• Title/Summary/Keyword: Dissolved precipitates

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Transient Liquid Phase Bonding of Directionally Solidified Ni Base Superalloy, GTD-111(II) -Microstructural Change of Base Metal during Bonding Process - (일방향응고 Ni기초내열합금 GTD-111의 천이액상확산접합(II) -접합공정에서 모재조직의 변화-)

  • 강정윤;황형철;김인배;김대업;우인수
    • Journal of Welding and Joining
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    • v.21 no.2
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    • pp.89-96
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    • 2003
  • The change of microstructures in the base metal during transient liquid phase bonding process of directionally Ni base superalloy, GTD-111 was investigated. Bonds were fabricated using a series of holding times(0-7.2ks) at three different temperatures(1403, 1418 and 1453K) under a vacuum of 13.3mPa. In raw material, ${\gamma}$- ${\gamma}$' eutectic phases, platelet η phases, MC carbide and PFZ were seen in interdendritic regions or near grain boundary and size of primary ${\gamma}$' precipitates near interdendritic regions were bigger than core region. The primary ${\gamma}$' precipitates in dendrite core were dissolved early in bonding process, but ${\gamma}$' precipitates near interdendritic regions were dissolved partially and shape changed. The dissolution rate increased with increasing temperature. Phases in interdendritic regions or near pain boundary continually changed with time at the bonding temperature. In the bonding temperature of 1403K, eutectic phases had not significantly changed, but η phases had transformed from platelet shape to needle morphology and PFZ region had widened with time. The interdendritic region and near pain boundary were liquated partially at 1423k and fully at 1453k by reaction of η phases and PFZ. In the bonding temperature of 1453K, interdendritic region and near pain boundary were liquated and then new phases which mixed with η phases, PFZ and MC carbide crystallized during cooling. Crystallized η phases transformed from rod shape to platelet shape with increasing holding time.

Effects of PWHT on the toughness of weld HAZ in Cu-bearing HSLA-100 steel (Cu를 함유한 HSLA-100강 용접 열 영향부의 인성에 미치는 PWHT의 영향)

  • 박태원;심인옥;김영우;강정윤
    • Proceedings of the KWS Conference
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    • 1995.04a
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    • pp.91-93
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    • 1995
  • A study was made to examine the effects of post-weld heat treatment (PWHT) on the toughness and microstructures in the weld heat-affacted zone(HAZ) of Cu-bearing HSLA-100 steel. The Gleeble thermal/mechanical simulator was used to simulate the weld HAZ. The behavior of Cu-precipitates in HAZ is similar to that in base plate. PWHT at 55$0^{\circ}C$ shows highest hardness and lowest toughness, whereas PWHT at $650^{\circ}C$ shows reasonable toughness. Cu precipitated during agcing for increasing the strength of base metal is dissolved during single thermal cycle to 135$0^{\circ}C$ and is precipitated little on cooling and heating during subsequent weld thermal cycle. It precipitates by introducing PWHT.

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Geochemical Equilibria and Kinetics of the Formation of Brown-Colored Suspended/Precipitated Matter in Groundwater: Suggestion to Proper Pumping and Turbidity Treatment Methods (지하수내 갈색 부유/침전 물질의 생성 반응에 관한 평형 및 반응속도론적 연구: 적정 양수 기법 및 탁도 제거 방안에 대한 제안)

