• Title/Summary/Keyword: Dry Chemistry

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Optimization of Process Parameters for Dry Film Thickness to Achieve Superior Water-based Coating in Automotive Industries

  • Prasad, Pranay Kant;Singh, Abhinav Kr;Singh, Sandeep;Prasad, Shailesh Kumar;Pati, Sudhanshu Shekher
    • Corrosion Science and Technology
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    • v.21 no.2
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    • pp.121-129
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    • 2022
  • A study on water-based epoxy coated on mild steel using the electroplating method was conducted to optimize the process parameters for dry film thickness to achieve superior paint quality at optimal cost in an automotive plant. The regression model was used to adjust various parameters such as electrode voltage, bath temperature, processing time, non-volatile matter, and surface area to optimize the dry film thickness. The average dry film thickness computed using the model was in the range of 15 - 35 ㎛. The error in the computed dry film thickness with reference to the experimentally measured dry film thickness value was - 0.5809%, which was well within the acceptable limits of all paint shop standards. Our study showed that the dry film thickness on mild steel was more sensitive to electrode voltage and bath temperature than processing time. Further, the presence of non-volatile matter was found to have the maximum impact on dry film thickness.

Charge Transfer between STM Tip and Au(100) in Dry, H2O, and D2O Atmospheres

  • Utami, Anggi;Chung, Yonghwa;Lee, Chi-Woo
    • Journal of Electrochemical Science and Technology
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    • v.4 no.4
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    • pp.153-156
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    • 2013
  • Charge transfer between STM tip and Au(100) has been investigated by using a Scanning Tunneling Microscopy (STM) technique in dry, $H_2O$, and $D_2O$ atmospheres. Dry atmosphere was indicated by humidity as low as 5 % and high humidity as high as 98% was managed by injecting $H_2O$ and $D_2O$ to the chamber. The current decayed more slowly in high humidity than in dry atmosphere. The plateau currents were found to appear at separations larger than ca. $5{\AA}$ where the current decay stopped depending on applied bias voltages. The polarity dependence was observed at the STM junction between Pt-Ir tip and the gold. On the contrary, little dependence was seen at the one between Au tip and the substrate electrode.

Performance of MPS Bacterial Inoculation in Two Consecutive Growth of Maize Plants

  • Park, Myung-Su;Gadagi, Ravi;Singvilay, Olayvanh;Kim, Chung-Woo;Chung, Hee-Kyung;Ahn, Ki-Sup;Sa, Tong-Min
    • Korean Journal of Environmental Agriculture
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    • v.20 no.5
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    • pp.335-339
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    • 2001
  • Two successive in vitro experiments were carried out to examine the effect of MPS bacterial inoculation on growth, and nitrogen and phosphorus accumulation of maize plants under greenhouse condition in the same soil. There were four treatments, uninoculated control and three phosphate solubilizing bacterial inoculations, viz., Pseudomonas striata, Burkholderia cepacia and Serratia marcescens. The inoculated plants showed the higher plant height, total dry mass, nitrogen and phosphorus accumulation when compared to uninoculated control plants in both experiments. In the combined data analysis from two experiments, the plants inoculated with P. striata and B. cepacia showed significantly higher plant height, total dry mass and P accumulation when compared to S. marcescens inoculated plant and uninoculated control plants. The P. striata and B. cepacia inoculation enhanced total dry matter accumulation by 14% and phosphorus accumulation by 25% over the uninoculated control plants. The nitrogen and phosphorus concentration of maize plants were also increased due to MPS bacterial inoculation, however, the effect was not significant.

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Roles of Azospirillum spp. Inoculation in Two Consecutive Growth of Maize Plants

  • Choi, Seung-Ju;Gadagi, Ravi;Park, Myung-Su;Yang, Jin-Chul;Sa, Tong-Min
    • Korean Journal of Environmental Agriculture
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    • v.21 no.1
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    • pp.74-79
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    • 2002
  • Two consecutive green house experiments were carried out to examine the effect of Azospirillum spp. inoculation on growth, nitrogen and phosphorus accumulation in maize plants grown in pots. There were eight treatments including an uninoculated control and Azospirillum strains OAD-3, OAD-9, AZ-22, AZ-8, AZ-9, Azospirillum brasilense BR-11001 and Azospirillum lipoferum BR-11080. The inoculated plants showed higher values in each of the following measurements; plant height, total dry mass and nitrogen and phosphorus accumulation in shoot when compared to the uninoculated control plants in two consecutive experiments conducted in the same soil. Among Azospirillum strains, Azospirillum sp. OAD-3 inoculated plants showed higher nitrogen accumulation by 44.5% and 45.1%, total dry mass by 48.6% and 66.9% in two consecutive experiments respectively. The nitrogen concentration in the maize plants was not changed significantly in the first experiment, however it increased significantly in the second experiment due to Azospirillum inoculation. In addition, Azospirillum sp. OAD-9 and A. brasilense BR-11001 also proved to be effective with respect to total dry mass, total nitrogen accumulation and total phosphorus accumulation. The nitrogen concentrations in maize plants were increased in the second experiment due to Azospirillum inoculation.

