• Economic and Environmental Geology
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• v.34 no.1
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• pp.105-117
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• 2001

The characteristics of hydrogeochemistry and fluorine distribution in drinking groundwater from limestone and granite were studied in the Keumsan-Wanju area, where major important fluorite-deposits are distributed. The hydrochemical properties of groundwater from studied area arc commonly characterized as $Ca-HC0_3$ water type. However, some of the groundwater samples collected from Jurassic and Cretaceuus granites belong to $Ca-Na-HC0_3 and Na-HC0_3$ type, respectively. The contamination of drinking groundwater by minewater from the nearby fluorite deposits is not found yet. However, groundwater having high F contents up to 1].4 mgll, which is higher than the drinking water limit, is found from the wells located in Cretaceous granite. The tluorine contents in groundwater generally increase with increasing well depth. The concentrations of F in the groundwater show a positive relationship with the values of Na, $HC0_3, Cl. Si0_2$, pH, whereas a negative relationship with Ca. The positive correlation of F-concentrations to major elements ($Si0_2$, Na, CI) and trace elements (Li, B, Rb) may suggest that the groundwater come from the decomposition of tluoride-bearing silicate minerals within highly differentiated granitic rocks, Therefore, wells for drinking water should not be developed or should be drilled within shallow level in the Cretaceous granite region to reduce the F contents in the groundwater.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.04a
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• pp.289-292
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• 2004

In order to identify the origin and nature of the spilled oil in the potential source, we analyzed the pattern of alkyi PAM(Polynuclear Aromatic Hydrocarbons) in fuel standard and environmental samples. Alkyl PAM patterns are used for fuel-type identification in weathered environmental samples. Detection of alkyl PAH was achieved by operation CC/MS in the SIM mode. We chose ions of naphthalene(m/z 128), C1-naphthalene(m/z 142), C2-naphthalene(m/z 156), C3-naphthalene(m/z 170), C4-naphthalene(m/z 184) for the comparison of this pattern according to the type of fuel. We analyzed tile pattern of alkyl PAH in neat gasoline, kerosene, diesel, and JP-8, and in groundwater samples which were collected in monitoring wells. The distribution map of alkyl-naphthalene shows different patterns among four different fuel types (gasoline, kerosene, diesel, and JP-8). Particularly, tile distribution map of kerosene and JP-8 is found to be of value in identifying fuel type in that the difference is clear. Therefore distribution patterns of alkyl-PAH compounds provide another useful tool for fuel-type identification of petroleum fuels.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.34 no.6
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• pp.1797-1806
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• 2014

By far, groundwater management has been conducted by 'safe yield' policy based on the estimation of annual average of groundwater recharge throughout the world. However, as groundwater recharge show spatiotemporal variation, dynamic analysis must be carried out to evaluate the sustainable groundwater resources. In this study, an integrated surface-groundwater model, SWAT-MODFLOW was used to compute the spatial distribution of groundwater recharge in Gyungju region. Frequency analysis is adopted to evaluate the existing values of potential amount of groundwater development which is made by the 10 year drought frequency rainfall multiplied by recharge coefficient. The conservative methods for estimating recharge rates of 10 year drought frequency in subbains are newly suggested and compared with the existing values of potential amount of groundwater development. This process will promote the limitations for existing precesses used for computing potential amount of groundwater development.

