• 제목/요약/키워드: Distribution of particles

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충격보강제의 함유량과 분산이 나일론 6 복합체의 충격강도에 미치는 영향의 컴퓨터 해석 (Computer Simulation of the Effects of Content and Dispersion of Impact Modifier on the Impact Strength of Nylon 6 Composites)

  • 우정우;류민영
    • Elastomers and Composites
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    • 제49권4호
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    • pp.284-292
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    • 2014
  • 고분자 소재는 금속 소재에 비해 기계적 강도, 특히 충격강도가 매우 취약하기 때문에 이의 증대를 위해 충격보강제를 이용하는 경우가 많다. 이러한 충격강도는 충격보강제의 함량과 분포에 따라 변화한다. 본 연구에서는 충격보강제가 함유된 나일론 6 시편에 대해서 충격시험을 모사하였고 충격시편 단면에서의 응력분포를 통해 충격강도 증대원리를 관찰하였다. 시편 단면에서 충격보강제의 개수와 분포에 따른 해석을 하여 비교하였다. 충격보강제의 개수가 증가할수록 부피가 감소하는 모델의 경우 놋치 표면의 응력과 주응력의 크기가 점차 높게 나타났다. 충격보강제의 개수가 증가할수록 충격보강제 전체의 총 표면적이 증가하는 모델의 경우에는 응력과 주응력이 점차 높게 관찰되었다.

저농도의 HPC 영역에서 에멀젼법에 의해 제조된 구형 알루미나 분말의 입자 크기 변화 (Change of Particle Size of Spherical Alumina Powders Prepared by Emulsion Method in the Region of Low Hydroxypropylcellulose Concentration)

  • 안치원;박건식;유한수;조건;이영우;양명승
    • 한국세라믹학회지
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    • 제32권5호
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    • pp.594-600
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    • 1995
  • Spherical alumina gel powders were produced by hydrolysis of aluminum sec-butoxide (Al(sec-OC4H9)3) in a n-octanol/acetonitrile mixed solvent. The enlargement of particle size was induced by increasing HPC (hydroypropylcellulose) concentration (0.005, 0.1, and 0.05 g/ι) and emulsion-state aging time (10 min and 360 min). Mean particle sizes of dried alumina gel powders increased from 1.4 ${\mu}{\textrm}{m}$ to 3.5${\mu}{\textrm}{m}$ at 10-min emulsion-state aging time and from 1.9${\mu}{\textrm}{m}$ to 4.1${\mu}{\textrm}{m}$ at 360-min emulsion-state aging time as HPC concentration increased from 0.005 g/ι to 0.05 g/ι. At the same HPC concentration, particle size of dried alumina gel powder increased with increasing of emulsion-state aging time from 10 min to 360 min. The increase in the average particle size of dried alumina gel powder with increase in HPC concentration was interpreted as the enlargement of particles from alkoxide emulsions unprotected by HPC. The produced dried gel powder calcined at 115$0^{\circ}C$ for one hour transformed to $\alpha$-alumina.

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Modification of isotropic coal-tar pitch by acid treatments for carbon fiber melt-spinning

  • Yoo, Mi Jung;Ko, Hyo Jun;Lim, Yun-Soo;Kim, Myung-Soo
    • Carbon letters
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    • 제15권4호
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    • pp.247-254
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    • 2014
  • In this work, thermal treatment accompanied with different acid treatments was applied to a commercial coal tar pitch (CTP) to obtain a spinnable precursor pitch for carbon fiber. In the case of thermal treatment only, a relatively high reaction temperature of between $380^{\circ}C$ and $400^{\circ}C$ was required to obtain a softening point (SP) range of $220^{\circ}C-260^{\circ}C$ and many meso-phase particles were created during the application of high reaction temperature. When nitric acid or sulfuric acid treatment was conducted before the thermal treatment, the precursor pitch with a proper SP range could be obtained at reaction temperatures of $280^{\circ}C-300^{\circ}C$, which were about $100^{\circ}C$ lower than those for the case of thermal treatment only. With the acid treatments, the yield and SP of the precursor pitch increased dramatically and the formation of meso-phase was suppressed due to the lower reaction temperatures. Since the precursor pitches with acid and thermal treatment were not spinnable due to the inhomogeneity of properties such as molecular weight distribution and viscosity, the CTP was mixed with ethanol before the consecutive nitric acid and thermal treatments. The precursor pitches with ethanol, nitric acid, and thermal treatments were easily spinnable, and their spinning and carbon fiber properties were compared to those of air blowing and thermal treated CTP.

