• Title/Summary/Keyword: Dissolution property

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Development of chemical conversion coating technology by environment friendly method for Zn electroplated steel (아연 전기 도금 강의 환경친화적인 화성처리 기술 개발)

  • Kim, Seong-Jong;Kim, Jeong-Il;Jang, Seok-Ki
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2006.06a
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    • pp.271-272
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    • 2006
  • Zinc confers high corrosion resistance by acting as a sacrificial anode, and a zinc coating improves the appearance of steel. Chromate conversion coating (CCC) films are still one of the most efficient surface treatments for steel. Although such films can self-repair via the dissolution of Cr(VI), dissolved Cr(VI) have adverse effects on humans, and the environment. Therefore, we examined the corrosion protection property and morphology of colloidal silica conversion films as an alternative to CCC films. The corrosion behavior was investigated in 3% NaCl solution using electrochemical techniques, including electrochemical impedance spectroscopy, open circuit potential, and the salt spray test(SST). Corrosion was implied by the appearance of red rust on the specimen surface. In corrosion resistance at 3% NaCl solution, red rust appeared at 15-20, 55-70, and 83-98 days on Zn-electroplated steel, colloidal silica conversion-coated specimens, and CCC-coated specimens, respectively. In the salt spray test, the colloidal silica film provided better corrosion protection than CCC films, i.e., red rust appeared at 96 hours on the Zn-electroplated steel sheet, at 432 hours with the CCC films, and at 888 hours with silica conversion coating.

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A Study on the form of spatial expression shown in Rietveld's works - Focused on comparing with Mondrian's works - (리트벨트 작품의 공간표현 형식에 관한 연구 - 몽드리앙 작품과의 비교를 중심으로 -)

  • 박영경
    • Korean Institute of Interior Design Journal
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    • no.40
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    • pp.68-75
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    • 2003
  • The purpose of this study is to find out the expression style of space in Rietveld's early works in comparison with Mondrian's paintings. Through investigating the development of their works and analyzing the composition and disposition type of elements such as point, line, plane, color in the selected works, we can draw the following conclusions. .First, Rietveld pursues the dissolution of traditional volume and the de-composition of elements as Mondrian does. Second, the painterly property of plane is emphasized by the projection of separately floating elements on the picture plane. Third, the separating the layer of lines from the layer of planes and the re-combination of these two layers present the superimpositional image of three-dimensional objects. This leads into new conception of architectural space and develops the transparency and the extension of plan in modem architecture.

Mechanical Property Variations of Handsheets by Mixing Ratios of Sw-BKP, Hw-BKP, and PVA Fibers (Sw-BKP, Hw-BKP, PVA 섬유의 배합비에 따른 수초지의 물성과 파괴인성의 변화)

  • Yoon, Sang-Gu;Park, Jong-Moon
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.4
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    • pp.60-65
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    • 2015
  • In order to improve the strength of paper, mixing ratio of Sw-BKP and Hw-BKP and PVA (polyvinyl alcohol) fibers dosage were investigated. When the Sw-BKP fraction was increased, strength properties were increased because of average fibers length increased. When PVA fraction increased, paper strength was increased, but there was dissolution of PVA in water. The reason for improving handsheet strength that contained PVA was due to increased bonding action between the fibers by the PVA. The addition of PVA to kraft pulp would be helpful for packaging paper materials to increase strength and fracture toughness.

The Insulation Property of Microcellular Injection Molding Plastics (초미세 발포 사출 성형품의 단열 특성)

  • Lee, Jung-Hyun;Hong, Soon-Kug;Kim, Ji-Hyun;Yoon, Jae-Dong
    • Proceedings of the KSME Conference
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    • 2001.06c
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    • pp.263-268
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    • 2001
  • MCPs means Micro Cellular Plastics. The micro-cells are generated in the products by the difference of dissolution through the pressure drop after super critical fluid of CO2 or N2 dissolves into polymer. We have developed injection molding process adopting MCPs and applied it to a broad range of injection molded thermoplastic materials and applications. It can prevent the leakage of impact strength and increase the thermal conductivity, moreover regulate the thermal conductivity. Then we can develop the high strength foaming plastics. Also, it can be gained a competitive advantage by utilizing its processing benefits, e.g. the lightweight products and significant reductions in material consumption.

