• Title/Summary/Keyword: Dynamic coating

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Influence of Current Density on Corrosion Properties of AZ91 Mg Alloy Coated by Plasma Electrolytic Oxidation Method (인가전류밀도에 따른 플라즈마 전해산화코팅된 AZ91 마그네슘 합금의 내식성 변화)

  • Lee, Byung Uk;Hwang, In Jun;Lee, Jae Sik;Ko, Young Gun;Shin, Dong Hyuk
    • Korean Journal of Metals and Materials
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    • v.49 no.8
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    • pp.601-607
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    • 2011
  • The study investigated the influence of current density on the corrosion-protection properties of an AZ91 Mg alloy subjected to plasma electrolytic oxidation coating. The present coatings were carried out under an AC condition at three different current densities, i.e., 100, 150, and $200mA/cm^2$. From microstructural observations, the micro cracks connecting each micro pore were pronounced on the oxide surface of the samples coated at current densities higher than $150mA/cm^2$ since increasing the current density in this study led to an increment in the relative volume fraction of the MgO compound. Based on potentio dynamic polarization and immersion tests, the sample coated at a current density of $100mA/cm^2$ showed superior corrosion resistance.

Surface Modification of Steel Tire Cords via Plasma Etching and Plasma Polymerization Coating : Part II. Characterization (플라즈마 고분자 코팅에 의한 강철 타이어 코드의 표면 개질 : 제2부. 타이어 코드의 분석)

  • Kang, H.M.;Chung, K.H.;Kaang, S.;Yoon, T.H.
    • Elastomers and Composites
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    • v.35 no.1
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    • pp.63-70
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    • 2000
  • Zinc plated steel tire cords were subjected to RF plasma etching of argon, followed by plasma polymerization coating of acetylene or butadiene in order to enhance adhesion to rubber compounds. Plasma polymerization was carried out under optimized conditions of 10 W, 30 sec, 30 mTorr for acetylene and butadiene gas, while plasma etching was performed at 90W, 10min and 30mTorr. The adhesion of tire cords was evaluated via Tire Cords Adhesion Test (TCAT) and the failure surfaces of the tested samples were analyzed by SEM. Polymer coating by plasma polymerization was also characterized by FT-IR, Alpha-Step and dynamic contact angle analyzer in order to elucidate the adhesion mechanism.

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Characterization of Fluorocarbon Thin Films by Contact Angle Measurements (접촉각 측정을 통한 불화 유기박막의 특성 평가)

  • 박진구;차남구;신형재;박장호
    • Journal of the Microelectronics and Packaging Society
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    • v.6 no.1
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    • pp.39-49
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    • 1999
  • Monolayer thick fluorocarbon films were characterized by the contact angle measurements. The contact angles of three different liquids, water, formamide and diiodomethane were measured on spun coated, vapor phased deposited films and Teflon surface. The highest contact angle over $130^{\circ}$was observed on fluorocarbon films deposited on Al substrates while the lowest angles below $70^{\circ}$deposited on oxide. The surface energies were calculated based on Lewis acid /base theory. The surface energies of Teflon and spin coated FC films were calculated to have 18 and 8.4 dynes /cm, respectively. Higher energies of 31 to .35 dynes /cm were calculated on vapor phase deposited films on silicon and oxide. However vapor phase deposited films on aluminum only showed a large Lewis base energy term. It might be explained by the surface roughness and heterogeneity as observed by dynamic contact angles and AFM measurements.

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A Study on Developing the Modern Fashion Design with the Application of Plasticity of Patchwork Wrapping Cloth (조각보의 조형성을 응용한 현대복식디자인 개발에 관한 연구)

  • Kim Jeong-Mee
    • Journal of the Korean Society of Clothing and Textiles
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    • v.30 no.4 s.152
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    • pp.507-518
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    • 2006
  • This study aims to prove that traditional patchwork wrapping cloth can be a creative motive for modem fashion, and the application of it can be a way of expressing not only the pride in our cultural heritage but also the originality of fashion design. The analysis of the plasticity of 108 patchwork wrapping clothes has come up with the following findings: Firstly, the plane structure consists of 41 basic forms and 67 applied ones. Secondly, 61 contrast color harmony and 47 similarity color harmony. Thirdly, the fabric consists of 88 silk clothes, 19 ramie clothes, and 1 silk and ramie cloth. Fourthly, 47 unlined clothes and 61 lined ones. The study also expresses the analyzed plasticity of patchwork wrapping cloth for fashion with the following findings: Firstly, basic plane structures, contrast color harmony, silk cloth and the press flower coating technique become one piece dress to express splendid and elegant image. Secondly, application plane structures, similarity color harmony of natural dyeing method using persimmon, ramie cloth and the press flower coating and over lock technique become a jacket and a blouse to express calm and dynamic image. Thirdly, the needling and over lock technique used to patch clothes has become a desirable way to express fabric with unique surface effects. Fourthly, the press flower coating which modernizes embroidery in patchwork wrapping. cloth has become a new technique which can create high values with its extended the visual effects of the material. Fifthly, Patchwork wrapping cloth in Chosun Dynasty has now become a motive for modem fashion design to express tradition and creation.

