• Bulletin of the Korean Chemical Society
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• v.29 no.3
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• pp.580-584
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• 2008

Second-order rate constants (kN) have been measured spectrophotometrically for reactions of Y-substituted phenyl benzoates (1a-h) with azide ion (N3) in 80 mol % H2O/20 mol % DMSO at 25.0 0.1 oC. The Brnsted-type plot for the azidolysis exhibits a downward curvature, i.e., the slope (b lg) changes from 0.97 to 0.20 as the basicity of the leaving group decreases. The pKao (defined as the pKa at the center of the Brnsted curvature) is 4.8, which is practically identical to the pKa of the conjugate acid of N3 ion (4.73). Hammett plots correlated with s o and s constants exhibit highly scattered points for the azidolysis. On the contrary, the corresponding Yukawa-Tsuno plot results in an excellent linear correlation with r = 2.45 and r = 0.40, indicating that the leaving group departs in the rate-determining step. The curved Brnsted-type plot has been interpreted as a change in the rate-determining step in a stepwise mechanism. The microscopic rate constants (k1 and k2/k1 ratio) have been calculated for the azidolysis and found to be consistent with the proposed mechanism.

• Bulletin of the Korean Chemical Society
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• v.29 no.3
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• pp.585-589
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• 2008

Second-order rate constants (kN) have been measured for reactions of Y-substituted phenyl 2-thiophenecarboxylates (6a-h) with morpholine and piperidine in 80 mol % H2O/20 mol % DMSO at 25.0 0.1 oC. The Brnsted-type plot for the reactions of 6a-h with morpholine is linear with b lg = 1.29, indicating that the reactions proceed through a tetrahedral zwitterionic intermediate (T?). On the other hand, the Brnsted-type plot for the reactions of 6a-h with piperidine exhibits a downward curvature, implying that a change in the rate-determining step occurs on changing the substituent Y in the leaving group. Dissection of kN into microscopic rate constants (i.e., k1 and k2/k1 ratio) has revealed that k1 is smaller for the reactions of 6a-h than for those of Y-substituted phenyl 2-furoates (5a-h), while the k2/k1 ratio is almost the same for the reactions of 5a-h and 6a-h. It is also reported that modification of the nonleaving group from the furoyl (5a-h) to the thiophenecarbonyl (6a-h) does not influence pKao (defined as the pKa at the center of the Brnsted curvature) as well as the k2/k1 ratio.

• Journal of Biomedical Engineering Research
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• v.17 no.1
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• pp.49-60
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• 1996

An experimental investigation was performed under steady flow condition to assess hydrodynamic performance of floating-type monoleaflet polymer valves (MLPV) withdifferent leaflet thickness. The St. Jude Medical valve (SJMV) was also used for comparison test. Pressure drops of MLPVS are larger than those for other types of polymer valves and mechanical valves. Furthermore, the thicker is the leaflet thickness of the polymer valve, the larger are the corresponding pressure drop. The velocity profiles for MLPs reveal a large reversed flow region downward to the valve position. The maximum wall shear stresses of MLPVS at a flow rate of $30{\ell}$/min are in the range 50-130 dyn/$cm^2$, and the corresponding maximum Reynolds shear stresses are in the range of 100-500 dyn/$cm^2$, respectively, which are beyond the allowable limit clinically. In contrast, floating-type monoleaflet polymer valves show better hydrodynamic performance in leakage volume. From the designing point of view, it may be concluded that the optimum thickness of leaflet for better hydrodynamic performance is one of the Important parameters.

• Proceedings of the KOSOMBE Conference
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• v.1995 no.05
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• pp.241-246
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• 1995

An experimental investigation was performed under steady flow condition to assess hydrodynamic performance of floating-type monoleaflet polymer valves (MLPV) with different leaflet thickness. The St. Jude Medical valve (SJMV) was also used for comparison tests. Pressure drops of MLPVs are larger than those for other types of polymer valves and mechanical valves. Furthermore, the thicker is the leaflet thickness of a polymer valve, the larger arc the corresponding press drop. The velocity profiles for MLPV reveal a large reversed flow region downward to the valve position. The maximum wall shear stresses of MLPVs at a flow rate of 30 l/min are in the range $54-130\;dyn/cm^2$, and the corresponding maximum. Reynolds shear stresses are in the range of $100-500\;dyn/cm^2$, respectively. Both arc beyond the allowable limit clinically. In contrast, floating-type monoleaflet polymer valves show better hydrodynamic performance in leakage volume. From the designing point of view, it can be concluded that the optimum thickness of leaflet for better hydrodynamic performance is one of the important parameters.

