• 한국의류산업학회지
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• 제11권5호
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• pp.827-832
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• 2009

The purpose of this study is to scientifically proof possibility of development of natural dye which has antimicrobial activity with Chelidonium majus var. asiaticum. For that silk fabrics dyed with Chelidonium majus var. asiaticum extracts were tested for anti-microbial activity. Bacterials used for test of anti-microbial activity were Staphylococcus aureus ATCC 6538, Klebsiella pneumoniae ATCC 4352 and Trichophyton mentagrophytes IFO 5466. The results of experiment were as follows ; 1. The more the number of times of dyeing increase the more value of K/S increased. 2. Reduction of bacterium against Staphylococcus aureus ATCC 6538 of silk fabrics dyed with Chelidonium majus var. asiaticum extracts was 99.9% without reference to the number of times of dyeing. 3. Reduction of bacterium against Staphylococcus aureus ATCC 6538 of silk fabrics dyed with Chelidonium majus var. asiaticum extracts was 99.9% after irradiation of 20 hour without reference to the number of times of dyeing. 4. Reduction of bacterium against Staphylococcus aureus ATCC 6538 of silk fabrics dyed with Chelidonium majus var. asiaticum extracts was over 94.8% after dry cleaning. As above silk fabrics dyed with Chelidonium majus var. asiaticum extracts were acquired a high anti-microbial activity against Staphylococcus aureus ATCC 6538.

• 한국의류산업학회지
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• 제4권1호
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• pp.79-85
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• 2002

To develope natural dyeing materials from the unused plant materials, we had several dyeing experiments to investigate the optimum conditions of dyeing fabrics with the waste grape juice. Dyeing experiments were done under different dyeing conditions of dyeing time, dyeing temperature, pH and concentration of dyebath and mordants which were treated after dyeing. Experimental fabrics were silk, cotton, ramie and hemp. Color difference(${\Delta}E$) and Munsell's HV/C of the dyed fabrics and color fastness of silk dyed fabrics to dry cleaning, washing, rubbing, perspiration and light were measured. The color differences of dyed experimental fabrics were very slightly increased with dyeing time and the color of dyed silk was light purple and the cotton, ramie and hemp was light red purple. The color differences of dyed experimental fabrics were decreased and the color became lighter with dyeing temperature increased. The color differences of dyed experimental fabrics were decreased and the color changed from light purple to blue with the pH of dyebath increased. The color differences of dyed experimental fabrics were slightly increased with the concentration of dyebath increased. The color of dyed fabric changed with the mordant treatment and were different among the experimental fabrics. On the whole, blue tone increased with the Al and Fe mordant and green tone increased with the Cu mordant. The color fastness of dyed silk fabrics to light, washing (change) and perspiration (change) was bad and color fastness to dry cleaning and rubbing were good.

• 한국잠사곤충학회지
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• 제47권2호
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• pp.78-87
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• 2005

본 연구는 우리 야생화중 비교적 대량번식이 가능한 종인 물레나물의 줄기, 꽃, 잎을 채취하여 염액을 추출하고, 다양한 염색 조건에서 견과 면 소재를 염색하여 염색거동을 살펴보고 염색된 색상에 대하여 고찰하여 다음과 같은 결과를 얻었다. 1. pH에 따른 염색에서 견이 면보다 진하게 염색되었고 pH가 중성일때 물레나물은 견 일때 가장 진하게 염색되었다. 2. 염색온도에 따른 염착량은 견과 면 구분 없이 큰 차이가 없었으나 물레나물의 경우 온도가 높아질수록 견이 면보다 약간 진하게 염색되었다. 3. 염색시간이 1시간에서 2시간 사이에서 급격한 Y값의 감소를 보여 이 시간대에서 많은 염착이 이루어 졌다. 4. 면은 염 첨가 농도로 높을수록 Y값이 낮아져 염이 촉염효과 역할을 하는 것으로 보여 졌으나 견의 경우 염 첨가에 따른 Y의 값은 끈 변화가 없는 것으로 나타났다. 5. 물레나물의 염액 농도에 따른 염색성은 견, 면 모두 농도가 작아지면 염착량이 작아졌다. 6. 견의 경우 매염제의 대한 매염효과가 높게 나타나고 있으나 농도는 큰 영향을 미치지 않았다. 면에서 물레나물은 매염효과가 전혀 없는 것으로 나타났다.

