• 제목/요약/키워드: Dissolution behavior

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Factors Affecting the Dissolution Behavior of Metals from Binary Alloys

  • Han, Kenneth N.
    • 자원리싸이클링
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    • 제10권1호
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    • pp.49-55
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    • 2001
  • The strategy of recovering metals from scrap is in general much different from primary sources. One of the main differences between the treatment of scrap and that of primary sources lies with the fact that metals are frequently associated with other met-als to form alloys in scrap, while metals occur in primary sources as oxides or sulfides. In this paper, factors affecting the dis-solution behavior of metals from various alloy systems have been reviewed and discussed. Specific examples have been drawn from Au/Ag, Au/cu and Ag/cu systems. Results of the dissolution behavior of various metals from these alloys have been reviewed and compared to the dissolution behavior of single metal systems in various lixiviants such as acids, cyanide and ammonia. It has been observed that the presence of other metals in alloys would significantly affect the dissolution rate of the metal in question. The leaching behavior of metals from homogeneous alloys relies on the chemical interaction between atoms in the lattice of the alloys, while that from heterogeneous alloys is affected by galvanic interaction established in the solution The manner in which the dissolution of a certain metal is influenced by surrounding metals has been discussed in terms of pas-sive and noble nature of the metal in relation to the neighboring metals. The role of the standard electrochemical Potential of these metals on the selective dissolution for a given lixiviant has also been discussed.

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패션상품 소비자의 점포 관계단절에 관한 연구 (A Study on the Relationship Dissolution between Fashion Product Consumers and Stores)

  • 김은숙;이선재
    • 한국의류학회지
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    • 제33권3호
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    • pp.366-378
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    • 2009
  • The purpose of this study was to understand fashion product consumers' relationship dissolution by considering the characteristics of customer behavior and examining the connection between the main variables. The survey was conducted on 623 women over 20 years old who had experienced relationship dissolution or problems with regular fashion stores in the areas of Seoul and Kyungki in September 2005. The SPSS 12.0 package and Amos program were used to analyze the data. The results of this study were as follows: First, service recovery justice of a fashion store, interactional justice, distributive justice, and procedural justice had effects on encounter satisfaction. Furthermore, encounter satisfaction influenced relationship dissolution behavior, voice, exit, loyalty, neglect via overall satisfaction. Second, there were differences in relationship dissolution behavior according to consumer loyalty and switching costs.

석영광물의 용해 및 수산화 이온의 확산에 관한 균질화해석 (Homogenization Analysis of Problems related to Quartz Dissolution and Hydroxide Diffusion)

  • 최정해
    • 지질공학
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    • 제20권3호
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    • pp.271-279
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    • 2010
  • 광물의 용해현상과 밀접하게 관련된 암석의 시간의존성 변형과 파괴현상은 실내시험에서 비교적 용이하게 관찰된다. 본 연구에서는 고준위 방사성폐기물의 지하 처분장 건설시 완충제로 사용되어지는 벤토나이트에 많이 포함된 석영의 고 알칼리 환경 하에서의 용해 현상을 정량적으로 관찰하기 위해서 수산화 이온의 확산과 석영의 용해 문제를 균질화 해석법을 이용하여 평가하였다. 해석결과에 의하면 석영의 용해량은 주변 환경의 온도 및 층간수의 두께와 비례한다. 특히 고알칼리 환경 하에서는 층간수의 두께가 작아지면서 반응표면적이 커지게 되고 그 결과 용해 속도는 층간수의 두께가 작아질수록 커지는 결과를 나타내고 있다.

Diesel 용출에 따른 지하수 오염물질의 거동 (Modeling of Dissolution Potential of Diesel Components)

  • 김낙경;김현성;염익태
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2003년도 봄 학술발표회 논문집
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    • pp.577-584
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    • 2003
  • This study investigated the modeling of dissolution Diesel to estimate the behavior of contaminants in the ground. The modeling based on the initial concentration change considering dissolution potential of pure Diesel and Xylene was performed using VISUAL MODFLOW, and was compared with general modeling ignored the initial concentration change condition.

