• Title/Summary/Keyword: Dispersion interaction

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Washing Effects on Generation of Pretilt Angle in NLC, 5CB, on a Polyimide Surface with Trifluoromethyl Moieties

  • Lee, Sang-Keuk;Hwang, Jeoung-Yeon;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.04a
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    • pp.133-135
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    • 2003
  • The washing effects on pretilt angle generation in a nematic liquid crystal (NLC), 4-n-pentyl-4’-cyanobiphenyl (5CB) on a rubbed polyimide (PI) surface with trifluoromethyl moiety have been successfully studied. The pretilt angle of 5CB is increased by the washing process on the rubbed PI surface. The surface tension on the rubbed PI surface increases with the rubbing strength RS and then saturated above RS=150 mm. The pretilt angle of 5CB for all washing processes on the rubbed PI surface decreases with the surface tension. We have found that the pretilt angle of 5CB on the rubbed PI surface may be attributed van der walls (VDW) dispersion interaction between the LC molecules and the polymer surfaces having trifluoromethyl moieties.

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Study of viscoelastic model for harmonic waves in non-homogeneous viscoelastic filaments

  • Kakar, Rajneesh;Kaur, Kanwaljeet;Gupta, Kishan Chand
    • Interaction and multiscale mechanics
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    • v.6 no.1
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    • pp.31-50
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    • 2013
  • A five parameter viscoelastic model is developed to study harmonic waves propagating in the non-homogeneous viscoelastic filaments of varying density. The constitutive relation for five parameter model is first developed and then it is applied for harmonic waves in the specimen. In this study, it is assumed that density, rigidity and viscosity of the specimen i.e., rod are space dependent. The specimen is non-homogeneous, initially unstressed and at rest. The method of non-linear partial differential equation has been used for finding the dispersion equation of harmonic waves in the rods. A simple method is presented for reflections at the free end of the finite non-homogeneous viscoelastic rods. The harmonic wave propagation in viscoelastic rod is also presented numerically with MATLAB.

The Effect of Impinging Land Size on Diesel Spray Behavior in OSKA Type Combustion Chamber (OSKA형 연소실에서 충돌면크기변화가 디젤분무거동에 미치는 영향)

  • 임덕경;박권하
    • Transactions of the Korean Society of Automotive Engineers
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    • v.9 no.4
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    • pp.18-26
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    • 2001
  • OSKA engine was developed to remove the dense core of injection sprays. The engine uses impinging spray on a small pip, which spray after impinging is broken into smaller drops and disperses into fee space in chamber. In this paper the pip size is analyzed to give more dispersion of spray and fuel vapor. The gas phase is modelled by the Eulerian continuum conservation equations of mass, momentum, energy and fuel vapour fraction. The liquid phase is modelled following the discrete droplet model approach in Lagrangian form, and the droplet wall interaction is modelled as a function of the velocity normal to impaction lands. The droplet distributions, vapor fractions and gas flows are analyzed for various injection pressure cases. Numerical results indicate that the land diameter of 5.6mm has the best performance of spray dynamics and vaporization in the test sizes.

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Liquid crystal alignment and pretilt angle generation using oblique UV light irradiation on polymer surface (경사진 자외선조사를 이용한 셀의 프리틸트각의 입사각도 의존성)

  • 서대식;한정민;박두석;박태규;황율연
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.267-270
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    • 1998
  • In this study, we investigated the generation of pretilt angle for nematic liquid crystal (NLC) in a cell with oblique non-polarized ultraviolet (UV) light irradiation on polyimide (PI) surfaces. It was found that the monodomain alignment of the NLC is obtained in a cell with an angle of incidence of 70∼85$^{\circ}$on PI surface. We consider that the monodomain alignment of NLC is attributed to anisotropic dispersion force effect due to Photo-depolymerization of polymer on PI surfaces. Also, pretilt angle of NLC is generated about 3$^{\circ}$ with an angle of incidence of 70∼75$^{\circ}$. It is considered that the pretilt angle generation in NLC is attributed to interaction between the LC molecules and the polymer surfaces.

