• Title/Summary/Keyword: Dry deposition

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The Concentration of Polychlorinated biphenyls and Bozenehexachlorides in Plants (식물 중 PCBs와 BHCs의 농도)

  • 최민규;김희강;천만영;김태욱;여현구;선우영
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.11a
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    • pp.94-95
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    • 2000
  • PCBs(polychlorinated biphenyls)와 BHCs(benzene hexachlorides)와 같은 SOCs(semivolatile organic compounds)는 모든 대륙에서 검출되어지고 있으며, 심지어 장거리 수송에 의해 청정지역인 북극에서도 검출되고 있다. 이들 성분들은 친지질성(lipophilic)으로 대부분이 가스상으로 존재하여 식물의 표면에 존재하는 지질(lipid)에 건성침착(dry deposition) 또는 습성 침착(wet deposition)된다. 이렇게 침착된 성분들의 농도는 대기중 농도와 밀접한 관계가 있다고 보고되고 있다(천만영,1998; Simonich and Mites, 1995). (중략)

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Comparison of Chemical Characteristics between Rain and Snow on the Western Coast of Korea (서해안 지역 강우와 강설의 화학적 특성 비교)

  • 강공언;방소영;신대윤
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2001.11a
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    • pp.443-444
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    • 2001
  • 대기오염물질이 대기중에 배출되게 되면 그 일부는 오염 발생원의 인접한 지표면에 건성 침착하여 제거되지만 그 대부분은 장거리 이동하면서 2차 오염물질로 변환되어 건성침착 (dry deposition)하거나 강수시 습성 침착 (wet deposition)에 의해 지표면으로 제거된다 (원 굉, 1991, Legge and Krupa, 1990). 습성침착의 대표적인 형태로는 강우와 강설이 있으며, 이것은 대기중 오염물질이 지표로 제거되는 중요한 경로라 하겠다. (중략)

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Dry Cleaning of Si Contact Hole using$UV/O_3$ Method ($UV/O_3$을 이용한 Si contact hole 건식세정에 관한 연구)

  • 최진식;고용득;구경완;김성일;천희곤
    • Electrical & Electronic Materials
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    • v.10 no.1
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    • pp.8-14
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    • 1997
  • The UV/O$_{3}$ dry cleaning has been well known in removing organic molecules. The UV/O$_{3}$ dry cleaning method was performed to clean the Si wafer surfaces and contact holes contaminated by organic molecules such as residual PR. During the cleaning process, the Si surfaces were analyzed with X-ray photoelectron spectroscopy (XPS), atomic force microscope (AFM) and ellipsometer. When the UV/O$_{3}$ dry cleaning at 200'C was performed for 3 minutes, the residual photoresist was almost removed on Si wafer surfaces, but Si surfaces were oxidized. For UV/O$_{3}$ application of contact hole cleaning, the contact string were formed using the equipment of ISRC (Inter-university Semiconductor Research Center). Before Al deposition, UV/O$_{3}$ (at 200.deg. C) dry cleaning was performed for 3 minutes. After metal annealing, the specific contact resistivity was measured. Because UV/O$_{3}$ dry cleaning removed organic contaminants in contact holes, the specific contact resistivity decreased. Each contact hole size was different, but the specific contact resistivities were all much the same. Thus, it is expected that the UV/O$_{3}$ dry cleaning method will be useful method of removal of the organic contaminants at smaller contact hole cleaning.

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Characteristics of Atmospheric Dry Deposition of Nitrogen-containing Compounds (대기 중 질소산화물의 건식침적 특성)

  • Yi, Seung-Muk;Han, Young-Ji;Cheong, Jang-Pyo
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.4
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    • pp.775-784
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    • 2000
  • Nitrate dry deposition fluxes were directly measured using knife-leading-edge surrogate surface (KSS) covered with greased strips and a water surface sampler (WSS). The average gaseous flux ($8.3mg/m^2/day$) was much higher than the average particulate one ($3.0mg/m^2/day$). The best fit gas phase mass transfer coefficient (MTC) of $HNO_3$ was obtained by linear regression analysis between measured gaseous flux containing nitrogen compounds and measured ambient $HNO_3$ concentration. The result showed that the MTCs of $HNO_3$ were approximately two times higher than those of $SO_2$. Especially, during the ozone action day, measured gaseous fluxes containing nitrogen compounds were much higher than those ones calculated as the product of measured ambient $HNO_3$ concentration and gas phase MTC of $HNO_3$, which is calculated from MTC of $SO_2$ using Graham's diffusion law. This result indicated that other nitrogen compounds except $HNO_3$ contributed to gaseous flux containing nitrogen compounds into the water surface sampler. The theoretical calculations suggest the contributions of nitrous acid ($HNO_2$) and PAN to the gaseous dry deposition flux of nitrogen containing compounds to the WSS.

