• 제목/요약/키워드: Dissolved carbon

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유해화학물질의 생태계 모델링 - I. 동경만 Nonylphenol의 환경동태 해석 - (Ecological modeling for toxic substances - I . Numerical simulation of transport and fate of Nonylphenol in Tokyo Bay-)

  • 김동명
    • 한국환경과학회지
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    • 제14권9호
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    • pp.827-835
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    • 2005
  • A three-dimensional ecological model (EMT -3D) was applied to Nonylphenol in Tokyo Bay. EMT -3D was calibrated with data obtained in the study area. The simulated results of dissolved Nonylphenol were in good agreement with the observed values, with a correlation coefficient(R) of 0.7707 and a coefficient of determination (R2) of 0.5940. The results of sensitivity analysis showed that biodegradation rate and bioconcentration factor are most important factors for dissolved Nonylphenol and Nonylphenol in phytoplankton, respectively. In the case of Nonylphenol in particulate organic carbon, biodegradation rate and partition coefficient were important factors. Therefore, the parameters must be carefully considered in the modeling. The mass balance results showed that standing stocks of Nonylphenol in water, in particulate organic carbon and in phytoplankton are $8.60\times 10^5\;g,\;2.19\times 10^2\;g\;and\;3.78\times 10^0\;g$ respectively. With respect to the flux of dissolved Nonylphenol, biodegradation in the water column, effluent to the open sea and partition to particulate organic carbon were $6.02\times10^3\;g/day,\;6.02\times10^2\;g/day\;and\;1.02\times10^1\;g/day$, respectively.

탄성도 이론을 이용한 낙동강유역 난분해성 용존 유기탄소 미래 추세 분석 (Analysis of Future Trends for Refractory Dissolved Organic Carbon in the Nakdong River Basin using Elasticity Theory)

  • 박윤경;최대규;이재운;강임석;김상단
    • 한국물환경학회지
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    • 제29권4호
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    • pp.476-488
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    • 2013
  • Refractory Dissolved Organic Carbon (RDOC) is becoming more important index on management of water quality, water regulation as well as ecosystem management. We analyzed trends of RDOC using elasticity in the Nakdong river basin. If climate elasticity of streamflow is positive, change of streamflow can be defined by the proportional change in a climatic variable such as precipitation and temperature. Elasticity of streamflow to precipitation and elasticity of RDOC to precipitation were estimated in the present, and we also analyzed the variation of elasticity in the future using climate change scenarios, RCP 8.5/ 4.5. Mean streamflow elasticity is 1.655, and mean RDOC elasticity is 1.983. RDOC is more sensitive to precipitation change than streamflow. The variation of RDOC is directly proportion to precipitation in all scenarios, but the Load of RDOC is dependent on precipitation as well as others. There is a need for additional correlation analysis between RDOC and other factors for accurate prediction.

Opitimization of culture conditions involved in dissolved oxygen for production of pullulan by Aureosidium pullulan

  • 서형필;손창우;이유정;김성구;;이진우
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2002년도 생물공학의 동향 (X)
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    • pp.173-176
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    • 2002
  • Effect of carbon source and culture conditions involved in the concentration of dissolved oxygen on cell growth and the production of pullulan by A. pullulans HP2001 were investigated. Among those carbon sources, glucose was found to be the best carbon source for the production of pullulan by A. pullulans HP2001. Maximal production of pullulan by A. pullulans HP2001 was 26.6 g/ f when concentrations of glucose and yeast extract were 8% (w/v) and 0.25% (w/v), respectively. It was found that aeration rate, agitation speed and inner pressure of a bioreactor, which were some of physiological factors involved in the dissolved oxygen in the medium may affect cell growth and the production of pullulan by A. pullulans HP2001.

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Separation of dissolved gases from water using synthesized gases based on exhalation characteristics

  • Heo, Pil Woo;Park, In Sub
    • Journal of Advanced Marine Engineering and Technology
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    • 제38권10호
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    • pp.1347-1353
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    • 2014
  • It's possible for a human to breathe under water, if dissolved oxygen is effectively used. Fish can stay under water using the gill which extracts dissolved oxygen from water. Water includes small amounts of oxygen, so a human needs larger amounts of water to acquire oxygen enough for underwater breathing. The exhalation gas from a human is another method to get higher amounts of oxygen under water. It mainly composes of oxygen, nitrogen and carbon dioxide. So, if only carbon dioxide is decreased, the exhalation gas has good characteristics for breathing of a human under water. In this paper, composition of the exhalation gas from a human was analyzed using GC. Based on these results, the synthesized gas was prepared and mixed into water which was used for experimental devices to analyze separation characteristics of dissolved gases from water. Experimental devices included a water pump, a hollow fiber membrane module and a vacuum pump. The effects of pressure and water flow on separation characteristics of synthesized gas were investigated. The compositions of gases separated from water using synthesized gas were investigated using GC. These results expect to be applied to the development of underwater breathing technology for a human.