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Effect of Surface Modification by Heat Treatment of Co-Cr Alloy (Co-Cr alloy의 열처리에 따른 표면개질의 영향)

  • Park, J.M.;Kim, W.C.
    • Journal of the Korean Society for Heat Treatment
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    • v.23 no.3
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    • pp.137-141
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    • 2010
  • The Co-Cr alloys have clinical histories in dental and orthopaedic implants, and recently in cardiovascular stent applications because the alloys exhibit a high elastic modulus and radiopacity. In order to improve mechanical property of the Co-Cr alloys, electropolishing is employed as the final process. Electropolishing, an anodic dissolution process in the transpassive state, is sensitively affected by process conditions such as current density, machining time, electrode gap. In this study, the effect of heat treatment conditions on surface roughness and inclusion analysis is investigated in Co-Cr alloy (L605). The most smooth surface of Co-Cr alloy is obtained when electropolishing is performed at 15-20 V for 15-30 sec with a electrode gap of 3.5 mm.

해양환경하에서의 알루미늄 합금 선박용 재료의 기계적 특성과 전기화학적 특성 평가

  • 김성종;고재용;정석기;김정일
    • Proceedings of KOSOMES biannual meeting
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    • 2005.05a
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    • pp.161-165
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    • 2005
  • Recently, it is on the increase interest for Al alloy with new material for ship application to substitute for FRP ship. The reason is thatAl alloy ship has beneficial characteristics such as high sea speed, increase of loadage and easy to recycle compared with FRP ship. In this paper, mechanical and electrochemical properties are investigated by slow strain rate test experiment in various applied potential condition. These results will provide as reference data to design ship by deciding optimum protection potential regard to hydrogen embrittlement and stress corrosion cracking. In general, Al and Al alloys are not corroded with forming film which has the corrosion resistance property in neutral solution. However, it was observed that formation and destruction of passive film by $Cl^-$ ion in sea water environment. At comparison of current density after 1200 sec in potentiostatic experiment, the current density in the potential range of -0.68 $\~$-1.5 V is shown low value. The low current density means protection potential range. Elongation in applied potential of 0 V was high. However, the corrosion protection application in this condition is impossible potential because the toughness is low value by decreasing strength by active dissolution reaction at parallel part of specimen. The film composed with $CaCO_3$ and $Mg(OH)_2$ has a corrosion resistance property. However, the uniform electrodeposition coating at below -1.6 V potential is not formed since the time to form the uniform electrodeposition coating is short. Therefore, it is concluded that mechanical property is poor because effect by hydrogen gas generation is larger than that of electrodeposition coating. It is concluded that the optimum protection potential range from comparison of_maxim urn tensile strength, elongation and time to fracture is -1.3$\~$0.7 V (SSCE).

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Effects of Low Temperature Retrogression on RRA Treatment of 7075 AI Alloy (7075 Al합금의 RRA처리에서 저온 퇴화처리의 효과)

  • Kim, Chang-Joo;Lee, Jung-Moo
    • Korean Journal of Materials Research
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    • v.4 no.1
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    • pp.24-30
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    • 1994
  • Effect of low temperature retrogression on RRA treatment were investigated in the thermomechanically treated 7075 Al alloy. The complete dissolution of GP zones did not occur during retrogression at $170^{\circ}C$ in T6 material. llrop in strength during initial stage of retrogression was due to the partial dissolution of GP zones. And the strength increased with the formation of $\mu '$ and decreased again with the growth of $\mu '$ and/or formation of $\mu '$ When RRA treatment was applied at the minimum or the secondary peak (maximum) in the hardness curve of retrogression treatment, SCC property was improved markedly without reduction of the strength in comparision with that of T6 materials. And the rhanges in the matrix were not sensitive with time during retrogression at low temperature of $170^{\circ}C$ that the strength and SCC properties were similar at both points in the hardness curve of retrogression treatment.

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Hydrophobic Cyclodextrin Derivatives as a Sustained Release Carrier of Azidothymidine (아지도싸이미딘의 지속성방출형담체로서의 소수성시클로덱스트린유도체)