자갈하천 총유사량에 대한 소류사의 비율 (Ratio of Bedload to Total Sediment Load in Gravel-bed Rivers)

  • 박상덕
    • 한국지형학회지
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    • 제25권2호
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    • pp.15-29
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    • 2018
  • The sediment transport process in a river reflects the process of geomorphological change in the watershed, influencesthe river bed variation and the river channel migration, and is a parametric phenomenon that exhibits a dynamic self-adjusting process. Sediment load is divided into bedload and suspended load depending on the dominant mechanism. Quantitative sediment load is important information for solving river problems. Because it is difficult and time consuming to measure bedload, compared to that ofsuspended load, data on the sediment transport load and the research required for the gravel-bed rivers are insufficient. This study is to analyze the ratio of the bedload to the total sediment load in gravel-bed rivers. The sediment load ratio in gravel-bed rivers increases with the flow rate per unit width, and the rate of the bedload varies more rapidly than the suspended load. The sediment transport efficiency coefficient has been affected by the ratio of the flow depth to the mean diameter of particles and has been dependent on the shear velocity Reynolds number. So $A^{\ast}$ and $B^{\ast}$ are introduced to compensate for the uncertainties such as bed materials, sediment transport, and flow velocity distribution, and the coefficient of bedload ratio has been presented. For the sediment load data in experimental channels and rivers, A* was 3.1. The dominant variables of $B^{\ast}$ were $u_*d_m/{\nu}$ in the gravel-bed and h/dm in the sand-bed. When $B^{\ast}$ the is the same, in the experimental channels the coefficient of bedload ratio was affected by the bed forms, but in the rivers it was of little difference between the gravel-bed and sand-bed.

두파장 스캐닝 라이다 시스템을 이용한 고해상도 미세먼지 질량 농도 산출 (High Resolution Fine Dust Mass Concentration Calculation Using Two-wavelength Scanning Lidar System)

  • 노영민;김덕현;최성철;최창기;김태경;김가형;신동호
    • 대한원격탐사학회지
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    • 제36권6_3호
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    • pp.1681-1690
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    • 2020
  • 532와 1064 nm 두 파장 관측 채널을 구비하고 수평으로 360° 스캐닝 관측이 가능한 스캐닝 라이다 시스템을 개발하였다. 또한, 두 파장에서의 후방산란계수를 이용하여 미세먼지를 PM2.5-10(조대)와 PM2.5(미세)입자로 구분하는 분석도 개발하여 스캐닝 라이다 시스템의 데이터 분석에 적용하였다. 개발된 스캐닝 라이다를 이용한 울산 온산공단에서 관측에서 각각 22 - 110 ㎍/㎥과 7 - 78 ㎍/㎥의 분포를 보이는 PM10과 PM2.5의 질량 농도를 성공적으로 산출하였다. 분석된 결과는 라이다 관측 영역 주변에서 지상에서 측정된 질량농도와 유사한 값을 보였으며, 공장 등에서 배출되는 지점에서는 이 각각 80-110 ㎍/㎥과 60-78 ㎍/㎥의 고농도가 측정되는 사례를 확인하였다.

