• 제목/요약/키워드: Double resonance

검색결과 244건 처리시간 0.026초

루비듐 5S1/2-5P3/2-4D3/2, 5/2 전이선에서의 이중공명 광펌핑 분광 (Bouble Resonance Optical Pumping in the Transition 5S1/2-5P3/2-4D3/2, 5/2 of Rb Atoms)

  • 문한섭;이림;김중복
    • 한국광학회지
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    • 제16권4호
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    • pp.297-303
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    • 2005
  • 우리는 $^{87}Rb$ 원자의 $5S_{1/2}-5P_{3/2}-4D_{3/2,\;5/2}$ 전이선을 이용하여 레이저의 세기, 편광조합, 그리고 정렬상태에 따른 이중공명광펌핑(double resonance optical pumping; DROP) 스펙트럼을 조사하였다. $5P_{3/2}-4D_{5/2}$ 전이선에서 레이저의 세기에 따른 초미세 구조간의 DROP 신호의 변화가 크게 나타났고, 그 원인은 순환전이선의 낮은 광펌핑 효율 때문이었다. 두 레이저의 편광조합을 달리 했을 때 이중공명의 전이율이 변하고, 이러한 효과가DROP스펙트럼의 변화로 나타났다. 또한 두 레이저가 같은 방향으로 진행하는 경우와 반대 방향으로 진행하는 경우를 비교했을 때, 스펙트럼의 선폭은 각각 12.2 MHz 와 6.9 MHz로 측정되었다.

무선전력전송의 효율에 영향 미치는 안테나 구조와 주파수 효과 (The Effects of Antenna Type and Frequency on Wireless Power Transmission)

  • 김응수
    • 한국멀티미디어학회논문지
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    • 제18권4호
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    • pp.541-545
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    • 2015
  • Wireless power transmission which can transmit the electrical power through the air is the promise technology. In this paper, the effects of wireless power transmission using magnetic resonance method have been studied on coil material, resonance frequency, and antenna type. We have found copper tube as a coil material had the better characteristics than that of enameled wire, and the optimal resonance frequency was 13.6MHz in the range of from 1MHz to 20MHz. And the double square spiral type antenna as a load coil was the best. The power transmission distance by magnetic resonance method with 13.6MHz was 150 cm.

Quantitative Evaluation of the First Order Creatine-Kinase Reaction Rate Constant in in vivo Shunted Ovine Heart Treated with Oxandrolone Using Magnetization Transfer 31P Magnetic Resonance Spectroscopy (MT-31P-MRS) and 1 H/31P Double-Tuned Surface Coil: a Preliminary Study

  • Thapa, Bijaya;Dahl, Marjanna;Kholmovski, Eugene;Burch, Phillip;Frank, Deborah;Jeong, Eun-Kee
    • Investigative Magnetic Resonance Imaging
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    • 제22권1호
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    • pp.26-36
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    • 2018
  • Purpose: Children born with single ventricle physiology demonstrate poor growth rate and suffer from malnutrition, which lead to increased morbidity and mortality in this population. We assume that an anabolic steroid, oxandrolone, will promote growth in these infants by improving myocardial energy utilization. The purpose of this paper is to study the efficacy of oxandrolone on myocardial energy consumption in these infants. Materials and Methods: We modeled single ventricle physiology in a lamb by prenatally shunting the aorta to the pulmonary artery and then postnatally, we monitored cardiac energy utilization by quantitatively measuring the first order reaction rate constant, $k_f$ of the creatine-kinase reaction in the heart using magnetization transfer $^{31}P$ magnetic resonance spectroscopy, home built $^1H/^{31}P$ transmit/receive double tuned coil, and transmit/receive switch. We also performed cine MRI to study the structure and dynamic function of the myocardium and the left ventricular chamber. The spectroscopy data were processed using home-developed python software, while cine data were analyzed using Argus software. Results: We quantitatively measured both the first order reaction rate constant and ejection fraction in the control, shunted, and the oxandrolone-treated lambs. Both $k_f$ and ejection fraction were found to be more significantly reduced in the shunted lambs compared to the control lambs, and they are increased in oxandrolone-treated lambs. Conclusion: Some improvement was observed in both the first order reaction rate constant and ejection fraction for the lamb treated with oxandrolone in our preliminary study.

Electron Paramagnetic Resonance Study on the Photoproduced Cation Radical of N-Methylphenothiazine in the Gel Matrices

  • Lee, Don-Keun;Zhang, Dong-Ri;Kang, Youn-Soo
    • 한국자기공명학회논문지
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    • 제6권2호
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    • pp.103-112
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    • 2002
  • The photoproduced cation radical of N-methylphenothiazine $(PC_1)$ doped into phenyltriehtoxysilane (PhiTEOS), vinyltriethoxysilane (VTEOS) and methyltriethoxysilane (METOS) was studied with electron spin resonance (ESR) and electron nuclear double resonance (ENDOR). The photoinduced charge separation efficiency was determined by integration of ESR spectra which correspond to the amount of photoproduced cation radical in the matrices. This was correlatively studied with the polarity and pore size of the gel matrices. The relative polarity of the matrices was determined by measuring ${\lambda}_{max}$ values of $PC_1$ in the different matrices. The relative pore size among the matrices was determined by measuring relative proton matrix ENDOR line widths of the photoproduced cation of $PC_1$. The decay kinetic constants of the cation radical of $PC_1$ in the different matrices with relatively studied with fitting the biexponential decay curves after exposure at the ambient condition. This is correlatively interpreted with the polarity and pore size of the matrices.

