With the 1 ton/day-class entrained-bed gasification system, heavy residual oil from local refinery was gasified at the operating conditions of 1,000~1,20$0^{\circ}C$ and 3 $kg_f$/$\textrm{cm}^2$ in order to determine the variation of syngas composition, carbon conversion, and cold gas efficiency. Produced syngas consists of mainly CO, H$_2$, $CO_2$, and the methane concentrations. Results yielded a maximum syngas composition of 45% H$_2$ and 26%, CO at the 31 kg/hr feeding condition. The maximum carbon conversion and cold gas efficiency were 87% and 68%, respectively at the feeding conditions of 20 kg/hr and oxygen/feed ratio of 1.2. When oxygen feeding amount that is one of the most important operating parameter in gasification was increased, concentration of hydrogen in the syngas is greatly increased comparing to the concentration of CO and $CO_2$. The temperature exhibited about 11$0^{\circ}C$ raise while oxygen/feed ratio changed from 0.6 to 1.2. Methane concentration showed enhanced dropping rate with increase in gasifier temperature and the useful relationship between the gasifier temperature and methane concentration existed such that it can be employed as an indirect measure of inside gasifier temperature.
Journal of the Korean Society of Marine Environment & Safety
/
v.28
no.6
/
pp.946-954
/
2022
More than half of barges have been surveyed and designated as an "unmanned barge". The main advantage of the unmanned barge is that it can carry more cargo equivalent to 25 percent of freeboard compared to that of a manned barge. In contrast, it needs an onboard crew barge because the bargeman is in charge of several tasks during sailing such as mooring or unmooring barges to or from a wharf, dropping and heaving up an anchor and turning on and of navigational lights and shapes. The instant recognition is that a tug assume the responsibility of operating a barge; however, different situations exist in which the shipper, as the operator of the barge, hires a tug. Although a tug might be a carrier of a barge under a specific contract, the master of the tug should fulfill his duty to complete its voyage. Most masters are not provided with the particulars of a barge and the information regarding the bargemen onboard, which is believed not to respect the master's authority and lead to an unintended violation of relevant laws. This paper presents three recommendations for resolving these issues: the policy approach for changing unmanned barges to manned barges, issuing a minimum safe manning certificate, and providing the master of tug information on the barge and the crew onboard. Thus, the proposed approach can be expected to improve the crew's working conditions, diminish the violation of the maximum number of persons onboard the barge, and ensure the authority of the master of tug through such recommendations.
Lee K. H.;Chung H. W.;Lee W. K.;Lee S. C.;Kim Y. S.
Korean journal of applied entomology
/
v.4
/
pp.33-38
/
1965
1. This survey was conducted to make a basis for the cause of severe epidemic and disease control to the losses due to bacterial leaf blight of rice in Chun-Nam rice paddy field areas in the first part of October in 1965. The severe epidemic areas were included Taijun-Myun, Tamyang-Eup, riverside in Youngsanpo and seaside in the suburbs of Mokpo. 2. A drought in the period of rice transplanting and flooding due to a heavy rain in July were resulted reasonable weather conditions that the disease occurred more early and severe epidemic. 3. In Tamyang area, frist outbreak of the disease was on the middle part of July in the paddy flooded after heavy rainfall of the first fart of July. It is recognized to farmers that the disease is known as a now serious one. 4. The more date of transplanting is followed, the more serious damage is happened and especially, in the paddy field flooded, too. 5. Flooded areas showed more serious epidemic. 6. Varietal difference to the disease was surely noticed, and Kumnampoong and Chunbonwuk were susceptible, whereas Norin 6 was resistant. 7. Damage was occurred more in plant paddy area than tile slopping paddy area. 8. Fallow paddy field was more serious than the field using double cropping a year. 9. Moist and semimoist paddy field were more serious damage, while light damage in dry paddy field. 10. Near part of flood gate for drainage of submerge paddy was more serious damage than inside part of the field. 11. Soft type is often seen in the mode of the disease occurrences. 12. The most farmers insisted that dropping water is caused to promote disease dissemination when disease occurred.
Jung, Jong Hwa;Chang, Duk Jin;Lee, Bu-Yong;Seo, Mu Ryong;Kim, Jae Sang;Lee, Shim Sung
Analytical Science and Technology
/
v.5
no.3
/
pp.239-247
/
1992
The complexations and selectivities of the 10 species of mono- and dimethylsubstituted anilinium ions with 18-crown-6 in methanol are examined at dropping mercury electrode. The stability constants of these complexes varies drastically due to the steric hindrance by the positions and numbers of methyl groups. And the analyses of the isomeric mixtures of methylanilinium, which are impossible to detect due to the overlapped peaks in normal conditions, were also accomplished by the additions of 18-crown-6 as the supporting complexing agent using the selective complexations by the steric hindrance effects. As results in case of the difference of stability, ${\Delta}log\;K$ were about 0.7~1.3, it was possible to confirm the existence of two species qualitatively. Otherwise when ${\Delta}log\;K$ were large than 1.6, the quantitative determinations of each species could be accomplished sucessfully. From these results it is deduced that the selective recongnition of the positions and numbers of methyl groups as the steric hindrance in anililniums by 18-crown-6 cause the large variation of the magnitudes of negative shift of reduction waves for guest ions in mixtures.