• 한국염색가공학회지
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• 제21권3호
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• pp.10-18
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• 2009

Dyeing process of the natural indigo powder onto ramie and silk fabrics was investigated by using glucose and calcium hydroxide as a reducing system. Effect of reduction and dyeing conditions such as temperature and time of reduction/dyeing, and concentrations of glucose and calcium hydroxide on the dyeing process were explored. Indigo powder was obtained by drying the conventional niram paste in an oven at $50^{\circ}C$. Color strength of the dyed fabrics was evaluated by K/S value measured at the wavelength of maximum absorption(${\lamda}$max). Munsell color coordinates(H V/C) were used to compare fabric colors of ramie and silk. Ramie fabric showed purple-blue color for all the temperature and time. On the contrary, silk fabric showed wide range of color including brown, brown-green, green at the different temperature. With the increase of K/S value, the coordinate of value(lightness) decreased for both of ramie and silk fabrics. The coordinate of hue(shade) changed drastically with the increase of K/S value for silk fabric, compared with that of ramie fabric which showed nearly constant value at the whole range of K/S value. Optimum concentrations of calcium hydroxide were for 6 g/L for ramie and 4 g/L for silk at $60^{\circ}C$ and 50 min. K/S value increased with the indigo concentration. Maximum K/S value was shown at $10{\sim}12$ g/L of glucose concentration. For both of ramie and silk fabrics, the colorfastness of washing and light was lower than that of rubbing. All the colorfastness values were improved with the increase of color strength.

• 한국염색가공학회지
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• 제29권3호
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• pp.171-179
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• 2017

This study was to investigate the practicality and functionality of water lily(Nymphaea tetragona) leaves as a natural dye resource while searching for various dyeing methods to utilize them. Effect of dyeing condition including methanol ratio of dyebath, dyeing temperature and time, mordanting method, etc were investigated. Colorants were prepared by extraction in methanol and followed drying process. When composing 30% of methanol in the dyebath, better dyeuptake and uniform dyeing were resulted. Pre-mordanting method gave better results in terms of dye uptake than post-mordanting method on the wool fabrics. Fe and Ti were effective for increasing the dye uptake on the silk fabrics. Depending on mordant type and mordanting method, the dyed fabrics got various color showing green, khaki, brownish yellow, dark brown, dark gray and so on. As for color fastness, the silk fabrics dyed with water lily extract showed relatively high rating in light fastness(3~4, 4~5 rating), washing fastness(4~5, 5 rating), and rubbing fastness(4, 4~5 rating). The silk and wool fabrics dyed with water lily leaves extract showed excellent antimicrobial activity over 98% of bacterial reduction rate against Staphylococcus aureus and Klebsiella pneumoniae. It was confirmed that water lily leaves can be used as a natural dye resource for dyeing wool and silk fabrics because its colorants showed excellent affinity and antimicrobial functionality as well as good colorfastness.

• 한국염색가공학회지
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• 제14권2호
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• pp.85-85
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• 2002

The interaction between berberine and tannin in aqueous solution was investigated spectrophotometerically. The dyeing mechanism of silk fabrics (control and tannin treated silk fabrics) with berberine was based on thermodynamic parameters obtained from equilibrium adsorption experiments. In adsorption spectra of aqueous solution of berberine and tannin mixture two isosbestic points (328nm, 357nm) were found and the mole fraction of reaction of components was 1:1. Initial dyeing rates were increased and the diffusion of dye was more effective by tannin treatment. Without regard to tannin treatment the adsorption isotherm of berberine was the langmuir type except high temperature, 80℃. By tannin treatment the saturation dye uptake was increased, the increase of dye uptake appeared to be a result of entropy change rather than enthalpy change. All these results can be interpreted by the hydrophobic interaction between berberine and silk treated with tannin and it is reasonable to conclude that not only the ionic force, but also the hydrophobic interaction contributes to the binding of berberine and tannin treated silk treated with tannin.

