• 한국물환경학회지
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• 제20권5호
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• pp.432-436
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• 2004

The principle and methodology of risk assessment was applied to establish the quality standard of potential impurities of drinking water treatment chemicals. The impurities(arsenic, lead, cadmium, chromium, mercury, etc.) are regulated as the contained quantity of chemicals in Korea while they are regulated as the quality standard with the idea of 10% of the national safety drinking water standard in U.S.A(NSF) and Japan(JWWA). According to risk assessment of the current standard implemented in Korea, the excess cancer risk of arsenic and lead were determined in around $10^{-5}$ and the hazard quotient(HQ) of cadmium and chromium were below $10^{-2}$, respectively. And the standard concentration of the impurities are regulated as much as 2%~6% of the national drinking water quality standard. The values are more enforced rather than the standards in U.S.A(NSF) and Japan(JWWA) regulating the concentration of impurities the 10% of the national drinking water quality standard. We conclude that the impurities standard of drinking water treatment chemicals should be reconsidered comprehensively concerning the national safety drinking water quality standard and risk assessment.

• 한국물환경학회지
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• 제22권6호
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• pp.1107-1108
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• 2006

As expanding municipal and industrial areas since started the economic development plan in earnest in 1970's, the water resource, mainly river surface water has been seriously polluted. Nevertheless, being upgraded in their treatment technologies for the drinking water, the safety has been issued one of crucially social problem in Korea. The water authorities has tried to improve the quality such as amending the drinking water quality standard to be monitored; hazardous chemicals and microorganis have been added and now 55 items, before 47 items, since in 2002. The Water Authorities of Seoul, the capital city of Korea, planned to assess the safty of drinking water quality after amended the standard. This study was conducted to assess the risk due to polluted chemicals including 21 heavy metals, VOCs, pesticides, PAHs, DBPs and organic chemicals among the regulated items. The risk assessment were undertaken hazard identification, exposure assessment, dose-response assessment and risk characterization. For the exposoure assessment, tap water, bottled water and purified water were sampled and analyzed in February, 2004. Risk characterization of detected chemicals was categorized into carcinogenecity and noncarcinogenecity, and estimated the excess of carcinogens and compapared with the reference dose (RfD) of noncarcinogenns. The excess risk of carcinogens from samples were considered comparatively in the acceptable levels; $10^{-6}$ for cancer risk and hazard quotient (HQ) 1.0 for noncancer risk. The deteced levels were estimated in $10^{-5}{\sim}10^{-6}$ of cancer risk and below 1.0 of HQ of noncancer risk. While three kinds of water were determined within the acceptal levels, DBPs were detected in tap water and purified were and some undesireable chemicals such as more fluoride detected rather than the quality stanadard. For the drinking water safety, it shoud be continuously monitored, assessed and managed as well risk communiction between the authoritis and public.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1995년도 하계학술대회 논문집 B
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• pp.766-768
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• 1995

This paper presents the applied example of "A" city about optimum of chemicals imjection rate. The water treatment plant of "A" city make raw water into drinking water according to the injection of PAC, Alkali and chlorine. Computer performs multiple regression analysis about preoperation data, DCS has been done chemicals optimun control.

• 상하수도학회지
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• 제21권3호
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• pp.341-348
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• 2007

The efficiency of powdered activated carbon (PAC) for removing taste and odor (T&O) in drinking water supplies is dependent on the contact time, quality of mixing, and the presence of competing compounds. All of these are strongly influenced by the stage in the treatment process at which the PAC is added. In conventional water treatment plants (WTPs), PAC is commonly added into the rapid mixing basin where chemicals such as coagulants, alkaline chemicals, and chlorine, are simultaneously applied. In order to prevent interference between PAC and other water treatment chemicals, alternative locations for addition of PAC, such as at transmission pipe in the water intake tower or into a separated PAC contactor, were investigated. Whatever the location, addition of PAC apart from other water treatment chemicals was more effective for geosmin removal than simultaneous addition. Among several combinations, the sequence 'chlorine-PAC-coagulant' produced the best result with respect to geosmin removal efficiency. Consequently, when PAC has to be applied to cope with T&O problems in conventional WTPs, it is very important to prevent interference with other water treatment chemicals, such as chlorine and coagulant. Adequate contact time should also be given for adsorption of the T&O compounds onto the PAC. To satisfy these conditions, installation of a separated PAC contactor would be the superior alternative if there is space available in the WTP. If necessary, PAC could be added at transmission pipe in the water intake tower and still provide some benefit for T&O treatment.

• 한국물환경학회지
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• 제23권2호
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• pp.193-200
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• 2007

The AOPs research defined by creating a sufficient amount of OH radicals from the dissolution of organic materials through photoxidation and research for a complete elimination of residual organic materials by membrane are actively ongoing. This research focuses on the hybrid processing of AOPs and M/F membrane to dissolve and eliminate organic chemicals in drinking water which are suspected of carcinogens. For this purpose, underground water was used as a source of drinking water for the hybrid processing of AOPs oxidation and M/F membrane, and a pilot plant test device was installed indoor. Carcinogenic chemicals of VOCs and pesticide were artificially mixed with the drinking water, which was then diluted close to natural water in order to examine treatment efficiency and draw optimal operation conditions. The samples used for this experiment include four chemicals phenol, chloroform, in VOCs and parathion, carbaryl in pesticide. As a result of the experiments conducted with simple, and compound solutions, the conditions to sufficiently dissolve and eliminate carcinogenic chemicals from the hybrid processing of where carcinogens were artificially added are : (hydrogen peroxide) prescribed solution 100 mg/L under pH 5.5~6.0, and the temperature $12{\sim}16^{\circ}C$, at the normal temperature and pressure. $d-O_3$ volume of 5.0 ppm and above and 30-40 minutes of reaction time are most appropriate and using MF/UF for membrane was ideal.