Characteristics of dissolved gases separated from water mixed with exhalation gases without using a compressor

  • Heo, Pil Woo
    • Journal of Advanced Marine Engineering and Technology
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    • 제40권10호
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    • pp.916-921
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    • 2016
  • It is possible for humans to breathe underwater using dissolved oxygen. However, unlike fish, humans need large amounts of oxygen to breathe underwater. Water generally contains small amounts of dissolved oxygen. To get enough dissolved oxygen from water, great volumes of it should be supplied into a separation device. If exhalation gases are used, the amounts of water supplied into the membrane can be decreased. However, the characteristics of exhalation gases after passage through the separation device need to be investigated. To reuse the exhalation gases, the concentration of carbon dioxide should be decreased. A compressor is needed to supply the exhalation gases because of the high pressure generated in the membrane inlet. However, compressors require a lot of power and are heavy, so it is not proper to get the portable separation device. A system without the compressor is needed. If the pressure of the position mixed from the exhalation is less than atmosphere, the compressor is not needed. In this thesis, characteristics of the gases which are mixed with exhalation gases and separated from water after passing the membrane are investigated. The compositions of carbon dioxide, oxygen, and nitrogen are measured with the gas chromatography. The effects of water and exhalation gas flow rates on characteristics of gases separated from water after the membrane are showed.

만경강 하구역의 유기탄소 거동 및 분포 (Organic carbon behavior and distribution in the Mankyoung River Estuary)

  • 박준건;김은수;김경태;조성록;박용철
    • 한국해양환경ㆍ에너지학회지
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    • 제9권3호
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    • pp.131-140
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    • 2006
  • 만경강 하구역의 입자성 부유물질 및 유기탄소 거동에 관한 연구가 2003년 2월, 5월, 7월, 8월에 이루어졌다. 갈수기인 2, 5월과 풍수기인 7, 8월에 만경강을 통한 담수 유입량의 차이는 매우 컸으며, 용존유기탄소의 유입량은 갈수기와 풍수기에 각각 약 $8.16{\times}10^2tonC\;month^{-1}$$5.77{\times}10^3tonC\;month^{-1}$, 입자성유기탄소의 유입량은 갈수기와 풍수기 각각 약 $9.37{\times}10^2tonC\;month^{-1}$$3.14{\times}10^4tonC\;month^{-1}$로 나타났다. 특히 많은 강우가 집중되었던 풍수기에 방조제 내 북측 수역의 용존유기탄소 농도가 증가하는 경향을 보였다. 조사기간 중 만경강 히구역에서의 용존유기탄소 분포는 염분에 대해 비교적 보존적인 특성을 보이고 있어, 담수와 해수사이의 물리적 희석작용에 영향을 많이 받는 것으로 나타났다. 그러나 입자성유기탄소의 분포는 부유물질의 거동과 유사하게 60-90% 정도가 하구역에 침강, 제거되는 것으로 나타났다. 이러한 결과로 볼 때 새만금 방조제 완공 후 만경강 하구역이 외해와의 물질 교환이 차단 될 경우, 저층에 퇴적된 다량의 유기 탄소가 저층 용존 산소 고갈의 주요 원인이 될 수 있음을 시사하고 있다.

