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The Configuration and Polyelectrolyte Behavior of Carboxymethyl Chitin in Low Concentration Solution (저농도 용액에서의 Carboxymethyl Chitin의 사슬배좌와 전해질 거동)

  • PARK Seong-Min;LEE Keun-Tae;KIM Sang-Moo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.28 no.4
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    • pp.451-456
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    • 1995
  • To elucidate the intrinsic rheological properties of carboxymethyl chitin (CM-chitin) from the shell of red snow cyab (Chinonecetes japonicus), the configuration and polyelectrolyte behavior of CM-chitin in low concentration solution were investigated. Unperturbed dimensions were ranged from $127{\AA}\;to\;113{\AA}$ as root mean square end-to-end distance$(r_0)$, $52{\AA}$ to $46{\AA}$ as radius of gyration$(S_0)$. The intramolecular expansion tarter(a) was not varied with molecular weight and was 2.1. And effective bond length $(b_0)$ was $14.5{\AA}$. In perturbed condition, Flory constant was $2.35\times10^{21}$. When ionic strength were 0.02 and 1.0, intrinsic viscosity were 1.95dl/g and 1,06 dl/g, respectively. These results suggested that CM-chitin is a polyelectrolyte in aqueous media. At infinite ionic strength, intrinsic viscosity was 0.91dl/g. The intrinsic stiffness of CM-chitin backbone was estimated by evaluating the stiffness parameter (B) as 0.11 and agreed well with the results of k-carrageenan.

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Effect of Plant Hormone on the Regeneration of Myagropsis myagroides(Fucales, Sargassaceae) (외톨개모자반(Myagropsis myagroides)의 재생장에 미치는 식물호르몬의 효과)

  • KIM Joong-Rae;LEE Jong-Hwa
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.18 no.3
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    • pp.271-277
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    • 1985
  • As the fundamental studies for the population of Myagropsis myagroides, the effect of plant hormones on the regeneration for the primary, secondary lateral and receptacle segments were investigated. At high concentration($10^{-3}M\;and\;10^{-4}M$) of plant hormones inhibits from regenerating and lower concentrations advance the regeneration. The most effective concentrations of hormones on the primary lateral segments are $10^{-6}M$ of kinetine, IAA, NAA and $10^{-5}M$ of 2, 4-D in order, meanwhile in the secondary lateral segment $10^{-6}M$ of NAA, $10^{-8}M$ of kinetine, $10^{-7}M$ of IAA, and $10^{-5}M$ of 2, 4-D in order. The net regeneration rates of primary and secondary lateral segments which are measures by the wet weight are $124.1\%\;and\;228.9\%$, respectively. The influence of apical dominanace on the primary lateral segments decreases, on the other hand, increases in the secondary lateral segments because of the distance from the apex, Especially, the secondary lateral segments treated with below $10^{-5}M$ plant hormone are matures with receptacle of small branching by the regenerated branching.

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Development and Verification of the Automated Cow-Feeding System Driven by AGV (무인이송로봇기반 자동 소사료 공급 시스템 개발 및 검증)

  • Ahn, Sung-Su;Lee, Yong-Chan;Yoo, Ji-Hun;Lee, Yun-Jung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.3
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    • pp.232-241
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    • 2017
  • This paper presents an automated cow-feeding system based on an AGV and screw conveyor for domestic livestock farms, which are becoming larger and more commercialized. The system includes a hopper module for loading pellet-type mixed feed at the top of the system, a transfer module mounted with a screw conveyor to transfer feed from the hopper module to the outlet module, an outlet module composed of belt conveyors, and an electromagnetic guided driving-type AGV. The weight of the loaded feed is measured by a load cell located under the transfer module. The system reads the feed discharge information stored in RFID tags installed in each cowshed cell, and a predetermined amount of feed is discharged while the AGV is moving. A cow-feed test system was constructed to determine the design parameters of the screw conveyor in the transfer module that determine the feeding capacity. These parameters include the screw's outer diameter, the screw shaft outer diameter, and screw pitch. The parameters were applied to the finalized cow-feed system construction. A DSP-based main controller and cow-feeding algorithm for different scenarios were also developed to control the system. Experimental results confirmed that the system could supply a total of 21 kg of feed uniformly at 420 g/s for a cowshed cell which has 7 cows. The driving distance was 5 m and the speed was 0.1 m/s. Thus, the proposed system could be applied to standardized domestic livestock farms.

