• Journal of the Korean Chemical Society
• /
• v.40 no.12
• /
• pp.724-732
• /
• 1996

The organic precipitate flotation using Cu(II)-pyrrolidinedithiocarbamate complex as a coprecipitant was studied for the preconcentration and determination of trace Cd, Pb, Bi and Co in several water samples. Experimental conditions such as pH of solution, amounts of Cu(II) and ammonium pyrrolidinedithiocarbamate(APDC), stirring time, the type and amount of surfactant, etc. were optimized for the effective flotation of analytes. After 3.0 mL of 1,000 ${\mu}g/mL$ Cu(II) solution was added to 1.00 L water sample, the pH of the solution was adjusted to 2.5 with HNO3 solution. Trace amounts of analytes were coprecipitated by adding 2.0% APDC solution. And the precipitates were flotated onto the surface of solution with the aid of nitrogen gas and sodium lauryl sulfate. The floats were collected from mother liquor, and filtered through the micropore glass filter by suction. The precipitates were dissolved with 4 mL conc. HNO3, and then diluted to 25.00 mL with deionized water. The analytes were determined by graphite furnace atomic absorption spectrophotometry. This flotation technique was applied to the analysis of some water samples, and the 90 to 120% of recoveries were obtained from the spiked samples, this procedure could be concluded to be simple and applicable for the trace element analysis in various kinds of water.

• Journal of the Korean Chemical Society
• /
• v.37 no.3
• /
• pp.327-333
• /
• 1993

A method was developed for the determination of trace elements in seawater by precipitate flotation preconcentration and subsequent flame atomic absorption detection. In order to quantitatively coprecipitate trace ions such as Cd(II), CuI(II), Fe(III), Mn(II), Pb(II) and Pd(II), 2.0 ml of 1.0M cerium(III) solution was added to 1.0l of seawater and the pH was adjusted to 9.5 with 5.0 M sodium hydroxide solution while stirring with a magnetic stirrer. The precipitate was floated with the aid of surfactant solution (1.0 ml of 0.3% sodium oleate) by bubbling nitrogen gas through a porous (No. 4) fritted glass disk. The floats was collected in a small Erlenmeyer flask by suction. The washed precipitate was dissolved in 8.0 M nitric acid and marked with deionized water in the volumetric flask of 10.0 ml. The analyte was determined by measuring the atomic absorbances in 100-fold concentrated solution. Above all analytes in Kangnung (East Sea) and Kanghwado (West Sea) sea waters were found to be under the detection limit of this method. The recoveries of over 92% for all analytes spiked into seawater samples showed that this method was applicable to the analysis of real seawater.

• Proceedings of the Materials Research Society of Korea Conference
• /
• 2009.05a
• /
• pp.26.1-26.1
• /
• 2009

최근 반도체 세정에 있어서 지난 40년 동안 지속적으로 사용되고 있는 알칼라인 기반의 RCA 세정법은 많은 초순수 및 화학액 소모량과 세정시 불필요한 박막의 손실, 환경적인 문제로 인하여 이를 대체하고자 하는 새로운 새정액 및 세정 방법에 대한 연구가 활발하게 이루어지고 있다. 특히 초순수에 가스를 혼합하여 메가소닉을 이용한 기능수 세정은 기존 RCA 세정액의 문제점들을 해결하기 위한 세정액으로 최근 반도체 제조 공정 뿐만 아니라 Photo mask, FPD 세정 공정에서 널리 이용되고 있다. 하지만 기능수에 대한 기초적인 특성 연구와 메가소닉에 의한 세정력 변화에 대한 연구는 부족한 상태이다. 본 연구에서는 고순도의 수소가스(99.999%)를 가스 접촉기, pHasorII (Entigris, USA) 와 순환 속도의 조절이 가능한 펌프, BPS-3 (Levitronix, USA) 를 이용하여 지속적으로 초순수와 수소가스를 혼합하는 방법으로 수소수를 제조하였으며, 용존 수소 농도계, DHDI-1 (TOA-DKK, Japan)으로 수소수의 농도를 확인하였다. 0.1 MPa 압력과, 3 LPM의 수소가스 유출속도에서 최대 2.0 ppm의 수소수를 얻을 수 있었으며, 수소수의 기초 특성을 평가하기 위하여 수소 농도 변화에 따른 pH, 표면 에너지를 측정하였다. 또한 압력 변화에 따른 반감기를 측정하여 bath형태의 세정기에서 적용 가능성을 평가하였다. 수소수의 세정력은 $Si_3N_4$ 입자가 임의로 오염된 실리콘 웨이퍼를 이용하여 bath 및 매엽식 세정기에서 수소수 농도와 메가소닉 형태 및 첨가제 변화에 따른 세정효율을 기존의 SC-1 세정액과 각각 비교 평가하였다. 기능수 발생장치에서 압력이 제거된 상태에서는 평균 20분의 반감기를 갖는 것이 관찰되었고, 압력이 유지된 상태에서는 수소수의 농도가 유지되는 것을 확인하였으며, pH의 경우 수소수의 농도가 점차 증가함에 따라 감소하여 2.0 ppm의 농도에서 pH 5.3정도의 값을 나타내었다. 표면 장력은 초순수와 비교했을 때 큰 변화가 없음을 확인할 수 있었다. Bath 형태의 세정기에서 메가소닉을 인가하여 수소수의 세정효율을 측정한 결과, 같은 조건에서 실험한 초순수와는 비슷하며, SC-1보다는 낮은 세정효율이 측정되었다. 반면 매엽식 세정기에서 동등한 조건의 실험을 실시한 결과, 수소수 세정에서 첨가제에 의한 영향으로 SC-1을 대체할 수 있는 높은 입자 제거효율을 가짐을 확인할 수 있었다.

