• Title/Summary/Keyword: Distillate

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A Case Study on Lower Extremity Ulcer (하지부 궤양 치험 1례)

  • Kyou Young Lee
    • The Journal of Korean Medicine Ophthalmology and Otolaryngology and Dermatology
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    • v.37 no.1
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    • pp.86-96
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    • 2024
  • Objectives : The aim of this study is to report a case showing rapid skin regeneration and recovery by applying Korean medicine treatment to lower extremity ulcer. Methods : We treated a female patient with idiopathic right leg ulcer by Korean medicine treatment such as herbal medicine, acupuncture, pharmacopuncture, Coptidis Rhizoma distillate wet dressing, and Jawoongo application. The treatment effect was evaluated by visual observation through photography, measurement of the area of the affected area, NRS(Numeral Rating Scale) for the level of discomfort, DLQI(Dermatology life quality index), and treatment satisfaction. Results : After Korean medicine treatment, recovery of skin tissue, reduction in affected area, and decrease in NRS for discomfort and DLQI were observed, and satisfaction with Korean medicine treatment was also high at 80%. Conclusions : This study shows that Korean medicine treatment can be effective in treating skin ulcers. We hope that research of Korean medicine treatment on skin ulcers will be promoted in the future.

Physical and Chemical Characteristics of Oilsands Bitumen Using Vacuum Distillation (감압증류장치를 이용한 Oilsands Bitumen의 물리화학적 특성 연구)

  • Kim, Kyoung-Hoon;Jeon, Sang-Goo;Roh, Nam-Sun;Kim, Kwang-Ho;Shin, Dae-Hyun;Park, Hyo-Nam;Han, Myung-Wan
    • Journal of Energy Engineering
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    • v.17 no.1
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    • pp.15-22
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    • 2008
  • This study was carried out to investigate physical and chemical characteristics of the distillates and residue of Athabasca oilsand bitumen obtained from Canada, using a vacuum distillation unit. The distillates and residue produced from the vacuum distillation were characterized through atomic analysis, SARA analysis, and measurement of boiling point distribution, molecular weight, and API gravity. The vacuum distillation equipment consisted of a 6-litter volume vessel, a glass-packed column, a condenser, a reflux device, a flask fer collecting distillates, and a temperature controller. The cutting of distillates was performed with four steps under the condition of full vacuum and maximum temperature of $320^{\circ}C$. The results showed that the sulfur amount and average molecular weight of the distillates were significantly reduced compared to those of oilsand bitumen. As the cutting temperature increased, the hydrogen amount decreased but the sulfur amount and average molecular weight increased in the distillates.

Separation and Purification of 2,6-dimethylnaphthalene in the Light Cycle Oil(II) - Separation of Individual Isomers of Dimethylnaphthalene - (접촉분해경유에 함유된 2,6-dimethylnaphthalene의 분리, 정제(II) - Dimethylnaphthalene 이성체 성분간 분리 -)

  • Kim, Su Jin;Kim, Sang Chai;Kawasaki, Junjiro
    • Applied Chemistry for Engineering
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    • v.7 no.5
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    • pp.869-876
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    • 1996
  • Purification of 2,6-dimethylnaphthalene(2,6-DMNA) from the distillate containing a mixture of dimethylnaphthalene(DMNA) isomers of very high concentration was investigated by crystallization-recrystallization combination as a after-treatment for separation and purification of 2,6-DMNA in the light cycle oil(LCO). The separation of individual isomers of DMNA was studied by crystallization with the distillate as a feed. 2,6-DMNA, 2,7-dimethylnaphthalene(2,7-DMNA) and 2,3-dimethylnaphthalene(2,3-DMNA) were concentrated to crystal, and it was fould that separation between a group of 2,6-, 2,7-, 2,3-DMNA isomers and a group of the other DMNA isomers was possible. However, it was not possible to separate 2,6-, 2,7- and 2,3-DMNA from one another. To select the most suitable recrystallization solvent for purification of 2,6-DMNA, several conventional solvents, which have been employed commercially as recrystallization solvents for high purity performance, were tested, through measurement of solubility of 2,6- and 2,7-DMNA. The solvent used were hexane, iso-propyl ether, ethyl acetate and ethanol. From the solubility results for 2,6- and 2,7-DMNA, ethanol seemed to be the most suitable solvent for purification of 2,6-DMNA. Finally, with crystal recovered by crystallization as a feed and ethanol as a solvent, recrystallization experiments were conducted under various conditions. Purification of 2,6-DMNA was easily done with increasing operating temperature and solvent to feed ratio. These results show that the crystallization-recrystallization combination is an effective one for separation of individual isomers of DMNA.

