• Bulletin of the Korean Chemical Society
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• v.19 no.4
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• pp.434-436
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• 1998

The mechanism of nucleophilic displacement was studied by using three variable systems of ${\rho}_X,\; {\rho}_Y,\; and {\rho}_Z$ obtained from the change of substituent X, Y, and Z for the reaction of (Z)-substituted benzyl (X)-benzensulfonates with (Y)-substituted thiobenzamides in acetone at 45 ℃. The results ${\rho}_Z$<0 and ${\rho}_YZ$>${\rho}_XZ$ indicate that this reaction series proceeded via a dissociative $S_N2$ mechanism. The prediction of the movement of TS by using the sign of ${\rho}_XZ{\cdot}{\rho}_{YZ}$ accorded with the Hammond postulate.

• Journal of Power System Engineering
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• v.7 no.4
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• pp.61-66
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• 2003

In this paper, the relation between displacement of piezoelectric material and electric field was proposed. FEA was introduced to predict the displacement and reaction force of plate spring attached in the piezoelectric material. The relation between displacement of piezoelectric material forced by plate spring and applied electric field were further verified by experimental investigation. Also, the flow rate of gas in piezoelectric valve was examined by experiment. Finally, the relation between electric field and gas flow was derived. Based on these results, these relations can be used in the design of mass flow controller.

• Transactions of the Korean Society of Automotive Engineers
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• v.8 no.4
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• pp.149-157
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• 2000

Computer simulations of the mechanical behavior of a three point bend specimen with a quarter notch under impact load are performed. The case with a load application point at the side is considered. An elastic-plastic von Mises material model is chosen. Three phases such as impact bouncing and bending phases are found to be identified during the period from the moment of impact to the estimated time for crack initiation. It is clearly shown that no plastic deformation near the crack tip is appeared at the impact phase. However it is confirmed that the plastic zone near the crack tip emerges in the second phase and the plastic hinge has been formed in the third phase. Gap opening displacement crack tip opening displacement and strain rate are compared with rate dependent material(visco-plastic material). The stability during various dynamic load can be seen by using the simulation of this study.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2005.05a
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• pp.360-363
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• 2005

Biomimetic actuators composed of cellophane with an electrically conducting polyaniline(PANI) film have been fabricated and tested in air ambience conditions doped with two different counter ions such as perchlorate (${ClO_4}^-$) and tetrafluoroborate (${BF_4}^-$). Fabrication of the trilayer CP//CELLOPHANE//CP substantially enhanced the tip displacement (13.2mm) compared to the small displacement (8.3mm) of the bilaye. CP//CELLOPHANE. The ion migration among layers is the main factor behind the expansion of cellophane, while the expansion/contraction of PANI are dependent on the redox reaction of the polymer. The displacement of the composite is dominated by the humidity content. This implies that the actuation principle is possibly due to the assistance of water existing.

• Proceedings of the KIEE Conference
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• 2001.07c
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• pp.1530-1532
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• 2001

The displacement current measuring system used for detecting the dynamic behavior of monolayers at the air-water interface is described. It basically consists of a film balance, a pair of electrodes connected to each other through a sensitive ammeter. Here, one electrode is suspended in air and the other electrode is placed in the water. With Maxwell-displacement-current-measuring method, the phase transitons of Poly-$\gamma$-benzyl p-glutamate (PBDG) on a water surface were detected. Measured surface pressure, displacement current and dipole moment of monolayers of PBDG on the water surface. Also, we measured that compression velocity(30, 40, 50[mm/min]) when the sample spread volume was about 400[ul]. From the result, it is known that current is generated in the range of high surface pressures as compression velocity become faster.

