• Title/Summary/Keyword: Dye analysis

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Cochineal Printing Using Pretreated Fabrics with Chitosan (키토산이 전처리된 직물을 이용한 코치닐 날염)

  • Kim, Kyung-Sun;Jeon, Dong-Won
    • Journal of the Korean Society of Clothing and Textiles
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    • v.33 no.10
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    • pp.1644-1654
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    • 2009
  • The concentration of dye uptake and the fastness improved when cotton and silk fabrics were treated with chitosan, a natural polymer. In this study, the effect of chitosan treatment was reviewed after the printing of cotton and silk fabrics padded with chitosan. When the change of physical and mechanical properties of printed fabrics was reviewed (as the concentration of chitosan increased) the thickness and weight increased a little, and the air permeability increased significantly than those untreated with chitosan. The dye uptake increased, accompanying a darker color shade, and the wash fastness increased 1/2-1 grade. The analysis results of enlarged images of printed patterns indicated that the width and area deformations were minimal as the concentration of chitosan increased when compared to untreated fabrics. Therefore, the dyeability and pattern quality were excellent after printing the chitosan-treated cotton and silk fabrics with cochineal dyestuff.

Technology Trends Related with the Natural Dyeing by Patent Analysis (특허분석을 통한 천연염색기술의 현황)

  • Kim, Ho-Jung
    • Fashion & Textile Research Journal
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    • v.11 no.6
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    • pp.942-946
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    • 2009
  • The trends of patents related to natural dyeing were examined in order to guide the development of natural dyeing into a high value-added technology. Total 181 patents data provided from KISTI were analyzed and following results were drawn. Korea had the overwhelming number of patents related to natural dyeing over Japan or United States of America from 1970 to 2007. In case of domestic, the number of patent applications were heavily focused on the metropolitan area in 1990's, but started to increase in the Honam region and Youngnam region in the first half of the year 2000 which indicated that the researches and the developments of natural dyeing were very active. In the case of foreign countries, most of their patent applications comes from the corporation such as a company while the number of patents applications from individuals overwhelms that of corporation in South Korea. Also, more of individuals' patent applications were denied than corporations' patents applications. The vegetable dye, a type of dyestuff which is a research subject for patent application, had the most research done above all other dyestuff.

Calculation and Analysis of Hydrophobicity of the Dyes Synthesized for Unmodified Polypropylene Fibers Using Molecular Descriptors

  • Kim, Tae-Kyeong;Jang, Kyung-Jin;Jeon, Seon-Hee
    • Textile Coloration and Finishing
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    • v.21 no.5
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    • pp.21-26
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    • 2009
  • In order to analyze numerically the hydrophobicity of the new dyes synthesized for unmodified pure polypropylene fibers, the octanol-water partition coefficient (logP), which is one of molecular descriptors representing hydrophobicity of organic compounds, was obtained by a semi-empirical method using Chem3D software. For the dyes of higher logP than around 5, the affinity of the dyes towards unmodified polypropylene fiber was substantial. In contrast to the new dyes for polypropylene, conventional disperse dyes have logP values lower than 5 and exhibited poor affinity.

Nanostructured Photoelectrode Materials for Improving Light-Harvesting Properties in DSSCs

  • Jeong, Hyeon-Seok
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.7.2-7.2
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    • 2011
  • Photoelectrochemical solar cells such as dye-sensitized cells (DSSCs), which exhibit high performance and are cost-effective, provide an alternative to conventional p-n junction photovoltaic devices. However, the efficiency of such cells plateaus at 11~12%, in contrast to their theoretical value of 33%. The majority of research has focused on improving energy conversion efficiency of DSSC by controlling nanostructure and exploiting new materials in photoelectrode consisting of semiconducting oxide nanoparticles and a transparent conducting oxide electrode (TCO). In this presentation, we introduce monodisperesed TiO2 nanoparticles prepared by forced hydrolysis method and their superiority as photoelectrode materials was characterized with aids of optical and electrochemical analysis. Inverse opal-based scattering layers containing highly crystalline anatase nanoparticles are also introduced and their feasibility for use as bi-functional light scattering layer is discussed in terms of optical reflectance and charge generation properties as a function of optical wavelength.

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Photocatalytic Performance of CoS2-Graphene-TiO2 Ternary Composites for Reactive Black B (RBB) Degradation

  • Ali, Asghar;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.54 no.4
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    • pp.308-313
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    • 2017
  • In this study we examined the photo-degradation efficiency of $CoS_2-G-TiO_2$ nanocomposites under visible light irritation using Reactive Black B (RBB) as standard dye, $CoS_2-G-TiO_2$ nanocomposites synthesized by facial microwave assist technique, and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and Raman spectroscopic analysis. Our results show the efficiency of the $CoS_2-G-TiO_2$ ternary nanocomposite is better than $CoS_2-G$ and $TiO_2-G$ nanocomposite. The degradation efficiency of $CoS_2-G-TiO_2$ nanocomposite was found approximately 89% of Reactive Black B (RBB) degraded after 180 min. Our results will open new way for the development of a new ternary nanocomposite photocatalytic application.