Preparation of Polymethylene-bridged Half-Titanocenes and Investigation of Their Styrene Polymerization Properties (폴리메틸렌 다리를 가진 Dinuclear Half-Titanocene 합성과 이에 의한 스티렌 중합 연구)

  • 태원태;김상현;노석균;김태학;이동호
    • Polymer(Korea)
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    • v.24 no.2
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    • pp.159-167
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    • 2000
  • The polymethylene-bridged dinuclear half-titanocenes [(CH$_2$)$_{n}$(C$_{5}$ H$_4$)$_2$][TiCl$_3$]$_2$ (n=5(10), 7(11), 9(12)) have been synthesized by treating the distannylated derivatives of the ligands with two equivalents of TiCl$_4$ in toluene. All complexes are characterized by IR, $^1$H NMR, $^{13}$ C NMR and mass spectrometry. In order to examine the catalytic properties of the dinuclear complexes styrene polymerization has been conducted in the presence of MMAO. From the polymerization experiments it was found that ( i ) all the prepared complexes 10-12 produced syndiotactic polystyrenes, ( ii ) the complex 12 holding the longest bridging ligand exhibited the highest activity but produced a polymer having the smallest molecular weight among the polymethylene-bridged dinuclear half-titanocenes. This behavior was attributed to the influence of electron-donating caused by the polymethylene bridge between two active centers as well as the effect of steric congestion around metal center caused by the proximal distance between two active sites.s.

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Population Structure of Bluegill, Lepomis macrochirus in Lakes of the Han River System, Korea (한강수계 댐호의 블루길, Lepomis macrochirus 개체군 구조)

  • Song, Ho-Bok;Byeon, Myeong-Seop;Kang, Dong-Won;Jang, Chang-Yeol;Moon, Jeong-Sook;Park, Hae-Kyung
    • Korean Journal of Ichthyology
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    • v.24 no.4
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    • pp.278-286
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    • 2012
  • This study was examined for information of management of bluegill, Lepomis macrochirus which is disturbance species of underwater ecosystem in Korea. Research of bluegill population was investigated spring-summer and autumn periods in the Han river system from 2009 to 2012. Bluegill inhabited mostly lakes, and restrictedly lived at still area in downstream. The range of relative abundance were 0.2~18.2% in individual number and 0.2~40.0% in biomass and it was subdominant or superiority species for the most part of the lakes. Population structure were analyzed r-strategy in Lake Soyang and Paldang and K-strategy in Lake Uiam and Cheongpyeong. But Lake Chungju was estimated transition period from K-strategy to r-strategy. Condition factor and body weight-total length relations were presented favorable condition. For the nesting, bluegill was formatted the group. And the water depth and the distance from shore were mean 56.3 cm and 191.9 cm respectively in nesting ground. Diameter and depth of nests were mean 42.4 cm and 9.7 cm respectively. These results are available for research of population dynamics and reproductive ecology of bluegill.

Disaster Recovery Priority Decision for Credit Bureau Business Information System: Fuzzy-TOPSIS Approach (신용조회업무 정보시스템의 재난복구 우선순위결정: 퍼지 TOPSIS 접근방법)

  • Yang, Dong-Gu;Kim, Ki-Yoon
    • Management & Information Systems Review
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    • v.35 no.3
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    • pp.173-193
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    • 2016
  • The aim of this paper is to extend the TOPSIS(Technique for Order Preference by Similarity to Ideal Solution) to the fuzzy environment for solving the disaster recovery priority decision problem in credit bureau business information system. In this paper, the rating of each information systems and the weight of each criterion are described by linguistic terms which can be expressed in trapezoidal fuzzy numbers. Then, a vertex method is proposed to calculate the distance between two trapezoidal fuzzy numbers. According to the concept of the TOPSIS, a closeness coefficient is defined to determine the ranking order of all information systems. The combination between the fuzzy set and TOPSIS brings several benefits when compared with other approaches, such that the fuzzy TOPSIS require few fuzzy judgements to parameterization, which contributes to the agility of the decision process, it does not limit the number of alternatives simultaneously evaluated, and it does not cause the ranking reversal problem when a new alternative is included in the evaluation process. This paper is demonstrated with a real case study of a credit rating agency involving 9 evaluation criteria and 9 credit bureau business information systems assessed by 6 evaluators, and provide the systematic disaster recovery framework for BCP(Business Continuity Planning) to practitioner. Finally, this paper show that the procedure of the proposed fuzzy TOPSIS method is well suited as a decision-making tool for the disaster recovery priority decision problem in credit bureau business information system.

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Theoretical Evaluation of the Post Tensioning Effect in Continuous Slabs (연속 슬래브의 포스트 텐셔닝 보강에 대한 이론적 분석)

  • Kim, Chang-Hyuk;Kim, Kang-Su;Kim, Sang-Sik
    • Journal of the Korea Concrete Institute
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    • v.21 no.1
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    • pp.105-116
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    • 2009
  • Reinforced concrete (RC) structures have been most widely used because of their good economic efficiency. However, it is very weak in tensile stresses and difficult to control deflection due to the heavy self-weight of concrete. On the other hand, it is generally known that prestressed concrete structures can be the most effective to overcome the demerits of RC structures by using various tendon lay-out and its amount. In the prestressed concrete members, the inflection points of tendons should be placed effectively for the deflection control and the moment reduction. Therefore, in this study, the equations of tendon profiles are derived in terms of polynomials that satisfy essential conditions of tendon geometries such as inflection points and natural curved shapes of tendons placed in continuous members, from which vertical components of prestressing forces can be also calculated. The derived high order polynomial expression for the distributed shape of the upward and downward forces was transformed to an simplified equivalent uniform vertical force in order to improve the applicability in the calculation of member deflection. The influences of vertical forces by tendons to deflection and moment in a continuous slab were also considered depending on the distance from column face to the location of tendons. The applicability of the proposed method was examined by an example of deflection calculation for the cases of slabs with and without tendons, and the efficiency of deflection control by tendons was also quantitatively estimated.