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Deposition flux of dioxin-like polychlorinated biphenyls(DLPCBs) in urban environment of Busan (도심 지역의 다이옥신류 폴리염화비페닐류의 침적 플럭스)

  • Mun, Hyo-Bang;Lee, Su-Jeong;Choe, Hui-Gu;Ok, Gon
    • Journal of Environmental Science International
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    • v.13 no.5
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    • pp.469-478
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    • 2004
  • Atmospheric bulk (wet and dry) samples were monthly collected in an urban environment (Daeyeon-dong) of Busan over a year, to assess the deposition flux and seasonality of dioxin-like polychlorinated biphenyls (DLPCBs) using stainless steel pots. Deposition fluxes of DLPCBs in bulk samples were determined using high resolution gas chromatography coupled to high resolution mass spectrometry (HRGC/HRMS). Particle deposition fluxes in the urban environment varied from 23 to 98 $mg^2$/year (mean 41 $gm^2$/year). DLPCB deposition fluxes in atmospheric bulk samples ranged from 0.09 to 0.77 ng-$TEQ/m^2$/year (mean 0.35 ng-$TEQ/m^2$/year). Seasonal atmospheric deposition fluxes of DLPCBs were high in winter and low in summer. Atmospheric deposition fluxes of particles and DLPCBs in this study were comparable to or slightly lower values than those of different locations in the world. Monthly DLPCB profiles in deposition bulk samples were similar over a year. Non-ortho PCBs were higher contributions to the total DLPCBs fluxes than mono-ortho PCBs. In particular, PCB 126 had the highest concentrartion (>75%) in all deposition samples, followed by PCB 169 and PCB 156. A highly positive correlation was found among the deposition fluxes of DLPCB species, suggesting the possibility of that the DLPCB contamination originated from one source. The deposition fluxes of DLPCBs were not significantly correlated with temperature and the amount of precipitation even though the summer season with the highest temperature and the largest amount of precipitation showed the lowest DLPCB deposition flux.

Prediction of radioactivity releases for a Long-Term Station Blackout event in the VVER-1200 nuclear reactor of Bangladesh

  • Shafiqul Islam Faisal ;Md Shafiqul Islam;Md Abdul Malek Soner
    • Nuclear Engineering and Technology
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    • v.55 no.2
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    • pp.696-706
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    • 2023
  • Consequences of an anticipated Beyond Design Basis Accident (BDBA) Long-Term Station Blackout (LTSBO) event with complete loss of grid power in the VVER-1200 reactor of Rooppur Nuclear Power Plant (NPP) of Unit-1 are assessed using the RASCAL 4.3 code. This study estimated the released radionuclides, received public radiological dose, and ground surface concentration considering 3 accident scenarios of International Nuclear and Radiological Event Scale (INES) level 7 and two meteorological conditions. Atmospheric transport, dispersion, and deposition processes of released radionuclides are simulated using a straight-line trajectory Gaussian plume model for short distances and a Gaussian puff model for long distances. Total Effective Dose Equivalent (TEDE) to the public within 40 km and radionuclides contribution for three-dose pathways of inhalation, cloudshine, and groundshine owing to airborne releases are evaluated considering with and without passive safety Emergency Core Cooling System (ECCS) in dry (winter) and wet (monsoon) seasons. Source term and their release rates are varied with the functional duration of passive safety ECCS. In three accident scenarios, the TEDE of 10 mSv and above are confined to 8 km and 2 km for the wet and dry seasons, respectively in the downwind direction. The groundshine dose is the most dominating in the wet season while the inhalation dose is in the dry season. Total received doses and surface concentration in the wet season near the plant are higher than those in the dry season due to the deposition effect of rain on the radioactive substances.