  • 채기탁;윤성택;염승준;김남진;민중혁
    • Journal of the Korean Society of Groundwater Environment
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    • v.7 no.3
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    • pp.103-115
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    • 2000
  • The formation of brown-colored precipitates is one of the serious problems frequently encountered in the development and supply of groundwater in Korea, because by it the water exceeds the drinking water standard in terms of color. taste. turbidity and dissolved iron concentration and of often results in scaling problem within the water supplying system. In groundwaters from the Pajoo area, brown precipitates are typically formed in a few hours after pumping-out. In this paper we examine the process of the brown precipitates' formation using the equilibrium thermodynamic and kinetic approaches, in order to understand the origin and geochemical pathway of the generation of turbidity in groundwater. The results of this study are used to suggest not only the proper pumping technique to minimize the formation of precipitates but also the optimal design of water treatment methods to improve the water quality. The bed-rock groundwater in the Pajoo area belongs to the Ca-$HCO_3$type that was evolved through water/rock (gneiss) interaction. Based on SEM-EDS and XRD analyses, the precipitates are identified as an amorphous, Fe-bearing oxides or hydroxides. By the use of multi-step filtration with pore sizes of 6, 4, 1, 0.45 and 0.2 $\mu\textrm{m}$, the precipitates mostly fall in the colloidal size (1 to 0.45 $\mu\textrm{m}$) but are concentrated (about 81%) in the range of 1 to 6 $\mu\textrm{m}$in teams of mass (weight) distribution. Large amounts of dissolved iron were possibly originated from dissolution of clinochlore in cataclasite which contains high amounts of Fe (up to 3 wt.%). The calculation of saturation index (using a computer code PHREEQC), as well as the examination of pH-Eh stability relations, also indicate that the final precipitates are Fe-oxy-hydroxide that is formed by the change of water chemistry (mainly, oxidation) due to the exposure to oxygen during the pumping-out of Fe(II)-bearing, reduced groundwater. After pumping-out, the groundwater shows the progressive decreases of pH, DO and alkalinity with elapsed time. However, turbidity increases and then decreases with time. The decrease of dissolved Fe concentration as a function of elapsed time after pumping-out is expressed as a regression equation Fe(II)=10.l exp(-0.0009t). The oxidation reaction due to the influx of free oxygen during the pumping and storage of groundwater results in the formation of brown precipitates, which is dependent on time, $Po_2$and pH. In order to obtain drinkable water quality, therefore, the precipitates should be removed by filtering after the stepwise storage and aeration in tanks with sufficient volume for sufficient time. Particle size distribution data also suggest that step-wise filtration would be cost-effective. To minimize the scaling within wells, the continued (if possible) pumping within the optimum pumping rate is recommended because this technique will be most effective for minimizing the mixing between deep Fe(II)-rich water and shallow $O_2$-rich water. The simultaneous pumping of shallow $O_2$-rich water in different wells is also recommended.

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Impact of the Silicate Polymerization on the Formation of Insoluble Aluminium Silicate (수 중 존재하는 실리케이트의 존재형태가 불용성 알루미늄실리케이트 형성에 미치는 영향)

  • Gwon, Eun-Mi;Hong, Seung-Kwan;Kim, Ji-Hyong;Jung, Wook-Jin;Yoo, Myung-Jin
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.6
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    • pp.654-661
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    • 2007
  • The goal of this research was to identify the impact of silicate polymerization on the formation of insoluble aluminiumsilicate salts which could be a cause of irreversible fouling in the membrane process by lab-scale test. For this, the amount and characteristics of precipitates that were formed in six samples with different Al and Si concentration were analyzed. And the particles was also observed by SEM-EDS(Scanning Electron Microscope - Electron Dispersion Spectrophotometer) to compare morphology and ratio of Al and Si in each precipitates. Finally the reactive and nonreactive silicate contents in the solution and precipitates were analyzed to calculate silicate form content in each fraction. The amount of precipitates was in proportion to the total concentration of both element in solution. And the amount of insoluble particle that was not dissolved in the acid solution was recorded the highest in the sample 2 of which Si concentration was lower than the saturation concentration, 50 mg/L. The content of reactive silicate in precipitates was also recorded the highest value in sample 2 of which almost silicate form was reactive. When the silicate concentration is same, that value was recorded the highest in the sample with highest Al concentration. The SEM morphology of the precipitates was similar to that of Aluminiumhydroxide and the insoluble precipitates was not dissolved in acidic solution with pH 2.7 was able to observed only in sample 2. The ratio of Al and Si in the precipitates was ranged $0.48\sim3.14$, thai of sample 2 was recorded the highest value, 3.14. It is concluded that the insoluble aluminiumsilicate could be easily formed in the solution of which silicate exist as a reactive form and coexisting Al is sufficient.