Enhancement of the Chaperone Activity of Alkyl Hydroperoxide Reductase C from Pseudomonas aeruginosa PAO1 Resulting from a Point-Specific Mutation Confers Heat Tolerance in Escherichia coli

  • Lee, Jae Taek;Lee, Seung Sik;Mondal, Suvendu;Tripathi, Bhumi Nath;Kim, Siu;Lee, Keun Woo;Hong, Sung Hyun;Bai, Hyoung-Woo;Cho, Jae-Young;Chung, Byung Yeoup
    • Molecules and Cells
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    • v.39 no.8
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    • pp.594-602
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    • 2016
  • Alkyl hydroperoxide reductase subunit C from Pseudomonas aeruginosa PAO1 (PaAhpC) is a member of the 2-Cys peroxiredoxin family. Here, we examined the peroxidase and molecular chaperone functions of PaAhpC using a site-directed mutagenesis approach by substitution of Ser and Thr residues with Cys at positions 78 and 105 located between two catalytic cysteines. Substitution of Ser with Cys at position 78 enhanced the chaperone activity of the mutant (S78C-PaAhpC) by approximately 9-fold compared with that of the wild-type protein (WT-PaAhpC). This increased activity may have been associated with the proportionate increase in the high-molecular-weight (HMW) fraction and enhanced hydrophobicity of S78C-PaAhpC. Homology modeling revealed that mutation of $Ser^{78}$ to $Cys^{78}$ resulted in a more compact decameric structure than that observed in WT-PaAhpC and decreased the atomic distance between the two neighboring sulfur atoms of $Cys^{78}$ in the dimer-dimer interface of S78C-PaAhpC, which could be responsible for the enhanced hydrophobic interaction at the dimer-dimer interface. Furthermore, complementation assays showed that S78C-PaAhpC exhibited greatly improved the heat tolerance, resulting in enhanced1 survival under thermal stress. Thus, addition of Cys at position 78 in PaAhpC modulated the functional shifting of this protein from a peroxidase to a chaperone.

A Study of High School Students' Conceptions for Density (고체와 액체의 밀도에 대한 고등학생들의 개념 조사)

  • Cho, In-Young;Kang, Young-Jin
    • Journal of the Korean Chemical Society
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    • v.54 no.6
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    • pp.809-817
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    • 2010
  • The primary purpose of this study was to investigate high school students' conceptual understanding of density for solids and liquids in pure and mixed substances who had preceded formal school science instruction on density and related topics. A concept assessment on density was developed and administered by demonstrative experiments accompanied by a written assessment test method to 120 general high school students in a metropolitan city. The scientific conceptions and alternative conceptions from students' responses were identified and the percentages of them were calculated. Then, their alternative conceptions and implicit theories on density were analyzed. About half of the students couldn't differentiate weight-volume-density and regarded density as an innate property of matter. Furthermore, the greater the number of variables involved in an experimental condition of the question, the more complicated and undifferentiated students' density concepts were. Students employed more improper variables such as particle size, intermolecular distance, surface tension, polarity of the solvent, etc. in explaining counter-intuitive observations. The implications for school science instruction were discussed.

Weed Control Technology with Low Concentration Ethanol in Protected Cereal Crop Cultivation (비닐하우스 내 조 재배시 저농도 에탄올을 이용한 잡초억제 효과)

  • Hwang, Jae-Bok;Yun, Eul-Soo;Park, Chang-Young;Jung, Ki-Youl;Choi, Young-Dae;Jeon, Sung-Ho;Lee, Yong-Hwan
    • Korean Journal of Weed Science
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    • v.32 no.2
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    • pp.115-120
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    • 2012
  • Weed control is of fundamental importance when planting cereal crops, particularly during the establishment phase. Weeds compete for nutrients, water and light, and can severely threaten the survival and early growth of newly planted crops. Field experiment was conducted to evaluate the effect of ethanol treatment on the weed control efficacy in cereal crops in protected vinylhouse. Five treatments like water, 25 L, 50 L, 75 L, and 100 L per $m^{-2}$ at 2% ethanol were applied and covered with vinyl on 10 days before foxtail millet seeding. After that, foxtail millet seeds were sown on June 20 at $60{\times}10cm$ planting distance and weed control efficacy was recorded at 30, and 50 days after seeding based on the dry weight. Soil oxidation-reduction potential was recorded -200~-400 mV after treatment 2 days. Weed control efficacy of at 75 L, and 100 L per $m^{-2}$ was observed 92%, 84% in 2% ETOH, respectively. Yields of foxtail millet at 75 L, and 100 L per $m^{-2}$ were 1,570 kg $ha^{-1}$, 1,230 kg $ha^{-1}$, respectively.