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H-1, C-13, and N-15 resonance assignments of ENOD40B, a plant peptide hormone

  • Young Kee Chae
    • 한국자기공명학회논문지
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    • 제27권2호
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    • pp.5-9
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    • 2023
  • t ENOD40B, a plant peptide hormone, was doubly labeled with C-13 and N-15 by recombinant production in Escherichia coli. The peptide was prepared by affinity chromatography followed by protease cleavage and reverse-phase chromatography. To elucidate the mode of action against its receptor, sucrose synthase, we proceeded to assign the backbone and side-chain resonances using a set of double and triple resonance experiments. This result will be used to determine the three-dimensional structure of the peptide at its bound state as well as to observe the chemical shift changes upon binding.

Extraordinary Optical Transmission and Enhanced Magneto-optical Faraday Effect in the Cascaded Double-fishnet Structure with Periodic Rectangular Apertures

  • Lei, Chengxin;Man, Zhongsheng;Tang, Shaolong
    • Current Optics and Photonics
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    • 제4권2호
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    • pp.134-140
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    • 2020
  • A significant enhancement of the magneto-optical Faraday rotation and extraordinary optical transmission (EOT) in the cascaded double-fishnet (CDF) structure with periodic rectangular apertures is theoretically predicted by using the extended finite difference time domain (FDTD) method. The results demonstrate that the transmittance spectrum of the CDF structure has two EOT resonant peaks in a broad spectrum spanning visible to near-infrared wavebands, one of them coinciding with the enhanced Faraday rotation and large figure of merit (FOM) at the same wavelength. It is most important that the resonant position and intensity of the transmittance, Faraday rotation and FOM can be simply tailored by adjusting the incident wavelength, the thickness of the magnetic layer, and the offset between two metallic rectangular apertures, etc. Furthermore, the intrinsic physical mechanism of the resonance characteristics of the transmittance and Faraday rotation is thoroughly studied by investigating the electromagnetic field distributions at the location of resonance. It is shown that the transmittance resonance is mainly determined by different hybrid modes of surface plasmons (SPs) and plasmonic electromagnetically induced transparency (EIT) behavior, and the enhancement of Faraday rotation is mostly governed by the plasmonic electromagnetically induced absorption (EIA) behavior and the conversion of the transverse magnetic (TM) mode and transverse electric (TE) mode in the magnetic dielectric layer.

Development of 600-MHz 19F-7Li Solid-State NMR Probe for In-Situ Analysis of Lithium Ion Batteries

  • Jeong, Ji-Ho;Park, Yu-Geun;Choi, Sung-Sub;Kim, Yongae
    • Bulletin of the Korean Chemical Society
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    • 제34권11호
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    • pp.3253-3256
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    • 2013
  • Lithium is a highly attractive material for high-energy-concentration batteries, since it has low weight and high potential. Rechargeable lithium-ion batteries (LIBs), which have the extremely high gravimetric and volumetric energy densities, are currently the most preferable power sources for future electric vehicles and various portable electronic devices. In order to improve the efficiency and lifetime, new electrode compounds for lithium intercalation or insertion have been investigated for rechargeable batteries. Solid-state nuclear magnetic resonance (NMR) is a very useful tool to investigate the structural changes in electrode materials in actual working lithium-ion batteries. To detect the in-situ microstructural changes of electrode and electrolyte materials, $^7Li-^{19}F$ double-resonance solid-state NMR probe with a static solenoidal coil for a 600-MHz narrow-bore magnet was designed, constructed, and tested successfully.

양단 공진과 듀티 컨트롤을 이용한 1-2cm 공극을 통한 에너지 전달 (Transcutaneous Energy Transmission with Double Tuned Duty Cycle Control)

  • 김창균;조보형
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1996년도 하계학술대회 논문집 A
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    • pp.486-488
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    • 1996
  • A dc-dc converter which transfers l2-48W of power(regulated output voltage 24V) across a large, variable air gap(1-2cm) has been designed. This converter employs double resonance to compensate the large leakage inductance of the primary and secondary of the transcutaneous transformer. To maximize the effect of resonance, a constant frequency, duty cycle control method is used. The duty cycle control presents advantages over a frequency control in terms of increase in dc voltage gain and reduction of the primary current. The analysis and design procedure for the proposed scheme is presented and the performance result is simulated and verified experimentally.

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Electronic Spectroscopy and Structure of CLF

  • Vadim A. Alekseev;D. W. Setser
    • Bulletin of the Korean Chemical Society
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    • 제21권1호
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    • pp.9-22
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    • 2000
  • Optical-optical double resonance experiments have been used to identify and characterize five ion-pair states and several of the bound and repulsive valence states of ClF. This report provides a description of these experiments for $^{35}CIF$ and $^{37}CIF$, and a summary of the current knowledge of the valence and ion-pair states. The important role of perturbations among the rovibronic levels of the bound valence states and their utilization in the double resonance technique is discussed. The ion-pair states of the same symmetry, ${\Omega}$=$0^+$ (E and f) and 1( $\beta$ and G) interact very strongly and the spectroscopy of these states is anomalous and, hence, interesting. Comparison is made to some recent ab initio calculations for ClF. One possible explanation of the irregular vibrational energy levels and rotational constants of the ion-pair states of $O^+$ and 1 symmetry is a crossing of the diabatic potentials of these states. Some currently unresolved questions about ClF spectroscopy are posed for future work. Where appropriate, analogy is made between the electronic states of ClF and the corresponding valence and ion-pair states of $Cl_2.$.