Preparation of Cyclosporin A-loaded Nanoparticles Containing Ethyl Myristate or Chitosan and Pharmacokinetics in Rats

  • Nam, Dae-Sik;;Lee, Woo-Kyoung
    • Journal of Pharmaceutical Investigation
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    • v.37 no.1
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    • pp.15-22
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    • 2007
  • An oil-in-water solvent evaporation method was used to prepare the cyclosporin A (CyA)-loaded nanoparticles varying in poly (D,L-lactide-co-glycolide) (PLGA) polymer (RG 502H, RG 503H) and the amount of additive ethyl myristate (EM) or chitosan (CS). The particles were characterized for drug loading and entrapment efficiency by HPLC, surface morphology by scanning electron microscopy, particle size by dynamic light scattering and surface charge by Zetapotential. The results showed drug loadings ranging from 10.9% to 15.8% with high encapsulation efficiency (82.0-97.8%). SEM and DLS studies showed discrete and spherical particles with smooth surfaces and mean size ranging 257.6-721.7 nm. The additive EM or CS did not change the mean sizes of the nanoparticles, whereas by the coating effect of CS, the Zetapotential values of the CS-added nanoparticles were moved to the more positive direction as the amount of CS was increased. From the pharmacokinetic analysis, the nanoparticles formulations showed the higher bioavailability and MRT than $Neoral^{\circledR}$ While little adding effect of EM or CS was detected in pharmacokinetic profile when RG 503H was used as polymer carrier, more noticeable different pharmacokinetic behaviors could be observed in case of RC 502H. EM incorporation was found to elevate the $K_{el}$, whereas CS coating resulted in the decrease of F and $K_{el}$, which seems to be due to the function of CS as a barrier and a mucoadhesive coating.

An Experimental Study on the Self-Consolidating Concrete with EP Nylon Fiber (EP 나일론섬유를 혼입한 자기충전콘크리트(SCC)에 관한 실험적 연구)

  • Ryou, Jae Suk;Lee, Yong Soo;Jeon, Joong Kyu;Jeon, Chan Ki
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.15 no.1
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    • pp.159-168
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    • 2011
  • In this study, we find out the feasibility of self-consolidating concrete with EP nylon fiber. Three kinds of method were used; when length of nylon fiber is differed for the experiment to investigate usability of nylon fiber with enhanced performance by dispersing-agent coating in self-consolidating concrete, when mixing in other organic fibers (polypropylene, cellulose) and in case of Binary Blended and Ternary Blended concrete mixed with different types of mineral admixtures (blast-furnace slag and fly ash). Based on the results of the experiment described above, comparison was made on the basic properties and dynamic characteristics of general fiber reinforced concrete mixed with enhanced performance nylon fiber and SCC mixed with enhanced performance nylon fiber as a Mock-up test prior to the experiment of application to the actual structure. Considering characteristics and durability of the fresh and hardened self-compacting concrete, dynamic characteristics and durability were found to be more outstanding when using nylon fiber for the mineral admixtures used, dynamic characteristics and durability were found to be more outstanding when using blast-furnace slag.

Fabrication and Characterization of Carbon Nanotube/Carbon Fiber/Polycarbonate Multiscale Hybrid Composites

  • Cho, Beom-Gon;Hwang, Sang-Ha;Park, Young-Bin
    • Composites Research
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    • v.29 no.5
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    • pp.269-275
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    • 2016
  • Multiscale hybrid composites, which consist of polymeric resins, microscale fibers and nanoscale reinforcements, have drawn significant attention in the field of advanced, high-performance materials. Despite their advantages, multiscale hybrid composites show challenges associated with nanomaterial dispersion, viscosity, interfacial bonding and load transfer, and orientation control. In this paper, carbon nanotube(CNT)/carbon fiber(CF)/polycarbonate(PC) multiscale hybrid composite were fabricated by a solution process to overcome the difficulties associated with controlling the melt viscosity of thermoplastic resins. The dependence of CNT loading was studied by varying the method to add CNTs, i.e., impregnation of CF with CNT/PC/solvent solution and impregnation of CNT-coated CF with PC/solvent solution. In addition, hybrid composites were fabricated through surfactant-aided CNT dispersion followed by vacuum filtration. The morphologies of the surfaces of hybrid composites, as analyzed by scanning electron microscopy, revealed the quality of PC impregnation depends on the processing method. Dynamic mechanical analysis was performed to evaluate their mechanical performance. It was analyzed that if the position of the value of tan ${\delta}$ is closer to the ideal line, the adhesion between polymer and carbon fiber is stronger. The effect of mechanical interlocking has a great influence on the dynamic mechanical properties of the composites with CNT-coated CF, which indicates that coating CF with CNTs is a suitable method to fabricate CNT/CF/PC hybrid composites.