이단 필터 샘플러에 의한 대기 부유분진의 포집 및 금속 성분의 계절별 거동에 관한 연구 (Aerosol Sampling with Two Stage Filter Sampler and Seasonal Variation of Metal Components in the Atmosphere)

  • 이용근;김남훈;명노승;황규자
    • 한국대기환경학회지
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    • 제4권2호
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    • pp.20-27
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    • 1988
  • A simple two stage aerosol filter sampler which allows simultaneous and fractional collection of two different-size particles, coarse and fine, was constructed and applied to the collection of Seoul atmospheric particulate for inorganic analysis. The sampler consist of two 47-mm diameter filter holder, a pneumatic pump, and a flowmeter. Filtering rate normally runs around 20$\ell$/min for 8 hrs. Using the sampler, a series of seasonal aerosol samples were collected from June 1986 to March 1988 at Yonsei University campus, Seoul and subsequently analysed for ten environmentally important metals using an atomic absorption spectrometer and an inductively coupled plasma emission spectrometer. The analysed metals are Al, Cd, Cr, Cu, Fe, Mn, Ni, Pb, V, and Zn. The analytical results showed the following order of metal abundance; Al > Fe > Zn > Pb > Mn > Cu > V > Ni > Cr > Cd. Based upon their size distribution pattern, the analyzed matals could be clasified into two groups, those present primarily in coarse particle and those in fine particle. Fe, Al, Mn, V, and Cr belong to the former group while the rest to the latter. Most metal concentration were highest in spring or winter, and lowest in autumn. Statistical analysis showed strong correlations between Al and Fe, Pb and Zn, and Cu and Mn.

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SEN6 마그네슘합금의 미세조직과 인장 특성에 미치는 압출비와 압출 온도의 영향 (Effects of Extrusion Ratio and Extrusion Temperature on Microstructure and Tensile Properties of SEN6 Magnesium Alloy)

  • 김현지;이지윤;진상철;박성혁
    • 소성∙가공
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    • 제33권3호
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    • pp.178-184
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    • 2024
  • In this study, we investigated the effects of extrusion ratio and extrusion temperature on the microstructure and tensile properties of extruded Mg-6Al-0.3Mn-0.3Ca-0.2Y (SEN6) alloy. As the extrusion ratio and temperature increase, dynamic recrystallization during extrusion is promoted, leading to the formation of a fully recrystallized microstructure with increased grain size. Additionally, the increases in extrusion ratio and temperature lead to texture strengthening, exhibiting a higher maximum texture intensity. The extruded materials contain three types of secondary phases, i.e., Al8Mn4Y, Al2Y, and Al2Ca, with irregular or polygonal shapes. The quantity, size, distribution, and area fraction of the second-phase particles are nearly identical between the two materials. Despite its larger grain size, the tensile yield strength of the material extruded at 450 ℃ and an extrusion ratio of 25 (450-25) is higher than that of the material extruded at 325 ℃ and an extrusion ratio of 10 (325-10), which is mainly attributed to the stronger texture hardening effect of the former. The ultimate tensile strength is similar in the two materials, owing to the higher work hardening rate in the 325-10 extrudate. Despite differences in grain size and recrystallization fraction, numerous twins are formed throughout the specimen during tensile deformation in both materials; consequently, the two materials exhibit nearly the same tensile elongation.

수계 테이프 케스팅 법에 의한 봉상 γ-LiAlO2 입자 강화 MCFC 매트릭스 제조 공정의 최적화 (Optimization of Rod-shaped γ-LiAlO2 Particle Reinforced MCFC Matrices by Aqueous Tape Casting)

