• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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• pp.170-170
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• 2013

형광체를 조명과 디스플레이 산업에 응용하기 위해서는 충분히 밝은 빛을 제공하는 형광체의 발광 세기가 중요한 변수이다. 이러한 발광 특성은 주로 모체 격자에 도핑 되는 활성제의 농도, 입자의 형상과 크기 분포의 균일성, 결정성에 따라 달라진다. 본 연구에서는 Ca2SiO4 모체 결정에 도핑한 활성제 Eu3+와 Dy3+ 이온의 농도를 변화시키면서 고상 반응법을 사용하여 높은 발광 효율을 갖는 Ca2-1.5xSiO4::Eux3+ 적색 형광체와 Ca2-1.5xSiO4:Dyx3+ 백색 형광체를 합성하였다. 특히, 활성제 Eu3+와 Dy3+ 이온 농도의 변화가 형광체의 결정 구조, 소성 온도, 입자의 표면 형상, 광학 스펙트럼의 발광 효율에 미치는 영향을 조사하여 최적의 합성 조건을 결정하였으며, 회절 신호의 반치폭과 발광 세기의 상호 관계를 조사하였다. Ca2-1.5xSiO4::Eux3+와 Ca2-1.5xSiO4:Dyx3+ 형광체 초기 분말 시료는 CaO (99.9% 순도), SiO2 (99.9%), Dy2O3 (99.9%)와 Eu2O3 (99.9%)인 화학 물질을 구입하여 초정밀 저울로 화학양론적으로 측정하였다. 이때 Eu와 Dy의 함량비는 x=0, 0.01, 0.05, 0.1, 0.15, 0.2 mol로 변화 시키면서 합성하였다. Ca2-1.5xSiO4: Dyx3+ 형광체 분말 시료의 경우에 소결 온도를 각각 $1000^{\circ}C$와 $1100^{\circ}C$로 달리하여 흡광과 발광 스펙트럼의 세기를 비교해 본 결과, 서로 다른 두 소결 온도에서 합성한 두 형광체 분말은 동일하게 Dy3+의 몰 비가 0.05 mol일 때 주 발광 스펙트럼의 세기는 최대값을 나타내었다. 파장 355 nm로 여기시킨 Dy3+ 함량비에 따른 Ca2-1.5xSiO4:Dyx3+ 형광체 분말의 발광 스펙트럼은 Dy3+ 함량비에 관계 없이 581 nm에서 가장 강한 황색 발광을 보였다. 함량비가 증가함에 따라 발광 스펙트럼의 변화가 관측되었는데, Dy3+의 몰 비가 0.01 mol~0.05 mol인 영역에서는 발광 세기가 증가하여 0.05 mol에서 최대를 나타내다가 Dy3+의 몰 비가 더욱 증가함에 따라 발광세기는 현저히 감소하는 경향을 나타내었는데, 이 현상은 농도 소광 현상으로 해석 할 수 있다. 이외에도, Eu3+와 Dy3+ 이온의 함량비와 소결 온도가 결정 입자의 크기와 흡광 스펙트럼에 미치는 결과를 조사하였다.

• 한국재료학회지
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• 제17권11호
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• pp.612-617
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• 2007

Both photoluminescence and thermal characteristics for $SrAl_2O_4:Eu^{+2},\;Dy^{+3}$ phosphors synthesized with various aluminum compounds (${\alpha}-Al_2O_3$, ${\gamma}-Al_2O_3$, amorphous-$Al_2O_3$ and $Al(OH)_3)$ were investigated in this study. The formation temperature of the host $SrAl_2O_4$ crystal is changed by these various aluminum compounds, as a result of the different thermal decomposition temperature of $SrCO_3$ phase. Among these compounds, the amorphous-$Al_2O_3$ phase shows the lowest formation temperature of the host $SrAl_2O_4$ crystal. The PL emission and excitation spectra of $SrAl_2O_4:Eu^{+2},\;Dy^{+3}$ phosphor are not affected by these aluminum compounds. After the removal of the Xenon lamp excitation (360 nm), however, the excellent longphosphorescent property of the phosphor is obtained by the amorphous-$Al_2O_3$ phase, although the decay time for all phosphors decrease exponentially.