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Alkaline Weight Reduction Monitoring of Sea-island Type Polyarnide Microfiber Fabrics

  • Kwon Yoon-Jung;Koh Joon-Seok;Oh Myung-Joon;Kim Sung-Dong
    • Fibers and Polymers
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    • 제7권1호
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    • pp.20-25
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    • 2006
  • The alkaline dissolution behavior of sea-island type polyarnide microfibers were successfully monitored using a cationic dye staining method. Weight reduction behavior of the alkali-treated microfiber fabrics and the treated fabrics stained with cationic dye were investigated in a comparative manner. The termination of dissolution monitored by both methods was also confirmed by scanning electron microscopy.

Dissolution Behavior and Hydrate Effect on $CO_{2}$ Ocean Sequestration

  • Kim Nam Jin;Kim Chong Bo
    • Journal of Mechanical Science and Technology
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    • 제19권5호
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    • pp.1216-1225
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    • 2005
  • $CO_{2}$ ocean sequestration is one of the promising options to reduce $CO_{2}$ concentration in the atmosphere because the ocean has vast capacity for $CO_{2}$ absorption. Therefore, in the present investigation, calculations for solubility and dissolution behavior of liquid $CO_{2}$ droplets released at 1000 m and 1500 m deep in the ocean from a moving ship and a fixed pipeline have been carried out in order to estimate the $CO_{2}$ dissolution characteristics in the ocean. The results show liquid $CO_{2}$ becomes bubble at around 500 m in depth, and the solubility of seawater is about $5{\%}$ less than of pure water. Also, it is shown that the injection of liquid from a moving ship is a more effective method for dissolution than from a fixed pipeline, and the presence of hydrate on liquid $CO_{2}$ acts as a resistant layer in dissolving liquid $CO_{2}$.

용해재료가 포함된 지반의 전단강도 특성 (Shear Strength Characteristics of Geo - Soluble - Materials)

  • 짠밍콰;박정희;변용훈;신호성;이종섭
    • 한국지반공학회논문집
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    • 제27권12호
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    • pp.17-25
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    • 2011
  • 흙입자의 구조는 흙을 구성하는 용해성 입자의 용해작용, 건조작용 그리고 고결화 현상과 같은 특정요인에 의해 영향을 받으며 입자구조의 변화는 흙의 역학적 거동에 큰 영향을 미친다. 본 논문에서는 흙속에 포함된 용해성입자의 용해작용이 전단강도에 미치는 영향을 조사하였다. 직접전단실험을 위해 소금과 모래로 구성된 혼합재를 이용하여 시료를 조성하고 전체시료에 대한 용해성 입자의 부피비를 조절하면서 실험을 수행하였으며 실험과 동일한 조건하에 서 수치해석을 수행하였다. 입자의 소실과정을 위해 실험에서는 소금-모래 혼합재를 포화시켜 소금을 용해시켰으며 수치해석에서는 용해성 입자의 크기를 줄이는 것으로 용해과정을 모사하였다. 실험결과, 용해성 입자의 부피비가 증가할수록 내부마찰각은 감소하였고, 시료의 수직변형은 팽창거동에서 수축거동으로 변화하였다. 수치해석은 실험 결과와 유사한 거시적 거동을 보여주었다. 미시적관점에서, 입자가 용해됨에 따라 간극비의 증가, 접촉점 수의 감소, 전단접촉력의 증가, 접촉력 연결고리의 이방성에 의해 새로운 입자구조가 생성됨을 보여주었다. 이러한 미시적 거동의 변화는 입자의 용해작용 후 전단거동에 영향을 주게 된다. 본 연구에서는 기초나 지반구조물의 설계와 시공 시 지반재료의 용해에 따른 전단강도을 고려해야 함을 보여준다.

