• Restorative Dentistry and Endodontics
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• v.20 no.1
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• pp.33-54
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• 1995

The degree of conversion of composite resin was known to have influence on the mechanical properties of composite materials such as hardness, strength, wear resisitance, dimensional and color stability. Also unreacted monomer was reported to be harmful to the pulp. So the degree of conversion was a very important factor in the success of composite resin restorations. In recent, the dual cure resin cement was developed with the advocations that it could increase the curing rates in the sites where the curing ligt could not reach. Moreover many manufactors added some adhesive components in the resin cement. This study was undertaken to observe the effects of curing depth and light curing times on the degree of conversion of dual cure resin cements. CR INLAY CEMENT, DUAL CEMENT and OPTEC BOND, by the Fourier transform Infrared analysis, changing the curing depth 1mm, 2mm and 3mm, and varying the light curing time 20 seconds, 40 seconds and 80 seconds at each depth. The cytotoxicity of dual cure resin cements was tested by the in vitro MTT method using L929 cell. The results was evaluated and compared statistically. The results were obtained as follows : 1. The dual cure resin cements reavealed various degree of conversion, CR INLAY CEMENT and DUAL CEMENT had a tendency to be more reactive to the light cure and OPTEC BOND was a more chemical one. 2. CR INLAY CEMENT and DUAL CEMENT showed the lowest degree of conversion in 2 mm depth, and in 3mm depth the degree of conversion increased, which were due to the chemical cure of dual cures, but OPTEC BOND showed decreasing degree of conversion with increasing curing dept h and all experimental groups showed lower degree of conversion than CHEMICAL group which cured in dark room with no light, so the weak light-curing of dual cure resin cement prevented the chemical cure. (P<0.05) 3. CR INLAY CEMENT and DUAL CEMENT showed increasing degree of conversion in 1 mm and 3 mm, according to the increasing cure times, but in 2 mm depth the degree of conversion decreased with increasing light-curing times and OPTEC BOND showed contrary tendency, but there was no ststistical importance in the differences among the experimental group.(P>0.05) 4. The optical density by MTT assay of extractions of CR INLAY CEMENT, DUAL CEMENT and OPTEC BOND revealed no statitically important differences comparing with optical density of negative control.(P>0.05) 5. CR INLAY CEMENT showed a tendency of increaing cytotoxicity with days and DUAL CEMENT and OPTEC BOND showed higher cytotoxicity in 2 days than in 4 days, but there was no statistical importance in the differences.(P>0.05).

• Fibers and Polymers
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• v.2 no.4
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• pp.184-189
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• 2001

Continuous photografting/crosslinking of polyethyleneglycol dimethacrylate oligomers onto cotton using a water-soluble benzophenone photoinitiator was investigated. Photografting increased with increasing irradiation dose, oligomer concentration and photoinitiator concentration. Maximum grafting efficiency of DM 400 and 600 were 83% and 79%, respectively. the photografting increased the wrinkle resistance of cotton implying surface crosslinking of cotton. bothsurface crosslinking and bulk crosslinking of cotton were accomplished via dual curing of a mixed formulation containing both a thermally curable component (BTCCA/SHP) and a UV-curable component. The wrinkle resistance of the crosslinked cotton was found to be higher when cured by thermal curing due to the facile post-polymerization of the UV active component. The presence of crosslinks in the dually crosslinked cotton was verified with FT-IR and thermogravimetric analysis.

• Journal of the korean academy of Pediatric Dentistry
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• v.23 no.4
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• pp.906-914
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• 1996

Due to the various reason, sealing of pit & fissure might be imperfect. One of these reason can be the fracture of sealant material because of the low hardness value of sealing material. The purpose of this in vitro study was to evaluate the microhardness of two different curing type pit and fissure sealants: Dual-cure and Light-cure. The result from the present study can be summarized as follows: 1. All pit and fissure sealants that used in this study showed statistically significant difference in their microhardness of upper and lower surface. (P <0.05) 2. Except of lower surface of teethmate, microhardness of 40-second curing sealant was statistically higher than that of 20-second curing sealant. (P <0.05) 3. In comparison of sealants, microhardness of dual-cure sealant was statistically higher than that of light-cure sealant. Above results suggest that the use of dual-cure sealant and longer curing time are recommended.