Laboratory Weathering Experiment on Mica and Feldspar and Their Mineralogical Characteristics (운모와 장석의 실내 풍화실험 및 광물학적 특성)

  • Lee, Seung-Yeop;Kim, Soo-Jin;Cho, Won-Jin
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.2 s.48
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    • pp.63-69
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    • 2006
  • When rocks are exposed to the near surface environment, they are broken down due to several factors such as physical and chemical weathering during the geologic time. The feldspar and mica, which are the main rock-forming minerals, are easily broken down relative to other minerals. In order to reproduce some weathered minerals similar to the ones exist in natural weathered granite, there was an experimental interaction between fresh minerals and acidic solution. In low pH condition, biotite initially dissolved and its surface structure broke down, whereas plagioclase dissolved and had a needle-shaped dissolved morphology with some precipitates composed of Al element. The minerals were deeply dissolved in a strong acid condition, showing the prominent dissolved structure. Some etch pits and dissolved textures developed on the natural mineral surfaces are similarly found in our experiment, suggesting the development of mineral dissolution and weathering texture by the influence of the mineral's intrinsic nature.

A Study of Al(III) Hydrolysis Species Characterization under Various Coagulation Condition (응집 pH와 응집제 종류에 따른 Al(III)가수분해종 특성변화에 대한 연구)

  • Song, Yu-Kyung;Jung, Chul-Woo;Sohn, In-Shik
    • Journal of Korean Society on Water Environment
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    • v.22 no.5
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    • pp.958-967
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    • 2006
  • The overall objective of this research was to find out the role of rapid mixing conditions in the species of hydrolyzed Al(III) formed by Al(III) coagulants and to evaluate the distribution of hydrolyzed Al(III) species by coagulant dose and coagulation pH. When an Al(III) salt was added to water, monomers, polymers and solid precipitates may form. Different Al(III) coagulants (alum and PSOM) show to have different Al(III) species distribution over a rapid mixing condition. During the rapid mixing period, for alum, formation of dissolved AI(III) (monomer and polymer) increases, but for PSOM, precipitates of $Al(OH)_{3(S)}$ increases rapidly. During the rapid mixing period, for high coagulant dose, Al-ferron reaction increases rapidly. The kinetic constants, Ka and Kb, derived from AI-ferron reaction. The kinetic constants followed very well the defined tendencies for coagulation condition. For pure water, when the rapid mixing time increased, the kinetic constants, Ka and Kb showed lower values. Also, for raw water, when the rapid mixing time increased, the kinetic constants, Ka and Kb showed lower values. At A/D(Adsorption and Destabilization) and sweep condition, both $Al(OH)_{3(S)}$ and dissolved Al(III) (monomer and polymer) exist, concurrent reactions by both mechanism appear to cause simultaneous precipitation.

Characteristics of Salt Weathering and Environmental Variation on the Usuki Stone Buddha Statues in Oita, Japan (일본 오이타현 우스키 마애불상군의 환경변화와 염풍화 특성)

  • Cho, Ji Hyun;Lee, Chan Hee
    • Economic and Environmental Geology
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    • v.53 no.6
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    • pp.677-685
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    • 2020
  • The host rock of the Usuki Stone Buddha Statues is dark gray welded tuff involved the Aso-4 pyroclastic flow sediments. This Buddha Statues are processing chlorosis from rainfall flowing above and underground water which were urgently needed for conservation measurement. White precipitates, the main source of salt weathering, on the surface of the Buddha Statues are mainly consisted of thenardite, gypsum and dolomite. Extraction experiment result shows that thenardite was dissolved at the beginning of stirring and then redissolved after 4 hours, and gypsum was detected until stirring for 2 hours, and then dissolved after stirring for 4 hours. As a result of monitoring the microclimate environment for 11 months to determine the recrystallization environment of white precipitates, the phase transition between thenadite and mirabilite appears widely in spring, and is maintained in an aqueous solution due to high temperatures in summer and fall. In winter, mirabilite is shown the widest by decreasing temperature. Therefore we requires details monitoring for blocking water transfer port and solved humidity environment in shelter.