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Studies on the Distillation Operation of Baikha-ju (백하주의 증류조작에 관한 연구)

  • Min, Young-Kyoo;Yun, Hyang-Sik;Jeong, Heon-Sang
    • Applied Biological Chemistry
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    • v.37 no.1
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    • pp.9-13
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    • 1994
  • Baikhaju, the traditional Korean rice wine was brewed and distilled at various conditions-at different pressure (760, 460, 260 mmHg), different reflux ratio (3.1 : 1, 1 : 1) and different column conditions (packed and unpacked), and distillation operation was investigated. The sample wine, Baikhaju showed alcohol content of 14.2%, acidity 8.3 (g/100 ml), ethyl acetate 49 ppm, fusel oil 657 ppm. As the distillation was proceeded, alcohol concentration of distillate was decreased and that was higher in atmospheric pressure rather than reduced pressure. When the pressure was increased, the slope showed the relation of alcohol concentration between still liquid and vapour was increased, and also as the reflux ratio was increased, alcohol concentration of distillate was increased, and that was 0.56 mole at the reflux ratio 3.1 : 1 at atmospheric pressure, where 0.54 mole at 1 : 1 reflux ratio. As the distillation was proceeded, the rate of distillation was decreased, and that was higher values in the reduced pressure than atmospheric pressure. The maximum value (0.14 ml/s) of rate of distillation was observed in the packed column at 260 mmHg. As the reflux ratio was increased, the rate of distillation was decreased, and that was 0.05 ml/sec at reflux ratio 3.1 : 1 at atmospheric pressure, where 0.06 ml/sec at 1 : 1 reflux ratio.

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A New Method to Identify PCA Oil Type through Solvent Extraction and Separation Skills in a SBR Vulcanizate (SBR 가황물에서 용매추출 및 분리에 의한 PCA 오일 Type 확인법)

  • Kim, Min-Saeng;Sohn, Kyung-Suk;Lee, Jung-Hun;Kim, Ik-Sik;Choi, Sung-Seen
    • Elastomers and Composites
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    • v.47 no.1
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    • pp.36-42
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    • 2012
  • More than 3 wt% of polycyclic aromatics (PCAs) in process oil is known to cause skin cancer. The criterion of distinguishing between low PCA oil and high PCA oil is based on 3 wt% of PCA. High PCA oil is called as a carcinogen like distillate aromatic extract (DAE). Low PCA oil is considered as safety oils like treated distillate aromatic extract (TDAE), mild extract solvate (MES), and paraffinic oil. Four types of process oils such as DAE, TDAE, MES, and paraffinic oil purified by solvent extraction and separation skills from SBR vulcanizates were measured by FT-IR techniques. The effects of rubber chemicals such as N-1,3-dimethylbutyl-N'-phenyl-p-phenylnenediamine (HPPD), polymerized 2,2,4-trimethyl-1,2-dihydroquinoline (TMDQ), paraffin wax as antidegradants, and processing aid like Structol 40MS on paraffinic oil from SBR vulcanizates were also studied. The type of low or high PCA was identified by the relative abundance of absorbance at the aromatic substitution patterns of 864, 810, and $754cm^{-1}$ and at the paraffinic or naphthenic pattern of $721cm^{-1}$.

A Numerical Study for the Maximizing Water Vapor Flux and Thermal Efficiency in Direct Contact Membrane Distillation (DCMD) Process (직접 접촉식 막증류 공정에서 담수 투과량 및 열효율 극대화를 위한 수치적 연구)

  • Kim, Sang-Hun;Lee, Jung-Gil;Kim, Woo-Seung
    • Membrane Journal
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    • v.22 no.5
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    • pp.369-380
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    • 2012
  • A one-dimensional numerical model based on the energy and mass equations have been developed to predict the trans membrane water vapor flux and thermal efficiency under various operating conditions in Direct Contact Membrane Distillation (DCMD) process. The model validation have been carried out by experimental data from literature and showed good agreement. The effect of operating parameters such as brine inlet temperature and velocity, and distillate inlet temperature and velocity to increase water vapor flux and thermal efficiency were predicted by the steady-state model. The results showed that the inlet temperature and velocity in brine side are dominant factors to control the water vapor flux and thermal efficiency because the effect of inlet temperature and velocity in brine side showed the higher water vapor flux and thermal efficiency than that of inlet temperature and velocity in distillate side. The water vapor flux was increased 3.4 times in the range of 21.22 $kg/m^2h$ to 71.26 $kg/m^2h$ and the thermal efficiency was increased 37.5% in that of 0.556 to 0.765 with increasing brine inlet temperature from $60^{\circ}C$ to $95^{\circ}C$. Meanwhile, the water vapor flux was increased 30% in that of 27.91 $kg/m^2h$ to 36.33 $kg/m^2h$ and thermal efficiency increased 7.5% in that of 0.6 to 0.646 as the brine inlet velocity was increased from 60 m/h to 300 m/h.