• The Journal of Engineering Geology
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• v.28 no.4
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• pp.593-603
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• 2018

The most of groundwater with high U-concentration occur in the Jurassic granite of Gyeonggi massif and Ogcheon belt, and some of them occur in the Cretaceous granite of Ogcheon belt. On the contrary, they do not occur in the Jurassic granite of Yeongnam massif and the Cretaceou granite of Gyeongsang basin. The Jurassic and Cretacous granite, the host rock of high U-groundwater, were resulted from parental magma with high ratio of crustal material and highly differentiated product of fractional crystalization. These petrogenetic characteristics explain the geological evidence for preferential distribution of uraniferous groundwater in each host rock. It were reported recently that high U-content, low Th/U ratio and soluble mineral occurrence of uraninite in the two-mica granite of Daejeon area which have characteristics of S-type peraluminous and highly differntiated product. It is the mineralogical-geochemical evidences supporting the fact that the two-mica granite is the effective source of uranium in groundwater. The biotite granite and two-mica granite of Jurassic age were reported as biotite granite in many geological map even though two-mica granite occur locally. This fact suggest that the influence of two-mica granite can not be ignored in uraniferous groundwater hosted by biotite granite.

• 한국신재생에너지학회:학술대회논문집
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• 2005.06a
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• pp.701-704
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• 2005

Aquifer Thermal Energy Storage (ATES) can be a cost-effective and renewable geothermal energy source, depending on site-specific and thermohydraulic conditions. To design an effective ATES system having influenced by groundwater movement, understanding of thermo hydraulic processes is necessary. The heat transfer phenomena for an aquifer heat storage are simulated using FEFLOW with the scenario of heat pump operation with pumping and waste water reinjection in a two layered confined aquifer model. Temperature distribution of the aquifer model is generated, and hydraulic heads and temperature variations are monitored at the both wells during 365 days. The average groundwater velocities are determined with two hydraulic gradient sets according to boundary conditions, and the effect of groundwater flow are shown at the generated thermal distributions of three different depth slices. The generated temperature contour lines at the hydraulic gradient of 0.00 1 are shaped circular, and the center is moved less than 5m to the groundwater flow direction in 365 days simulation period. However at the hydraulic gradient of 0.01, the contour center of the temperature are moved to the end of boundary at each slice and the largest movement is at bottom slice. By the analysis of thermal interference data between two wells the efficiency of the heat pump system model is validated, and the variation of heads is monitored at injection, pumping and no operation mode.

• Journal of the Korean Association of Geographic Information Studies
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• v.9 no.3
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• pp.107-122
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• 2006

The main objective of this study is to develop a web-based Geographic Information System (GIS) application, IGIS(Integrated Groundwater Information Service System), for efficient management of groundwater data. This integrated system includes various groundwater measurements, monitoring data, well data, hydrogeochemical data, hydrogeological maps and diversely analyzed results including time series analysis data for water levels and quality. It will be used efficiently for local government officers to manage groundwater within their districts and also for drillers and investigators to develop wells and assess groundwater conditions. This web-based GIS system was implemented firstly for Cheonan and Daegu city. As a result, the system makes the efficient management, distribution and utilization of groundwater data possible by web-based GIS technology.

• Journal of Soil and Groundwater Environment
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• v.21 no.6
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• pp.101-113
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• 2016

To properly manage and remediate groundwater contaminated with chlorinated hydrocarbons such as trichloroethylene (TCE), it is necessary to assess natural attenuation processes of contaminants in the aquifer along with investigation of contamination history and aquifer characterization. This study evaluated natural attenuation processes of TCE at an industrial site in Korea by delineating hydrogeochemical characteristics along the flow path of contaminated groundwater, by calculating reaction rate constants for TCE and its degradation products, and by using geochemical and reactive transport modeling. The monitoring data showed that TCE tended to be transformed to cis-1,2-dichloroethene (cis-1,2-DCE) and further to vinyl chloride (VC) via microbial reductive dechlorination, although the degree was not too significant. According to our modeling results, the temporal and spatial distribution of the TCE plume suggested the dominant role of biodegradation in attenuation processes. This study can provide a useful method for assessing natural attenuation processes in the aquifer contaminated with chlorinated hydrocarbons and can be applied to other sites with similar hydrological, microbiological, and geochemical settings.

