• 한국전기전자재료학회논문지
• /
• 제28권5호
• /
• pp.314-319
• /
• 2015

In this research, we focused on the development of cy3 dye with high thermal stability and good solubility for LCD color filter. Cy3 dyes were prepared through the synthetic procedure of two steps. The synthesized cy3 dyes were characterized by using NMR, FT-IR, UV/Vis spectroscopy, and TGA. These cy3 dyes showed maximum absorption wave length (${\lambda}_{max}$) in the range of 549~555 nm in UV/Vis spectrum. And we confirmed that solubility characteristics and thermal stability of cy3 dyes were dependent on the structure of counter cation. Cy3 dyes with methyl counter cation and ethyl counter cation have good solubility in organic solvents such as chloroform, ethanol, and PGME. Moreover, Cy3 dye with ethyl counter cation gave excellent thermal stability in TGA thermograms. And Cy3 dye with ethyl counter cation showed good result in photoresist film test.

• 복식문화연구
• /
• 제19권2호
• /
• pp.324-333
• /
• 2011

This study was accomplished for the purpose of developing a textile processing ingredient that is harmless to the human body and environment. The research method consists of dyeing cotton textiles by extracting the dye solution from ginseng. Then, chrominance, after treatment, antibacterial ratio and deodorization ratio of cotton fabrics dyed with ginseng extracts were tested and results were examined. The research procedure involved first extracting the dye solution from the ginseng's by-product (fine roots) and then dyeing was effectuated differently according to the test samples temperature and dyeing time requirements. Brightness in all dye substances was lower in pre-mordanting. Beige color could be extracted from pre-mordanted samples. And dark orange from postmordanted samples. Color-festness was high in all samples. Most of samples show a big antibacterial ratio and deodorization ratio. Through this research it has been discovered that, when applied to textiles, Korea's ginseng extract possessed reproducibility features as a natural dye and a possibility to be used in cutting which plays a crucial role in hygienic processing. In addition, by using ginseng's by-product for dyeing processing as the dye solution, efficient application of resources and occurrences of no water waste damages were demonstrated and thus, proved to be environmentally-friendly. Specifically, through this experiment, it was found that saponin, ginseng's special characteristics, possessed excellent antibacterial odor repelling functions to clothing as well as the capability to prevent skin disease.

• 한국의류학회지
• /
• 제24권1호
• /
• pp.87-95
• /
• 2000

The changes on shrinkage, dyeability, antimicrobial activities and other physical properties of wool fabrics by chitosan treatment were investigated. A acid dye, a basic dye and natural artemisia were used for dyeing of wool fabrics. For Antimicrobial test of wool fabrics, S.Aureus was used. As the results, The wool fabrics treated with chitosan showed a marked decrease in shrinkage. Dyeability increased slightly as concentration of chitosan treatment increased, Dyeability of acid dye was the highest than other dyes. On the other hand, the dyeability of basic dye on chitosan treated fabrics was lower than untreated fabrics. Reduction rates of colony of chitosan-treated wool fabrics showed from 64.8% to 85.24% as chitosan concentration increased. Reduction rates of colony of the chitosan-treated fabrics decreased by dyeing with acid and basic dye. But increased by retreating with chitosan. Fabrics dyeing with atremisia showed above 90% reduction rate against S.Aureus on all chitosan concentrations. The Tensile properties of chitosan-treated fabrics showed little decrease. The moisture regain and the air permeability was decreased on chitosan concentration on 0.1% but recovered as chitosan concentration increased. The warmth retention was increased a little by chitosan treatment. The drapeability became hard as chitosan concentration increased.

• 상하수도학회지
• /
• 제23권4호
• /
• pp.431-438
• /
• 2009

The purpose of this study was to evaluate the performances of zero-valent iron (ZVI) combined SBR (Z-SBR) process in decolorization and organic removal of synthetic dye wastewater. The batch test for optimizing the operation parameters of ZVI column showed that the appropriate EBCT was around 11 min and the pH of the dye wastewater was below 7.0. During the step increase of influent color unit from 300 to 1,000cu, about 53 to 79% decolorization efficiency could be achieved in control SBR (C-SBR, without ZVI column), which resulted from destroying azo bond of synthetic dye in anaerobic condition. For the same influent color loading, Z-SBR showed always higher decolorization efficiency than C-SBR with an aid of ZVI reducing power. The TCOD concentration in Z-SBR effluent was 20-30mg/L lower than C-SBR effluent although the TCOD before and after ZVI column was nearly same. It means that breakdown of azo bond by ZVI reducing power could increase biodegradability of synthetic dye wastewater.

