• Bulletin of the Korean Chemical Society
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• 제33권11호
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• pp.3805-3809
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• 2012

Results for molecular dynamics simulation method of small liquid drops of argon (N = 1200-14400 molecules) at 94.4 K through a Lennard-Jones intermolecular potential are presented in this paper as a preliminary study of drop systems. We have calculated the density profiles ${\rho}(r)$, and from which the liquid and gas densities ${\rho}_l$ and ${\rho}_g$, the position of the Gibbs' dividing surface $R_o$, the thickness of the interface d, and the radius of equimolar surface $R_e$ can be obtained. Next we have calculated the normal and transverse pressure tensor ${\rho}_N(r)$ and ${\rho}_T(r)$ using Irving-Kirkwood method, and from which the liquid and gas pressures ${\rho}_l$ and ${\rho}_g$, the surface tension ${\gamma}_s$, the surface of tension $R_s$, and Tolman's length ${\delta}$ can be obtained. The variation of these properties with N is applied for the validity of Laplace's equation for the pressure change and Tolman's equation for the effect of curvature on surface tension through two routes, thermodynamic and mechanical.

• Journal of Welding and Joining
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• 제11권1호
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• pp.73-79
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• 1993

The phenomenon of metal transfer has been investigated for different transfer modes using a digital high speed motion analyzer and an arc shadow-graphing system based on a laser source and related optical system. It was observed that the pinch instability phenomenon did not occur for the globular transfer mode, since the liquid globule was then spherical rateher than a cylindrical liquid bar. On increasing the ratio of carbon dioxide to argon, the transition current from globular to spray transfer generally increased, but it is interesting that the transition was observed to occur at the lowest current in a 5% CO$_{2}$-95% argon gas mixture. For pure carbon dioxide and helium shielding gases, the drop frequency increased slowly with increasing current. At high currents or an argon based shielding gas, the length of liquid bar decreased as the carbon dioxide content increased. The acceleration of a droplet within the arc was determined using the gas drag force theory and was found to be greater than the experimental results.