Kim Kyeong-Su;Song Young-Suk;Cho Yong-Chan;Kim Won-Young;Jeong Gyo-Cheol
The Journal of Engineering Geology
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v.16
no.2
s.48
/
pp.201-214
/
2006
To study the relationship between rainfall conditions and landslides according to a geological condition in land-slides areas such asJangheung Kyounggi, Sangju and Pohang Kyoungbuk, the data of rainfall and landslides are investigated and analyzed. Many landslides occurred at these areas because of the heavy rainfall in two or four days of the summer 1998. The data of rainfall are collected in observatories within a 50km radius from landslides occurrence areas, and the data of landslides are investigated directly in landslides areas. The data of rainfall are the accumulative rainfall and the rainfall intensity, and the data of landslides are the occurrence frequency considering the geological condition. These data are analyzed statistically to know the relationship the rainfall and landslides. The landslides are concentrated in the heavy rainfall area from the analysis of these data. It knows that the land-slides are triggered by the heavy rainfall. Meanwhile, the rainfall factors such as the accumulative rainfall, the rain-fall intensity and the dropping time are different in each landslides area, and the shape and frequency of landslides are different respectively. The landslides have occurred in the area of high accumulative rainfall, while the land-slides have not occurred around that area. Therefore, the rainfall is very important factor induced by the landslides, and the accumulative rainfall is really related to the frequency of landslides.
Journal of the Korean Applied Science and Technology
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v.38
no.2
/
pp.476-487
/
2021
To prepare acrylic resin coatings containing 70% of solids, we used n-butyl methacrylate(BMA), methyl methacrylate(MMA), 2-hydroxyethyl methacrylate(2-HEMA), and acetoacetoxyethyl acrylate(AAEA), caprolactone acrylate(CLA) as raw materials, the glass transition temperature(Tg) of acrylic copolymer was adjusted around 50 ℃. The viscosity and molecular weight of the acrylic resins was increased with increasing OH values. Di-tert-amyl peroxide was found to be the suitable initiator to get high-solids acrylic resins. The optimum reaction conditions found in the study are 5 wt% of initiator, 4 wt% of chain transfer agent, 4 hrs of dropping time, and 140 ℃ of reaction temperature. The structure of the synthesized resins were characterized by FT-IR and 1H-NMR spectroscopy. Number average molecular weight of 1900~2600 and molecular wight distribution of 1.4~2.1 were obtained. Crosslinked acrylic urethane clear coatings were obtained by curing reaction between the synthesized acrylic resins and hexamethylene diisocyanate trimer(Desmodur N-3300), the equivalent ratio of NCO/OH was 1.2/1.0. The physical properties from the following studies were carried out: viscosity(Zahn cup #2), adhesion, drying time, pot-life, pensil hardness, and 60° specular gloss. Various properties of the acrylic urethane clear coatings were also evaluated on the coating specimens. Adhesion property to a substrate, drying time, pot-life, pencil hardness, and 60° specular gloss of prepared paint showed quite good properties. Futhermore, prepared paint containing 10% of CLA showed quite good properties for adhesion, low viscosity and high hardness.
Kim, Dae-Hyun;Park, Jong-Han;Lee, Jung-Sup;Han, Kyung-Sook;Han, You-Kyoung;Hwang, Jeong-Hwan
Research in Plant Disease
/
v.15
no.3
/
pp.187-192
/
2009
Pepper powdery mildew, Leveillula taurica is one of the most important pathogens of pepper in the greenhouses and fields in Korea and is becoming a worldwide disease. These experiments were carried out to investigate the optimal germination, disease development conditions, disease incidence and effective inoculation methods of pepper powdery mildew. The incidence of powdery mildew was investigated throughout the country based on the major pepper growing areas in 2009. The average rate of infected leaves ranged from 15.3% to 81.8% in greenhouses and fields. Powdery mildew incidences were more severe in greenhouses than those of fields. The optimal temperature for conidial germination was $25^{\circ}C$ and showed the highest germination at 6 hs after treatment. The range of temperature for germination was $10^{\circ}C$ to $35^{\circ}C$. Temperature of greater than $30^{\circ}C$ and below $20^{\circ}C$ affected the abnormal germination and germ tube elongation. The optimal relative humidity for germination and germ tube elongation was 85% and germination increased as relative humidity increased. Disease development started 8 days after inoculation and showed the highest disease severity at 15 days in greenhouse and field regardless of varieties. Among three different inoculation methods tested the spore dropping method was better than touching with infected leaves and spraying with spore suspension. However, the method has limitation in mass inoculation due to the amount of time consumed.