• Proceedings of the Korean Geotechical Society Conference
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• 2002.10a
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• pp.65-84
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• 2002

The Observational Method proposed by Terzaghi can be applied for the safe and economic construction projects where the exact prediction of the behavior of the structures is difficult as in the underground excavation. The method consists of measuring lateral displacement, ground settlement and axial force of supports in the earlier stage of the construction and back analysis technique to find the best fit design parameters such as earth pressure coefficient, subgrade reaction etc, which will minimize the gap between calculated displacement and measured displacement. With the results, more reliable prediction of the later stage can be obtained. In this study, back analysis programs using the Direct Method, based on the Hill Climbing Method were made and evaluated, and to overcome the limits of the method, Genetic Algorithm(GA) was applied and tested for the actual construction cases.

• Bulletin of the Korean Chemical Society
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• v.16 no.11
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• pp.1060-1064
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• 1995

The reactivity of superoxide ion (O2-.) with halogenated substrates is investigated by cyclic voltammetry and rotated ring-disk electrode method in aprotic solvents. The more positive the reduction potential of the substituted nitrile, the more facile is nucleophilic displacement by O2-.. The reaction rates of halogenonitriles with O2-. vary according to the leaving-group propensity of halide (Br > Cl > F). The relative reaction rates of other substituted nitriles are in the order of electron-withdrawing propensity of the substituent group (CN > C(O)NH2 > Ph ≒ CH2CN). The reaction of O2-. with dihalocarbons indicates that five-membered rings can be rapidly formed by the cyclization of substrate and O2-., and the relative rates of cyclization depend on the number of methylenic carbons {Br(CH2)nBr, [n=1 < 2 < 3 > 4 > 5]}. Mechanisms are proposed for the reaction of O2-. with halogenated substrates.

• International Journal of Highway Engineering
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• v.10 no.2
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• pp.81-89
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• 2008

Shear test procedure for concrete-dowel interaction was proposed along with determination of dowel support reaction factor or shear spring stiffness constant using the spreadsheet example. For this task, three AASHTO-type standard specimens were prepared to simulate behavior of the jointed concrete pavement. A side support system was adopted to minimize twisting of the test specimen which had been observed in a preliminary test. A typical elastic behavior of the dowel-concrete interaction was observed from several test loops of loading, unloading and reloading procedures. However load versus slab displacement represents to be nonlinear. Test results show that the dowel support reaction factor ranges from 550-880 GN/m3, which is 1.4-2.2 times greater than 407GN/m3 proposed by Yoder and Witczak. This is because less torsional distraction was occurred with the help of a side support system adopted in this experiment. The dowel support reaction factor or shear spring stiffness constant obtained from the procedures proposed in this paper may be used as a reference data for the structural analysis of jointed concrete pavement.

• Structural Engineering and Mechanics
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• v.51 no.1
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• pp.131-140
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• 2014

This study focuses on seismic behaviour of tall piers characterized by high slender ratio. Two analysis models were developed based on elastic-plastic hinged beam element and elastic-plastic fiber beam element, respectively. The effect of the division density of elastic-plastic hinged beam element on seismic demand was discussed firstly to seek a rational analysis model for tall piers. Then structural seismic behaviour such as the formation of plastic hinges, the development of plastic zone, and the displacement at the top of the tall piers were investigated through incremental dynamic analysis. It showed that the seismic behaviour of a tall pier was quite different from that of a lower pier due to higher modes contributions. In a tall pier, an additional plastic zone may occur at the middle height of the pier with the increase of seismic excitation. Moreover, the maximum curvature reaction at the bottom section and maximum lateral displacement at the top turned out to be seriously out of phase for a tall pier due to the higher modes effect, and thus pushover analysis can not appropriately predict the local displacement capacity.

• Proceedings of the KIEE Conference
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• 2000.07c
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• pp.1693-1695
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• 2000

In this paper with deposition 8A5H induce monolayers which has photoisomerization response displacement current was detected by photoisomerization and the amplifier was designed in order to amplify detected displacement current and then secondary current characteristic was measured. The experimental results are as following: In case of ultraviolet(${\lambda}_1$) and visible(${\lambda}_2$) irradiation on 8A5H induce monolayers depositioned on board the peak of current was detected about 9[fA]. Displacement current amplified as secondary transition form was measured but there was any particular reaction for detailed and accurate measurement restruction of the circuit is required.