• Title/Summary/Keyword: Dyestuffs

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Decolorization in Dyebath by Dye Adsorption of Chitin -Effects on the Adsorption in Direct Dyebath- (키틴의 염료 흡착에 의한 염액의 색도제거에 관한 연구 -직접염료의 염액을 중심으로-)

  • 유혜자;김정희;이혜자;이전숙
    • Textile Coloration and Finishing
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    • v.13 no.1
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    • pp.38-44
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    • 2001
  • The adsorption ability of dyes on chitin, a natural polymer was investigated for decolorization of dye wastewater. Chitin was manufactured in lab by decalcification in dilute aqueous hydrochloric acid solution and deproteination in dilute aqueous sodium hydroxide solution with shrimp shells. Absorbance of residue solution of dyebaths after dye adsorptions of chtin were measured in varieties of dye concentration and dipping periods. Three kinds of Direct dyes -C.I. Direct Red 81 (red 81), C.I. Direct Brown l(brown 1) and C.I. Direct Green 26(green 26) - were used. Red 81 and brown 1 have smaller molecular weight than green 26. The results from experimentals were of]tamed as follows: 1) Adsorption of green 26 was improved in dyebath by addition of salt, but red 81 and brown 1 were not found any improvements. 2) Smaller size of chitin particles could be absorbed much more speedy. In this experiments, the smallest range of chitin particle size was $250\mu{m}$ and less. 3) The most efficient amount of chitin for 20m1 of dyebath was 0.2g, 4) Both of red 81 and brown 1 showed good and speedy adsorption abilities as dyestuffs of over 90 percent in just one minute in dyebath of 0.01% dye concentration. But green 26 was absorbed slowly because of its large molecular weight. It took 40minutes to absorb dyestuffs of over 90 percent in dyebath of 0.01% dye concentration.

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Studies on the Production of Anthraquinone Derivatives by Tissue Culture of Rubia Species

  • Shin, Soon-Hee
    • Archives of Pharmacal Research
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    • v.12 no.2
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    • pp.99-102
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    • 1989
  • The tissue culture of Rubia cordifolia var. pratensis and R. akane were performed to enhance the biosynthesis of anthraquinone pigments under various conditions. The production of alizarin and purpurin in the callus was separately analysed and was quantitatively compared. The pigment biosynthesis was more active in the callus from R. cordifolia var. pratensis than from R. akane. The addition of ${\alpha}-ketoglutaric$ acid, a biosynthetic precursor of anthraquinones, enhanced the production of alizarin and purpurin remarkably.

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An Experimental Study on the Brazil-Wood Dyestuff(I) (소방염에 관한 실험적 연구(I) -매염에 따른 견뇌도와 색상의 변화-)

  • 소황옥
    • Journal of the Korean Home Economics Association
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    • v.25 no.3
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    • pp.1-13
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    • 1987
  • In this study, I have tested the effects of the agents and dyeing conditions on the Brazil-wood dyestuff as one plant dyestuffs. According to the tests, I have fount that color differenciation depending opon the agents and procedual condtitions. As the agents, Alm induced redness and light yellowness by Aluminum Acetate, dark greenness or blueness by Ferrous chloride, dark redness by Stannous Chloride, dark grenness or blueness by Copperous Chloride, light yellowness or greenness by Calcium Dihydroxide. On the other hand, color-fastness differed from various mordant agents. The color-fastnes was solid using multiple agents than sole agent.

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Development of Amphoteric Levelling Agent for the Application of Reactive Dyestuffs Having $\alpha$-Bromoacrylamide Structure to Wool Fibers ($\alpha$-Bromoacrylamide계 반응성 염료용 양성균염제 개발연구)

  • 김갑진;김택현;김대기;오익환
    • Proceedings of the Korean Fiber Society Conference
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    • 2001.10a
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    • pp.41-46
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    • 2001
  • 양모의 염색에서 특히 fiber dyeing, top dyeing, yarn dyeing이 양모 염색에서 큰 비중을 차지하고 있다. 그런데 이와 같이 섬유나 실 형태로 염색되는 경우에는 후속의 여러 습식 공정 중의 염색견뢰도가 매우 중요하기 때문에 $\alpha$-bromo acrylamide를 반응기로 갖는 반응성 염료의 사용량이 급격히 증가하고 있다. (중략)