To reduce the environmental pollution by $NO_x$ from ship engine, International maritime organization (IMO) announced Tier III regulation, which is the emmision regulation of ship's exhaust gas in Emission control area (ECA). Selective catalytic reduction (SCR) process is the most commercial $De-NO_x$ system in order to meet the requirement of Tier III regulation. In generally, commercial ceramic honeycomb SCR catalyst has been installed in SCR reactor inside marine vessel engine. However, the ceramic honeycomb SCR catalyst has some serious issues such as low strength and easy destroution at high velocity of exhaust gas from the marine engine. For these reasons, we design to metallic structured catalyst in order to compensate the defects of the ceramic honeycomb catalyst for applying marine SCR system. Especially, metallic structured catalyst has many advantages such as robustness, compactness, lightness, and high thermal conductivity etc. In this study, in order to support catalyst on metal substrate, coating slurry is prepared by changing binder. we successfully fabricate the metallic structured catalyst with strong adhesion by coating, drying, and calcination process. And we carry out the SCR performance and durability such as sonication and dropping test for the prepared samples. The MFC01 shows above 95% of $NO_x$ conversion and much more robust and more stable compared to the commercial honeycomb catalyst. Based on the evaluation of characterization and performance test, we confirm that the proposed metallic structured catalyst in this study has high efficient and durability. Therefore, we suggest that the metallic structured catalyst may be a good alternative as a new type of SCR catalyst for marine SCR system.
Mountainous wetland have many species such as II grade endangered species of wild flora and fauna(Drosera rotundifolia) and environmental indicator species(Utricularia racemosa, Habenaria linearifolia, Parnassia palustris, Molinia japonica, etc.). Accordingly, the mountainous wetlands is very important. However, most mountainous wetlands will disappear by natural or artificial aridness processes. Thus, it needs to manage mountainous wetland for protecting from aridness. This study has found out the wetland status of the environmental ecology and aridness processes moreover, it has suggested ways of improving wetland conservation plan and wetland aridness management plan. According to the results of topography structure survey, Hwaeom wetland's altitude is ranged within 750~810m(87.4%), and slope is less than $10^{\circ}$. There was ideally suited mountainous wetland. However, the water supply(1.6 meters depth and 0.8 meters wide) was built on under the wetland. For that reason, there was concerned about the aridness processes by sweeping away peat layer and dropping the water level. The distribution area of hygrophyte was narrowed to 6.7% whereas, woody plants and xerophytic plants was achieved a dominant position. If it leaves the situation as it is, the mountainous wetland will be developed next succession as forest ecosystem. Therefore, in order to sustain the mountainous wetland from aridness, it is set to the base direction of conservation and management as main schemes. Moreover, we have suggested that setting the vegetation conservation and management area which considering a ecological vegetation characteristics, managing the ecotone vegetation, setting the buffer zone for protection of ecological core areas, protecting the mountainous wetland indicator species and designating the management vegetation. In conclusion, in order to sustain and maintain a soundly wetland ecosystem, it needs to several management of wetlands damage factors. 1) suppression of the excessive groundwater to basin, 2) stabilization of wetland via hydrologic storage, 3) suppression of changing and transforming wetland into forest by succession via management of xerophytic plants.
One of the distinguishing features of late Jeosun's Hanshi (poem in Chinese) is the numerous creation of Yeonjachyung Keesokshi (serial poem on folklore) which describes the folk manner and folk way of life in detail. Keesokshi's subject matter is the folklike in general including local features, geography, climate, local production, humanity, social conducts, and daily labor for living as well. By its material characteristics, Keesokshi reflects detailed life conditions of the society members in each levels, and represents the local customs as well as the folk emotions. Among the several kinds of Keesokshis, a Sesi Keesokshi focuses only in reciting the folk customs on each seasonal festival days, and the great numbers of such serial poems appear during the latter part of the Jeosun Dynasty. Its overall background is the transition of artistic trend which came after many social changes such as expansion of realism, uprising national consciousness, shaken status system, and the rising of 'Jeosunsi' motives in the Hansi history. Moreover, each writer's various experiences and their interests in the reality and critical minds of common people contributed a crucial roll in creation of Sesi Keesokshi. 178 of the 584 remaining serial Sesi Keesokshi are written particularly about the folk customs in The Grand Full Moon Festival (the first full moon of a year by the lunar calendar). These Hanshis widely reflect the common ways of living by directly accepting the seasonal folk customs as the subject matters. Especially, close to the reality, these poems positively express the people's simple vigorous lives and create unrestrained lively image by describing the joys and sorrows of the folk existence along with their craving. Also, it is notable to have customs such as 'Shil-Ssa-Um' and 'No-gu-ban-kong-yang' as subjects for its rarity in other literatures.
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