• Korean Chemical Engineering Research
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• v.58 no.4
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• pp.524-529
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• 2020

To increase the mechanical durability of the proton exchange membrane fuel cells, a reinforced membrane in which a support is placed in the polymer membrane is used. The support mainly uses e-PTFE, which is hydrophobic and does not transfer ions, which may cause performance degradation. In this study, we investigated the effect of e-PTFE support on PEMFC performance and electrochemical durability. In this study, the reinforced membrane with the support was compared with the single membrane (non-reinforced membrane). Due to the hydrophobicity of the support, the water diffusion coefficient of the reinforced membrane was lower than that of the single membrane. The reinforced membrane had a lower water diffusion coefficient, resulting in higher HFR, which is the membrane migration resistance of ions, than that of a single membrane. Due to the low hydrogen permeability of the support, the OCV of the reinforced membrane was higher than that of the single membrane. The support was shown to reduce the hydrogen permeability, thereby reducing the rate of radical generation, thereby improving the electrochemical durability of the reinforced membrane.

• Advances in concrete construction
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• v.7 no.4
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• pp.231-239
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• 2019

The present study deals with the development of metakaolin-based geopolymer concrete (GPC) and thereafter studying the effects of adding ultra-fine slag on its mechanical and permeability characteristics. The mechanical characteristics including compressive, split tensile, flexural strengths and elastic modulus were studied. In addition, permeability characteristics including water absorption, porosity, sorptivity and chloride permeability were studied up to 90 days. The results showed the effective utilization of metakaolin for the development of elevated temperature cured geopolymer concrete having high 3-day compressive strength of 42.6 MPa. The addition of ultra-fine slag up to 15%, as partial replacement of metakaolin resulted in an increase in strength characteristics. Similar improvement in durability properties was also observed with the inclusion of ultra-fine slag up to 15%. Beyond this optimum content of 15%, further increase in ultra-fine slag content affected the mechanical as well as permeability parameters in a negative way. In addition, the relationship between various properties of GPC was also derived.

• Journal of the Korea Concrete Institute
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• v.27 no.4
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• pp.435-441
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• 2015

Concrete, as a porous media, has permeability and it is considered as a major parameter for durability evaluation. Cold joint caused by delayed placing of concrete accelerates water permeation and intrusion of harmful ions. In the paper, concrete specimens containing GGBFS (Ground Granulated Blast Furnace Slag) and OPC (Ordinary Portland Cement) are prepared with cold joint section, and water permeability and water flow at the age of 91 days are measured for 2 weeks. Sound concrete with GGBFS shows decreased permeability to 89% for sound concrete with OPC and 0.86 of decreasing ratio is evaluated in GGBFS concrete with cold joint. Through WPT (Water Penetration Test), the effects of mineral admixture and cold joint on water permeability are evaluated, and variation in water behavior via cold joint is analyzed through probabilistic method as well.

• Advances in concrete construction
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• v.3 no.4
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• pp.317-331
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• 2015

This paper presents the effect of different micro-silica (MS) contents of 5, 10 and 15 wt.% as partial replacement of cement on mechanical and durability properties of high volume fly ash - recycled aggregate concretes (HVFA-RAC) containing 50% class F fly ash (FA) and 35% recycled coarse aggregate (RCA) as partial replacement of cement and natural coarse aggregate (NCA), respectively. The measured mechanical and durability properties are compressive strength, indirect tensile strength, elastic modulus, drying shrinkage, water sorptivity and chloride permeability. The effects of different curing ages of 7, 28, 56 and 91 days on above properties are also considered in this study. The results show that the addition of MS up to 10% improved the early age (7 days) strength properties of HVFA-RAC, however, at later ages (e.g. 28-91 days) the above mechanical properties are improved for all MS contents. The 5% MS exhibited the best performance among all MS contents for all mechanical properties of HVFA-RAC. In the case of measured durability properties, mix results are obtained, where 10% and 5% MS exhibited the lowest sorptivity and drying shrinkage, respectively at all ages. However, in the case of chloride ion permeability a decreasing trend is observed with increase in MS contents and curing ages. Strong correlations of indirect tensile strength and modulus of elasticity with square root of compressive strength are also observed in HVFA-RAC. Nevertheless, it is established in this study that MS contributes to the sustainability of HVFA-RAC significantly by improving the mechanical and durability properties of concrete containing 50%less cement and 35% less natural coarse aggregates.