• 한국재료학회지
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• 제27권6호
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• pp.339-344
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• 2017

A series of $CaNb_2O_6:Dy^{3+}$, $CaNb_2O_6$:$Eu^{3+}$ and $CaNb_2O_6:Dy^{3+}$, $Eu^{3+}$ phosphors were prepared by solid-state reaction process. The effects of activator ions on the structural, morphological and optical properties of the phosphor particles were investigated. XRD patterns showed that all the phosphors had an orthorhombic system with a main (131) diffraction peak. For the $Dy^{3+}$-doped $CaNb_2O_6$ phosphor powders, the excitation spectra consisted of one broad band centered at 267 nm in the range of 210-310 nm and three weak peaks; the main emission band showed an intense yellow band at 575 nm that corresponded to the $^4F_{9/2}{\rightarrow}^6H_{13/2}$ transition of $Dy^{3+}$ ions. For the $Eu^{3+}$-doped $CaNb_2O_6$ phosphor, the emission spectra under ultraviolet excitation at 263 nm exhibited one strong reddish-orange band centered at 612 nm and four weak bands at 536, 593, 650, and 705 nm. For the $Dy^{3+}$ and $Eu^{3+}$-codoped $CaNb_2O_6$ phosphor powders, blue and yellow emission bands due to the $^4F_{9/2}{\rightarrow}^6H_{15/2}$ and $^4F_{9/2}{\rightarrow}^6H_{13/2}$ transitions of $Dy^{3+}$ ions and a main reddish-orange emission line at 612 nm resulting from the $^5D_0{\rightarrow}^7F_2$ transition of $Eu^{3+}$ ions were observed. As the concentration of $Eu^{3+}$ ions increased from 1 mol% to 10 mol%, the intensities of the emissions due to $Dy^{3+}$ ions rapidly decreased, while those of the emission bands originating from the $Eu^{3+}$ ions gradually increased, reached maxima at 10 mol%, and then slightly decreased at 15 mol% of $Eu^{3+}$. These results indicate that white light emission can be achieved by modulating the concentrations of the $Eu^{3+}$ ions incorporated into the $Dy^{3+}$-doped $CaNb_2O_6$ host lattice.

• 한국전기전자재료학회논문지
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• 제20권8호
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• pp.680-684
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• 2007

In this study, we investigated the effects of structural and electrical properties of $(Ba_{0.6},\;Sr_{0.3},\;Ca_{0.1})TiO_3$ thick films with variation $Dy_2O_3$ contents. $(Ba_{0.6},\;Sr_{0.3},\;Ca_{0.1})TiO_3$ powders, prepared by the sol-gel method, were mixed organic vehicle. The BSCT thick films doped with 0.1, 0.3, 0.5, 0.7 mol% $Dy_2O_3$ were fabricated by the screen-printing techniques on the alumina substrates and the structural and dielectric properties were investigated with variation of $Dy_2O_3$ doping contents. All BSCT thick films were sintered at $1420^{\circ}C$, for 2hr. In the TG-DTA analysis, the formation of the polycrystalline perovskite phase was observed at around $670 ^{\circ}C$. In the XRD analysis, all BSCT thick films showed the cubic perovskite structure. The average thickness of BSCT thick films was approximately $65{\mu}m$. The Curie temperature decreased with increasing $Dy_2O_3$ amount. The relative dielectric constant and dielectric loss of BSCT thick films doped with $Dy_2O_3$ 0.1 mol% were 6267 and 2.6 %, respectively.

• 한국표면공학회지
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• 제51권5호
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• pp.271-276
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• 2018

The effects of activator ion on the structural, morphological, and optical properties of $LaNbO_4:RE^{3+}$ (RE = Dy, Dy/Sm, Sm) phosphors were investigated. X-ray diffraction patterns exhibited that all the phosphors showed a monoclinic system with a main (112) diffraction peak, irrespective of the concentration and type of activator ions. The grain size showed a slightly decreasing tendency as the concentration of $Sm^{3+}$ ions increased. The excitation spectra of the $LaNbO_4:Dy^{3+}$, $Sm^{3+}$ phosphor powders consisted of a strong charge transfer band centered at 259 nm in the range of 220-290 nm and five weak peaks. The emission spectra of the $La_{0.95}NbO_4$:5 mol% $Dy^{3+}$ phosphors exhibited two intense yellow and blue bands centered at 575 nm and 479 nm respectively, which resulted from the $^4F_{9/2}{\rightarrow}^6H_{13/2}$ and $^4F_{9/2}{\rightarrow}^6H_{15/2}$ transitions of $Dy^{3+}$. As the concentration of $Sm^{3+}$ was increased, the intensity of the yellow emission band was gradually decreased, while those of orange and red emission bands centered at 604 and 646 nm began to appear and reached maxima at 5 mol%, and then decreased rapidly with further increases in the $Sm^{3+}$ concentration. These results indicated that white light emission could be realized by controlling the concentrations of the $Dy^{3+}$ and $Sm^{3+}$ ions incorporated into the $LaNbO_4$ host crystal.