• Journal of Dental Rehabilitation and Applied Science
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• v.31 no.1
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• pp.1-9
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• 2015

Purpose: The purpose of this study was to evaluate the mechanical properties of several dual-cure cements by different curing modes. Materials and Methods: One resin-modified glass ionomer cement (FujiCEM 2), two conventional dual-cure resin cements (RelyX ARC, Multilink N), and two dual-cure self-adhesive resin cements (RelyX U200, G-CEM LinkAce) were used. To evaluate the influence of the curing methods, each cements divided into four conditions (n = 20); Condition 1: self-curing for 10 minutes, Condition 2: immediate after 20 seconds light-curing, Condition 3: 24 hours after self-curing, Condition 4: 24 hours after light-curing. The compressive strength and diametral tensile strength were measured with a universal testing machine. All data were statistically analyzed using t-test, one-way ANOVA and Scheffe's test. Results: The results showed the compressive strength and diametral tensile strength after 24 hours in all curing modes were higher than immediate except RelyX ARC light-cured and Multilink N light-cured. The FujiCEM 2 showed lowest values (P < 0.05). Conclusion: The outcome was cement-depend, but there is no significant difference about compressive strength and diametral tensile strength between dual-cure self-adhesive resin cements and conventional resin cements. And this result will be used as a base line data selecting resin cement for favorable long-term prognosis.

• The Journal of Korean Academy of Prosthodontics
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• v.43 no.1
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• pp.1-14
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• 2005

Statement of problem. Among the physical properties of adhesion luting cement, the aspect that requires the most important factor is the degree of solubility and water sorption. Dissolution or an inadequate due to excessive water sorption inside the oral cavity compromises the while concurrently increasing the susceptibility to secondary dental caries. Susceptibility to dissolution and difficulty of removing remnant cement from the gingival sulcus have hindered the use of dental resin cement in the clinical practice, but the improved characteristics of newer generation resin cements have interest in and enabled resin cements to be widely used in adhesion of fixed prosthesis, such as laminate veneers and all-ceramic crowns. Purpose. The purpose of this study is to compare and analyze the degrees of solubility and water sorption of a variety of resin cements widely used for clinical purposes with different curing methods. Material and methods. Self-curing resin cements, $Avanto^{(R)}$, $C&B^{TM}$ CEMENT and Superbond C&B cements comprised group 1, 2 and 3. The dual-curing resin cements $Panavian^{TM}$ F, $Calibra^{(R)}$ and $Variolink^{(R)}$ II were divided into groups 4, 5, and 6, respectively. The investigation was carried out using disc-shaped specimens as specified by ANSI/ADA Specification No. 27. The degree of water sorption, water solubility and lactic acid solubility of each test group was analyzed statistically leading to the following conclusion. Results. The degree of water sorption was shown to increase in the following order : group 6, 5, 4, 2, 1 and 3. There were significant differences between the water sorption of each group. Results of the degree of water solubility were shown to increase in the following order : group 6, 5, 4, 2, 1 and 3. Statistically significant differences were found between each group, with the exception of groups 1 and 3. Finally, the degree of lactic acid solubility was found to increase in the following order : group 6,5,4,2,3 and 1. Significant differences were found between each group. In general dual-curing resin cements displayed substantially lower values than self-curing resin cements with regard to water sorption, water solubility, and lactic acid solubility. Conclusions. From the results of this study, dual-curing resin cements show a significantly lower degree of water sorption and solubility than their self-curing counterparts. Clinically, when selecting resin cements, the product with a lower degree of water sorption and solubility are preferred. The results of this study indicate that the use-of dual-curing resin cements is preferable to self-curing cements.

