• Title/Summary/Keyword: Droplet Evaporation

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Highly Sensitive and Selective Gas Sensors Using Catalyst-Loaded SnO2 Nanowires

  • Hwang, In-Sung;Lee, Jong-Heun
    • Journal of Sensor Science and Technology
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    • v.21 no.3
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    • pp.167-171
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    • 2012
  • Ag- and Pd-loaded $SnO_2$ nanowire network sensors were prepared by the growth of $SnO_2$ nanowires via thermal evaporation, the coating of slurry containing $SnO_2$ nanowires, and dropping of a droplet containing Ag or Pd nanoparticles, and subsequent heat treatment. All the pristine, Pd-loaded and Ag-loaded $SnO_2$ nanowire networks showed the selective detection of $C_2H_5OH$ with low cross-responses to CO, $H_2$, $C_3H_8$, and $NH_3$. However, the relative gas responses and gas selectivity depended closely on the catalyst loading. The loading of Pd enhanced the responses($R_a/R_g$: $R_a$: resistance in air, $R_g$: resistance in gas) to CO and $H_2$ significantly, while it slightly deteriorated the response to $C_2H_5OH$. In contrast, a 3.1-fold enhancement was observed in the response to 100 ppm $C_2H_5OH$ by loading of Ag onto $SnO_2$ nanowire networks. The role of Ag catalysts in the highly sensitive and selective detection of $C_2H_5OH$ is discussed.

Lean burn Combustion Characteristics of Direct Injection Gasoline Engine with Swirl Control Valve (스월 제어 밸브를 적용한 직접분사식 가솔린 엔진의 희박연소 특성)

  • Lee, Min-Ho;Moon, Hak-Hoon;Cha, Kyung-Ok
    • Journal of ILASS-Korea
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    • v.9 no.2
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    • pp.9-17
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    • 2004
  • The performance characteristics of lean burn system in gasoline engine are mainly affected by the air-fuel mixture in cylinder, gas exchange process of manifold system, exhaust emission of engine, and the electronic engine control system. In order to obtain the effect of performance factors on the optimum conditions of lean burn engine, this study deal with the behavior of mixture formation, gas flow characteristics of air, flow and evaporation analysis of spray droplet in cylinder, vaporization and burning characteristics of lean mixture in the engine, and the control performance of electronic engine control system. The optimum flow conditions were investigated with the swirl and tumble flows in the combustion chamber with swirl control valve. The performance characteristics and optimum condition of flow field in intake system were analyzed by the investigation of inlet flow of air and combustion stabilization on cylinder.

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Studies on the Formation of Liquid Crystal and the Stability in W/O Emulsion Systems using Beeswax and Silicone Surfactant (Beeswax와 실리콘계 계면활성제를 사용한 W/O유화계에서 액정의 형성 및 안정도에 관한 연구)

  • Choi, Moon-Jae;Lee, Young-Moo;Jin, Byung-Suk
    • Journal of the Korean Applied Science and Technology
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    • v.21 no.4
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    • pp.279-288
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    • 2004
  • Liquid crystal (LC) system was introduced into W/O emulsion in order to enhance the stability and moisturizing effect. The LC system, composed of beeswax, surfactant, and water was formed on the surface of emulsion droplet, which was investigated through a polarized microscope. The phenomenon that the viscosity in W/O emulsion system is decreased with time, was reduced by the formation of LC with the addition of beeswax. Centrifugal separation test showed that the stability of emulsion system was increased with the addition of beeswax to 3%. The color change of vitamin C was delayed in LC emulsion systems, which indicates stabilization effect against the oxidation of vitamin C. Evaporation rate in W/O emulsion was retarded by LC, so that high moisturizing effect is expected in W/O LC system.

Effect of Premixed Fuels Charge on Exhaust Emission Characteristics of HCCI Diesel Engine (HCCI 디젤엔진의 배기특성에 미치는 예혼합 연료의 영향)

  • Kim Myung Yoon;Yoon Young Hoon;Hwang Suk Jun;Kim Dae Sik;Lee Chang Sik
    • Transactions of the Korean Society of Automotive Engineers
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    • v.13 no.4
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    • pp.182-189
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    • 2005
  • In order to investigate the effect of premixed gasoline, diesel fuel, and n-heptane charges on the combustion and exhaust emission characteristics in a direct injection (DI) diesel engine, the experimental studies are performed. The premixed fuels are injected into the premixing chamber that installed upstream of the intake port in order to minimize the inhomogeneity effect of premixed charge. The injection nozzle for directly injected fuel is equipped in the center of the combustion chamber. The air temperature control system is equipped in the intake manifold to examine the effect of air temperature. The experimental results of this study show premixing fuel is effective method to reduce the NOx and soot emissions of diesel engine. NOx emissions are linearly decreased with increasing premixed ratio for the three kinds of premixed fuels. The heating of intake air $(80^{\circ}C)$ reduced the deterioration of BSFC in high premixed ratio, because it promotes evaporation of premixed diesel droplet in the premixing chamber.