• 전기학회논문지
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• 제56권9호
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• pp.1609-1613
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• 2007

(Ba,Sr,Ca)$TiO_3$ powders, which were prepared by sol-gel method using a solution of Ba-, Sr- and Ca-acetate and Ti iso-propoxide, were mixed with organic vehicle and the BSCT thick films were fabricated by the screen-printing techniques on high purity alumina substrates. The structural and dielectirc properties were investigated for various $Dy_2O_3$ doping contents. As a result of thermal analysis, the exothermic peak was observed at around 670^{\circ}C $ due to the formation of the polycrystalline perovskite phase. All BSCT thick films, sintered at $1420^{\circ}C$ for 2h, showed the typical XRD patterns of perovskite polycrystalline structure and no pyrochlore phase was observed. The average grain size of the specimens decreased with increasing amount of $Dy_2O_3$. The average grain size and thickness of the BSCT specimens doped with 0.1 mol% $Dy_2O_3$ were approximately $1.9{\mu}m$ and $70{\mu}m$, respectively. The relative dielectric constant decreased and dielectric loss increased with increasing amount of $Dy_2O_3$, the values of the BSCT thick films doped with 0.1 mol% $Dy_2O_3$ were 3697 and 0.4% at 1 kHz, respectively. The leakage current densities in all BSCT thick films were less than $10^{-9}A/cm^2$ at the applied electric field range of 0-20 kV/cm.

• 한국세라믹학회지
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• 제45권8호
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• pp.477-481
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• 2008

$Eu^{2+}$ and $Dy^{3+}$ co-doped strontium aluminate, $SrAl_2O_4$ long phosphorescent phoshor was fabricated and its photoluminescence was characterized. The phosphor, $SrAl_2O_4:Eu^{2+},Dy^{3+}$ was synthesized by a coprecipitation in which metal salts of $Sr(NO_3)_2$, $Al(NO_3)_3{\cdot}9H_2O$, were dissolved in $(NH_4)_2CO_3$ solution with adding $Eu(NO_3)_3{\cdot}5H_2O$ and $Dy(NO_3)_3{\cdot}5H_2O$ as a activator and co-activator, respectively. The coprecipitated products were separated from solution, washed, and dried in a vacuum dry oven. The dried powders were then mixed with 3 wt% $B_2O_3$ as a flux and heated at $800{\sim}1400^{\circ}C$ for 3 h under the reducing ambient atmosphere of 95%Ar+$5%H_2$ gases. For the synthesized $SrAl_2O_4:Eu^{2+},Dy^{3+}$, properties of photoluminescence such as emission, excitation and decay time were examined. The emission intensity increased as the annealing temperature increased and showed a maximum peak intensity at 510 nm with a broad band from $400{\sim}650\;nm$. Monitored at 520 nm, the excitation spectrum showed a maximum peak intensity at $315{\sim}320\;nm$ wavelength with a broad band from $200{\sim}500\;nm$ wavelength. The decay time of $SrAl_2O_4:Eu^{2+},Dy^{3+}$ increased as the annealing temperature increased.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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• pp.172-172
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• 2013