Preparation and Properties of UV-Curable Polyurethane Acrylates(I) -Effect of Molecular Weights of Polyol and Diol with Low Molecular Weight into Polymer Chain- (UV-경화 폴리우레탄 아크릴레이트의 제조와 특성(I) -폴리올의 분자량과 저분자량 디올의 도입의 영향-)

  • 최준영;이동진;김한도
    • Textile Coloration and Finishing
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    • v.11 no.4
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    • pp.1-7
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    • 1999
  • Urethane-acrylate propelymers for secondary coating of optical fiber and high - performance material were prepared from the 4,4'-diphenylmethane diisocyanate(MDI), poly(tetramethylene oxide)glycol(PTMG, Mw 650 or 1000), 1,6-hexanediol(HD), 2-hydroxyethyl acrylate(HEA), and dibutyltin dilaurate as a catalyst. UV-Curable polyurethane acrylates were formulated from the urethane-acrylate prepolymers, three types of reactive diluents(DTs) having mono-, di-, and trifunctional-phenoxyethyl acrylate(PEA), hexanediol diacrylate(HDDA), and trimethylolpropane triacrylate(TMPTA), and 1-hydtoxycyclohexyl phenyl ketone(Irgacure 184) as a photoinitiator. The UV-cured films of polyurethane acrylates were obtained by curing using a medium-pressure mercury lamp(U W/cm, $\lambda_{max}=365\;nm)$. In this work, the effects of molecular weights of polyol and diol with low molecular weight into polymer chain on mechanical and dynamic mechanical properties of UV-cured polyurethane acrylates were studied. The structure and properties of the films obtained from the UV photopolymerization of urethane-acrylate prepolymer were investigated by FT-IR spectroscopy, dynamic mechanical measurement, tensile testing, and X-ray diffractometry.

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Unambiguous Fiber Fabry-Perot Temperature Sensor by an Additional Partial Mirror (보조 반사체를 이용한 광섬유 페브리페로 간섭계형 온도센서의 성능향상)

  • Kim, Gwang-Su;Lee, Hong-Sik
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.49 no.7
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    • pp.418-423
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    • 2000
  • The fiber Fabry-Perot interferometric(FFPI) sensor is well known in the field of industrial diagnosis due to its outstanding properties such as tiny size, simple and rugged structure, and easy interrogation. As other fiber interferometric sensors, it also suffers from ambiguous output caused by highly periodic feature in its optical transfer function. In most cases, the ambiguity leads to relatively short dynamic operating range and long processing time during power-on reset, which limits its application to some specific fields requiring very high resolution. In this paper a method based on double sensing scheme was proposed to overcome the above difficulty. By employing a fringe selection auxiliary FFPI sensor the original FFPI sensor can identify its true position on the phase domain. The performance test with 10mm FFPI sensor and a thermocouple temperature sensor for reference shows wide dynamic range 0-900$\ell$ keeping a reasonable resolution of 0.1$\ell$ over the entire range.

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Sorption of Arsenite Using Nanosized Mackinawite (FeS)-Coated Silica Sand (나노 크기 매킨나와이트로 코팅된 규사를 이용한 아비산염의 흡착)

  • Lee, Seungyeol;Kang, Jung Chun;Park, Minji;Yang, Kyounghee;Jeong, Hoon Young
    • Journal of the Mineralogical Society of Korea
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    • v.25 no.4
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    • pp.185-195
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    • 2012
  • Due to the high reduction and sorption capacity as well as the large specific surface area, nanosized mackinawite (FeS) is useful in reductively transforming chlorinated organic pollutants and sequestering toxic metals and metalloids. Due to the dynamic nature in its colloid stability, however, nanosized FeS may be washed out with the groundwater flow or result in aquifer clogging via particle aggregation. Thus, these nanoparticles should be modified such as to be built into permeable reactive barriers. This study employed coating methods in efforts to facilitate the installation of permeable reactive barriers of nanosized mackinawite. In applying the methods, nanosized mackinawite was coated on non-treated silica sand (NTS) and chemically treated silica sand (CTS). For both silica sands, the maximum coating of mackinawite occurred around pH 5.4, the condition of which was governed by (1) the solubility of mackinawite and (2) the surface charge of both silica and mackinawite. Under this pH condition, the maximum coating by NTS and CTS were found to be 0.101 mmol FeS/g and 0.043 mmol FeS/g respectively, with such elevated coatings by NTS likely linked with impurities (e.g., iron oxides) on its surface. Arsenite sorption experiments were performed under anoxic conditions using uncoated silica sands and those coated with mackinawite at the optimal pH to compare their reactivity. At pH 7, the relative sorption efficiency between uncoated NTS and coated NTS changed with the initial concentration of arsenite. At the lower initial concentration, uncoated NTS showed the higher sorption efficiency, whereas at the higher concentration, coated NTS exhibited the higher sorption efficiency. This could be attributed to different sorption mechanisms as a function of arsenite concentration: the surface complexation of arsenite with the iron oxide impurity on silica sand at the low concentration and the precipitation as arsenic sulfides by reaction with mackinawite coating at the high concentration. Compared to coated NTS, coated CTS showed the lower arsenite removal at pH 7 due to its relatively lower mackinawite coating. Taken together, our results indicate that NTS is a more effective material than CTS for the coating of nanosized mackinawite.