• Title/Summary/Keyword: Dispersion variation

검색결과 275건 처리시간 0.026초

초음파 진동자의 반복진동에 의한 슬러지유의 균질효과 (The Homogenizing Effect of Sludge Oil by Repeated Vibration of Ultrasonic Transducer)

  • 한원희;정지선;하만식;이진열;고성정
    • 해양환경안전학회:학술대회논문집
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    • 해양환경안전학회 2001년도 추계학술발표회
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    • pp.17-24
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    • 2001
  • The sludge oils were produced necessarily in the ships operation, so that it will be the best way to manage the sludge oils inside ship itself from a viewpoint of the prevention of marine oil pollution from ship. The present study deal with the ultrasonic breaking systems which recycle the sludge oil from ships into usable oil to be burnt. The first place, experimental studies were carried out to investigate the homogenizing effect of the marine oils by repeated vibration of ultrasonic transducer. Variation of the properties(viscosity, specific gravity and pH) and the matrix structures for the environment of various marine oils were interpreted to analyze the breaking, dispersion effects by cavity. The experimental results can be useful to the development of sludge oil disposing systems.

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EPR의 전기특성에 미치는 방사선의 영향 (Effect of the Co$^{60}$ -Rays due to Electric properties of EPR-)

  • 이성일
    • 대한안전경영과학회:학술대회논문집
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    • 대한안전경영과학회 2002년도 추계학술대회
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    • pp.253-259
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    • 2002
  • The value of charge currnet, discharge current, ${\varepsilon}r^'$,${\varepsilon}r^{'}$ residual voltage was measured inorder to investigate electric properties in Ethylene Prophylene Rubber for is irradiated C0$^{60}$$\gamma$ ray 0~38.1 Mrad. The value of charge current and the discharging current of the EPR is influenced by C0$^{60}$-$\gamma$- irradiation dose. The charging current and the discharging current of EPR increas, depending on the ratio of degradation. As the irradiatin dose is increased, the peak of residual voltage moves to the slorter time. The properties specific electric constant due to time variation was appeared dispersion by plentiful C0$^{60}$$\gamma$- irradiation dose. The increase of peak in ${\varepsilon}r^{'}$ is attrib uted to the irratiation dose almost proportionally.

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Preparation of Au fine particle dispersed $TiO_2$ film by sol-gel and photoreduction process

  • Hyun, Buh-Sng;Kim, Byeong-Il;Kang, Won-Ho
    • 한국결정성장학회:학술대회논문집
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    • 한국결정성장학회 1998년도 PROCEEDINGS OF THE 15TH KACG TECHNICAL MEETING-PACIFIC RIM 3 SATELLITE SYMPOSIUM SESSION 4, HOTEL HYUNDAI, KYONGJU, SEPTEMBER 20-23, 1998
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    • pp.103-111
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    • 1998
  • Au fine particle dispersed TiO2 film was prepared on silica glass substrate by sol-gel dip and firing process. The films were fabricated from the system of titanium tetraisoproxie-EtOh-HCl_H2O-hydrogen tetrachloroaurate(III) tetrahydrate. The conditions for the formation of the clear solution and dissolving high concentration of Au compound were examined. And a photoreduction process was adopted to control the size of gold metal particles. Phase evolution of matrix TiO2 and variation of Au particle with UV irradiation were investigated by XRDA, SEM, TEM and UV-visible spectrophotometer. And the effect of CPCl(Cetylpyridinium chloride monohydrate) as a dispersion agent was evaluated.

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Particle Growth in Oxalate Process I

  • Park, Zee-Hoon;Shin, Hyo-Soon;Lee, Byung-Kyo
    • The Korean Journal of Ceramics
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    • 제2권2호
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    • pp.63-69
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    • 1996
  • Barium titanyl oxalates, strontium titanyl oxalates and calcium zirconyl oxalates were prepared with variation of solution concentration and method of adding mixed metal ion solution into oxalic acid. Then they were aged in distilled water, ethanol or methanol, respectively. Barium titanyl oxalates and calcium zironyl oxalates were grown in water and strontium titanyl oxalates were groun in both water and methanol. They were supposed to be grown through the solutionl and reprecipitation mechanism. Nonuniform dispersion of particles in liquid phase is thought to cause abnormal particle growth.

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SPECTRO-ELLIPSOMETRIC STUDIES OF STRUCTURE AND OPTICAL PROPERTIES OF PLSMA-GROWN DLC FILMS

  • Rhee, Sung-Gyu;Lee, Soon-Il;Oh, Soo-Ghee;Lee, Kwang-Ryeol
    • 한국표면공학회지
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    • 제29권5호
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    • pp.532-539
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    • 1996
  • Diamond-like carbon (DLC) films were deposited on silicon substrates by the plasma decomposition of hydrocarbons under various conditions, and studied by the spectroscopic ellipsometry (SE). We used the effective medium approximation with the dispersion model developed by Forouhi and Bloomer to determine simultaneously both the structure and the optical constants of the DLC films from their ellipsometric spectra. Especially, we investigated the variation of the multilayer structure including the interface layer, of the refractive indices, and of the extinction coefficients as the deposition conditions were varied; substrate pretreatment procedure, hydrocarbon precursors, and the substrate bias voltage were varied.