• Journal of the Korea institute for structural maintenance and inspection
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• v.16 no.3
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• pp.75-83
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• 2012

Porosity in concrete has close relationship with durability characteristics. Additionally mixed water can help easy mixing and workability but causes increased porosity, which yields degradation of durability performance. In this paper, cement mortar samples with 0.45 of w/c (water to cement ratio) are prepared and durability performances are evaluated with additional water from 0.45 to 0.60 of w/c. Various durability tests including strength, chloride diffusion, air permeability, saturation, and moisture diffusion are performed. Then they are analyzed with changing porosity. Changing ratios and the patterns of durability performance are quantitatively evaluated considering pore size distribution, total porosity, and additional water content.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.29 no.2A
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• pp.171-179
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• 2009

The porosity in porous media like concrete can be considered as a durability index since it may be a routine for the intrusion of harmful ions and room for the keeping moisture. Recently, modeling and analysis techniques for deterioration are provided based on the pore structure with the significance of durability and the relationship between porosity and durability characteristics is an important issue. In this paper, a series of mortar samples with five water to cement ratios are prepared and tests for durability performance are carried out including porosity measurement. The durability test covers those for compressive strength, air permeability, chloride diffusion coefficient, absorption, and moisture diffusion coefficient. They are compared with water to cement ratios and porosity. From the normalized data, when porosity increases to 1.45 times, air permeability, chloride diffusion coefficient, absorption, and moisture diffusion coefficient decrease to 2.3 times, 2.1 times, 5.5 times and 3.7 times, respectively, while compressive strength decreases to 0.6 times. It was evaluated that these are linearly changed with porosity showing high corelation factors. Additionally, intended durability performances are established from the test results and literature studies and a porosity for durable concrete is proposed based on them.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.581-584
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• 2006

This study is analyzed mechanical properties and durability of permeability porous concrete to mix polymer and steel fiber for the enhance of performance and durability of porous concrete. It proves that void ratio and permeability are tallied with internal and external standard of paving porous concrete. A property of strength is increased according as the mixing rate of polymer and steel fiber increase, but it showed the tendency to be reduced on the contrary when mixed upwards of 20% of polymer mixing rate and 0.9vol.% of steel fiber mixing rate. As a result, it is possible to make an enhanced which increased 16% of compressive strength and 30% of flexural strength steel fiber reinforced polymer porous concrete at the mixing rate of 10vol.% of polymer and 0.6% of steel fiber.

• Proceedings of the Korean Geotechical Society Conference
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• 2009.03a
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• pp.836-843
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• 2009

The Water Glass grouting method has been applied frequently to impermeable grouting in practice. But there is raising problems which are durability decrease by passage time and environmentally adverse effect. So, Earth Natural Grouting method which uses micro cement is developed to overcomes the problems of the Water Glass grouting method. And it is displayed ground injection extent like Water Glass grouting method. For verifying impermeability of ENG, it is carried out a triaxial permeability test about manufacturing specimen of ENG, SGR method which is a presentative Water Glass grouting method. Although Coefficient of permeability, k, of SGR is measured a little high than k of ENG whose value is $a{\times}10^{-6}cm/sec$, the value of ENG belong to impermeable rage. And, k of SGR shows relatively rapid increase according to cure time due to durability decrease of water glass. Also, in-situ test result of ENG has similar value with SGR method for similar ground.

• Proceedings of the Korea Concrete Institute Conference
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• 1999.10a
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• pp.259-262
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• 1999

In underground reinforced concrete structures, such as drainage structure, water and chloride ion penetrated into concrete through the cracks of concrete and its permeable property, cause the corrosion of reinforcing steel bar, which accelerates the expansive cracks and deterioration of concrete. It is necessary to control those deterioration of underground structure by improving its permeability and durability through the reasonable solutions in design, construction and materials. In the present study, fly ash concrete, which has good material properties in long-term period, was compared and studied with plain concrete using ordinary portland cement in terms of fundamental mechanical properties, permeability, drying shrinkage and durability. Also, the mix design and field test of low permeable concrete using fly ash were performed. From this study, fly ash concrete can control the penetration of water and chloride ion effectively by forming dense micro-structure of concrete. Therefore, fly ash concrete may increase the long-term function, performance and serviceability of underground structures.

• International Journal of Concrete Structures and Materials
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• v.1 no.1
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• pp.57-61
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• 2007

This study investigated the mechanical and durability performance of roller-compacted concrete (RCC) with fly ash for dam applications. A test program studied the effects on the properties of fresh and hardened RCC with fly ash replacement ratio, as well as the long-term durability of the resulting mixture. Fly ash replaced 20, 30, 40, and 50% by mass of the cement. Laboratory tests of the compressive strength, splitting tensile strength, shear strength, chloride ion permeability, abrasion, and drying shrinkage were conducted. The test results demonstrated that 30% fly ash replacement is an optimum level, and that this mixture has excellent mechanical and durability properties.