• Journal of the Korean Ceramic Society
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• v.42 no.10 s.281
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• pp.649-653
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• 2005

A mono-disperse Ni powders for multilayer ceramic capacitors were prepared in a large scale by solution reduction method using $NiSO_{4}$ $N_{2}$$H_{4}$and NaOH. The exothermic reactions such as Ni-complex formation between highly concentrated $NiSO_{4}$ and $N_{2}$$H_{4}$ and the reduction of $Ni^{2+}$ into Ni provided thermal energy sufficient for spontaneous solution-reduction reaction. Because well-defined Ni particles could be prepared without external heating, the present method was named as 'auto-thermal method'. The formation of Ni­complex, the precipitation of $Ni(OH)_{2}$ gel triggered by NaOH addition, and its reduction into Ni by dissolution-recrystallization route were the reaction mechanism. The preparation of mono-disperse and spherical Ni powder was attributed to uniform distribution of reducing agent $N_{2}$$H_{2}$ within $Ni(OH)_{2}$ gel due to the decomposition of$NiSO_{4}$-$N_{2}$ $H_{4}$ complex.

• Journal of Sensor Science and Technology
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• v.10 no.2
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• pp.118-124
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• 2001

When particles are dissolved in solution, they have different zeta-potentials depending on pH. Zeta-potential has an influence on particle separation, which can control particle size. And the size of $WO_3$ particle affects the sensitivity of $WO_3$ sensor for detecting NO gas. Therefore we study influence of pH on NO-sensing $WO_3$ gas sensor fabricated by Sol-Coprecipitation method. As pH increases from 2 to 7, dynamic mobility of $WO_3$ precursor was increased. When pH was 7, it showed the largest distribution separation. It means when pH is 7, we can make $WO_3$ powder which has smaller particle size. And it is confirmed by particle size analysis of $WO_3$ powder, X-ray diffration result of $WO_3$ sensing layer and surface morphology. It also affect NO sensing characteristics of $WO_3$ gas sensor. The sensing film synthesized at pH 7 showed the largest sensitivity.

• Applied Chemistry for Engineering
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• v.18 no.6
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• pp.552-556
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• 2007

In this study, noble metals (Pd, Ru, Ir) were supported to $TiO_2$ catalyst. In order to distribute metals uniformly, $H_2O-H_2$ pretreatment technique was used. Xylene, toluene, and MEK were used as reactants. The monometallic or bimetallic catalysts were prepared by the excess wetness impregnation method and were characterized by XRD, and XPS analysis. Pd-Ru, Pd-Ir bimetallic catalysts had multipoint active sites which improved the range of Pd metal state. Bimetallic catalysts had a higher conversion of VOCs than that of monometallic one. The effect of $H_2O-H_2$ pretreatment technique was the enhancement of uniform distribution of Pd particles and promotion of catalytic efficiency. In this study, addition of Ru and Ir metals to Pd promoted oxidation conversion of VOCs. In addition, $H_2O-H_2$ pretreatment promoted removal efficiency of VOCs on the $TiO_2$ support.

• Proceedings of the SAREK Conference
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• 2008.11a
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• pp.561-566
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• 2008

The reciprocating compressor is widely used in the industry field, because it has simple principle and high efficiency. In this work, in order to improve design of discharge passage line in hydrogen compression system Numerical analysis was conducted. General information about an internal gas flow is presented by numerical analysis approach. Relating with hydrogen compressing system, which have an important role in hydrogen energy utilization, this should be a useful tool to observe the flow quickly and clearly. Flow characteristic analysis, including velocity, pressure and turbulence kinetic energy distribution of hydrogen gas going out from the cylinder to discharge-path line are presented in this paper. Discharge-passage model is designed based on real model of hydrogen compressor. Pressure boundary conditions are applied considering the real condition of operating system. The result shows velocity, pressure and turbulent kinetic energy are not distributed uniformly along the passage of the Hydrogen system. Path line or particles tracks help to demonstrate flow characteristics inside the passage. The existence of vortices and flow direction can be precisely predicted. Based on this result, the design improvement might be done.

• Elastomers and Composites
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• v.55 no.1
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• pp.59-66
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• 2020

Herein, we investigated the thermal conductivity and thermal stability of natural rubber composite systems containing hybrid fillers of boron nitride (BN) and aluminum nitride (AlN). In the hybrid system, the bimodal distribution of polygonal AlN and planar BN particles provided excellent filler-packing efficiency and desired energy path for phonon transfer, resulting in high thermal conductivity of 1.29 W/mK, which could not be achieved by single filler composites. Further, polyethylene glycol (PEG) was compounded with a commonly used naphthenic oil, which substantially increased thermal conductivity to 3.51 W/mK with an excellent thermal stability due to facilitated energy transfer across the filler-filler interface. The resulting PEG-incorporated hybrid composite showed a high thermal degradation temperature (T₂) of 290℃, a low coefficient of thermal expansion of 26.4 ppm/℃, and a low thermal distortion parameter of 7.53 m/K, which is well over the naphthenic oil compound. Finally, using the Fourier's law of conduction, we suggested a modeling methodology to evaluate the cooling performance in thermal management system.

