• 대한안전경영과학회:학술대회논문집
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• 대한안전경영과학회 2000년도 춘계학술대회
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• pp.369-374
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• 2000

• 한국전기화학회:학술대회논문집
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• 한국전기화학회 2000년도 추계총회 및 학술발표회
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• pp.44-44
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• 2000

• 대한안전경영과학회:학술대회논문집
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• 대한안전경영과학회 1999년도 추계학술대회
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• pp.345-354
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• 1999

A new type of capacitor named "Super Capacitor" has been developed, in which the properties of electric double layer formed at the interface of activated carbon electrode- liquid organic electrolyte is applied. This capacitor is small In size, light in weight, wide In temperature range(-25~$70^{\circ}C$), large in charge-discharge capability and good in voltage preservation. And this super capacitor is applied as a power back-up for electricity failure in volatile memory devices etc., a power source for a short time and a power source for operating actuators. At present the development of high power back-up types of the capacitor system and improvement of their characteristics are being actively conducted in order to find wider applications.lications.

• 전기화학회지
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• 제6권2호
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• pp.153-157
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• 2003

전기이중층 축전용량(electric double layer capacitance)과 유사축전용량(pseudo-capacitance)을 함께 갖는 하이브리드 전기화학 축전기에 대한 연구를 수행하였다. 양극은 $Ni(OH)_2$ 활성탄소가 복합된 전극을 사용하였으며 음극은 활성탄소를 활물질로 사용하므로써 비대칭 전극 구조를 갖는다. 셀 실험을 위하여 $5\times5cm^2$ 크기인 전극을 제작 사용하였다. Cyclic voltammetry측정 및 교류 임피던스 측정실험을 통하여 각각의 셀들이 갖는 전기화학적 거동을 조사하였고 충 방전 실험을 통하여 양극과 음극의 최적 질량비를 조사하였다.

• 한국전자통신학회논문지
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• 제11권11호
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• pp.1093-1100
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• 2016

본 연구는 슈퍼캐패시티 EDLC(:Electric double layer capacitor)를 적용한 가로등용 태양광-풍력 하이브리드 발전시스템 성능의 우수함과 안정성을 입증하고자 한다. 독립전원용 태양광-풍력 하이브리드 발전시스템의 부하로 LED 광원을 이용한 조명장치를 적용하고 고출력 발전시스템을 통한 가로등 시스템 장치의 개발을 목표로 하고 있다. 발전된 전력을 배터리에 저장하는데 있어서 보조장치로 적용될 EDLC는 기존의 컨트롤러와는 달리 배터리의 고출력과 긴 수명을 보장할 수 있어 기존장치에 비해 유지보수가 적게 들고 우수한 성능을 확보할 수 있다.

• 한국태양에너지학회 논문집
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• 제31권5호
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• pp.119-125
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• 2011

In this paper, we have studied about minimizing the Energy Storage System (ESS) capacity for mitigating the fluctuation of Wind Turbine Generation System (WTGS) by using Electric Double Layer Capacitor (EDLC) and Battery Energy Storage System (BESS). In this case, they have some different characteristics: The EDLC has the ability of generating the output power at high frequency. Thus, it is able to reduce the fluctuation of WTGS in spite of high cost. The BESS, by using Li-Ion battery, takes the advantage of high energy density, however it is limited to use at low frequency response. To verify the effectiveness of the proposed method, simulations are carried out with the actual data of 2MW WTGS in case of worst fluctuation of WTGS is happened. By comparing simulation results, this method shows the excellent performance. Therefore, it is very useful for understanding and minimizing the ESS capacity for mitigating the fluctuation of WTGS.

• Journal of Electrochemical Science and Technology
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• 제13권4호
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• pp.479-485
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• 2022

The power of energy storage devices is characterized by capacitance and the internal resistance. The capacitance is measured on an assumption that the charges are stored at the electrode interface and the electric double layer behaves like an ideal capacitor. However, in most cases, the electric double layer is not ideal so a constant phase element (CPE) is used instead of a capacitor to describe the practical observations. Nevertheless, another problem with the use of the CPE is that CPE does not give capacitance directly. Fortunately, a few methods were suggested to evaluate the effective capacitance in the literature. However, those methods may not be suitable for supercapacitors which are modeled as an equivalent circuit of a CPE and resistor connected in series because the time constant of the equivalent circuit is not clearly studied. In this report, in order to study the time constant of the CPE and find its equivalent capacitor, AC and DC methods are utilized in a complementary manner. As a result, the time constants in the AC and DC domains are compared with digital simulation and a proper equation is presented to calculate the effective capacitance of a supercapacitor, which is extended to an electrochemical system where faradaic and ohmic processes are accompanied by imperfect charge accumulation process.