Study of Experimental and Numerical Analysis on Behavior Characteristics of Emulsified Fuel (에멀젼연료 거동특성에 관한 실험 및 수치해석 연구)

  • Yeom, Jeong-Kuk
    • Journal of Power System Engineering
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    • v.21 no.4
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    • pp.34-41
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    • 2017
  • Diesel engines with compression-ignition type have superior thermal efficiency, durability and reliability compared to gasoline engine. To control emitted gas from the engines, it can be applied to alternative fuel without any modification to the engine. Therefore, in this study, as a basic study for applying emulsified fuel to the actual diesel engine, analysis of spray behavior characteristics of emulsified fuel was carried out simultaneously by experimental and numerical method. The emulsified fuel consist of diesel, hydrogen peroxide, and surfactant. The surfactant for manufacturing emulsified fuel is comprised of span 80 and tween 80 mixed as 9:1 and fixed with 3% of the total volume of the emulsified fuel. In addition, six kinds of emulsified fuel(EF0, EF2, EF12, EF22, EF32, and EF42) were manufactured according to the mixing ratio of hydrogen peroxide. The droplet and spray experiments were performed to observe the behavior characteristics of the emulsified fuel. The numerical analysis was carried out using ANSYS CFX to confirm the microscopic behavior characteristics. Consequently, rapid mixture formation can be expected due to evaporation of hydrogen peroxide in emulsified fuel, and it is confirmed that Reitz&Diwakar breakup model is most suitable as breakup model to be applied to the numerical analysis.

Study of Behavior Characteristics of Emulsified Fuels with Evaporative Field (증발장에서 에멀젼연료의 거동특성에 관한 연구)

  • Yeom, Jeong Kuk;Yoon, Jeong Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.3
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    • pp.237-243
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    • 2015
  • In this study, the effects of the mixing ratio of emulsified fuel on the droplet evaporation and spray behavior characteristics were analyzed. A surfactant comprising span 80 and tween 80 mixed at a 9:1 ratio was used for the emulsified fuel. The fuel and surfactant were mixed at a ratio of 3:1 for the emulsified fuel. In addition, considering the mixing ratio of the surfactant, the mixing ratio of $H_2O_2$ in the emulsified fuel was set as EF (emulsified fuel)0, EF2, EF12, EF22, EF32, and EF42. To observe the evaporation characteristics, droplets of the emulsified fuel were dropped on a heating plate and observed using scattered light and a Schlieren system. In addition, to analyze the effect of the $H_2O_2$ mixing ratio, the behavior characteristics of the evaporative free spray were investigated in the mixing ratio range of EF0 to EF22 using a constant volume chamber with heaters. Consequentially, it was found that in the case of EF22, the free spray development of the emulsified fuel was faster than that of EF0 (diesel only) because of the promotion of the evaporation due to the phase change in the peroxide contained in the emulsion fuel.

VISUALIZATION AND MEASUREMENT OF A NARROW-CONE DI GASOLINE SPRAY FOR THE IMPINGEMENT ANALYSIS

  • Park, J.S.;Im, K.S.;Kim, H.S.;Lai, M.C.
    • International Journal of Automotive Technology
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    • v.5 no.4
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    • pp.221-238
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    • 2004
  • Wall interactions of direct injection spray were investigated using laser-sheet imaging, shadowgraphy, wetted footprint and phase Doppler interferometry techniques. A narrow-cone high-pressure swirl injector is used to inject iso-octane fuel onto a plate, which has three different impact angles inside a pressurized chamber. Heated air and plate conditions were compared with unheated cases. Injection interval was also varied in the heated case to compare dry- and wet- wall impingement behaviors. High-speed macroscopic Mie-scattering images showed that presence of wall and air temperature has only minor effect on the bulk spray structure and penetration speed for the narrow-cone injector tested. The overall bulk motions of the spray plume and its spatial position at a given time are basically unaffected until a few millimeters before impacting the wall. The surface properties of the impact surface, such as the temperature, the presence of a preexisting liquid film also have a small effect on the amount of wetting or the wetted footprint; however, they have strong influence on what occurs just after impact or after a film is formed. The shadowgraph in particular shows that the plate temperature has a significant effect on vapor phase propagation. Generally, 10-20% faster horizontal vapor phase propagation is observed along the wall at elevated temperature condition. For impingement onto a preexisting film, more splash and evaporation were also observed. Contrary to some preconceptions, there is no significant splashing and droplet rebounding from surfaces that are interposed in the path of the DI gasoline spray, especially for the oblique impact angle cases. There also appears to be a dense spray front consists of large sac spray droplets in the oblique impact angle cases. The bulk of the spray is not impacted on the surface, but rather is deflected by it The microscopic details as depicted by phase Doppler measurements show that the outcome of the droplet impaction events can be significantly influenced. Only droplets at the spray front have high enough Weber numbers for wall impact to wet, splash or rebound. Using the sign of vertical velocity, the time-resolved downward droplets and upward droplets are compared. The Weber number of upward moving droplets, which seldom exceeds unity, also decreases as the impact angle decreases, as the droplets tend to impact less and move along the wall in the deflected spray plume.

