• Title/Summary/Keyword: Drop-casting

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PEDOT:PSS Thin Films with Different Pattern Structures Prepared Using Colloidal Template

  • Yu, Jung-Hoon;Lee, Jin-Su;Nam, Sang-Hun;Boo, Jin-Hyo
    • Applied Science and Convergence Technology
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    • v.23 no.5
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    • pp.254-260
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    • 2014
  • Organic solar cells have attracted extensive attention as a promising approach for cost-effective photovoltaic devices. However, organic solar cell has disadvantage of low power conversion efficiency in comparison with other type of solar cell, due to the recombination ratio of hole and electron is too large in the active layer. Thus we have change the surface structure of PEDOT:PSS layers to improve the current density by colloidal lithography method using various-size of polystyrene sphere. The two types of coating method were applied to fabricate the different pattern shape and height, such as spin coating and drop casting. Using the organic solvent, we easily eliminate the PS sphere and could make the varied pattern shapes by controlling the wet etching time. Also we have measured the electrical properties of patterned PEDOT:PSS film to check whether it is suitable for organic photovoltaics.

Novel Flexible Supercapacitors Fabricated by Simple Integration of Electrodes, Binders, and Electrolytes into Glass Fibre Separators

  • Yoo, Joung Eun;Bae, Joonho
    • Journal of the Korean Electrochemical Society
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    • v.17 no.4
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    • pp.237-244
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    • 2014
  • We report novel and simple structure of supercapacitors fabricated by using flexible glass fibre separators as templates. This method does not require separate electrodes, binders and high pressure/temperature to build the supercapacitor unit cells as required by the conventional technology. The supercapacitors were fabricated by drop-casting solution mixtures of carbonaceous active materials/gel electrolytes onto two sides of glass fibre separators. Two carbonaceous materials (nanoscaled activated carbons, multi-walled carbon nanotubes) were investigated as electrode materials. The electrochemical measurements reveal that the separatorbased supercapacitors using ACs successfully demonstrated significant mass specific capacitance ($22.3F\;g^{-1}$) and energy density ($9.7Wh\;kg^{-1}$), indicating this method can be useful in fabricating flexible, wearable and stretchable energy storage devices in more straightforward and cost-effective way than current technology.

Hydrogen Bonding-Driven Assembling of Thin Multiwalled Carbon Nanotubes (수소결합에 의한 얇은 다중벽 탄소나노튜브의 자기조립)

  • Han, Joong-Tark;Kim, Sun-Young;Woo, Jong-Seok;Lee, Gun-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.426-427
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    • 2007
  • Here we describe the formation of a self-assembled film of thin multiwalled carbon Nanotubes(t-MWNT) modified with hydroxy groups through hydrogen peroxide treatment. Morphologies of t-MWNT films could be controlled by the various coating method, such as filtering, drop casting, spraying method, etc. The results show that on densification of the CNT suspension during drying, multiple hydroxy group-modified MWNTs can be self-assembled through strong surface hydrogen bond interaction while MWNTs usually exist an entangled state in the film. The interaction between t-MWNT was illustrated from Raman spectrum of spray coated films.

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Rabid detection of chloride ions in fresh concrete using a chromium-free paper-based analytical device (µPAD) (경화 전 콘크리트의 염소이온 신속측정 페이퍼 센서 개발에 관한 실험적 연구)

  • Subbiah Karthick;Park, Tae-joon;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.11a
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    • pp.123-124
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    • 2023
  • This study successfully developed a chromium-free paper-based analytical device (µPAD) for chloride detection in fresh concrete. The sensing materials were chemically synthesized and coated to the paper through drop casting. The fabricated µPAD was thoroughly tested with various concentrations of chloride ions. Upon interaction with the µPAD, the chloride ions in the solution react with a chromium-free silver compound, exhibiting a specific coloring height proportional to the absolute chloride concentration. The height of the color change during a reaction can vary based on the chloride concentration, which allows for predicting the chloride concentration in a solution. The results reveal that µPAD has extraordinary precision in identifying chloride in fresh concrete, which highlights its immense potential for future applications.