GTL(Gas-to-Liquid) 기술 현황

  • Jun, Gi-Won
    • Journal of Energy Engineering
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    • v.16 no.2
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    • pp.58-63
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    • 2007
  • In recent years, the technologies for the production of synthetic fuel from natural gas have been attracting considerable interest because of high oil prices. While oil prices remaining high, GTL (Gas-to-Liquids) technology would provide an attractive option for utilizing gas resources. Furthermore, GTL fuels contain almost zero sulfur and low aromatics and have a very high cetane so that they are estimated to be environmentally friendly diesel fuels able of meeting the advanced fuel specifications of the 21st century. GTL process generally consists of three primary steps: synthesis gas production from natural gas reforming, hydrocarbon production from synthesis gas by Fischer-Tropsch (F-T) synthesis, product upgrading by hydrocracking/hydroisomerization. This paper presents a brief summary of GTL technology and worldwide development trend about it focusing on the reforming of natural gas and the F-T synthesis.

Volatile Sulfur Components from Fresh Radishes of Korean Origin (한국산 무우의 휘발성 함유황화합물에 관하여)

  • Kim, Mee-Ree;Rhee, Hei-Soo
    • Korean journal of food and cookery science
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    • v.1 no.1
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    • pp.33-39
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    • 1985
  • The volatile sulfur components from two varieties of radishes ('Taeback' and 'Altali'), obtained by steam distillation and solvent ($CCl_4$) extraction, were isolated and charac-terized by GC/MS analysis. The GC profile of the volatile sulfur com-pounds in the steam distillates from two types of radishes was quite similar. 4-Me-thylpentyl, 3-methylthiopropyl, 4-methylthio-3-butenyl, 4-methylthiobutyl and 5-methyl-thiopentyl isothiocyanates, 5-methylthio-4-pentenenitrile, 1-methylthio-3-pentanone, and dimethyl sulfides were commonly identified. In the $CCl_4$ extract, 4-methylsulfinyl-3-bu-tenyl isothiocyanate was obtained as another major constituent. Whereas 4-methylthiobutyl isothiocyanate was found to be a predominent component in the steam distillate, 4-methylthio-3-butenyl isothiocyananate was a major one in the $C1_4$ extract.

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Desalination of geothermal water by membrane distillation

  • Gryta, M.;Palczynski, M.
    • Membrane and Water Treatment
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    • v.2 no.3
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    • pp.147-158
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    • 2011
  • Membrane distillation process was used for desalination of hot (333 K) geothermal water, which was applied in the plant producing heating water. The investigated water contained 120 g salts/$dm^3$, mainly NaCl. The mineral composition was studied using an ion chromatography method. The obtained rejection of solutes was closed to 100%, but the small amounts of $NH_3$ also diffused through the membrane together with water vapour. However, the composition of obtained distillate allowed to use it as a makeup water in the heating water system. The geothermal water under study was concentrated from 120 to 286 g NaCl/$dm^3$. This increase in the solution concentration caused the permeate flux decline by a 10-20%. The geothermal water contained sulphates, which was subjected to two-fold concentration to achieve the concentration 2.4-2.6 g $SO{_4}{^{2-}}/dm^3$ and the sulphates then crystallized in the form of calcium sulphate. As a results, an intensive membranes scaling and the permeate flux decline was observed. The XRD analysis indicated that beside the gypsum also the NaCl crystallites were deposited on the membrane surfaces. The fresh geothermal water dissolved the mixed $CaSO_4$ and NaCl deposit from the membrane surface. This property can be utilized for self-cleaning of MD modules. Using a batch feeding of MD installation, the concentration of geothermal water was carried out over 800 h, without significant performance losses.

Study on Lacquer Formation in Combined of Marine Fuel Oil and Marine Lubricant Oil (선박용 연료유와 윤활유의 조합에 의한 락커 형성에 관한 연구)

  • Hong, Sung-Ho;Park, JongKuk;Ryoo, Young Seok
    • Tribology and Lubricants
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    • v.31 no.3
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    • pp.86-94
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    • 2015
  • We perform lacquer formation experiments with various combinations of marine fuel oils and lubricant oils. We also investigate the influences of base number (BN) in lubricant oil and sulfur content in fuel oil. A dissolution test with 10% dilute sulfuric acid and pull-off force test are accomplished to distinguish whether the residual layers are lacquering or not. The lacquering layers are dissolved by dilute sulfuric acid and have a strong pull-off force. Moreover, the calcium content detected in the residual layers is compared by energy dispersive x-ray spectroscopy (EDS). More calcium is detected in the lacquer layers than in other residual layers. Distillate fuels containing low sulfur levels are more prone to lacquering when mixed with lubricant oil with a high BN. On the other hand, residual fuels with a high sulfur content do not form lacquer. We investigate the effect of mixture volume ratio. The mixture with higher fuel oil content is more prone to generate lacquer. These experiments indicate that a lubricant with an appropriate BN should be used to prevent lacquer forming on the surfaces such as cylinder liners depending on the sulfur content of fuel oil.