• 한국의류학회지
• /
• 제41권2호
• /
• pp.212-223
• /
• 2017

This research investigated the screen printing method for natural indigo dye on cotton fabric. We examined four types of thickening agents (arabic gum, guar gum, indalca, and CMC) based on their ability to retard the oxidation of natural indigo print paste while the paste remained on the screen frame. The results indicated that the retardation of arabic gum towards oxidation was the greatest among the four types of thickening agents. The highest K/S value of the printed cotton was observed with a dye concentration of 50g/L fermented indigo powder. The best printing results were obtained when the duration of dye efficiency was tested for the 10 minutes of the dye paste remaining on the screen with a thickening agent concentration of 26.56% that represented 530 cps viscosity. The test of colorfastness to washing and rubbing of the printed cotton resulted in grade 5, and the colorfastness to sunlight resulted in grade 4. Chinese traditional Naminwhapo printing was reproduced on cotton fabric using the natural indigo printing method derived from this study.

• Restorative Dentistry and Endodontics
• /
• 제19권2호
• /
• pp.585-601
• /
• 1994

The purpose of this study was to evaluate the ability of several intracoronal base materials to prevent cervical leakage of a bleaching agent into the dentinal tubules and along the root canal. In this study, thirty-two anterior teeth were used. After lingual access was prepared in each tooth, tooth was instrumented with a step-back technique to a Nos. 40-50 using K-type files. All teeth were obturated with a lateral condensation technique. Excess gutta percha was removed with a warm instrument to the facial level of the CEJ. Teeth were divided into four groups : Teeth in control group were not filled with base material. Teeth in groups 1, 2, and 3 had 2mm of gutta percha removed with a warm instrument, then Dycal, Fuki II LC and Z-100 were filled with palstic instruments on the top of the gutta percha respectively. All teeth were bleached for 7 days, fresh bleach was added for another 7 days, then a 10 % methylene blue dye was placed inside the access preparation. They were stored at $37^{\circ}C$ and $100^{\circ}C$ humidity for 5 days. Each tooth was sectioned perpendicular to the long axis using a diamond disk. Initial cuts were made at the most coronal level of facial and lingual CEJ's, then another cuts continued appically in the levels of 0.5mm, 1.5mm, and 2.0mm respectively. The amount of dye leakage through the dentinal tubules was determined at each cut section. In addition, when the cut specimen was determined to be last penetration of any dye, this level was recorded as depth of apical leakage from the coronal terminus of the gutta percha, Dycal, Fuji II LC and Z-100. The acquired data were analyzed by Tukey's Multiple Range Test adn Cochran-Mantel-Haenszel Test to see if there was any statistically significant difference in dye penetration and linear apical leakage among the groups. The results were as follows : 1. Control group at levels of CEJ and 0.5mm, group 3 at level of 1.5mm, and group 2 AND 3 at level of 2.0mm showed the least dye penetration through the facial or lingual dentinal tubules, but there were no significant difference among three groups. 2. Group 2 at levels of CEJ and 0.5mm, group 3 at level of 1.5mm, and group 2 and 3 at level of 2.0mm showed the least dye penetration through the proximal dentinal tubules, but there were no significant difference among control group, group 2, and group 3. 3. Group 1 showed the greatest dye penetration through the facial or lingual and proximal dentinal tubules at all levels, and there were significant difference with other three groups. 4. Control group and group 1 showed 2mm apical dye leakage at facial or lingual and proximal aspects, group 2 showed 1.5mm, and group 3 showed 0.5mm.

• Restorative Dentistry and Endodontics
• /
• 제31권5호
• /
• pp.337-343
• /
• 2006

본 연구에서는 색소 침투법을 이용한 5급 복합레진 수복물의 미세누출도와 주사전자 현미경을 이용한 변연적합도를 측정하고 두 방법 사이의 상관성을 평가하고자 하였다. 발거된 사람의 대구치 20개의 협면에 고속의 330번 버를 이용하여 5급 와동을 (백아법랑경계부를 중앙으로 가로 4 mm, 세로 3 mm, 깊이 1.5 mm) 형성하고, 평가시 참고점으로 사용하고자 1/2번 원형 버로 6개의 함몰부를 만들었다. 제조사의 지시에 따라 단일 단계의 올인원 접착제인 Xeno III로 치면을 처리한 다음, 미세혼합형 복합레진인 Esthet X로 단일 충전하였다. 시편을 식염수에 1일간 보관한 후 Sof-Lex 시스템으로 마무리 및 연마하였다. 이후 5도와 55도에서 1000회 열순환시킨 다음, 50%질산은 용액을 이용하여 침투시켰다. 실리콘 고무 인상재와 폴리우레탄 모형재로 수복물 주변의 레진 복제물을 제작하고 금도금한 다음 주사전자현미경으로 외부 및 내부 변연부의 변연적합도를 측정하였다. 또한 참고점을 기점으로 수복물을 3분한 다음, 미세누출도를 측정하였다. 내부 및 외부 변연적합도와 미세누출도 평가법 사이의 상관관계는 Spearman's rho test를 이용하여 다음과 같은 결과를 얻었다. 1. 미세누출도와 각각의 외부 및 내부 변연 적합도는 유의한 상관관계를 보였다 (p <0.01). 2.내부와 외부의 변연 적합도 사이에는 유의한 상관관계를 보이지 않았다.