Estimation of Deposition Rates of Dustfall and Metallic Elements in Kunsan (군산지역의 강하분진 및 금속원소의 침착속도 추정)

  • 김성천
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.5
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    • pp.431-443
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    • 2000
  • The purpose of this experimental study is to investigate seasonal deposition flux variations and deposition velocities of the total dusfall and various inorganic elements in it. Total 41 dustfall and TSP samples were collected from November, 1997 through December, 1998 in Kunsan. Each sample was analyzed by and AAS to determine he levels of 5 inorganic elements: Zn, Cd, Cr, Fe and Pb. Deposition fluxes, soluble/total fractions and deposition velocities for each element were extensively investigated. Estimated dry deposition fluxes of dustfall and elements in Kunsan were in the range of 14.6~48.8(mean 25.6) ton/$\textrm{km}^2$/yr for dustfall, 14.5~72.6(mean 44.1)kg/$\textrm{km}^2$/yr for Zn, 0.9~0.5(mean 3.0) kg/$\textrm{km}^2$/yr for Cd, 2.1~239.2(mean 63.9) kg/$\textrm{km}^2$/yr for Cr, 331.6~1,082.7(mean 873.9) kg/$\textrm{km}^2$/yr for Fe, 5.2~178.4(mean 49.2) kg/$\textrm{km}^2$/yr for Pb, respectively. And the concentra-tion of TSP and elements in Kunsan were 71$\mu\textrm{g}/m^3$ for TSP, $29.9ng/m^3$ for Zn, $0.6ng/m^3$ for Cd, $0.1 ng/m^3$ for Cr, $1,061.0 ng/m^3$ for Fe, $4.0 ng/m^3$ for Pb, respectively. And the estimated deposition velocity of dustfall and elements in Kunsan were 1.13$\times$ 10(sup)-2 cm/sec for dustfall, 4.67$\times$ 10(sup)-2 cm/sec for Zn, 16.92 cm/sec for Cd, 15.69 cm/sec for Cr, 1.72$\times$ 10(sup)-2 cm/sec for Fe, 0.36 cm/sec for Pb, respectively.

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A Study of The Photosensitive Characteristic and Fabrication of Polyimide Thin Film by Dry Processing (건식법을 이용한 폴리이미드 박막의 제조 및 광특성)

  • Lee, Boong-Joo
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.56 no.1
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    • pp.139-141
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    • 2007
  • Thin films of polyimide (Pl) were fabricated by a vapor deposition polymerization method (VDPM) and studied for the photosensitive characteristic. Polyamic acid (PAA) thin films fabricated by vapor deposition polymerization (VDP) from 6FDA and 4-4' DDE were converted to PI thin films by thermal curing. From AFM and Ellipsometer experimental, the films thickness was decreased and the reflectance was increased as the curing temperature was increased. Those results implies that thin film is uniform. From UV-Vis spectra, PI thin films showed high absorbance in 225 $\sim$ 260 [nm] region.

Nanocatalyst Materials Prepared by Arc Plasma Deposition (아크플라즈마 증착을 이용한 나노촉매 재료 제작)

  • Kim, Sang Hoon
    • Applied Chemistry for Engineering
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    • v.25 no.4
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    • pp.341-345
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    • 2014
  • Catalyst nanoparticles are prepared by arc plasma deposition (APD). First, overview of the APD technique is reviewed and second, some applications of the technique for nanocatalyst preparation are reviewed. Nanoparticles prepared by APD are typically 1~5 nm in size and their catalytic activity is generally better than that of conventional wet-chemically prepared nanocatalysts.

Preparation and Permeation Characteristics of Alumina Composite Membranes by CVD and Evaporation-Oxidation Process (화학증착 및 증발-산화법에 의한 알루미나 복합분리막의 제조 및 투과특성)

  • 안상옥;최두진;현상훈;정형진;유광수
    • Journal of the Korean Ceramic Society
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    • v.30 no.8
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    • pp.678-684
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    • 1993
  • Alumina composite membranes were prepared by chemical vapor deposition and evaporation-oxidation process. For CVD process, deposition was carried out using aluminum-tri-isopropoxide at 35$0^{\circ}C$, 2 torr by heterogeneous reaction, and for evaporation-oxidation process, alumina composite membranes were prepared by evaporation of aluminum and dry oxidation at 80$0^{\circ}C$. As deposition time increases, water flux and N2 gas permeability of the composite membranes prepared by both processes were reduced. Applying gas permeation model, permeability and cracking possibility of top layer were evaluated.

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