최근에 디스프로슘 이온이 도핑된 형광체의 백색 발광 현상 때문에 백색 발광 소재의 제조에 관한 연구가 상당한 관심을 끌고 있다. 본 연구에서는 $Eu^{3+}$와 $Dy^{3+}$ 이온의 몰 비를 변화시키면서 $BaNb_2O_6:RE^{3+}$ (RE=Eu, Dy) 형광체 분말을 합성한 결과를 보고한다. 특히 활성제 이온인 $Eu^{3+}$와 $Dy^{3+}$ 이온의 몰 비에 따른 $BaNb_2O_6$ 형광체 분말의 결정 구조, 입자의 모양과 크기, 흡광과 발광 스펙트럼의 변화를 관측하였고, 최적의 합성 조건을 제시하고자 한다. 파장 393 nm로 여기 시킨 $Dy^{3+}$ 이온의 몰 비에 따른 $BaNb_2O_6$ 형광체 분말의 발광 스펙트럼은 580 nm에 주 피크를 갖는 황색 스펙트럼이 관측되었다. 이 발광 신호는 $^4F_{9/2}-^6H_{13/2}$ 전이 신호이다. $Dy^{3+}$ 이온의 몰 비가 0 mol인 경우에는 발광 신호가 검출되지 않았다. $Dy^{3+}$ 이온의 몰 비가 0.10 mol일 때 발광 피크의 세기는 최대이었으며, $Dy^{3+}$ 이온의 몰 비가 더욱 증가함에 따라 발광 스펙트럼의 세기는 계속 증가하지 않고 갑자기 감소하기 시작하였다. 이것은 $Dy^{3+}$ 이온의 몰 비가 임계값을 초과하여 더욱 증가하면 모체 격자들 사이에 치환 고용되어 있는 $Dy^{3+}$ 이온들 사이의 거리가 더욱 가까워져서 $Dy^{3+}$ 이온들이 서로 용이하게 결합함으로써 내부 산란에 의하여 발광의 세기가 감소함을 의미한다. 흡광 스펙트럼의 경우에, $Dy^{3+}$ 이온의 몰 비가 0.01 mol일때 형광체 분말은 두 종류의 흡광 스펙트럼을 나타내었다. 첫째는 $Dy^{3+}$ 양이온과 $O^{2-}$ 음이온들 사이에 발생한 전하 전달 밴드에 의해 발생하는 310 nm를 정점으로 하여 280~340 nm 영역에 걸쳐서 광범위하게 분포하는 흡광 신호가 관측되었으며, 둘째는 $Dy^{3+}$ 이온의 $4f^9$ 전자 배열 내에서 발생하는 4f-4f 전이 신호로서, 이것은 350~500 nm 영역에 걸쳐서 비교적 밴드폭이 좁은 다수의 흡광 신호가 나타났다. 본 실험에서는 다섯 개의 피크를 갖는 흡광 신호가 검출되었는데, 이중에서 제일 강한 주 피크인 393 nm의 흡수 파장은 모체 격자 내에 있는 $Dy^{3+}$ 이온의 바닥 상태인 $^6H_{15/2}$ 준위에서 여기 상태인 $^4F_{7/2}$ 인 에너지 준위로 전이하면서 발생한 신호이며, 이에 비하여 상대적으로 흡광 세기가 약한 370, 432, 458, 370 nm의 흡수 파장이 관측되었다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2009년도 하계학술대회 논문집
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• pp.140-140
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• 2009

The Metal-ferroelectric-semiconductor (MFS) structure has superior advantages such as high density integration and non-destructive read-out operation. However, to obtain the desired electrical characteristics of an MFS structure is difficult because of interfacial reactions between ferroelectric thin film and Si substrate. As an alternative solution, the MFS structure with buffer insulating layer, i.e. metal-ferroelectric-insulator-semiconductor (MFIS), has been proposed to improve the interfacial properties. Insulators investigated as a buffer insulator in a MFIS structure, include $Ta_2O_5$, $HfO_2$, and $ZrO_2$ which are mainly high-k dielectrics. In this study, we prepared the Dy-doped $La_2O_3$ solution buffer layer as an insulator. To form a Dy-doped $La_2O_3$ buffer layer, the solution was spin-coated on p-type Si(100) wafer. The coated Dy-doped $La_2O_3$ films were annealed at various temperatures by rapid thermal annealing (RTA). To evaluate electrical properties, Au electrodes were thermally evaporated onto the surface of the samples. Finally, we observed the surface morphology and crystallization quality of the Dy-doped $La_2O_3$ on Si using atomic force microscopy (AFM) and x-ray diffractometer (XRD), respectively. To evaluate electrical properties, the capacitance-voltage (C-V) and current density-voltage (J-V) characteristics of Au/Dy-doped La2O3/Si structure were measured.

• 한국세라믹학회지
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• 제46권2호
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• pp.181-188
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• 2009

The electrical property and microstructure in $BaTiO_3$ ceramics doped rare-earth ions with intermediate ionic size ($Dy^{3+},Ho^{3+},Y^{3+}$) were investigated. Microstructures have been characterized using scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray diffraction (XRD). Incorporation of rare-earth ions to $BaTiO_3$ ceramics depended on their ionic radius sensitively. Compared to Ho and Y ions, Dy ions provide $BaTiO_3$ ceramics with the high rate of densification and well-developed shell formation, due to their high solubility in the $BaTiO_3$ lattice, but the microstructure of Dy doped $BaTiO_3$ ceramics is unstable at high temperature, because Dy ions could not play a role of grain growth inhibition, leading to diffuse into $BaTiO_3$ lattice continuously after completion of densification during sintering. Comparing electrical property and microstructure, it is shown that the reliability of capacitor improved by high shell ratio.