• Environmental Engineering Research
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• 제21권4호
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• pp.319-332
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• 2016

Micropollutants are often discharged to surface waters through untreated wastewater from sewage treatment plants and wastewater treatment plants. The presence of micropollutants in surface waters is a serious concern because surface water is usually provided to water treatment plants (WTP) to produce drinking water. Many micropollutants can withstand conventional WTP systems and stay in tap water. In particular, pharmaceuticals and endocrine disruptors are examples of micropollutants that are detected at the drinking water, ppb, or even ppb level. A variety of techniques and processes, especially advanced oxidation processes, have been applied to remove micropollutants from water to control drinking water contamination. This paper reviews recent researches on the occurrence and removal of micropollutants in the aquatic environments and during water treatment processes.

• 한국물환경학회지
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• 제21권6호
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• pp.659-663
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• 2005

Many studies have been conducted to develop new technologies for arsenic removal and to reveal the levels of arsenic and other chemicals in rivers, lakes and ground waters. However, there are few studies dealing with such compounds in the total water system of the city, and the way of management of these compounds in the water system. Because the occurrence of these hazardous compounds, which are geological origins, is almost impossible to control, it is very important to manage these compounds in the water system. In this research, it was revealed that the risk of arsenic in the water treatment system of S city in Japan. As a results, the parameters such as Q in river and E260 in drinking water treatment plant is proposed as a new indicator with simple and rapid method for controling arsenic level.

• 한국물환경학회지
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• 제28권5호
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• pp.754-761
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• 2012

Several drinking water treatment plants (DWTPs) produce the bottled tap waters (BTWs) as pilot production and provide them for noncommercial use. In 2008, acetaldehyde and chloral hydrate were detected in some BTWs and the public worry over the safety of the water. In this study, the BTWs produced from 7 DWTPs were tested for 13 chemicals including disinfection byproducts (DBPs). The level of four trihalomethanes (THMs) were increased up to 15 days. The average concentration of them was 0.0075 mg/L at the time of bottling and it was increased to 0.0214 mg/L after 15 days. The average acetaldehyde concentration was 0.0406 mg/L at the time of bottling but it was went up to 0.2251 mg/L after 11 days and then decreased. Although the initial concentrations of DBPs were below the drinking water standard, we also traced them at different storage conditions. Temperature affected the formations of THMs and acetaldehyde concentrations significantly. While the average concentration of THMs ranged from 0.0113 to 0.0182 mg/L at $25^{\circ}C$, it was increased to 0.0132 ~ 0.0256 mg/L at $50^{\circ}C$. In case of acetaldehyde, concentration ranged from 0.0901 to 0.2251 mg/L at $25^{\circ}C$, it was increased to 0.3394 ~ 1.0591 mg/L at $50^{\circ}C$. Throughout the tests with 7 BTWs samples, none of the chemicals was exceeded the drinking water standard of Korea. Therefore, it is recommended to avoid the exposure of BTWs to sunlight or high temperature during distribution and storage.

• 한국물환경학회지
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• 제20권3호
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• pp.245-250
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• 2004

This study investigated the micropollutants present in raw water supplied for the several drinking water treatment plants in Seoul. The target sample waters were collected from the several sites, such as Jayang (JY), Kuui (KI), Paldang (PD) and Kangbuk (KB) at the Han-River stream. The analytical method used in this study enable us to detect about 300 kinds of chemicals commonly found in surface water at ppt level by GC-ion trap MS. In this study, the consideration on the analytic results focused on the four hazardous organics, such as benzenes, phenols, phthalates and pesticides. The numbers of each detected micropollutant were 1~8 kinds for benzenes, 1~7 kinds for phenols, 5~7 kinds for phthalates and 1~9 kinds for pesticides. For the pesticides, the higher concentration was detected in the water samples collected from PD and KB adjacent to the farming area, and at June and July, which is the busy farming season. The total concentrations of each micropollutants detected at all the sites were significantly lower than those of drinking water regulation in Korea as well as other advanced countries. However, the frequently detected micropollutants requires the steady and precise monitoring for the effective management of drinking water source.

• 한국환경보건학회지
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• 제39권5호
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• pp.391-407
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• 2013

Micropollutants emerge in surface water through untreated discharge from sewage and wastewater treatment plants (STPs and WWTPs). Most micropollutants resist the conventional systems in place at water treatment plants (WTPs) and survive the production of tap water. In particular, pharmaceuticals and endocrine disruptors (ECDs) are micropollutants frequently detected in drinking water. In this review, we summarized the distribution of micropollutants at WTPs and also scrutinized the effectiveness and mechanisms for their removal at each stage of drinking water production. Micropollutants demonstrated clear concentrations in the final effluents of WTPs. Although chronic exposure to micropollutants in drinking water has unclear adverse effects on humans, peer reviews have argued that continuous accumulation in water environments and inappropriate removal at WTPs has the potential to eventually affect human health. Among the available removal mechanisms for micropollutants at WTPs, coagulation alone is unlikely to eliminate the pollutants, but ionized compounds can be adsorbed to natural particles (e.g. clay and colloidal particles) and metal salts in coagulants. Hydrophobicities of micropollutants are a critical factor in adsorption removal using activated carbon. Disinfection can reduce contaminants through oxidation by disinfectants (e.g. ozone, chlorine and ultraviolet light), but unidentified toxic byproducts may result from such treatments. Overall, the persistence of micropollutants in a treatment system is based on the physico-chemical properties of chemicals and the operating conditions of the processes involved. Therefore, monitoring of WTPs and effective elimination process studies for pharmaceuticals and ECDs are required to control micropollutant contamination of drinking water.