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가상 지진해일에 의한 동해안에서의 피해 예측 (The prediction of maximum wave height for virtual tsunami in the eastern coast of the Korea)

  • 심주열;최문규;조용식
    • 한국방재학회:학술대회논문집
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    • 한국방재학회 2008년도 정기총회 및 학술발표대회
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    • pp.229-232
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    • 2008
  • The Central East Sea Tsunami caused huge damage to the eastern coast of the Korean Peninsula, eapecially Imwon port was damaged relatively strongly beacause of water depth variation which makes the wave concentration on this port. there are many virtual tsunami in east sea which has a possibility of happening. So, it is very important to expect the region which may be damaged by vritual tsunmis. In this study, modified dispersion-correction terms are used. The modified scheme has the advantage of using the constant spatial grid size and time step size even in real topography. Dynamic linking technique and staggered grid system are used. Using this model some cases of virtual tsunami was simulated and check the region which is occured maximum wave heights on the eastern sea of the Korean peninsula.

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Electrolyte Effect on the Particle Characteristics Prepared by Soap-Free Emulsion Polymerization

  • Han, Seung-Tak;Lee, Kang-Seok;Shim, Sang-Eun;Saikia, Prakash J.;Choe, Soon-Ja;Cheong, In-Woo
    • Macromolecular Research
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    • 제15권5호
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    • pp.403-411
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    • 2007
  • Monodisperse micron-sized polystyrene (PS) spheres were successfully obtained using a single stage soap-free emulsion method in aqueous media mixed with ethanol (co-solvent) containing NaCI as the electrolyte. The optimum conditions for preparing the monodisperse PS microspheres, using soap-free emulsion polymerization in a water/ethanol mixture with an electrolyte, were studied. The presence of the co-solvent and electrolyte controlled the particle dispersion stability during the polymerization. The microspheres formed using PS, with a weight-average diameter of $2.6{\mu}m$, coefficient of variation of 5.3% and zeta potential of -15.1 eV, were successfully obtained in the presence of 0.1 wt% NaCI, 10 wt% monomer, 0.1 wt% initiator and 95/5 (g/g) of a water/ethanol mixture reacted at $70^{\circ}C$ for 24 h.

전자선 증착기술에 의해 성장된 다결정 CdSe 박막의 광학적 특성 (Optical properties of the polycrystalline CdSe thin films grown by the electron-beam evaporation technique)

  • 김화민
    • 한국진공학회지
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    • 제9권1호
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    • pp.60-68
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    • 2000
  • The optical constants ($E_g^d$, n, K) of the polycrystalline CdSe thin films deposited on the glass substrate by the electron-beam evaporation technique are determined over 400~2,500 nm photon wavelengths. In order to explain the variation of the optical contents with film thickness and substrate temperatures, the surface microstructural parameter are investigated by AFM (atomic forced microscope( images for the films deposited by different growth conditions. It is shown that the variations of optical constants are close related to changes of the surface morphology of the CdSe thin films. The decrease in the band gap with film thickness is connected with quantum size effects due to increase of the grain size. The refractive index of CdSe films decrease with increasing the grain size of the films, and the dispersion of the refractive index followed a single oscillator model according to the Sellmeier formulation.

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Experimental Study of Film Cooling Behaviors at a Cylindrical Leading Edge

  • Kim S. M.;Kim Youn-J.
    • 한국가시화정보학회:학술대회논문집
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    • 한국가시화정보학회 2002년도 추계학술대회 논문집
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    • pp.81-84
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    • 2002
  • Dispersion of coolant jets in a film cooling flow field is the result of a highly complex interaction between the film cooling jets and the mainstream. In order to investigate the effect of blowing ratios on the film cooling of turbine blade, cylindrical body model was used. Mainstream Reynolds number based on the cylinder diameter was $7.1\;\times\;10^4$. The free-stream turbulence intensity kept at $5.0\%$ by using turbulence grid. The effect of coolant flow rates was studied for blowing ratios of 0.9, 1.3 and 1.6, respectively. The temperature distribution of the cylindrical model surface is visualized by infrared thermography (IRT). Results show that the film-cooling performance may be significantly improved by controlling the blowing ratio. As blowing ratio increases, the adiabatic film cooling effectiveness is more broadly distributed and the area protected by coolant increases. The mass flow rate of the coolant through the first-row holes is less than that through the second-row holes due to the pressure variation around the cylinder surface.

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Transition-State Variation in the Solvolyses of Phenyl Chlorothionoformate in Alcohol-Water Mixtures

  • 구인선;양기열;강대호;박혜진;강금덕;이익춘
    • Bulletin of the Korean Chemical Society
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    • 제20권5호
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    • pp.577-580
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    • 1999
  • Solvolyses of phenyl chlorothionoformate in water, D2O, CH3OD, 50% D2O-CH3OD, and in aqueous binary mixtures of acetone, ethanol and methanol are investigated at 25.0℃. The Grunwald-Winstein plots of firstorder rate constants for phenyl chlorothionoformate with Ycl (based on 2-adamantyl chloride) show a dispersion phenomenon, and also the extended Grunwald-Winstein plots show a poor correlation for the solvolyses of phenyl chlorothionoformate. The ring parameter (I) has been shown to give considerable improvement when it is added as an hI term to the original and extended Grunwald-Winstein correlations. The dispersions in the Grunwald-Winstein correlations in the present studies are caused by the conjugation between the reaction center and the aromatic ring in the vicinity of the reaction center. This study has shown that the magnitude of l and m values associated with a change of solvent composition leads to predict the SN2 transition state. The kinetic solvent isotope effects determined in deuterated water and methanol are consistent with the proposed mechanism of the general base catalyzed SN2 mechanism.