• Restorative Dentistry and Endodontics
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• v.36 no.2
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• pp.132-138
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• 2011

Objectives: The purpose of this study was to evaluate curing degree of three dual-cure resin cements with the elapsed time in self-cure and dual-cure mode by means of the repeated measure of micro-hardness. Materials and Methods: Two dual-cure self-adhesive resin cements studied were Maxcem Elite (Kerr), Rely-X Unicem (3M ESPE) and one conventional dual-cure resin cement was Rely-X ARC resin cement (3M ESPE). Twenty specimens for each cements were made in Teflon mould and divided equally by self-cure and dual-cure mode and left in dark, $36^{\circ}C$, 100% relative humidity conditional-micro-hardness was measured at 10 min, 30 min, 1 hr, 3 hr, 6 hr, 12 hr and 24 hr after baseline. The results of micro-hardness value were statistically analyzed using independent samples t-test and one-way ANOVA with multiple comparisons using Scheffe's test. Results: The micro-hardness values were increased with time in every test groups. Dual-cure mode obtained higher micro-hardness value than self-cure mode except after one hour of Maxcem. Self-cured Rely-X Unicem showed lowest value and dual-cured Rely-X Unicem showed highest value in every measuring time. Conclusions: Sufficient light curing to dual-cure resin cements should provided for achieve maximum curing.

• The Journal of Advanced Prosthodontics
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• v.5 no.4
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• pp.464-470
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• 2013

PURPOSE. The aim of this Fourier transform infrared (FTIR) spectroscopic study was to measure the degree of conversion (DC) of dual-cured resin cements light-irradiated through zirconia ceramic disks with different thicknesses using various light-curing methods. MATERIALS AND METHODS. Zirconia ceramic disks (KT12) with three different thicknesses (1.0, 2.0, and 4.0 mm) were prepared. The light transmittance of the disks was measured using ultraviolet visible near-infrared spectroscopy. Four different light-curing protocols were used by combining two curing light modes (Elipar TriLight (standard mode) and bluephase G2 (high power mode)) with light-exposure times of 40 and 120 seconds. The DCs of the two dual-cured resin cements (Duo-Link and Panavia F2.0) light-irradiated through the disks was analyzed at three time intervals (3, 7, and 10 minutes) by FTIR spectroscopy. The data was analyzed using repeated measures ANOVA (${\alpha}$=.05).Two-way ANOVA and Tukey post hoc test were used to analyze the 10 minute DC results. RESULTS. The 1.0 mm thick disk exhibited low light transmittance (<25%), and the transmittance decreased considerably with increasing disk thickness. All groups exhibited significantly higher 10 minute DC values than the 3 or 7 minute values (P<.05), but some exceptions were observed in Duo-Link. Two-way ANOVA revealed that the influence of the zirconia disk thickness on the 10 minute DC was dependent on the light-curing methods (P<.001). This finding was still valid even at 4.0 mm thickness, where substantial light attenuation took place. CONCLUSION. The curing of the dual-cured resin cements was affected significantly by the light-curing technique, even though the additional chemical polymerization mechanism worked effectively.

• Restorative Dentistry and Endodontics
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• v.25 no.1
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• pp.109-115
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• 2000