• Resources Recycling
• /
• v.18 no.2
• /
• pp.3-15
• /
• 2009

To accomplish the greenhouse gas reduction which is over core unit project of the "Green growth" policy and "Resource circulation society", it is important to maintain proper balance and complement between energy recovery from waste and material recycling. This research(study) examined the related policies on the past of korea and foreign country, and also "The 4th resource recycling master plan" and "Energy recovery from waste plan" to provide advisable direction for resource recycling policy. The results of the research(study) showed that there were no significant difference between korea and developed foreign countries waste management policies. But in German policy, energy recovery from waste and pre-treatment are importantly considered and highly required for permission. Under current circumstance in korea, recycling will be more difficult than in the past. According to "The 4th resource recycling master plan", film type of synthetic resin was not sustainable recycled material in substance."Energy recovery from waste plan", proved that the energy recovery from RDF/RPF have lower efficiency than regular incineration generation and substance recycling. To solve these problems, the energy and remainder heat recovery must be generalized to "Energy recovery" concept and institutional improvement such as LCA(Life Cycle Assessment) system are need to support it. And also technology development to extract synthetic polymer by dissolved film type of synthetic resin must be provided.

• Journal of the Korean Applied Science and Technology
• /
• v.34 no.4
• /
• pp.1085-1093
• /
• 2017

Plasticizers are materials added to give softness and elasticity to plastics having rigid properties to give soft properties as products, and they are mainly added to high molecular materials to give flexibility to improve workability and to improve cold resistance, resistance to volatility and electrical properties. It is used for the purpose. Most plasticizers are inert liquids, similar in function to solvents but with high molecular weight and no volatility. In addition, when dissolved in petrochemical products, only the plasticizer is separated by the matrix effect with other compounds, and qualitative and quantitative analysis. In this study, qualitative and quantitative analysis of DOA and DOP, which are representative components of petrochemical products, were conducted using MD-GC/MS and developed an optimal plasticizer analysis method.

• Journal of Soil and Groundwater Environment
• /
• v.18 no.5
• /
• pp.7-14
• /
• 2013

The objectives of this study were to identify the characteristics of groundwater in the petroleum contaminated site and to evaluate the applicability of house-type landfarm facilities heated with briquette stoves in winter season. The six monitoring wells were installed at the site where pH, dissolved oxygen, and temperature were all measured. Also groundwater contaminants, benzene, toluene, ethylbenzene, xylene and total petroleum hydrocarbon, were analyzed twice. House-type two landfarm facilities ($12m{\times}40m{\times}4.8m$) each installed with four briquette stoves were constructed. During four rounds treatment process, VOCs, moisture, temperature were monitored and soil contaminants were analyzed. The pH was 6.37 and considered subacid and DO was measured to be 3.12 mg/L. The temperature of groundwater was measured to be $9.48^{\circ}C$. The groundwater contaminants were detected only in the monitoring wells within the contaminated area or close to it showing that the groundwater contaminated area was similar to the soil contaminated area. During the landfarm process, 73.3% of VOCs concentration in interior gas was decreased and moisture was lowered from 17.7% to 13.4%. In the morning, at 8:00 am, the temperature was decreased showing soil ($5.5^{\circ}C$) > interior ($4.8^{\circ}C$) > exterior ($3.5^{\circ}C$). In the afternoon, at 2:00 pm, the temperature was soil ($8.6^{\circ}C$) < interior ($9.9^{\circ}C$) < exterior ($11.5^{\circ}C$) with solar radiation. The temperature difference between interior and exterior was $0.7^{\circ}C$ in the morning, but it was $1.6^{\circ}C$ in the afternoon. A total of 130 days were taken for four round landfarm processes. Each process was completed within 33 days showing 80% of cleanup efficiency ($1^{st}$ order dissipation rate(k) = 0.1771).

• Journal of Life Science
• /
• v.29 no.2
• /
• pp.198-201
• /
• 2019

Recently, it has been reported that Bacillus mojavensis possesses antifungal properties and plant growth-promoting activities, which are similar to the characteristics of siderophore. In this study, the siderophore produced by B. mojavensis was assessed using a solid phase extraction (SPE) cartridge and liquid chromatography quadrupole time-of-flight tandem mass spectrometry (Q-TOF MS/MS). After B. mojavensis was incubated in phenol medium for 16 hr and lyophilized, the sample was dissolved in water and loaded to an SPE cartridge to remove interferences. The cartridge was washed with 5% methanol in water and eluted with 2% formic acid in methanol sequentially. The eluted solution was evaporated under a stream of nitrogen gas and reconstituted in methanol. The reconstituted sample was filtered, and $1{\mu}l$ of the sample was assessed using Q-TOF MS/MS. The mass spectrometer was operated using the positive electrospray ionization mode. Based on the mass spectrum and tandem mass spectrum, the siderophore produced by B. mojavensis was bacillibactin, one of the catechol types of siderophore with a molecular weight of 882.2556. This siderophore analysis could provide a justification for the study of B. mojavensis as a functional food and for pharmaceutical applications.