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Identification of Natural dyes used in 16th pink Dallryeong (Official's robe in Joseon Dynasty) Excavated from Cheonan, Chungnam (충남 천안시 출토 16세기 분홍 단령에 사용된 염재 동정)

  • Chae, Jeongmin;Ryu, Hyo-Seon
    • Journal of Conservation Science
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    • v.31 no.3
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    • pp.299-308
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    • 2015
  • Aim of this study is to identify dyestuff of the Dallryeong(official's robe in Joseon Dynasty, 16th century) excavated from Yuryang-dong, Cheonan, in 1996. For this purpose, extracted dyestuffs from Dallryeong fabric and from natural dyestuffs for red color(safflower, Sapanwood, Madder) which are presumed to have been used in the Dallryeong, are analyzed and compared by high performance liquid chromatography(HPLC). As a result, HPLC chromatogram of extracts of the Dallryeong's dyestuff and safflower are showed a peak at 17.5 minutes. The UV/Vis spectra of the samples are showed the maximum absorption wavelength at 519nm. This result is identical with the analysis of the previous studies on red dyestuff of safflower. In addition, the analysis of Mass Spectrometry(MS) showed the identical result of the peak with m/z 910. Following these results, excavated pink Dallryeong were considered to have been dyed with safflower.

Natural Dyeing of Silk Fabrics with the Extract of Leaves of Rose of Sharon [Hibiscus syriacus L.] (무궁화 잎을 이용한 견직물의 천연염색에 관한 연구)

  • Cho, Im Sun;Lee, Jeong Sook
    • Fashion & Textile Research Journal
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    • v.19 no.4
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    • pp.515-522
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    • 2017
  • The natural dyeing industry has been faced with increasing demands of constant needs for environmentally and body friendly clothing products among modern consumers. Natural dyeing has attracted attention as a next-generation technology in green textiles. Dyestuffs need to be diversified for technological development activation in order to meet the increasing demands for natural dyeing. This study extracted dyeing solutions from the leaves of the Rose of Sharon (the national flower of South Korea) and investigated its dyeing properties for the development of various natural dyestuffs. This study investigates the dyeability of silk fabrics with Rose of Sharon leaves extract. Optimal conditions for dyeing of silk fabrics with the extract of Rose of Sharon were $40^{\circ}C/80min$ and $90^{\circ}C/60min$ with 100% concentration. Looking at the results, it showed the best K/S value at pH3, Sn pre-mordanting and Fe post-mordanting. Color fastness to washing, dry cleaning, rubbing and perspiration was good at grade 4-5 or 4. However, light fastness was observed in grade 2. In aspect of functional property, it showed an excellent result of 90% deodorization rate. In addition, its proven functionalities (deodorant properties) will help to produce high value added environment-friendly products. Those findings demonstrate the possibilities of the Rose of Sharon as an environment-friendly dye.

A Study on the Dye Properties and Functionality of Clove Extract (정향 추출물을 이용한 염색직물의 염색성 및 기능성)

  • Park, Young-Hee
    • The Research Journal of the Costume Culture
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    • v.17 no.2
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    • pp.216-224
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    • 2009
  • This study was accomplished to examine the dyeing property and functionality of both cotton and silk fabrics dyed with clove extract. The purpose of this study was to investigate the effects of dyeing property, antibiosis, and sun protection effectiveness for a clove. The study method used in this study was the experimental research to extract dyestuffs from a clove, to treat dyestuffs with a mordant, and then to measure dyeing colorfastness, antibiosis, and sun protection for dyed fabrics. As a result of the test for dyeing colorfastness, in the case of colorfastness to laundry, the degree of discoloration showed grade $1\sim4$ and the degree of pollution showed grade $4\sim5$. Colorfastness to perspiration for both cotton and silk fabrics dyed showed grade $1\sim2$ to $4\sim5$. Colorfastness to sunlight showed grade 2 to $4\sim5$. Colorfastness to rubbing showed grade $3\sim4$ to $4\sim5$. In the colorfastness to dry cleaning, the degree of discoloration showed grade $3\sim4$ and the degree of pollution showed grade $4\sim5$. As a result of the antibiosis test, for the Staphylococcus aureus, both cotton and silk showed the bacteria reduction rate of 99.9% even after five times laundry, and for the Escherichia coli, cotton fabrics showed the bacteria reduction rate of 99.9% only after one time laundry, but silk fabrics showed the bacteria reduction rate of 99.9% even after five times laundry. As a result of the test for sun protection effectiveness, dyed silk fabrics showed the result more excellent than dyed cotton fabrics.

