• Title/Summary/Keyword: Dyeing, Fastness

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Effect of Cyanoethylation Pretreatment on the Sublimation Transfer Printing of Cotton Fabric (시아노에틸화 전처리가 면직물의 승화전사날염 공정에 미치는 영향)

  • Bae, Do Gyu
    • Textile Coloration and Finishing
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    • v.32 no.3
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    • pp.135-141
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    • 2020
  • The primary and secondary alcohols in cellulose reacted with acrylonitrile(AN) in the presence of strong alkalis to form cyanoethylated cellulose. The partially cyanoethylated cotton(CEC) fabric with AN in the presence of aqueous sodium hydroxide solution was described, including effects of treatment time and reagent concentrations. The weight increases of cotton fabric were shown to be linearly related to the treatment time, temperature and concentration of sodium hydroxide. The physical properties such as shrinkage ratio and tensile strength were proportional to the weight increases without significant impact on elongation. But the moisture regain decreased with decreasing hydrophilicity. The degree of substitution(DS) and transfer ratio were linearly related to the weight increases. In the CEC with increasing weight up to 24.9%, it has been obtained with DS up to 0.63-0.67 cyanoethyl groups per anhydroglucose and transferring ratio up to 87.7%. The color fastness to washing by sublimation transfer printing was improved by the cyanoethylation.

Relation between Chemical Structure of Yellow Disperse Dyes and Their Lightfastness

  • Kim, Sung-Dong;Park, Eun-Jin
    • Fibers and Polymers
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    • v.2 no.3
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    • pp.159-163
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    • 2001
  • Five yellow disperse dyes were synthesized and their dyeing, fastness and photodegradation behaviors were investigated. It was found that dyes derived from phenylindole and N-alkylaminobenzene showed dye uptake directly proportional to the dye concentration, but the build-up of dyes derived from carbazole and pyridone were not good. The wavelength at maximum absorption. molar extinction coefficient. and the tendency to the photodegradation were strongly dependent on the electron donating ability of the coupling component. The dye, whose coupling component was phenylindole, possessed the excellent dyeing properties and the high degree of lightfastness. UVA had an effect on the inhibition of the photodegradation especially for the easily photodegradabte dyes.

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Natural Dyeing using the Colorants extracted from American Fleabane (I) -Dyeing properties on wool- (개망초 추출물을 이용한 천연염색(I) -모섬유에 대한 염색성-)

  • Shin, Youn-Sook;Arang Cho
    • Journal of the Korean Society of Clothing and Textiles
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    • v.27 no.12
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    • pp.1434-1440
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    • 2003
  • 개망초로부터 색소를 추출, 분말화하여 FT-IR 분석을 행하고, 모섬유에 대한 염색조건과 매염이 염착량(K/S값) 및 색상에 미치는 영향을 조사하였다. 또한 염색한 시료의 견뢰도를 측정하여 실용성을 확인하였다. 개망초 색소는 모섬유에 높은 친화력을 보였으며, Langmuir형의 등온흡착곡선을 보여 염착이 주로 이온결합에 의해 이루어지는 것으로 나타났다. 염착략이 pH 3.0에서 최대가 되었으나 강한 산성조건은 강도 저하를 비롯한 섬유에 손상을 주기 때문에 pH를 조절하지 않고 염색하였다. 피염물의 색상은 모두 Y 계열을 나타내었다. 철매염 처리한 경우를 제외하고 매염처리가 염착량 증진에 미치는 영향은 그다지 크지 않았으며, 매염제 종류를 달리하여 염색한 모섬유의 색상은 크롬과 주석으로 매염한 경우 YR 계열을 나타내고 그 밖의 매염제에 의해서는 Y 계열의 색상을 나타내어 큰 변화는 없었다. 매염처리하지 않은 시료의 견뢰도는 매우 양호하였으며 매염처리가 견뢰도 증진에 미치는 영향은 크지 않았다.

Dyeing properties of PET-PU according to molecular structure of disperse dye (분산염료 분자구조에 따른 PET-PU blend의 염색성)

  • Park, Jong-Ho;Lee, Jong-Ryeol;Choe, Yeon-Ji;Lee, Ju-Eun;Kim, Seong-Dong
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2008.04a
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    • pp.80-82
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    • 2008
  • The distributions of 3 disperse dyes with different molecular structures among polyurethane (PU) and polyester (PET) in dyeing PET-PU blend and which dye structure contaminated less PU portion were studied. The amounts of dyes left substrates after reduction clearing and washing were measured to prove which dye structure had an effect on improving washing fastness. Disperse dye with high molecular weight showed similar distribution onto PU and polyester by dying both substrates with similar rate and less contamination to polyurethane while other dyes distributed to PU faster than to PET had.

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Dye Extraction and Silk Dyeing of Rubia Cordifolia Using Solvents (용제를 사용한 Rubia cordifolia의 색소 추출 및 Silk 염색)

  • Lim, Jee Young;Jang, Jeong Dae
    • Journal of the Korean Society of Clothing and Textiles
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    • v.37 no.4
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    • pp.506-513
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    • 2013
  • Rubia cordifolia L (Indian madder) contains red color purpurin (65-67%) and yellow color munjistin (10-12%) as well as nordamncanthal (9-10%). Purpurin is a traditional red dye. The purpose of this research is to increase the dyeability of silk and light fastness of dyed silk fabric. We dyed silk fabrics after pretreatment to remove the yellow component of madder using various solvents such as ethyl acetate, ethanol, methanol, chloroform, and acetone. The total K/S value was the highest in the case of chloroform and reflectance was the lowest at the red color region from 470nm to 530nm. Chloroform dissolved the yellow color of Rubia cordifolia; in addition, we found that the total K/S value increased and the ${\Delta}E$ value decreased by chloroform pretreatment for silk dyeing.