• 한국염색가공학회지
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• 제14권2호
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• pp.9-17
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• 2002

The interaction between berberine and tannin in aqueous solution was investigated spectrophotometerically. The dyeing mechanism of silk fabrics (control and tannin treated silk fabrics) with berberine was based on thermodynamic parameters obtained from equilibrium adsorption experiments. In adsorption spectra of aqueous solution of berberine and tannin mixture two isosbestic points (328nm, 357nm) were found and the mole fraction of reaction of components was 1:1. Initial dyeing rates were increased and the diffusion of dye was more effective by tannin treatment. Without regard to tannin treatment the adsorption isotherm of berberine was the langmuir type except high temperature, $80^\circ{C}$. By tannin treatment the saturation dye uptake was increased, the increase of dye uptake appeared to be a result of entropy change rather than enthalpy change. All these results can be interpreted by the hydrophobic interaction between berberine and silk treated with tannin and it is reasonable to conclude that not only the ionic force, but also the hydrophobic interaction contributes to the binding of berberine and tannin treated silk treated with tannin.

• 한국염색가공학회지
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• 제12권2호
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• pp.129-137
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• 2000

Silk fabrics were dyed by Cochineal extracts after mordanted with various mordants and their properties of dyeing, fastness and change of surface color were investigated. Silk fabrics were mordanted with aluminum potassium sulfate, copper acetate, tin chloride, iron sulfate or chromium potassium sulfate at $60^\circ{C}$ for 30 minutes and subsequently dyed at $60^\circ{C}$ for 60 minutes unless mentioned otherwise. The dye-uptake of silk fabrics increased with the concentration of Cochineal extracts and mordants used. Maximum dye-uptake was obtained at pH 3.5-4, regardless of the type of mordants used. Surface color of silk fabrics changed from red purple to purple when mordanted with Al or Cu mordant, from purple to purple blue with Fe mordant and showed red purple with Sn or Cr mordant, respectively. It also changed according to pH of dyeing bath. Dyed silk fabrics showed poor light fastness but good dry-cleaning, perspiration and rubbing fastness.

• 한국염색가공학회:학술대회논문집
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• 한국염색가공학회 2004년도 춘계학술발표회 논문집
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• pp.296-301
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• 2004

We focused our research interests on the characteristic of silk fabrics dyed with green tea extracts and, moreover, revealed the catechin content of silk fabrics after dyeing with Korean tea extract by measuring the residues. Three kinds of green tea samples were taken between April and May, 2003, from Bosung(southern province in South Korea), in different terms as the first corp, the second corp, and the third corp. Before and after dyeing the silk fabrics with these extracts, catechins in the residue were analyzed by HPLC. Four kinds of Catechins, such as (-)-epicatechin(EC), (-)-epicatechin gallate(ECG), (-)-epigallocatechin (EgC), (-)-epigallocatechin gallate(EgCG) were isolated from Korean green tea extracts. Catechine contents in Korean green tea leaves depend on the making process such as heating and steaming, and the younger the richer. The absorbed catechins in sillk fabrics after dyeing followed in a decreasing order of EgCG>EgC>ECG>EC. We have found a 68% uptake of EgCG, and 116.8mg/g of EgCG in the silk fabrics after dyeing with 1% Korean green tea extracts.

• 한국염색가공학회지
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• 제25권3호
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• pp.194-205
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• 2013

In this study, we report dyeing properties and functionality of cotton and silk fabrics dyed with methanol extract from Juniperus chinensis heartwood. Non-aqueous dye of Juniperus chinensis heartwood extracted with methanol was expressed reddish color. It showed relatively good affinity to silk than cotton. Dye uptake of cotton and silk continued to increase according to the increase of the dye concentration. Cotton was not affected by the dyeing temperature and time, however, dye uptake of silk was increased as the dyeing time and temperature were increased. Dye uptake of cotton and silk were the highest at pH 8 and pH 6 respectively. Dyed fabrics showed various colors depending on mordant types and mordant concentration. Washing, light and perspiration fastness were not good. However, rubbing and dry cleaning fastness showed relatively good grade. Dyed fabrics of ultraviolet-cut ability and deodorant ability were improved. Also, dyed fabrics showed very good antimicrobial abilities of 99.9%.