  • 최현종;신미영;현상훈;임희천
    • 한국세라믹학회지
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    • 제46권3호
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    • pp.282-287
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    • 2009
  • Rod-shaped particle reinforced $LiAlO_2$ matrices for MCFC were fabricated by an aqueous tape-casting technique. The hydrolysis reaction and agglomeration of $\gamma-LiAlO_2$ particles in aqueous slurries were inhibited by additions of $LiOH{\cdot}H_2O$ and glycerin to the aqueous $\gamma-LiAlO_2$ slurry. The tape-casting, performed using the aqueous slurry containing protein albumin, was fast and led to an effective drying at casting temperature range of $60{\sim}65^{\circ}C$. The strength of the particle reinforced matrix was improved about 4 times compared to that of matrix without reinforcement. Pore size distribution ($0.1{\sim}0.4{\mu}m$) and porosity ($50{\sim}60%$) of the reinforced matrices were determined to be appropriate for the MCFC matrix. The aqueous tape casting process is not only environmental-friendly but also efficient for fabricating MCFC matrices compared to non-aqueous tape casting.

분뇨잔사(糞尿殘渣)를 이용(利用)한 유기종합비료(有機綜合肥料) 개발(開發) (Development of Organic Compound Fertilizer Based on Treated Human Waste)

  • 신제성;성기석;임동규
    • 한국토양비료학회지
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    • 제17권1호
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    • pp.55-59
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    • 1984
  • 습식(濕式) 분뇨잔사중(糞尿殘渣中)의 인산(燐酸) 및 유기물(有機物)을 주축(主軸)으로하여 유기종합비료(有機綜合肥料)를 제조(製造)하였다. 분뇨잔사중(糞尿殘渣中)의 인산(燐酸) 가용율(可溶率)을 증가(增加)시키기 위하여 황산 및 당밀폐액을 처리(處理)하여 후숙시켰으며 황산 0.1N처리후(處理後) 24시간(時間) 후숙시킨 것이 인산(燐酸)의 가용율(可溶率)이 가장 높았다. 시제품(試製品)의 입도분포(粒度分布)는 접착제(接着劑)로 첨가(添加)된 당밀폐액양(量)에 따라 차이(差異)가 있었으며 양(量)이 증가(增加)될수록 입도(粒度)가 증가(增加)되었다. 시제품(試製品)의 입도(粒度)가 클수록 경도(硬度)는 증가(增加)되었으며 접착제(接着劑)로 처가(添加)된 당밀페액양(量)이 12.5%일 때 입자(粒子)의 경도(硬度)가 가장 높게 나타났다. 시제품(試製品)의 흡습도(吸濕度)는 요소(尿素)에 비(比)하여 대단(大端)히 높았으며 이는 시제품(試製品)의 물리(物理) 화학적(化學的) 특성(特性)에 기인(起因)되었다.

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나노 알루미늄 입자 첨가 추진제에 의한 탄소복합재 노즐의 기계적 삭마 감소 특성 예측 (Prediction of the Mechanical Erosion Rate Decrement for Carbon-Composite Nozzle by using the Nano-Size Additive Aluminum Particle)

  • ;김재호;;하동성;박재현;양희성
    • 한국추진공학회지
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    • 제19권6호
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    • pp.42-53
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    • 2015
  • 고체추진제에 첨가되는 알루미늄 입자의 크기에 따른 탄소 복합재 노즐의 기계적 삭마특성 변화를 예측하는 연구를 수행하였다. 추진제에 첨가되는 알루미늄 입자의 초기 크기에 따라 연소생성물 응집체($Al(l)/Al_2O_3(l)$)의 크기와 분포를 예측할 수 있는 모델을 개발하여 사용하였으며, 모델 예측 결과로 얻어지는 응집체의 크기를 초기조건으로 하여 상용 수치해석 프로그램(STAR CCM+)을 이용한 복합재 노즐에서의 기계적 삭마특성 해석을 수행하였다. 본 연구를 통해 초기 알루미늄 첨가제의 크기가 작을수록 응집체의 크기가 작아지고, 기계적 삭마가 감소하는 특성을 확인하였으며, 특히 나노입자를 사용할 때 기계적 삭마가 확연히 개선됨을 확인하였다.