• Journal of the Korean Chemical Society
• /
• v.66 no.3
• /
• pp.202-208
• /
• 2022

In this study, we tried to obtain the optimal conditions to reduce odors generated from pig wastewater using magnesia (MgO) through in-situ test after producing a reactor for removing odors. For this purpose, the filling amount of magnesia, the injection amount of pig wastewater, the aeration method, the aeration amount and the aeration time were considered. The field experiment was conducted at Cheongwoon Livestock Farm, which has a pig wastewater reservoir. As the amount of magnesia added to the weight of wastewater (500 kg) increases, the amount of ammonia (NH₃) and hydrogen sulfide (H₂S) generated tended to gradually decrease. As a result of the test, ammonia and hydrogen sulfide in the pig wastewater decreased up to 65% and 77%, respectively, for 2 days aeration after 0.8% of magnesia was added to the reaction tank. The initial pH of the pig wastewater in the reactor was 8.2, and the pH was found to be 9.2 when magnesia was added up to 0.8%. In the light of this trend, it can be known that magnesia gradually increases the pH in the pig wastewater and makes it weakly alkaline. As the pH increases, part of the ammonia gas present in the pig wastewater vaporizes into the air and the remaining part is removed by precipitation after chemical bonding with dissolved magnesium ions and phosphate ions. In order to remove the odor of pig wastewater and turn it into compost, most of the existing livestock farms go through a six-month aeration process using microorganisms. In contrast, the current study proved the effect of removing odors from pig wastewater within 2 days through chemical reactions that do not affect microbial activity.

• Journal of Korean Society on Water Environment
• /
• v.38 no.1
• /
• pp.19-30
• /
• 2022

Climate change has increased the average air temperature. Rising air temperature are absorbed by water bodies, leading to increasing water temperature. Increased water temperature will cause eutrophication and excess algal growth, which will reduce water quality. In this study, long-term trends of air and water temperatures in the Han-river basin over the period of 1997-2020 were discussed to assess the impacts of climate change. Future (~2100s) levels of air temperature were predicted based on the climate change scenarios (Representative concentration pathway (RCP) 2.6, 4.5, 6.0, and 8.5). The results showed that air and water temperatures rose at an average rate of 0.027℃ year^-1 and 0.038℃ year^-1 respectively, over the past 24 years (1997 to 2020). Future air temperatures under RCP 2.6, 4.5, 6.0, and 8.5 increased up to 0.32℃ 1.18℃, 2.14℃, and 3.51℃, respectively. An increasing water temperature could dissolve more minerals from the surrounding rock and will therefore have a higher electrical conductivity. It is the opposite when considering a gas, such as oxygen, dissolved in the water. Water temperature also governs the kinds of organisms that can live in rivers and lakes. Fish, insects, zooplankton, phytoplankton, and other aquatic species all have a preferred temperature range. As temperatures get too far above or below this preferred range, the number of individuals of the species decreases until finally there are none. Therefore, changes of water temperature that are induced by climate change have important implications on water supplies, water quality, and aquatic ecosystems of a watershed.

• Journal of the Korean GEO-environmental Society
• /
• v.23 no.3
• /
• pp.23-29
• /
• 2022

In this study, we investigated the ozone nanobubble process in which nanobubble and ultrasonic cavitation were applied simultaneously to improve the dissolution and self-decomposition of ozone. To confirm the organic decomposition efficiency of the process, a 200 mm × 200 mm × 300 mm scale reactor was designed and phenol decomposition experiments were conducted. The use of nanobubble was 2.07 times higher than the conventional ozone aeration in the 60 minutes reaction and effectively improved the dissolution efficiency of ozone. Ultrasonic irradiation increased phenol degradation by 36% with nanobubbles, and dissolved ozone concentration was lowered due to the promotion of ozone self-decomposition. The higher the ultrasonic power was, the higher the phenol degradation efficiency. The decomposition efficiency of phenol was the highest at 132 kHz. The ozone nanobubble process showed better decomposition efficiency at high pH like conventional ozone processes but achieved 100% decomposition of phenol after 60 minutes reaction even at neutral conditions. The effect by pH was less than that of the conventional ozone process because of self-decomposition promotion. To confirm the change in bubble properties by ultrasonic irradiation, a Zetasizer was used to measure the bubbles' size and zeta potential analysis. Ultrasonic irradiation reduced the average size of the bubbles by 11% and strengthened the negative charge of the bubble surface, positively affecting the gas transfer of the ozone nanobubble and the efficiency of the radical production.