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Effect of Chitosan and Mordant Treatments on the Air-permeability, Fastness and Antimicrobial Effect of Colon and Nylon Fabrics Dyed using Rhusjara ica (면과 나일론 직물의 오배자 염색 시 Chitosan 처리와 매염이 공기투과도, 견뢰도 및 항균성에 미치는 영향)

  • Bong Shin-Jee;Kim Jong-Jun;Jeon Jee-Bae;Jeon Dong-Won
    • The Research Journal of the Costume Culture
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    • v.13 no.4 s.57
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    • pp.540-549
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    • 2005
  • It was the purpose of this study to investigate the effect of chitosan treatment and mordanting on the air-permeability, fastness of the dyestuff to washing, fastness of the dyestuff to light, and antimicrobial effect of cotton and nylon fabrics dyed using Rhusjara ica. In the dyeing experiment, examinations were made on the difference between the chitosan treated fabrics and chitosan untreated fabrics, and on the difference according to the type of mordanting agents and the mordanting methods. Dyeing was carried out for the chitosan treated and untreated fabrics under the conditions of non-mordanting and Al, Sn, Fe mordanting. As a result, due to the dye-uptake of the dyestuff component of the Rhusjara ica, the air-permeability values decreased considerably. And due to the action of the mordanting agents, the air-permeability decreased also. The air-permeability decreased more conspicuously in the case of the dyestuffs uptake to the chitosan components than in the case of the dyestuffs uptake to the cotton fibers or nylon fibers. Nylon dyed fabric exhibited better wash fastness than the cotton dyed fabric. As the number of washing increased, the color of the cotton fabric specimens and nylon fabric specimens, dyed using Rhusjara ica, shifted toward yellowish. The light fastness values were in the range of grade 1${\~}$2, which were very inferior. The light fastness values did not improve according to the mordanting or to the chitosan treatment. In the case of chitosan untreated fabrics dyed using Rhusjara ica, the growth rate of the bacteria promoted, on the contrary, compared to that of the control white fabric.

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Dyeability and Colorfastness of Knitted Fabrics with Natural Dye PinuxTM (Part I)

  • Wang, Geom-Bong;Song, Kyung-Hun
    • Journal of the Korean Society of Clothing and Textiles
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    • v.35 no.12
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    • pp.1477-1485
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    • 2011
  • Dyeability and colorfastness of the blended knits of cotton/rayon (40/60; C/R) and wool/tencel (10/90; W/T) are examined using the natural dyestuff ($Pinux^{TM}$) manufactured from Pinus radiata pine bark extract. In addition, pre-treatments (such as bleaching, mercerization and cationization) are performed to improve dyeability and colorfastness. The $Pinux^{TM}$ powder dyestuffs produced by Pinux Co., Ltd. are used as dyestuffs and their properties are examined for dyeing concentration (0.5-2% (owb)), dyeing time (30-120 minutes) and dyeing temperature (30-$90^{\circ}C$). Dyeability is evaluated with K/S value at 400nm, which is the maximum absorption wavelength for $Pinux^{TM}$. The results show the dyeability of W/T sample containing protein fiber with $Pinux^{TM}$ is superior to all cellulose fiber C/R. A concentration of dyestuff greater than 1.5% (owb), dyeing time 120 minutes and dyeing temperature of $90^{\circ}C$ are the most optimized conditions. It shows that the dyeability of C/R and W/T samples are high in the condition of an acid-dyeing bath and that dyeability highly declined in alkaline bath due to the instability of the proanthocyanidin pigment. After analyzing the effect of bleaching, mercerizing and cationizing (as pre-treatments on dyeability) it was concluded that the dyeability of the C/R sample was enhanced by mercerization but no significant effect by cationization. However, the simultaneous treatment of cationizing and dyeing resulted in far improved dyeability compared to dyeing after cationizing pre-treatment. As for the W/T sample, the effect of cationization was more prominent than the C/R sample. Colorfastness to color changes in the control W/T sample was higher than that of C/R's level 1-2, and it increased to Level 2 when bleaching pre-treatment was given and when a simultaneous cationizing treatment was adopted to the dyeing process. Colorfastness to light in W/T control sample resulted in Level 3 and further increased to an excellent Level of 4 with bleaching and simultaneous cationizing during dyeing process.