• Title/Summary/Keyword: Dispersion factor

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Filler-Elastomer Interactions. 2. Cure Behaviors and Mechanical Interfacial Properties of Carbon Black/Rubber Composites (충전재-탄성체 상호작용. 2. 카본블랙/고무 복합재료의 경화 거동 및 기계적 계면 물성)

  • Kim, Jeong-Soon;Park, Soo-Jin
    • Elastomers and Composites
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    • v.35 no.2
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    • pp.122-131
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    • 2000
  • In this work, the effect of chemical surface treatments on morphology of carbon blacks was investigated in terms of cure behavior and tearing energy ($G_T$) of carbon blacks/rubber composites. As experimental results, the polar or nonpolar chemical treatment led to a significant physical change of carbon black morphology. The cure activation energies (Ea) and frequency factor (A) obtained from Kissinger equation decreased with improving the dispersion of carbon flacks, resulting in high reactivity. However, a significant advantage of carbon black/rubber composites is gained by carbon blacks treated in basic (BCB) or nonpolar (NCB) chemical solution, resulting in increasing the tearing energy. These results could be explained by changes of dispersion, agglomerate, surface functional group, void volume, and cross-linking density of carbon black/rubber composites.

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Frequency Dependent Properties of Tris(8-Hydroxyquinoline) Aluminum Thin Films

  • Lee, Yong-Soo;Park, Jae-Hoon;Choi, Jong-Sun
    • KIEE International Transactions on Electrophysics and Applications
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    • v.11C no.3
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    • pp.70-74
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    • 2001
  • Admittance or impedance spectroscopy is one of the powerful tools to study dielectric relaxation and loss processes in organic and inorganic materials. In this study, the frequency dependent properties of an indium tin oxide/tris(8-hydroxyquinoline) aluminum($Alq_3$)/aluminum structure have been studied. The conductance of the $Alq_3$ film increases with the DC applied voltage up to 4V and decreases above 4V in the low frequency region. This indicates that the resistance of the device decreases with the applied bias due to the carrier injection enhancement, thereafter the injected carriers form the space charge and the additional injection of carriers is prevented. The Cole-Cole plot of the admittance takes a one-semicircle shape, which means that the device can be modeled as a parallel resistor-capacitor network. The resistance and capacitance were estimated as 8.62k${\Omega}$ and 2.7nF, respectively, at 3V in the low frequency region. The dielectric constant ( ${\epsilon}'$ ) of the $Alq_3$ film is independent of the frequency in the low frequency region below 100kHz, while the frequency dependency was observed at above 100kHz. The dielectric loss factor ( ${\epsilon}"$ ) of the $Alq_3$ film shows the dielectric dispersion below 100kHz and dielectric absorption in higher frequency domain. The dispersion is thought to be related to the hopping process of the carriers. The ${\epsilon}"$ is proportional to the reciprocal of the frequency. The dielectric relaxation time was extracted to about 0.318${\mu}s$ from the dielectric absorption spectrum.

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Assessment of PM Emission Factors Made by Construction Machineries (건설현장의 공사장비에 의한 미세먼지 배출계수 평가)

  • Lee, Im Hack;Lee, Kyoung Bin;Kim, Jin Sik;Kim, Shin Do
    • Journal of Korean Society for Atmospheric Environment
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    • v.30 no.4
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    • pp.311-318
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    • 2014
  • The goles of this study were that we calculated the difference between the emission factors currently used officially and the emission factors that calculated by atmospheric dispersion modeling results and actual field measurements of dust concentrations and that we investigated how we applied to the emission factors appropriate to the reality in Korea. At the results, we calculated the Business As Usual ambient dust concentration concerning U.S. EPA method emissions, and we thought that the emission reduction efficiency had to be 99.7% if the ambient dust concentration that measured in this study could be satisfied. In other words, U.S. EPA dust emission calculation method is very overestimated than reality, so it is important that our country obtain reliable construction site dust emissions estimation methods by continuous researches.

Transmission of 10 Gb/s optical signais over 320 km of a dispersion shifted fiber (10Gb/s 광신호의 320km 분산천이 광섬유 전송실험)

  • 이상수
    • Korean Journal of Optics and Photonics
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    • v.10 no.1
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    • pp.64-67
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    • 1999
  • We have been implemented 10 Gb/s-320 km of dispersion-shifted fiber (DSF) transmission. The optical link consists of a 10 Gb/s optical transceiver, an optical booster amplifier, 3 sets of optical in-line amplifiers, an optical preamplifier and transmission fibers. Firstly, we investigated the Q-factor characteristics in terms of optical signal to noise ratio (OSNR) of 320 km of DSF, measured receiver sensitivity is -27 dBm and power penalty is 2 dB, respectively. We concluded that optical SNR degradation and path penalty gives rise to 1 dB penalty, respectively.