• 한국임상보건과학회지
• /
• 제4권3호
• /
• pp.634-643
• /
• 2016

Purpose. The purpose of this study was to progress the effect of gastrocnemius strength when groups are applicated on low-dye taping group and without taping group of flatfoot with arch-recovery exercise. Methods. Subjects were measured navicular drop test to confirm of 16 university student in J city, low-dye taping group and without taping group were applicated both with arch-recovery exercise, three times per a week for four weeks. The power track were measured four weeks, total 3 times. Comparative analysis of the control group and experimental group were investigated of gastrocnemius strength. Results. The results, we found that after of arch-recovery exercise were significantly increased than before of arch-recovery exercise in each foot. And application of low-dye taping(experimental group) in flatfoot with arch-recovery exercise were significantly increased than control group. Conclusions. In conclusion, the arch-recovery exercise application were effective to low-dye taping significantly increase the gastrocnemius strength of flatfoot.

• 한국의류학회지
• /
• 제33권12호
• /
• pp.1971-1978
• /
• 2009

본 연구는 염색 공정의 표준화와 재현성을 확립하기 위해 홍화 황색소의 모섬유에 대한 염색성을 조사하는데 목적이 있다. 홍화 황색소는 물로 추출한 후 농축, 동결건조하여 분말상태로 만들어 사용하였다. 염색 온도 및 시간, 염료 농도, 염액의 pH 등에 따른 염착성과 색상 변화에 대해 조사하였으며, 세탁 및 일광견뢰도를 평가하였다. 염착량은 $50^{\circ}C$까지 서서히 증가하다가 이후 급격히 증가하여 $90^{\circ}C$에서 최고 값을 나타냈다. 염착은 초기 10분 이내에 빠르게 일어났으며 이후 서서히 증가하다가 40~60분 사이에 평형에 도달하였다. 염료 농도가 증가함에 따라 염착량이 계속 증가하여 점점 진하고 어두운 노랑색이 되었다. 산성 조건에서 염착이 잘 되었으며 pH 3.0에서 최대염착량을 보였다. 얻은 결과를 근거로 최적 염색 조건은 $90^{\circ}C$, 40분, pH 3.5으로 설정하였으며, 최적 조건에서 염색한 시료들 간의 색차는 0.53~1.75로서 재현성이 우수하였다. 후매염은 염착성 증진에 효과가 없었으나, 다양한 톤과 농담의 노랑색을 얻을 수 있었다. 세탁(드라이크리닝)견뢰도는 4/5등급으로 좋은 편이었으나 20시간 조사 후 일광견뢰도는 Fe과 Cu매염한 경우 3/4등급으로 색차가 가장 적었다. 결과를 종합해 볼 때 매염제가 색상톤을 다양하게 하는 효과는 있었지만, 염착량과 견뢰도 향상에 기여하지 못하였다. 홍화 황색소는 모염색에서 매염제 없이 만족스러운 결과를 얻을 수 있고, 따라서 환경에 피해를 주지 않을 것으로 사료된다.

• 한국염색가공학회지
• /
• 제34권2호
• /
• pp.93-101
• /
• 2022

In this study, the dyeing properties of supercritical fluid dyed cotton fabrics were investigated which use two types of dyes, such as C.I. Disperse orange and C.I. Disperse red 167. Dyeing temperature, pressure and leveling time were equally applied at 130 ℃, 250 bar, and 60 minutes with reference to the related literature, and experiments were performed at concentrations of 0.04, 0.1, 0.4 and 0.8 % o.w.f with different concentrations. Dyeability was confirmed through measurement of washing fastness and color coordinate, and a calibration curve of each dye was drawn up and the absorbance of the residual dye was measured to confirm the amount of residual dye and the dye exhaustion rate at the corresponding concentration. As a result of color difference measurement, as the concentration increased, the L^* value decreased and the K/S value increased. However, as the concentration increased, the increase in K/S value decreased compared to the input amount, and this tendency was more obvious in C.I. Disperse red 167 than in C.I. Disperse orange 155. The dye exhaustion rate which was calculated by using the amount of residual dye in the pot was also C.I. Disperse orange 155 was 96.16 % and C.I. Disperse red 167 was 94.57 %. However, as the dyeing concentration increased, the dye exhaustion rate decreased, that C.I. Disperse orange was 95.33 % and C.I. Disperse red 167 was 90.63 %. As a result of the washing fastness test for both dyes, dyed samples of which concentrations were 0.4 and 0.8 % o.w.f decreased by 0.5 ~ 1.0 grade. This is predicted because the dye did not completely adhere to the amorphous region of the cotton fiber and the dye simply adsorbed. The fastness to rubbing also maintained at least grade 3-4 up to the 0.1 % o.w.f concentration, but at the concentration of 0.4 % o.w.f or higher, it fell to grade 1 or lower, showing a very poor friction fastness.