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역삼투식 해수담수화의 전처리공정으로서 유분 제거의 평가 (Evaluation of Oil Pollutants Removal in Seawater as Pretreatment Process for Reverse Osmosis Desalination Process)

  • 김우항
    • 해양환경안전학회:학술대회논문집
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    • 해양환경안전학회 2003년도 춘계학술발표회
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    • pp.205-209
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    • 2003
  • The various pretreatment processes were evaluated for removal of oil pollutants with weathered oil contaminated seawater in a reverse osmosis desalination process. Weathered oil contaminated seawater was made by biodegradation and photooxidation with oil containing seawater. Coagulation, ultrafiltration, advanced oxidation processes and granular activated carbon filtration was used with pretreatment for dissolved organic carbon. Crude oil was removed but. weathered oil contaminated seawater was not removed by biodegradation and coagulation. DOC and E260 was removed with about 20 % and 40 % by membrane filter of cut off molecular weight 500. So, the most of dissolved organic carbon in weathered oil contaminated seawater was revealed that molecular weight was lower than 500. It is difficult to remove DOC in weathered oil contaminated seawater by advanced oxidation processes treatment, but, E260 was removed more high. However, DOC in weathered oil contaminated seawater was easily adsorbed to GAC. It is revealed that DOC was removed by adsorption.

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Micromonospora inyoensis에 의한 시소마이신 생산에 영향을 미치는 인자들 (Factors affecting sisomicin production by Micromonospora inyoensis)

  • Lee, Jae-Heung;Gil, Gwang-Hoon;Cho, Young-Je;Yoo, Moo-Young
    • 한국미생물·생명공학회지
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    • 제14권5호
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    • pp.355-358
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    • 1986
  • M. inyoensis NRRL 3292에 의한 시소마이신 생산에 영향을 미치는 인자들에 관해 조사한 결과 cobalt chloride 및 methionine 모두가 시소마이신 생산을 현저히 촉진하였으며, 탄소원으로서는 전분 또는 덱스트린이 포도당에 비해 시소마이신 생성에 적합하였다. 특히 시소마이신 발효공정중 항생물질 생성시기에 발효액내의 용존 이산화탄소 농도가 낮을수록 시소마이신 생성 농도가 증가하였다.

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응집 및 한외여과 공정에 의한 상수원수의 유기물질 제거 특성 (The Removal Characteristics of Organic Matter in Drinking Water Source by Coagulation and Ultrafiltration Process)

  • 김현식;임지영;김진한
    • 유기물자원화
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    • 제26권2호
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    • pp.5-10
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    • 2018
  • 본 연구는 상수원수 내에 존재하는 유기물질 특성을 평가하고 혼화 응집 공정을 포함한 UF 막여과에 의한 유기물질의 제거 특성을 평가하였다. 연구결과, 상수원수내의 총유기탄소는 대부분 용존성 유기물질에 기인함을 알 수 있었으며, 원수의 SUVA 값이 낮게 측정됨으로써 용존성 유기물질은 친수성, 저분자 물질의 구성 비율이 높음을 알 수 있었다. 또한 혼화 응집 공정을 포함한 UF 막여과 처리 실험 결과 총유기탄소의 제거율은 평균 37.9%, 용존유기탄소의 제거율은 평균 30.3%, 그리고 $UV_{254}$의 제거율은 평균 28.2%로 나타났다.

오존/활성탄 공정을 이용한 용존 오존 및 페놀의 분해에 관한 연구 (A Study on the Decomposition of Dissolved Ozone and Phenol using Ozone/Activated Carbon Process)

  • 최재원;이학성
    • 공업화학
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    • 제23권5호
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    • pp.490-495
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    • 2012
  • 오존/활성탄 공정을 이용하여 페놀을 처리 할 경우, 활성탄에 의해 나타나는 촉매효과에 관한 연구를 수행하였다. 오존 단독공정에 활성탄을 추가할 경우, 활성탄 투입량이 증가할수록 용존 오존 및 페놀의 분해효율이 증가하는 것으로 나타났다. 이는 활성탄에 의해서 용존 오존이 분해되어 생성된 수산화 라디칼이 페놀 제거에 영향을 미쳤으며, 본 연구에서는 활성탄의 촉매효과([$\Delta$phenol] / $[{\Delta}O_{3}]_{AC}$)로 나타내었다. 활성탄 10~40 g/L 투입 시, 모든 활성탄의 최대 촉매효과 값은 $2.0\;{\pm}\;0.1$로 나타났지만, 10 g/L와 20 g/L를 투입한 경우, 40 min 경과 후 최대 촉매효과에 근접한 반면, 활성탄 30 g/L와 40 g/L를 투입한 경우, 반응 20 min 경과 후 최대 촉매효과에 도달하였다. 또한 Total Organic Carbon (TOC, 총유기탄소)의 제거율은 오존 단독공정에서 0.23으로 나타났으며, 오존/활성탄 공정에서는 0.63으로 나타났다.