  • Seo, Bo-Youn;Park, Gee-Bae;Lee, Kwang-Pyo
    • Journal of Pharmaceutical Investigation
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    • v.26 no.2
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    • pp.71-82
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    • 1996
  • This study has been undertaken to evaluate hydrophobic cyclodextrin(CD) derivatives as a sustained release carrier of azidothymidine(AZT), AZT, which has potent activity against AIDS and AIDS-related complex as thymidine analogue, has been reported that it has significant toxicity and short half life. Therefore, it is necessary to design sustained release oral dosage form to avoid undesirable side effects attributable to an excessive plasma concentration and to reduce the frequency of administration of AZT. Inclusion complexes of AZT with $acetyl-{\beta}-cyclodextrin\;(AC{\beta}CD)$ and $triacetyl-{\beta}-cyclodextrin(TA{\beta}CD)$ were prepared by solvent evaporation method. Interactions of AZT with CD were investigated by Differential Scanning Calorimetry(DSC) and Infrared Spectrophotometry(IR). The decreasing order of water solubilities of AZT and AZT-CD inclusion complexes were as follows; $AZT\;(27.873{\pm}0.015,mg/ml)\;>\;AZT-AC{\beta}CD\;(3.377{\pm}0.003)\;>\;AZT-TA{\beta}CD\;(2.528{\pm}0.001)$. Partition coefficients of $AZT-AC{\beta}CD\;and;\AZT-TA{\beta}CD$ inclusion complexes were increased by 1.27-fold, 1.54-fold in pH 1.2 and 1.32-fold, 1.47-fold in pH 6.8 in comparison with that of AZT. The mean dissolution time (MDT, min) which represents the rapidity of dissolution rate of AZT, $AZT-AC{\beta}CD,\;AZT-TA{\beta}CD$ were 5.12, 14.02 and 19.38 min in pH 1.2 and 2.52, 15.19 and 18.19 min in pH 6.8. AZT was very rapidly and completely dissolved in pH 1.2 and pH 6.8 within 5 minutes. But AZT-CD inclusion complexes showed the sustained release pattern in comparison with AZT alone. The simultaneous in situ nasal and jejunal recirculation study to compare the intrinsic absorptivity and the property of absorption sites revealed that the absorption of $AZT-TA{\beta}CD\;(N:35.35{\pm}1.08%,\;J:27.47{\pm}1.18%)$ was more than that of $AZT\;(N:16.89{\pm}2.25%,\;J:15.86{\pm}2.33%)$. The above results suggest that $TA{\beta}CD$ which is a hydrophobic cyclodextrin may serve as sustained release carrier with absorption enhancing effect.

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In vitro and in vivo studies on theophylline mucoadhesive drug delivery system

  • Bandyopadhyay, AK;Perumal, P
    • Advances in Traditional Medicine
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    • v.7 no.1
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    • pp.51-64
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    • 2007
  • Mucus is an aqueous gel complex with a constitution of about 95% water, high molecular weight glycoprotein (mucin), lipid, salts etc. Mucus appears to represent a significant barrier to the absorption of some compounds. Natural mucoadhesive agent was isolated and purified from the aqueous extract of the seeds of prosopis pallida (PP). Formulated tablet with the isolated material by wet granulation method. Some natural edible substances are in consideration for candidates as mucoadhesive agents to claim more effective controlled drug delivery as an alternative to the currently used synthetic mucoadhesive polymers. Subjected the materials obtained from natural source i.e. PP and standard synthetic substance, sodium carboxymethyl cellulose for evaluation of mucoadhesive property by various in vitro and in vivo methods. Through standard dissolution test and a model developed with rabbit, evaluated in vitro controlled release and bioadhesive property of theophylline formulation. Mucoadhesive agent obtained from PP showed good mucoadhesive potential in the demonstrated in vitro and in viνo models. The results suggest that the mucoadhesive agent showed controlled release properties by their application, substantially. In order to assess the gastrointestinal transit time in vivo, a radio opaque X-ray study performed in healthy rabbit testing the same controlled release formulation with and without bioadhesive polymer. Plasma levels of theophylline determined by the HPLC method and those allowed correlations to the in vitro mucoadhesive study results. Better correlation found between the results in different models. PP may acts as a better natural mucoadhesive agent in the extended drug delivery system.

Electrochemical properties of all solid state Li/LiPON/Sn-substituted LiMn2O4 thin film batteries

  • Kong, Woo-Yeon;Yim, Hae-Na;Yoon, Seok-Jin;Nahm, Sahn;Choi, Ji-Won
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.409-409
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    • 2011
  • All solid-state thin film lithium batteries have many applications in miniaturized devices because of lightweight, long-life, low self-discharge and high energy density. The research of cathode materials for thin film lithium batteries that provide high energy density at fast discharge rates is important to meet the demands for high-power applications. Among cathode materials, lithium manganese oxide materials as spinel-based compounds have been reported to possess specific advantages of high electrochemical potential, high abundant, low cost, and low toxicity. However, the lithium manganese oxide has problem of capacity fade which caused by dissolution of Mn ions during intercalation reaction and phase instability. For this problem, many studies on effect of various transition metals have been reported. In the preliminary study, the Sn-substituted LiMn2O4 thin films prepared by pulsed laser deposition have shown the improvement in discharge capacity and cycleability. In this study, the thin films of LiMn2O4 and LiSn0.0125Mn1.975O4 prepared by RF magnetron sputtering were studied with effect of deposition parameters on the phase, surface morphology and electrochemical property. And, all solid-state thin film batteries comprised of a lithium anode, lithium phosphorus oxy-nitride (LiPON) solid electrolyte and LiMn2O4-based cathode were fabricated, and the electrochemical property was investigated.

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