Effects of dissolution temperature on the rheological properties of polyvinyl alchol solutions in dimethyl sulfoxide

  • Cho, Yong-Han;Dan, Kyung-Sik;Kim, Byoung-Chul
    • Korea-Australia Rheology Journal
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    • 제20권2호
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    • pp.73-77
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    • 2008
  • The rheological properties of polar solutions are very sensitive to preparative methods as well as measuring conditions. The effects of dissolution temperature on the rheological properties of the solutions of polyvinyl alcohol (PVA) in dimethyl sulfoxide were investigated over the range of dissolution temperatures $70-130^{\circ}C$. Viscosity was increased as dissolution temperature was increased. PVA solutions prepared at 120 and $130^{\circ}C$ showed Bingham behavior, which became less noticeable with decreasing dissolution temperature. The modified Cole-Cole plot of the solutions gave slope less than 2, suggesting the solutions were a heterogeneous system irrespective of optical transparency. Further, the slope was decreased with increasing dissolution temperature, indicating that the solid character got more prominent as dissolution temperature was increased. However, the relaxation time of the solutions was little dependent on dissolution temperature.

Dissolution of North Korean Magnesite by using Hydrochloric Acid

  • Baek, Ui-Hyun;Park, Hyungkyu;Lee, Jin-Young;Kang, Jungshin
    • Korean Chemical Engineering Research
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    • 제55권5호
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    • pp.711-717
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    • 2017
  • A fundamental study was conducted on the dissolution of North Korean magnesite using hydrochloric acid to understand the dissolution behavior of the magnesium and impurities. The influence of the acid concentration, particle size of the magnesite, reaction temperature, and pulp density on the dissolution of magnesium, iron, calcium, aluminum, and silicon dioxide was studied. The experimental results showed that 98.5% of magnesium, 86.9% of iron, 87.3% of calcium, 23.6% of aluminum, and 20.4% of silicon dioxide were dissolved when magnesite particle sizes within the range of $75{\sim}105{\mu}m$ were reacted using 3 M HCl solution under 6% pulp density at 363 K for 3 h. The residues that remained after the dissolution were silicon dioxide, talc, and clinochlore.

염산과 수산화칼슘 수용액과의 반응에 의한 사장석의 용해 거동 (Dissolution Behavior of Plagioclase in HCl and KOH Solutions)

  • 현성필;김수진
    • 한국광물학회지
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    • 제9권2호
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    • pp.71-81
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    • 1996
  • Dissolution experiments were conducted to understand chemical nature of weathering of anorthosite from the Hadong area. Anorthosite and plagioclase from it were reacted with HCl or KOH solutions under various conditions concerning such as grain size, initial pH of solutions, and shaking Average composition of plagioclase used in the experiment was Na0.32Ca0.71Al1.71Si2.28O8.Under acidic conditions, solution pH increases rapidly in the initial stage and then gradually to reach palteau. Shaking agitates the reaction rate in the initial stage but does not affect after the system reached steady state. Ca and si concentrations show rapid increase and then gradual increase. Al concentration increases rapidly in the early stage and then decreases. Later decrease was interpreted as the precipitation of an Al-bearing material. Different dissolution rates of different constituents of plagioclase together the with precipitation of al-bearing material might be responsible for the non-stoichiometric dissolution of plagioclase.X-ray diffraction analyses on anorthosite before and after dissolution experiment show dissolution rates differ with different lattice planes of plagioclase. It suggests the crystallographic control on dissolution reaction. X-ray photoelectron spectroscopic result shows that the average composition of plagioclase surface reacted with HCL of initial pH 1.97 for 2000 hours is Na0.20Ca0.26Al1.7Si2.3O8. It means that Na- and Ca-depleted H-feldspar is developed without Al-depleted layer on the surface of plagioclase by reaction with HCl and that dissolution reaction takes place sparsely on the surface of plagioclase. Al and Si are dissolved preferentially over Ca from anorthosite powder in KHO solution. Reaction of acid-reacted anorthosite with KOH solution shows the same Si dissolution behavior as in the fresh anorthosite. This indicates that the Al-depleted and Si-enriched layer does not build up on the acid-reacted surface.

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