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A study on Characteristics of Installation object Appeared in Interior of contemporary Commercial Space (현대 상업공간 실내에 나타난 설치적 오브제의 표현특성에 관한 연구)

  • Kim, Ki-Young;Kim, Moon-Duck
    • Proceedings of the Korean Institute of Interior Design Conference
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    • 2008.05a
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    • pp.203-208
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    • 2008
  • Installation art in 20th century shows an expanded trend as a result of material, time, or spatial expansion of subject, therefore subjects could be either materials or non-materials. This trend says that three elements-objet, space, and spectator-is inseparable essence of installation art. Nowadays, the borderline between installation art and everyday human life is getting indistinctive, and both Installation art and human life are becoming a part of another. By adapting the flexibility of installation art into the interior space, more interaction could happen, therefore, people will recognize spatial and visual character of Interior space as a visually satisfying Installed object. The main goal of this study is to understand changing of spatial composition in consequence of expressional variety as a result of dispersion of spatial elements. Especially, this study gives a fundamental ideas about private character of installations art in commercial spaces and expressional character of modern installations.

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Generation of high pretilt angle in nematic liquid crystal by using photo-alignment techniques on polyimide surfaces (광배향 기술을 이용한 액정의 고프리틸트각 발생)

  • 한정민;황율연;이창훈;서대식
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.198-201
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    • 1997
  • We investigated the generation of pretilt angle for nematic liquid crystal (NLC) in a cell with slanted non-polarized ultraviolet (UV) light irradiation on mixtured polyimide (PI) surfaces. It was found that the monodomain alignment of NLC is obtained in a cell with an angle of incidence of 75∼85 degrees on PI surface. We consider that the monodomain alignment of NLC is attributed to anisotropic dispersion force effect due to photo-depolymerization of polymer on Pl surfaces. We successfully observed that the pretilt angle of NLC is generated above 5 degree with an angle of incidence of 75∼85 degree. It is considered that the pretilt angle generation in NLC is attributed to interaction between the LC molecules and the Polymer surfaces.

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Early Globalization and the Law of One Price: Evidence from Sweden, 1732-1914

  • Crucini, Mario J.;Smith, Gregor W.
    • East Asian Economic Review
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    • v.20 no.4
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    • pp.427-445
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    • 2016
  • We review research using departures from the law of one price to measure the advent of globalization in Europe and Asia. In an application, we then study the role of distance and time in statistically explaining price dispersion across 32 Swedish towns for 19 commodities from 1732 to 1914. The resulting large number of relative prices (502,689) allows precise estimation of distance and time effects, and their interaction. We find an effect of distance that declines significantly over time, beginning in the 18th century, well before the arrival of canals, the telegraph, or the railway.

Experimental Study of Film Cooling Behaviors at a Cylindrical Leading Edge

  • Kim S. M.;Kim Youn-J.
    • 한국가시화정보학회:학술대회논문집
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    • 2002.11a
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    • pp.81-84
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    • 2002
  • Dispersion of coolant jets in a film cooling flow field is the result of a highly complex interaction between the film cooling jets and the mainstream. In order to investigate the effect of blowing ratios on the film cooling of turbine blade, cylindrical body model was used. Mainstream Reynolds number based on the cylinder diameter was $7.1\;\times\;10^4$. The free-stream turbulence intensity kept at $5.0\%$ by using turbulence grid. The effect of coolant flow rates was studied for blowing ratios of 0.9, 1.3 and 1.6, respectively. The temperature distribution of the cylindrical model surface is visualized by infrared thermography (IRT). Results show that the film-cooling performance may be significantly improved by controlling the blowing ratio. As blowing ratio increases, the adiabatic film cooling effectiveness is more broadly distributed and the area protected by coolant increases. The mass flow rate of the coolant through the first-row holes is less than that through the second-row holes due to the pressure variation around the cylinder surface.

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$Ni/\gamma -Al_2O_3$ Catalyst Prepared by Liquid Phase Oxidation for Carbon Dioxide Reforming of Methane

  • 정경수;조병율;이호인
    • Bulletin of the Korean Chemical Society
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    • v.20 no.1
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    • pp.89-94
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    • 1999
  • Carbon dioxide reforming of methane on Ni/γ-Al2O3 catalyst was studied. A new 10 wt% Ni/γ-Al2O3 catalyst prepared by the liquid phase oxidation method (L10O) exhibited much higher activity as well as resistances to both sintering and coke formation during the reaction than the catalyst prepared by the conventional impregnation method (D10). The electrically strong attractive interaction between nickel and support during the liquid phase oxidation process and the resultant high nickel dispersion made the L10 have superior activity and stability to the D10. To elucidate the results, the experiments with nickel catalysts on the other supports as well as 7-AI203 were performed. The effect of sodium as a promoter was also studied.