Characteristics of Meroeyanine Dye LB Films Using Electron Spin Resonance Spectroscopy (전자 스핀 공명을 이용한 메로시아닌 색소 LB막의 특성)

  • Shin, Hoon-Kyu;Kwon, Young-Soo
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1569-1571
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    • 1996
  • The role of ESR spectroscopy in the characterization of functional LB films is discussed. Optical absorption were performed on LB films of binary mixtures of three kinds of merocyanine dyes where DS and 6Me-DS form J-like aggregates but not DO in single component films. The observed optical absorption spectra of mixed films were markedly dependant on the combination of dyes. We found the formation of J-aggregates in a mixed merocyanine dyes containing a non J-aggregate forming dye DO, in a single component case. In structural studios, ESR is of particular important in the analysis of molecular orientation of LB films. Development of new functional LB films may provide more cases where ESR spectroscopy will clarify the nature of such films.

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Low Temperature Synthesis of TiO2 Films for Application to Dye-sensitized Solar Cells

  • Wi, Jin-Seong;Choe, Eun-Chang;Seo, Yeong-Ho;Hong, Byeong-Yu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.475-475
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    • 2014
  • Dye sensitized solar cells (DSSCs) are regarded as potential inexpensive alternatives to conventional solid-state devices. The flexible version, employing conductive-plastic-film substrates, is appealing for commercialization of DSSCs because it not only reduces the weight and cost of the device but also extends their applications. However, the need for high temperature does not permit the use of plastic-film substrate. So, development of low-temperature methods is therefore realization of flexible DSSCs. In this work, the electrophoretic deposition combined with hydrothermal treatment was employed to prepare nanocrystalline $TiO_2$ thin film at low temperature. We confirmed the prepared $TiO_2$ thin films with different voltages and deposition times in the electrophoretic deposition process. Properties of the $TiO_2$ films were investigated by various analysis method such as X-ray diffraction, field emission scanning electron microscopy (FESEM) and UV-visible spectrophotometer.

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Natural dyeing with walnut hull(Ⅰ) - Dyeing properties of wool fabric - (호도외피를 이용한 천연염색(Ⅰ) - 양모의 염색성 -)

  • Sin, Yun Suk;Mun, Seong In
    • Textile Coloration and Finishing
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    • v.14 no.2
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    • pp.102-102
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    • 2002
  • The purpose of this study is to investigate dyeing properties of wool fabric with walnut colorants. Walnut colorants were extracted with water from walnut hull and characterized by FT-IR analysis. Effects of dyeing conditions and mordanting on dyeing properties and colorfastness were studied. Results obtained were as follows, 1. Higher K/S value was obtained at higher temperature and longer dyeing time, the highest K/S value was shown at 100℃, 60min. 2. Dye uptake was increased with the increase in colorants concentration up to 2%. Higher K/S value was obtained at acidic condition. 3. Mordanting was not effective for improving dye uptake and colorfastness and for changing color of the dyed fabric.

Natural dyeing with walnut hull( I ) - Dyeing properties of wool fabric - (호도외피를 이용한 천연염색( I ) - 양모의 염색성 -)

  • 신윤숙;문성인
    • Textile Coloration and Finishing
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    • v.14 no.2
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    • pp.26-32
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    • 2002
  • The purpose of this study is to investigate dyeing properties of wool fabric with walnut colorants. Walnut colorants were extracted with water from walnut hull and characterized by FT-IR analysis. Effects of dyeing conditions and mordanting on dyeing properties and colorfastness were studied. Results obtained were as follows, 1. Higher K/S value was obtained at higher temperature and longer dyeing time, the highest K/S value was shown at $100^\circ{C}$, 60min. 2. Dye uptake was increased with the increase in colorants concentration up to 2%. Higher K/S value was obtained at acidic condition. 3. Mordanting was not effective for improving dye uptake and colorfastness and for changing color of the dyed fabric.

Structural Analysis for the Single Crystal of 2-(4-(9H-carbazol-9-yl)benzylidene) based Dye Compound

  • Hwang, Jiyong;Son, Young-A
    • Textile Coloration and Finishing
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    • v.26 no.2
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    • pp.143-149
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    • 2014
  • The designed dye material, namely 2-(4-(9H-carbazol-9-yl)benzylidene) compound, was synthesized. After the reaction, the solid was filtered and purified by recrystalization with acetone/water. To confirm and analyze its synthesis and structural formation, the single crystal was prepared and its measurement was carried out. A yellow needle crystal of $C_{22}H_{13}N_3$ were made on a Rigaku R-AXIS RAPID diffractometer using graphite monochromated CuK${\alpha}$ radiation. All details were suggested and introduced to support and communicate this study.