• Bulletin of the Korean Chemical Society
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• v.19 no.7
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• pp.776-779
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• 1998

Second-order rate constants have been measured spectrophotometrically for the addition reaction of a series of alicyclic amines to 3-butyn-2-one to yield their respective enamines at 25.0 'C. The reactivity of the amines increases with increasing the basicity of the amines. However, the Bronsted-type plot obtained exhibits a downward curvature as the basicity of the amines increases, i.e. βnuc decreases from 0.3 for low basic amines (pKa < 9) and to 0.1 for highly basic amines (pKa > 9). Such a curvature in the Bronsted-type plot is clearly indicative of a change in the reaction mechanism or transition state structure. From the corresponding reactions run in D2O, the magnitude of kinetic isotope effect (KIE) has been calculated to be about 0.8 for highly basic amines and 1.21 for weakly basic amines. The difference in the magnitude of KIE also supports a change in the reaction mechanism or transition state structure upon changing the basicity of the amines. Furthermore, the small KIE clearly suggests that H+ transfer is not involved in the rate-determining step, i.e. the addition reaction is considered to proceed via a stepwise mechanism in which the attack of the amines to the acetylene is the rate-determining step. The curvature in the Bronsted-type plot has been attributed to a change in the degree of bond formation between the amine and the acetylene.

• Bulletin of the Korean Chemical Society
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• v.28 no.8
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• pp.1353-1357
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• 2007

Second-order rate constants (kN) have been determined spectrophotometrically for reactions of Y-substituted phenyl 2-furoates (1a-h) with piperidine and morpholine in 80 mol % H2O/20 mol % DMSO at 25.0 ± 0.1 oC. The Brønsted-type plot exhibits a downward curvature for the reactions with strongly basic piperidine but is linear for the reactions with weakly basic morpholine. The slope of the curved Brønsted-type plot changes from -1.25 to ?0.28 as the pKa of the conjugate acid of the leaving aryloxides decreases. The pKa at the center of the Brønsted curvature, defined as pKa°, was determined to be 6.4. The aminolysis of 1a-h has been concluded to proceed through a stepwise mechanism on the basis of the curved Brønsted-type plot. The reactions of Ysubstituted phenyl cinnamates (2a-g) with piperidine resulted in a curved Brønsted-type plot with a pKa° values of 6.4. However, the curved Brønsted-type plot has been suggested to be not due to a change in the RDS but due to a normal Hammond effect of a concerted mechanism, since the Brønsted-type plot for the corresponding reactions with morpholine results in also a curved Brønsted-type plot with a pKa° values of 6.1. The furoates with a basic leaving group (i.e., 1b-g) are less reactive than the corresponding cinnamates (i.e., 2b-g). The k2/ k-1 ratios for the reactions of 1b-h are much smaller than unity, which has been suggested to be responsible for their low reactivity.

• Journal of Astronomy and Space Sciences
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• v.28 no.3
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• pp.163-172
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• 2011

An intensive analysis of 185 timings of WZ Cep, including our new three timings, was made to understand the dynamical picture of this active W UMa-type binary. It was found that the orbital period of the system has complexly varied in two cyclical components superposed on a secularly downward parabola over about 80y. The downward parabola, corresponding to a secular period decrease of $-9.{^d}97{\times}10^{-8}y^{-1}$, is most probably produced by the action of both angular momentum loss (AML) due to magnetic braking and mass-transfer from the massive primary component to the secondary. The period decrease rate of $-6.^{d}72{\times}10^{-8}y^{-1}$ due to AML contributes about 67% to the observed period decrease. The mass flow of about $5.16{\times}10^{-8}M_{\odot}y^{-1}$ from the primary to the secondary results the remaining 33% period decrease. Two cyclical components have an $11.^{y}8$ period with amplitude of $0.^{d}0054$ and a $41.^{y}3$ period with amplitude of $0.^{d}0178$. It is very interesting that there seems to be exactly in a commensurable 7:2 relation between their mean motions. As the possible causes, two rival interpretations (i.e., light-time effects (LTE) by additional bodies and the Applegate model) were considered. In the LTE interpretation, the minimum masses of $0.30M_{\odot}$ for the shorter period and $0.49M_{\odot}$ for the longer one were calculated. Their contributions to the total light were at most within 2%, if they were assumed to be main-sequence stars. If the LTE explanation is true for the WZ Cep system, the 7:2 relation found between their mean motions would be interpreted as a stable 7:2 orbit resonance produced by a long-term gravitational interaction between two tertiary bodies. In the Applegate model interpretation, the deduced model parameters indicate that the mechanism could work only in the primary star for both of the two period modulations, but could not in the secondary. However, we couldn't find any meaningful relation between the light variation and the period variability from the historical light curve data. At present, we prefer the interpretation of the mechanical perturbation from the third and fourth stars as the possible cause of two cycling period changes.