Microstructural Evolution of Grade 91 Steel upon Heating at 760~1000℃

  • He, Yinsheng;Chang, Jungchel;Lee, Je-Hyun;Shin, Keesam
    • Korean Journal of Materials Research
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    • v.25 no.11
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    • pp.607-611
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    • 2015
  • The microstructural evolution of Grade 91 tempered martensite ferritic steels heat treated at $760{\sim}1000^{\circ}C$ for two hours was investigated using scanning electron microscopy(SEM), energy disperse spectroscopy(EDS), electron backscattered diffraction (EBSD), and transmission electron microscopy(TEM); a microhardness tester was also employed, with a focus on the grain and precipitate evolution process as well as on the main hardening element. It was found that an evolution of tempered martensite to ferrite($760{\sim}850^{\circ}C$), and to fresh martensite($900{\sim}1000^{\circ}C$), occurred with the increase of temperature. Simultaneously, the parabolic evolution characteristics of the low angle grain boundary(LAGB) increased with the increase of the heating temperature(highest fraction of LAGB at $925^{\circ}C$), indicating grain recovery upon intercritical heating. The main precipitate, $M_{23}C_6$, was found to be coarsened slightly at $760{\sim}850^{\circ}C$; it then dissolved at $850{\sim}1000^{\circ}C$. Besides this, $M_3C$ cementite was formed at $900{\sim}1000^{\circ}C$. Finally, the experimental results show that the hardness of the steel depended largely on the matrix structure, rather than on the precipitates, with the fresh martensite showing the highest hardness value.

In Vitro Reaction for Calcium Phosphate Ceramics

  • Ioku, Koji;Toya, Hiroyuki;Fujimori, Hirotaka;Goto, Seishi
    • The Korean Journal of Ceramics
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    • v.6 no.3
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    • pp.214-218
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    • 2000
  • Hydroxyapatite (HA) and $\beta$-tricalcium phosphate ($\beta$-TCP) are bio-compatible materials with bones and teeth. HA has been widely applied as bone substitutes because of chemical stability in vivo, while $\beta$-TCP has higher resorbability than HA when the material is implanted in a bone defect. In the present study, both HA and $\beta$-TCP porous ceramics were soaked in the simulated body fluid in order to investigate the reaction between the materials and the fluid. After the soaking test, carbonate hydroxyapatite was formed on HA surface at 1 week, and then the amount of precipitates increased with increasing period of the soaking test. While $\beta$-TCP was not dissolved in the fluid, carbonate hydroxyaopatite was also formed on $\beta$-TCP surface after 12 weeks, and the amount of precipitates was less than that on HA. In vitro behavior of HA was similar to that in vivo, but in vitro behavior of $\beta$-TCP was not similar to that in vivo.

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Simultaneous Preconcentration and Determination of Trace Elements in Water Samples by Coprecipitation-Flotation with Lanthanum Hydroxide $[La(OH)_3]$

  • 김영상;김기찬
    • Bulletin of the Korean Chemical Society
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    • v.16 no.7
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    • pp.582-588
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    • 1995
  • The preconcentration and determination of trace Cd(Ⅱ), Cu(Ⅱ), Pb(Ⅱ), Mn(Ⅱ) and Zn(Ⅱ) in water samples were studied by the precipitate flotation using La(OH)3 as a coprecipitant. The analytes were quantitatively coprecipitated by adding 3.0 mL of 0.1 M La(Ⅲ) solution in a 1,000 mL water sample and adjusting the pH to 9.5 with NaOH solution. After the addition of the 1:8 mixed surfactant solution of each 0.1% sodium oleate and sodium lauryl sulfate, the solution was stirred with a magnetic stirrer for 10 minutes. The precipitates were floated to the surface by bubbling with nitrogen gas and collected in a small sampling bottle. The precipitates were dissolved in nitric acid and then the solutions were diluted to 25.00 mL with a deionized water. The analytes were determined by flame atomic absorption spectrometry. This procedure was applied to the waste water analysis. This technique was simple, convenient and especially rapid for the analysis of a large volume of sample. And also, from the recoveries of better than 92% which were obtained from real samples, this method could be judged to be applicable to the preconcentration and quantitative determination of trace elements in water samples.