Effect of co-inoculation of Brevibacterium iodinum RS16 and Methylobacterium oryzae CBMB20 on the early growth of crop plants in Saemangeum reclaimed soil

  • Kim, Kiyoon;Kwak, Chaemin;Lee, Youngwook;Sa, Tongmin
    • Korean Journal of Soil Science and Fertilizer
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    • v.47 no.1
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    • pp.1-7
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    • 2014
  • The objective of this study was to determine the effect of single and co-inoculation of plant growth promoting bacteria (PGPB) on early plant growth in Saemangeum reclaimed soil. Plant growth promoting Brevibacterium iodinum RS16 and Methylobacterium oryzae CBMB20 were inoculated on maize (Zea mays L.) and sorghum-sudangrass hybrid (Sorghum bicolor L.) grown in Saemangeum reclaimed soil. Single and co-inoculation of B. iodinum RS16 and M. oryzae CBMB20 increased plant height, dry biomass accumulation and macro-nutrient accumulation of maize and sorghum-sudangrass hybrid. M. oryzae CBMB20 treatment increased plant height in maize by 41.2% at 30 days after sowing (DAS), shoot dry weight and total dry weight compared to non-inoculated treatment. Macro-nutrient accumulation (N and P) in maize roots was significantly increased with co-inoculation treatment, K and Ca content was significantly increased at B. iodinum RS16 treatment compared to non-inoculated treatment. Macro-nutrient accumulation (P, K, Ca and Mg) in shoot was higher with M. oryzae CBMB20 treatment compared to non-inoculated treatment. In case of sorghum-sudangrass hybrid, co-inoculation treatment showed 33.7% increase in plant height compared to non-inoculated treatment at 30 DAS. M. oryzae CBMB20 treatment increased root dry weight and total dry weight, macro-nutrient accumulation in roots and N, Ca and Mg accumulation in shoot compared to non-inoculated treatment. P and K accumulation in shoot was significantly increased at co-inoculation treatment compared to non-inoculated treatment. This pot culture experiment demonstrated that single and co-inoculation of B. iodinum RS16 and M. oryzae CBMB20 increased the early growth and nutrient accumulation of maize and sorghum-sudangrass hybrid.

Investigation of Coke Formation in Dry Methane Reforming over Nickel-based Monolithic Catalysts

  • Pornruangsakun, Pongsakorn;Tungkamani, Sabaithip;Ratana, Tanakorn;Phongaksorn, Monrudee;Sornchamni, Thana
    • International Journal of Advanced Culture Technology
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    • v.3 no.1
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    • pp.31-38
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    • 2015
  • Coking accumulations via dry methane reforming (DMR) over 10NAM monolithic catalyst and pelletized catalyst was investigated. 10NAM catalyst was synthesized and coated on a wall of monolithic reactor. Pelletized catalyst of 10NAM was also prepared for the comparison. Consequently, catalyst was characterized by BET, $H_2-TPR$ and $H_2-TPD$. The catalytic reaction was undergone at $600^{\circ}C$ under atmospheric pressure and $CH_4$ to $CO_2$ reactant ratio of 1:2. The coking formation over spent catalyst was then carried out in the hydrogen flow using temperature programmed technique (TPH). According to the results, DMR over 10NAM monolithic catalyst exhibits a minimized coking formation comparing to the use of pelletized catalyst. This could be attributed to a prominent heat transfer efficiency of the monolithic catalyst.

The Effect of K Promoter on Ni-Co (Bimetallic) Catalyst for Dry Methane Reforming

  • Dharmasaroja, Nichthima;Phongaksorn, Monrudee;Tungkamani, Sabaithip;Ratana, Tanakorn;Sornchammi, Thana
    • International Journal of Advanced Culture Technology
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    • v.3 no.2
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    • pp.110-117
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    • 2015
  • 10 wt% (Ni-Co) catalysts with different Ni and Co content : 10%Ni, 9%Ni1%Co, 7%Ni3%Co, 5%Ni5%Co, 3%Ni7%Co, and 10%Co; were prepared using sol-gel method followed by incipient wetness impregnation method. To investigate the catalytic activity including the stability, dry methane reforming were demonstrated over the pelletized catalysts at $620^{\circ}C$ under atmospheric pressure in a $CH_4:CO_2:N_2$ feedstock for 360 min. The results showed that bimetallic catalysts with the Co content equal to or greater than 3% were more stable than monometallic catalysts (10%Ni and 10%Co). The temperature programmed hydrogenation interpreted that the additional of Co into Ni catalyst improved the carbon resistance from methane cracking. Promoted this type of bimetallic catalyst using 1wt% K (trimetallic catalyst) prevented the carbon formation on the catalyst. The temperature programmed desorption of $CO_2$ indicated that this trimetallic catalyst has a greater number of strong basic sites. Moreover, the appearance of K lowered the number of weak basic sites and decreased the conversion of methane by 12 %.