Analysis of Fire Suppression Efficiency for Intermittent Water Spray Pattern by Fire Dynamics Simulator (FDS를 이용한 교번식 미분무방식의 소화 성능 분석)

  • Jee, Moon-Hak;Lee, Byung-Kon
    • Fire Science and Engineering
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    • v.22 no.3
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    • pp.216-220
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    • 2008
  • Water mist fire suppression system utilizes the fire suppression features such as cooling of fire source, dilution of ambient oxygen, and shielding of radiation heat with the evaporation of microscopic water droplets. The momentum of water mist is relatively lower than that of larger water droplet and the infiltration of water mist to the fire source is not effective. Contribution of evaporated water vapor is liable to decline to limited portion of fire source due to its light weight and sparse density. On the other hand, the cycling water mist pattern is expected to improve the penetration force of water mist as well as the air expelling capability with the stratified spray characteristics. At this paper, we present the analyzed fire suppression capability of intermittent water spray pattern by use of FDS which is computational fire dynamics fire model. We expect this analysis can support the basic concept to the development of the prototype of water mist nozzle.

Enhancing the Moisturizing Ability of the Skin Softener using Nanoemulsion Based on Phospholipid Liposome

  • Lee, Jinseo;Park, Su In;Heo, Soo Hyeon;Kim, Miok;Shin, Moon Sam
    • International Journal of Advanced Culture Technology
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    • v.8 no.1
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    • pp.236-242
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    • 2020
  • In this paper, we present the improvement in low moisturizing ability and stability that existing skin softeners have due to the low oil content, by developing skin softener using nanoemulsion of phospholipid liposome, based on the properties of nanoemulsion in cosmetic formulation. In this study, two types of oil; dimethicone (DC 200/6cs) or medium chain triglyceride (MCT), and two kinds of lecithin; unsaturated or saturated were respectively applied to produce nanoemulsion. In the particle size analysis of nanoemulsion, the droplet size of nanoemulsion containing DC200/6cs and unsaturated lecithin was the smallest, and all nanoemulsion showed high stability in the measurement of zeta potential. Therefore, with the smallest particle size and high stability, moisture contents and trans epidermal water loss(TEWL) were measured using the skin softener of DC200/6cs and unsaturated lecithin contained nanoemulsion, and the measurement was compared with the non-oil skin softener and the skin softener with only small amount of oil. The results showed that the moisture content of the skin softener using nanoemulsion increased greatly than other two skin softeners, showing high hydration ability and water retention capacity, and TEWL decreased greatly, therefore preventing the evaporation of moisture from the skin. As a result, the oil content and stability of the skin softener was improved by utilizing nanoemulson based of phospholipid liposome, and it is expected to be used in various ways in cosmetic industry.

Evaporative Self-Assembly of Single-Walled Carbon Nanotubes for Field Effect Transistor (용매증발기반 자기조립을 이용한 단일벽 탄소나노튜브 정렬 및 트랜지스터 응용)

  • Kang, Seok Hee;Jeong, Do Young;Eom, Seong Un;Hwang, Cheong Seok;Hong, Suck Won
    • Korean Journal of Materials Research
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    • v.23 no.8
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    • pp.453-461
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    • 2013
  • Controlling the stick and slip motions of the contact lines in a confined geometry comprised of a spherical lens with a flat substrate is useful for manufacturing polymer ring patterns. We used a sphere on a flat geometry, by which we could control the interfaces of the solution, vapor and substrate. By this method, hundreds of concentric ring-pattern formations of a linear conjugated polymer, poly [2-methoxy-5-(2-thylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV), were generated with excellent regularity over large areas after complete solvent evaporation. Subsequently, the MEH-PPV ring patterns played a role as a directed template to organize highly regular concentric rings of single-walled carbon nanotubes(SWCNTs); when a droplet of the SWCNT suspension in water was casted onto the prepared substrate, hydrophobic polymer patterns confined the water dispersed SWCNTs in between the hydrophilicized $SiO_2/Si$ substrate. As the solvent evaporated, SWCNT-rings were formed in between MEH-PPV rings with controlled density. Finally, we used a lift-off process to produce SWCNT patterns by the removal of a sacrificial polymer template with organic solvent. We also fabricated a field effect transistor using self-assembled SWCNT networks on a $SiO_2/Si$ substrate.