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AN EXPERIMENTAL STUDY ON THE MORPHOLOGIC CHANGES OF DIFFERENT SIMULATED CANALS ACCORDING TO THE PREPARATION METHOD (근관형성방법(根管形成方法)에 따른 모의근관형태(模擬根管形態)의 변화(變化)에 대(對)한 실험적(實驗的) 연구(硏究))

  • Hwang, Ho-Keel;Cho, Jae-O;Cho, Young-Kgon
    • Restorative Dentistry and Endodontics
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    • v.13 no.1
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    • pp.161-171
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    • 1988
  • The purpose of this study was to examine the morphological changes of different simulated canals according to the preparation procedures. With the use of clear casting resin, simulated straight and curved canals were created so that canal preparation procedures could be directly visualized and compared. Thirty clear polyester casting resin blocks which contained four simulated canals divided into three groups; Group A($0^{\circ}$), Group B($15^{\circ}$), and Group C($30^{\circ}$). In each block, 3 canals were prepared different preparation techniques, which were conventional method, step-back method, and giromatic filing. But, one canal was not prepared as a control group. The results were as follows: 1. There was no difference on canal shape among three canal preparation methods in straight canals (Group A). 2. When conventional method and Giromatic filing were used in curved canals (Group B, C), elbow, zip and hour-glass shape were formed in apical third. 3. When conventional method and Giromatic filing were used in curved canals (Group B, C), tear-drop appearance developed at the site of the canal exit in curved canals. 4. In curved canals (Group B, C), file tend to straighten within the canal. 5. There was no difference on canal shape according to curved angle in step-back method (p > 0.1). But there was significant difference on canal shape according to curved angle in conventional method and Giromatic filing (p < 0.001). 6. Step-back method was significantly more effective than conventional method and Giromatic preparation in morphologic aspects of apical third of original canals.

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The Effect of Dry Environment on Strength of Cement Mortar Immediately after Casting (성형직후 건조환경이 시멘트 모르터의 강도에 미치는 영향)

  • 오무영;김준희
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.33 no.2
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    • pp.61-72
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    • 1991
  • This study was carried out to research the strength drop of concrete in dry environment. The mixing ratio of cement-fine aggregate was 1: 1, 1 : 2, 1: 3 and 1 : 4. The curing was compared standard curing with dry curing immediately after casting. It is analysis of strength change by water-proof mixing. The curing age of cement mortar was 3days, 7days, l4days and 28days. The result obtained from this study are summarized as follows. 1. The compressive and bending strength change by increasing the curing age, dry curing mortar the increasing rate of strength was decreased than standard curing mortar. 2. The compressive and bending strength change in early curing, strength difference between standard curing mortar and dry curing motar was gradually closed by increasing the W/C. 3. The dry curing mortar was decreased than standard curing mortar in decreasing rate of compressive and bending strength by increasing the W/C. 4. The compressive strength of water-proof mortar in early curing, liquid water-proof mortar was shown high strength in dry curing than standard curing. The powder and liquid water-proof mortar have a small effect in dry environment. The liquid water-proof mortar was high strength without relation change of curing age in dry environment than standard curing. 5. The compressive strength of liquid water-proof mortar in poverty mix, dry curing was shown high strength than standard curing. 6. The bending strength was increased than compressive strength by decreasing the volume of cement in early curing. The increasing rate of bending strength was decreased to compressive stength by increasing the curing age.

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Fabrication of Ceramic 3D Integration Technology for Ink-jet Printing (Ink-jet Printing을 이용한 3D-Integration 구현)

  • Hwang, Myung-Sung;Kim, Ji-Hoon;Kim, Hyo-Tae;Yoon, Young-Joon;Kim, Jong-Hee;Moon, Joo-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.332-332
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    • 2010
  • We have successfully demonstrated the inkjet printing method to create $Al_2O_3$ films withouWe have successfully demonstrated the inkjet printing method to create $Al_2O_3$ films without a high temperature sintering process. In order to remove the coffee ring effect in the ink drop, we have introduced a co-solvent system in order to create Marangoni flow in the ink drop, which leads to the dense packing of ceramic powders on the substrate during inkjet process. The packing density of the Inkjet-printed $Al_2O_3$ films is around 60% (max. 70%) which is very high compared to the value obtained from the same material films by other conventional methods such as film casting, dip coating process, etc. The voids inside the films (which are around 40% of the entire film volume) are filled with the polymer resin (Cyanate ester) by the infiltration process. This resin infiltration is also implemented by the inkjet printing process right after the Ah03 film ink-jetting process. The microstructures of the printed $Al_2O_3$ films are investigated by Scanning Electron Microscope (SEM) to understand the degree of packing density in the printed films. The inkjet-printed $Al_2O_3$ films have been characterized to investigate its thickness and roughness. Quality factor of the printed $Al_2O_3$ film is also measured to be over 300 at 1MHz.