• Carbon letters
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• 제16권2호
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• pp.78-85
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• 2015

Activated carbons (ACs) were prepared by activation of coal tar pitch (CTP) in the range of $700^{\circ}C-1000^{\circ}C$ for 1-4 h using potassium hydroxide (KOH) powder as the activation agent. The optimal activation conditions were determined to be a CTP/KOH ratio of 1:4, activation temperature of $900^{\circ}C$, and activation time of 3 h. The obtained ACs showed increased pore size distribution in the range of 1 to 2 nm and the highest specific capacitance of 122 F/g in a two-electrode system with an organic electrolyte, as measured by a charge-discharge method in the voltage range of 0-2.7 V. In order to improve the performance of the electric double-layer capacitor electrode, various mixtures of CTP and petroleum pitch (PP) were activated at the optimal activation conditions previously determined for CTP. Although the specific capacitance of AC electrodes prepared from CTP only and the mixtures of CTP and PP was not significantly different at a current density of 1 A/g, the AC electrodes from CTP and PP mixtures showed outstanding specific capacitance at higher current rates. In particular, CTP-PP61 (6:1 mixture) had the highest specific capacitance of 132 F/g, and the specific capacitance remained above 90% at a high current density of 3 A/g. It was found that the high specific capacitance could be attributed to the increased micro-pore volume of ACs with pore sizes from 1 to 2 nm, and the high power density could be attributed to the increased meso-pore volume.

• 전력전자학회논문지
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• 제15권3호
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• pp.188-198
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• 2010

최근들어, 전기이중층 커패시터 등의 친환경 전력저장장치의 수요가 증가하면서, 이를 위한 양방향 충/방전기의 수요 또한 증가하고 있다. 그러나, 기존의 상용화된 아날로그 제어기를 사용하는 DC-DC 컨버터를 충 방전기로 사용하게 되면, 충/방전 레퍼런스를 제공하는 상위 디지털 제어기와 별도로 아날로그 제어기를 제작해야 하는 문제가 있고, 회로가 복잡해지며, 모드전환 시 과도응답이 좋지 않다. 이에 대한 대안으로 단일 디지털 제어기를 사용하게 되면 쉽게 구현 가능한 설계방식을 이용하여 양방향 시스템의 성능을 향상 시킬 수 있다. 본 논문에서는 단일 회로 단 양방향 벅-부스트 컨버터에 전기이중층 콘덴서를 이용한 친환경 전력저장장치의 양방향 충/방전 시스템을 구현하고, DSP(TI사 TMS320F28335)를 이용한 디지털 제어기를 적용하였다. MATLAB simulink를 이용하여 모의실험을 수행하였고, 하드웨어를 구성하여 실험한 결과, 모의실험과 마찬가지로 양방향 시스템의 응답특성이 개선되었음을 보여주었다.

• 한국재료학회지
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• 제32권5호
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• pp.270-279
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• 2022

In this study, N/S co-doped carbon felt (N/S-CF) was prepared and characterized as an electrode material for electric double-layer capacitors (EDLCs). A commercial carbon felt (CF) was immersed in an aqueous solution of thiourea and then thermally treated at 800 ℃ under an inert atmosphere. The prepared N/S-CF showed a large specific surface area with hierarchical pore structures. The electrochemical performance of the N/S-CF-based electrode was evaluated using both 3-electrode and 2-electrode systems. In the 3-electrode system, the N/S-CF-based electrode showed a good specific capacitance of 177 F/g at 1 A/g and a good rate capability of 41% at 20 A/g. In the 2-electrode system (symmetric capacitor), the freestanding N/S-CF-based electrode showed a specific capacitance of 275 mF/cm² at 2 mA/cm², a rate capability of 62.5 % at 100 mA/cm², a specific power density of ~ 25,000 mW/cm² at an energy density of 23.9 mWh/cm², and a cycling stability of ~ 100 % at 100 mA/cm² after 20,000 cycles. These results indicate the N/S co-doped carbon felts can be a promising candidate as a new electrode material in a symmetric capacitor.