• Journal of Environmental Science International
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• v.25 no.11
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• pp.1563-1573
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• 2016

The aim of this study was to evaluate the occurrence of vanadium in Jeju Island groundwater, focusing on the spatio-temporal patterns and geochemical controlling factors of vanadium. For this, we collected two sets of groundwater data: 1) concentrations of major constituents of 2,595 groundwater samples between 2008 and 2014 and 2) 258 groundwater samples between December 2006 and June 2008. The concentrations of groundwater vanadium were in the range of $0.2{\sim}71.0{\mu}g/L$ (average, $12.0{\mu}g/L$) and showed local enrichments without temporal/seasonal variation. This indicated that vanadium distribution was controlled by 1) the geochemical/mineralogical composition and dissolution processes of original materials (i.e., volcanic rock) and 2) the flow and chemical properties of groundwater. Vanadium concentration was significantly positively correlated with that of major ions ($Cl^-$, $Na^+$, and $K^+$) and trace metals (As, Cr, and Al), and with pH, but was negatively correlated with $NO_3-N$ concentration. The high concentrations of vanadium (>$15{\mu}g/L$) occurred in typically alkaline groundwater with high pH (${\geq}8.0$), indicating that a higher degree of water-rock interaction resulted in vanadium enrichment. Thus, higher concentrations of vanadium occurred in groundwater of $Na-Ca-HCO_3$, $Na-Mg-HCO_3$ and $Na-HCO_3$ types and were remarkably lower in groundwater of $Na-Ca-NO_3$(Cl) type that represented the influences from anthropogenic pollution.

• Journal of Soil and Groundwater Environment
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• v.18 no.3
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• pp.33-51
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• 2013

Spatial and temporal characteristics of nitrate contamination and hydrogeochemical parameters were investigated for springs and surficial and bedrock groundwaters in northeastern part of Hongseong. Two field investigations were conducted at dry and wet seasons in 2011 for 120 sites including measurement of field parameters with chemical analyses of major dissolved constituents. Nitrate concentrations were at background levels in springs while 45% of bedrock groundwater and 49% of surficial groundwater exceeded the drinking water standard of nitrate (10 mg/L as $NO_3$-N). The difference in nitrate concentrations between surficial and bedrock groundwater was statistically insignificant. Cumulative frequency distribution of nitrate concentrations revealed two inflection points of 2 and 16 mg/L as $NO_3$-N. Correlation analysis of hydrogeochemical parameters showed that nitrate had higher correlations with Sr, Mg, Cl, Na, and Ca, in surficial groundwater in both dry and wet season. In contrast, nitrate had much weaker correlations with other hydrogeochemical parameters in bedrock groundwater compared to surficial groundwater and had significant correlations only in wet season. Temporally, nitrate and chloride concentrations decreased and dissolved oxygen (DO) increased from dry season to wet season, which indicates that increased recharge during the wet season affected groundwater quality. Aerobic conditions were predominant for both surficial and bedrock groundwater indicating low natural attenuation potential of nitrate in the aquifers of the study area.

• Journal of Soil and Groundwater Environment
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• v.12 no.5
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• pp.64-72
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• 2007

Nationwide occurrence of arsenic in groundwater of Korea was investigated with the data from the groundwater quality monitoring stations. During 2001-2006, As has been quantitatively detected in 3.0 % of the total wells $(5.0{\sim}188{\mu}g/L)$, and its geographical distribution suggests 3 groups: an urbanized and industrialized area (Seoul and its neighbouring province), and two naturally occurring areas (Chungbuk and Gyeongnam provinces). Natural occurrence of As appears to be geologically related with Ogcheon metasedimentary rocks and Cretaceous volcanic rocks. Based on the results of the previous studies in the high As sites, the oxidation of sulfides can be a major control on As concentrations in groundwater in the mineralized and altered zone within the area of Cretaceous volcanic rocks. Desorption process under slightly high pH conditions may also be responsible for high As in groundwater in areas of Ogcheon metasedimentary rocks.