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Preparation of Porous Separators for Zn Air Batteries through Phase Inversions of Polyetherimide-PVP Solutions (Polyetherimide-PVP 용액의 상전이를 통한 아연공기전지의 다공성 분리막 제조)

  • Cho, Yu Song;Kim, Young Kyoung;Koo, Ja-Kyung
    • Membrane Journal
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    • v.24 no.3
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    • pp.231-239
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    • 2014
  • Polyetherimide (PEI) membranes for separators in Zn air batteries were prepared via phase inversion process from casting solution composed of PEI, n-methylpyrolidone (NMP), and polyvinylpurrolidone (PVP). Furthermore, Zn air batteries were fabricated with the separators. The effects of PEI content and PVP addition in the casting solution on the morphology, mechanical strength, ionic conductivity were investigated through SEM, stress-strain test and ac impedance test. The elelctrochemical performances of the batteries were evaluated through galvanostatic discharge analysis. The mechanical strength of the membrane increased with increasing PEI composition in the casting solution. Little effect of PVP addition into the solution on the mechanical strength of the membrane was investigated. The ionic conductivity value decreased with increasing PEI composition in the solution. With addition of PVP, ionic conductivity of membrane increased until 10 wt% to show the maximum value of 0.1 S/cm. In the higher range of PVP addition over 10%, the ionic conductivity decreased with increasing PVP addition. Ionic conductivity of separator strongly affected the capacity of Zn air battery, and the battery assembled with the separator which showed high ionic conductivity showed high capacity.

Mechanical Properties of a Cu55Zr30Ti10Pd5 Bulk Amorphous Alloy (Cu55Zr30Ti10Pd5 비정질 합금의 기계적 거동)

  • Choi Won Wook;Gato H.;Kim Hyoung Seop;Hong Sun Ig;Inoue A.
    • Korean Journal of Materials Research
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    • v.15 no.4
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    • pp.281-284
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    • 2005
  • Room and high temperature deformation behaviors of Cu-Zr-Ti-Pd bulk metallic glasses produced by copper mold casting were investigated. The addition of Pd was shown to enhance the glass forming ability and thermal stability of Cu-Zr-Ti base bulk metallic glass. The compressive strength of $Cu_{55}Zr_{30}Ti_{10}Pd_5$ bulk metallic glass was 2230 MPa with 1.8 plastic strain. The stress overshoot and yield drop phenomenon were observed below $487^{\circ}C$ and a drastic decrease in the flow stress was observed at $487^{\circ}C$. The stress overshoot is thought to be associated with stress-induced structural relaxation.

On demand nanowire device decalcomania

  • Lee, Tae-Il;Choi, Ji-Hyuck;Moon, Kyung-Ju;Jeon, Joo-Hee;Myoung, Jae-Min
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.11a
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    • pp.26.1-26.1
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    • 2009
  • A simple route of external mechanical force is presented for enhancing the electrical properties of polymer nanocomposite consisted of nanowires. By dispersing ZnO nanowires in polymer solution and drop casting on substrates, nanocomposite transistors containing ZnO nanowires are successfully fabricated. Even though the ZnO nanowires density is properly controlled for device fabrication, as-cast device doesn't show any detectable currents, because nanowires are separated far from each other with the insulating polymer matrix intervening between them. Compared to the device pressed at 300 kPa, the device pressed at 600 kPa currents increased by 50times showing the linear behavior against drain voltage and exhibits promising electrical properties, which operates in the depletion mode with higher mobility and on-current. Such an improved device performance would be realized by the contacts improvement and the increase of the number of electrical path induced by external force. This approach provides a viable solution for serious contact resistance problem of nanocomposite materials and promises for future manufacturing of high-performance devices.

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