain the complex eigenvalues and eigenvectors are doubled. Iterated IRS method is an efficient reduction technique because the eigenproperties obtained in each iteration step improve the condensation matrix in the next iteration step. However, although this reduction technique reduces the size of problem drastically, it is not efficient to apply this technique to a single domain finite element model with degrees of freedom over several thousands. Therefore, for a practical application of the reduction method, accompanying sub-structuring scheme is necessary. In the present study, iterated IRS method combined with sub-structuring scheme for nonclssically damped structures is developed. Numerical examples demonstrate the convergence and the efficiency of a newly developed scheme.

• Proceedings of the Earthquake Engineering Society of Korea Conference
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• 2003.03a
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• pp.329-336
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• 2003

The box system that is composed only of reinforced concrete walls and slabs are adopted on many high-rise apartment buildings recently constructed in Korea. And the framed structure with shear wall core that can effectively resist horizontal forces is frequently adopted for the structural system for high-rise building structures. In these structures, a shear wall may have one or more openings for functional reasons. It is necessary to use subdivided finite elements for accurate analysis of the shear wall with openings. But it would take significant amount of computational time and memory if the entire building structure is subdivided into a finer mesh. An efficient analysis method that can be used regardless of the number, size and location of openings is proposed in this study. The analysis method uses super element, substructure, matrix condensation technique and fictitious beam technique. Three-dimensional analyses of the box system and the framed structure with shear wall core having various types of openings were peformed to verify the efficiency of the proposed method. It was confirmed that the proposed method have outstanding accuracy with drastically reduced time and computer memory from the analyses of example structures.

• Proceedings of the Earthquake Engineering Society of Korea Conference
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• 2003.09a
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• pp.191-198
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• 2003

Flat slab system has been adopted in many buildings constructed recently because of the advantage of reduced floor heights to meet the economical and architectural demands. Structural engineers commonly use the equivalent frame method(EFM) with equivalent beams proposed by Jacob S. Grossman in practical engineering for the analysis of flat slab structures. However, in many cases, when it is difficult to use the EFM, it is necessary to use a refined finite element model for an accurate analysis. But it would take significant amount of computational time and memory if the entire building structure were subdivided into a finer mesh. An efficient analytical method is proposed in this study to obtain accurate results in significantly reduced computational time. The proposed method employs super elements developed using the matrix condensation technique and fictitious beams are used in the development of super elements to enforce the compatibility at the interfaces of super elements. The stiffness degradation of flat slab system considered in the EFM was taken into account by reducing the elastic modulus of floor slabs in this study. Static and dynamic analyses of example structures were peformed and the efficiency and accuracy of the proposed method were verified by comparing the results with those of the refined finite element model and the EFM.

• Elastomers and Composites
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• v.48 no.1
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• pp.67-75
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• 2013

E-TPE (Engineering Thermoplastic Polyether Ester) was Ester Elastomer with functional groups as recycling and fast processability. In addition, if the car's lightweight enough to highlight eco-friendly materials that help to improve fuel economy has become. Have all the attributes of the rubber and engineering plastics E-TPE the available temperature area is spacious, heat resistance and oil resistance is excellent but getting attention as a new material in the field of auto parts in the field of electrical and electronic domestic depends entirely on imports by the lack of core technology and has been research and development is urgently needed. In this study, the hard segments, polyester (TPEE) as the base soft elastomers of the segments Ethylen-prophylene-Copolymer and CSM (Choloro sulphonated polyethylene Rubber), VAMAC (Ethylene Acrylic Rubber), NBR (Acrylonitrin Butadiene Rubber), 1, 3-Phenylene-bisoxazoline is dealing with Dynamic Vulcanized by content and added rubber properties, thermal variation observed. As a result, the properties of the dynamic vulcanization with NBR compared to other rubber heat resistance and oil resistance is on the increase.