• Journal of the Korean Association of Geographic Information Studies
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• v.14 no.2
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• pp.109-127
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• 2011

Atmospheric aerosols, small particles in the atmosphere, are one of the important parameters in climate change and human health. Additionally, accurate estimates of aerosol species are increasingly important in environmental impact assessment studies. Recent advances in global satellite remote sensing provide powerful tool for air quality monitoring. This study explores the potential usage of satellite derived data such as atmospheric aerosols for air quality monitoring as well as climate change study. The objectives of this study is to understand the general features of the global distribution of type dependent aerosols. A detailed spatio-temporal variability of the each different satellite dataset shows the variation of the global zonal average and specific geographical regions where the strong emission sources are located. Especially, significantly large aerosol amounts are observed in Asia and Africa because of the desert dust storm, anthropogenic and biomass burning emissions.

• Korean Journal of Materials Research
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• v.25 no.8
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• pp.386-390
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• 2015

Fe-base superalloy powders with $Y_2O_3$ dispersion were prepared by high energy ball milling, followed by spark plasma sintering for consolidation. High-purity elemental powders with different Fe powder sizes of 24 and 50 mm were used for the preparation of $Fe-20Cr-4.5Al-0.5Ti-O.5Y_2O_3$ powder mixtures (wt%). The milling process of the powders was carried out in a horizontal rotary ball mill using a stainless steel vial and balls. The milling times of 1 to 5 h by constant operation (350 rpm, ball-to-powder ratio of 30:1 in weight) or cycle operation (1300 rpm for 4 min and 900 rpm for 1 min, 15:1) were applied. Microstructural observation revealed that the crystalline size of Fe decreased with an increase in milling time by cyclic operation and was about 15 nm after 3 h, forming a FeCr alloy phase. The cyclic operation had an advantage over constant milling in that a smaller-agglomerated structure was obtained. The milled powders were sintered at $1100^{\circ}C$ for 30 min in vacuum. With an increase in milling time, the sintered specimen showed a more homogeneous microstructure. In addition, a homogenous distribution of Y-compound particles in the grain boundary was confirmed by EDX analysis.

• Journal of Powder Materials
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• v.29 no.2
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• pp.99-109
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• 2022

Powder flowability is critical in additive manufacturing processes, especially for laser powder bed fusion. Many powder features, such as powder size distribution, particle shape, surface roughness, and chemical composition, simultaneously affect the flow properties of a powder; however, the individual effect of each factor on powder flowability has not been comprehensively evaluated. In this study, the impact of particle shape (sphericity) on the rheological properties of Ti-6Al-4V powder is quantified using an FT4 powder rheometer. Dynamic image analysis is conducted on plasma-atomized (PA) and gas-atomized (GA) powders to evaluate their particle sphericity. PA and GA powders exhibit negligible differences in compressibility and permeability tests, but GA powder shows more cohesive behavior, especially in a dynamic state, because lower particle sphericity facilitates interaction between particles during the powder flow. These results provide guidelines for the manufacturing of advanced metal powders with excellent powder flowability for laser powder bed fusion.

• Journal of Adhesion and Interface
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• v.13 no.3
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• pp.109-115
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• 2012

Monodisperse blue-colored poly(styrene-co-acrylic acid) latices were successfully prepared by seeded emulsion polymerization. Blue-colored latices with carboxyl anionic charge on the surface were synthesized at the second stage with the introduction of Blue 606 dye, acrylic acid, and 0.21 ${\mu}m$-polystyrene seed. All the blue-colored latices synthesized in this study were in the size range of 0.25~0.42 ${\mu}m$ and all uniform with less than 1.01 in PSD. The particle size increased with the addition of acrylic acid being delayed and colloidally stable latices were obtained over 30 min after its addition. The blue-colored latex with 20 wt% acrylic acid showed -145 mV of zeta-potential and $-9.4{\times}10^{-6}\;cm^2/Vs$ of electrophoretic mobility, and with 25 wt% of DVB showed high $T_g$ at 396.7 K.

• Journal of Environmental Science International
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• v.23 no.2
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• pp.275-289
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• 2014

Asian dust (or yellow sand) occurring mainly in spring in East Asia is affected by the distribution of weather systems. This study was performed to investigate the characteristics of suspended particulate for Asian dust at Busan, Korea in 20 March 2010, which was one of the extreme case for the last 10 years. There was used the data of weather chart, satellite, automatic weather system (AWS), $PM_{10}$, laser particle counter (LPC), and backward trajectories model. In synoptically, the high pressure was located in the northwestern part and low pressure was located in the northeastern part of Korea. The strong westerly winds from surface to upper layer makes it possible to move air masses rapidly. Air masses passing through Gobi Desert in Mongolia and Inner Mongolia plateau covered the entire Korean peninsula. As the results of aerosol analysis, $PM_{10}$ concentration at Gudeok mountain in Busan was recorded $2,344{\mu}g/m^3$ in 2300 LST 20 March 2010 and their concentration was markedly increased at coarse mode particle. In surface condition, westerly wind about 3 ~ 5 m/s was dominant and small particles of $0.3{\sim}0.5{\mu}m$ were distributed on the whole. In heavy metal components analysis, the elements from the land was predominated.