This study was designed to evaluate the microhardness of restorative composite resin and dual-cured composite resin cement which were light cured through the 1.5mm thickness composite overlay. For restorative materials, Z100 and Tetric Ceram were used. For dual cured composite cements, Variolink II((VL II) of three consistency (low, high, ultra high) were used. To determine the optimal microhardness of Z100, Tetric Ceram and Variolink II, each material was packed into the 1mm thickness teflon mold without composite overlay and light cured for 60 seconds. Then the microhardnesses of each sample were measured, averaged and regarded as optimal hardness of each material. To evaluate the microhardness of restorative composite resin and dual-cured composite resin cement which were light cured through the 1.5mm thickness composite overlay, the composites were packed into 1mm thickness teflon mold, coverd with celluloid strip, and then precured composite overlay which was made of Targis(Ivoclar/Vivadent, Liechtenstein) was positioned. 2 types of visible light curing machine, the power density of one of which was 400$mW/cm^2$ and the other was 900$mW/cm^2$, and one type of argon laser were used to cure the restorative composite and dual cured cement. For each group, 10 sample were assigned. The light curing tip was positioned over the composite overlay and light cured for 1min., 2min. or 3min with visible light curing machine or 15sec, 30 sec, 45sec, and 60 sec with argon laser. The Vickers hardnesses of upper and lower surface of Z100, Tetric Ceram, and 3 types of VL II cement were measured. When the 900 $mW/cm^2$ curing light was used, 2min. was needed for optimal curing of Z100 and Tetric Ceram. Variolink II did not be cured optimally even though the curing time was extended to 3min. When 400$mW/cm^2$ curing light was used, 3min. was necessary for Z100, whereas 3min. was not enough for Tetric Ceram. Variolink II was not cured optimally even though the curing time was extended to 3min. When argon laser was used, Z100, Tetric Ceram and Variolink II were not cured optimally in 60 seconds.

• Journal of Adhesion and Interface
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• v.13 no.1
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• pp.31-37
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• 2012

In this study, we investigated the curing properties of UV-LED curable color coating. Specially, the effects of UV-LED wavelength (365, 395, and 405 nm), inert gas, the concentration of photosensitizer, and dual curing on the curing behavior of UV-LED coating systems were studied. The photopolymerization behaviors and the unreacted acrylate groups at Film-air (FA) interface and Film-substrate (FS) interface were investigated by photo differential scanning calorimetry (Photo-DSC) and Fourier-transform infrared spectroscopy with attenuated total reflection (FT-IR/ATR), respectively. Photo-DSC results showed that the heat flow and the ultimate conversion for coating system cured by 405 nm UV-LED were higher than the corresponding values for coating systems cured by 395 and 365 nm UV-LED. FT-IR/ATR results showed that the UV-LED curing systems improved interior and through curing of the coating film, but significantly are affected by oxygen inhibition at FA-interface. The inert environment such as nitrogen purging and the dual curing improved the surface and interior curing of the coating films.

• Journal of the Korean Wood Science and Technology
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• v.38 no.4
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• pp.333-340
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• 2010

The Korean Dendropanax lacquer, made from a natural resinous sap from Dendropanax orbifera Lev., was used as a golden and transparent varnish for the traditional artifacts (armor uits, helmets, arrowheads, etc.) to make them be brilliant golden color. The cured film of the acquer has excellent protective properties such as weatherability, water resistance, and nticorrosive. But, one of disadvantages is that takes a long time and much energy to fulfill curing the lacquer. The chemical constituents of the lacquer contained conjugated diene compounds s the photopolymerizable monomers. These monomers easily polymerized in sunlight to form olden-colored, hard-coating films in a short time. Photooxidation may be one of the most mportant reactions in the chemistry of the lacquer. Although the Korean Dendropanax Lacquer hould be dried to a thoroughly dry stage to achieve optimal film properties, curing with elevated emperatures may be required for the protracted curing time at atmospheric temperature. So we ntended to accelerate the curing rate of the lacquer by dual curing of thermal and radiation uring. The effect of thermal initiator on the thermal curing reaction was evaluated by monitoring he changes in double bond peak with FT-IR. Then the curing rate of the lacquer blended with hermal initiator and photoinitiator together was measured during dual curing using a RPT with V spot curing machine. Thermal initiator not only accelerated the curing rate but also improved he physical property. And the curing rate of the Korean Dendropanax lacquer was improved by ual curing method of thermal and UV curing. According to these results, the application area of he Korean Dendropanax lacquer could be expanded to surface coatings for electronic devices uch as mobile phones or electronics.