• Journal of the Korean Institute of Gas
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• v.16 no.4
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• pp.59-64
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• 2012

The dispersion of gas discharged from the vent pipes of pressure relief valves attached LPG (Liquefied Petroleum Gas) storage tank was studied. In general, vent pipes should be positioned so that they discharge vertically upwards in a safe place, and installed so that, in the event of ignition of discharged gas, flame impingement on any vessel, equipment or piping is avoided[1][2]. In Korea, on the other hand, there are various type of the end of vent pipes because there is no rule for discharge directions from the vent pipes. In this paper, we took 4 types of vent directions from the pipes in to account, such as vertically upward, vertically downward, vertically 4-way and horizontally 2-way direction. A software package, FLACS, was adopted to simulate gas dispersion from the vent pipes. We found that vertically downward, vertically 4-way and horizontally 2-way discharge from vent pipes were undesirable to avoid ignition on near ground. Therefore, it was obvious that vertically upward opening of a vent pipe is the best option to discharge in a safe place.

• Journal of the Korea Institute of Military Science and Technology
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• v.18 no.4
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• pp.358-368
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• 2015

Recently, unmanned systems are largely utilized in various fields due to the persistency and the least operational risk and an unmanned surface vehicle(USV) is the one of the representative application in the naval field. To assign multiple roles to an USV, we developed a sonar system which consists of a forward detecting sonar for the long-range detection, a downward detecting sonar for the small target scan and identification, and a strut type body for mounting sonar systems. In this paper, we described the developed sonar system for USV and the sea test results for verifying system performance. The test results showed that the developed sonar system was able to detect the underwater target about several kilometers away and could recognize a small object at the downside of the sonar system. We expect that the developed sonar system will be easily applied to other unmanned platforms without serious consideration.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.7 no.2
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• pp.52-59
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• 2008

The objective of this study is to develop an automatic object changer unit to improve processing problems existed in the conventional horizontal machining center. To achieve this goal, this study designed a horizontal transfer as the second project continued to the first project that designed a upward and downward traverse unit. A horizontal traverse unit shows a symmetric structure and consists of frame, which consists of four unit tools, motor and reducer, which are fixed at a frame, operation unit with pinions, first traverse unit, and second traverse unit. Constraint conditions based on the operation mechanism with these elements were configured and obtained following results after modeling a model for a traverse motor. In the kinematic expression of sliding motion with one degree of freedom, the sliding motion is constrained. Also, the rack 3 installed at a frame is used to configure possible kinematic constraint conditions of the rack 2 according to the rolling motion of the pinion 2 in the first traverse unit. In addition, the moment of inertia that is a type of kinetic energy in a converted horizontal traverse unit in the side of the reducer can be applied to introduce the moment of inertia of a converted horizontal traverse unit in the side of the reducer by using the sum of kinetic energy in the rack and pinion, which is a part of the horizontal traverse unit. Also, the equation of motion of the converted upward and downward traverse unit in the side of the motor using the equation of motion of the motor. Furthermore, the horizontal traverse unit predetermines the mass of the first and second traverse unit and applied load including the radius and reduction ratio of the pitch circle in the pinion 1 and applied load to the rack 2. Then, a proper motor can be determined using several parameters in the upward and downward traverse unit in order to verify such predetermined specifications. In future studies later this study, a simulation that verifies the results of the previous two stages of studies using a finite element method.