Studies on the Printing of Silk Fabric II. Vinylsulfone Reactive Dye (견직물의 날염에 관한 연구 II. Vinylsulfone계 반응성염료)

  • 탁태문;김순심
    • Journal of Sericultural and Entomological Science
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    • v.27 no.1
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    • pp.42-46
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    • 1985
  • Silk fabric was printed with the reactive dye (vinylsulfone type) to investigate the change of adsorption and fixation by steaming time, viscosity of dyeing paste and alkali concentration. It was found that the amount of adsorption and fixation against silk increased with the increase of steaming time, and showed the maximum value at 340cp of dyeing paste. The amount of adsorption and fixation was influenced by alkali concentration. Light, washing, and perspiration fastness were very excellent.

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A Study on the Chrome Mordant with Dyed Silk Fabric (염색견직물의 크롬매염에 관한 연구)

  • 정인모;장병호
    • Journal of Sericultural and Entomological Science
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    • v.26 no.2
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    • pp.26-31
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    • 1984
  • In general, acid dyes been used for silk dyeing, but acid dyed silk shows weakness in color fastess, To improve this defect, the silk dyed with Acid Mordant Blue 13 was treated with chromes salts solution. Some mechanical properties and dyeing behaviors of the chrome mordant with dyed silk fabric were tested in this work. The tensile strength of silk fabric treated with chrome salts solution was decreased as the duration of treatment was increased. The mean rate constant (K) of photo-degradation was 1.019, and 1.047 after treated with Cr (III) and Cr (Ⅵ), respectively, whereas it was 1.304 in untreatment. The washing fastness of silk fabric also was improved by treatment with mordant and it was 3rd-4th grade and 4th grade when silk was treated with Cr (III) and Cr (Ⅵ), respectively, while untreatment gave 1st grade. The colour of dyed silk fabric was 2.5RP.3/10, but it was 5PB.4/3 and 5PB. 4/4 when the silk fabric was treated with Cr (III) for two hours and with Cr (Ⅵ) for one hour at 90$^{\circ}C$, respectively.

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A Study on the Degumming and Dyeing of Silk Fabric in One Bath under the High Temperature and High Pressure (견직물의 고온고압일욕 정련염색에 관한 연구)

  • Ahn Kyoung-Jo
    • Journal of the Korean Society of Clothing and Textiles
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    • v.12 no.2 s.27
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    • pp.133-144
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    • 1988
  • Silk fabrics were degummed and dyed in one bath under the condition of high temperature and high pressure and the results obtained were summerized as follows. 1. The degumming ratio is nearly the same as that of two bath method under the normal condition and the optimal condition is for 30 minutes at $120^{\circ}C$. 2. The dyeing absorption ratio is a little lower than that of two bath method. 3. The tensile strength and elongation are hardly shown the difference between two methods. 4. The fastness of the dyed fabric of one bath method is a little better than that of two bath method. (light, washing, rubbing) 5. The stiffness of the silk fabric treated by one bath method is a little harshier compare to that of two bath method.

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Synthesis of Antibiotic Red Reactive Dye and Its Dyeing Property (적색 항균성 반응염료의 합성과 염색특성)

  • 김이진;김삼수;김준호
    • Textile Coloration and Finishing
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    • v.16 no.2
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    • pp.15-24
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    • 2004
  • The antibiotic reactive dye was synthesized by coupling of reactive chromagen with diazotised silver sulfadiazine for an antibiotic property. The highly reactive MCT(monochlorotriazine) and DCT (dichlorotriazine) type functional groups which have heterocyclic ring and moderately reactive VS-type dye that has good dyeability were used for reactivity. The synthesized antibiotic reactive dye is expected to impart the antibiotic function with high durability on cotton fabric only by one-step dyeing process without further finishing treatment. The synthesis of antibiotic dye was easily proceeded thorough diazotisation of silver sulfadiazine and coupling with suitable chromogen. The dyeability of synthesized dye for cotton fabrics was excellent and the dyed fabrics showed good level of lightfastness, resistance to washing and rubbing. The antibiotic tests revealed that the dyed cotton fabrics with the synthesized dye had very good antibiotic properties.

Fabric dyeing with Laminaria japonica as a marine resources (해양자원을 활용한 직물염색-다시마-)

  • Kim, Sangyool;Jeon, Soonduk
    • The Research Journal of the Costume Culture
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    • v.22 no.6
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    • pp.890-898
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    • 2014
  • This study focuses on the effects of dyeing conditions and mordanting conditions, changes of colorfastness, antibacterial properties and UV protective of silk fabric dyed with Laminaria japonica extracts. A natural colorant was extracted from Laminaria japonica using distilled water as extractants. According to the results, maximum dye uptake (K/S) were obtained at 100% V/V colorant concentration, $80^{\circ}C$, 60 min and pH 2. Silk fabric was dyed with Laminaria japonica extract at $80^{\circ}C$ for 60 min with pre-treatment or post-treatment of various metal salts as mordants. The Laminaria japonica extracts produced yellow hue on silk fabric in pre-mordanting and manifested green yellow hue mordanted with $CuSO_4$ in post-mordanting method. Mordant $CuSO_4$ for silk fabric was found to give good light fastness (rating 4). UV protection property did not increase significantly upon mordanting.