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Hitting Probability on the Moving Target (이동표적에 대한 적중확률)

  • Oh H.J.
    • Journal of the military operations research society of Korea
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    • v.1 no.1
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    • pp.111-129
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    • 1975
  • U.S. Air Force Regulation 80-1 defines that a weapon system is composed of equipments, skills, and techniques, the composite of which ferns an instrument of combat. The complete weapon system includes all related facilities, equipments, materials, services, and personnels required for the operation of the system, so that the instrument of combat can be considered as a self-sufficient unit of striking power in its intended operational environment. Effectiveness of a weapon system can be expressed as a function of its liability, reliability and performance capability. Among these attributes which influence the weapon effectiveness, performance capability is considered to be the most critical factor for many weapon systems. In order to illustrate the application of the methodology of performance capability, a specific ease study on the effectiveness of Vulcan anti-air craft gun system is presented with special emphasis on hitting probability on moving targets, effects of artificial rounds dispersion, and several principles related to the deployment of the system. This thesis includes the thorough survey of the possibility of calculating the absolute value of hitting probability on moving targets, indicates that the effects of artificial rounds dispersion increase the value of probability only when the total number of rounds fired within fire range exceeds a certain critical number, and suggests that concentrated guns deployment is better than scattered deployment in order to obtain higher probability and lower average amount of rounds if it is assumed that the effects of counter-attack from enemy threats are not serious.

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Thixotropic Equation and Rheological Parameters on Non-Newtonian Flow Mechanism (비 뉴톤 유동 메카니즘에서 틱소트로피 식과 유변 파라메타)

  • Kim, Nam Jeong
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.3
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    • pp.386-393
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    • 2015
  • The rheological properties of complex materials such as colloid dispersion show complicated non-Newtonian flow phenomena when they are subjected to shear flow. These flow properties are controlled by the characteristics of flow units and the interactions among the flow segments. The rheological parameters of relaxation time $({\beta}_2)_0$, structure factor $C_2$ and shear modulus $X_2/{\alpha}_2$ for various thixotropic flow curves was obtained by applying thixotropic equation to flow curves. The variations of rheological parameters are directly related to non-Newtonian flows, viscosities and activation energies of flow segments.

Theoretical Estimation of Interfacial Tension between Molten Polymers (용융 고분자간의 계면장력에 대한 이론적 예측)

  • Youngie Oh;Joseph D. Andrade;Mu Shik Jhon
    • Journal of the Korean Chemical Society
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    • v.23 no.4
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    • pp.210-216
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    • 1979
  • A simple method to calculate the interfacial tension between two immiscible molten polymers has been developed. The theory is based on the significant structure theory of liquids. The energy of adhesion is expressed as a geometric mean of the cohesion energies multiplied by correction factor $({\Phi}12)$, ${\Delta}E_{12}={\Phi}_{12}\sqrt{{\Delta}E_{11}{\Delta}E_{22^{\circ}}$. In the calculation of ${\Delta}E_{11}\;and\;{\Delta}E_{22}$, a quasilattice of polymer chains has been assumed. It is assured that, besides the dispersion force, the polar force interactions between polymer constituent groups should be considered in the calculation of the interfacial tensions.

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Rheological Study on Oil in Water Microemulsion (수중유형 Miroemulsion의 유동학적 연구)

  • Min, Shin-Hong;Yang, Joong-Ik;Kwon, Jong-Won;Jeong, Dae-Sik;Jeong, Yeoub
    • Journal of Pharmaceutical Investigation
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    • v.17 no.1
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    • pp.38-40
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    • 1987
  • To optimize the preparation condition of oil in water microemulsion rheological method was used. The viscosity-temperature curve of refined soybean oil was recorded and from this result microemulsion was prepared at various temperatures and evaluated by Coulter counter during 3 weeks. The difference in rheograms of crude emulsion and the microemulsion varying the number of passes in the homogenizer was also examined. From above experiments following conclusions were obtained. 1) Through all the process, temperature was an important factor and the optimum was $60-80^{\circ}C$. 2) By first pass in the homogenizer, most oil droplets were finely dispersed. 3) In the homogenizing step the higher pressure results in the finer dispersion but as the pressure goes up, the differential efficiency of dispersion was decreased.

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A size-dependent quasi-3D model for wave dispersion analysis of FG nanoplates

  • Karami, Behrouz;Janghorban, Maziar;Shahsavari, Davood;Tounsi, Abdelouahed
    • Steel and Composite Structures
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    • v.28 no.1
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    • pp.99-110
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    • 2018
  • In this paper, a new size-dependent quasi-3D plate theory is presented for wave dispersion analysis of functionally graded nanoplates while resting on an elastic foundation and under the hygrothermaal environment. This quasi-3D plate theory considers both thickness stretching influences and shear deformation with the variations of displacements in the thickness direction as a parabolic function. Moreover, the stress-free boundary conditions on both sides of the plate are satisfied without using a shear correction factor. This theory includes five independent unknowns with results in only five governing equations. Size effects are obtained via a higher-order nonlocal strain gradient theory of elasticity. A variational approach is adopted to owning the governing equations employing Hamilton's principle. Solving analytically via Fourier series, these equations gives wave frequencies and phase velocities as a function of wave numbers. The validity of the present results is examined by comparing them with those of the known data in the literature. Parametric studies are conducted for material composition, size dependency, two parametric elastic foundation, temperature and moisture differences, and wave number. Some conclusions are drawn from the parametric studies with respect to the wave characteristics.

Surface modification of silica aerogel by surfactant adsorption and heat treatment methods (계면활성제 흡착 및 열처리를 이용한 실리카 에어로겔의 표면 개질)

  • Kim, Nam-Yi;Kim, Seong-Woo
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.3
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    • pp.282-289
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    • 2010
  • In preparation of silica aerogel-based hybrid coating materials, the combination of hydrophobic aerogel with organic polar binder material is shown to be very limited due to dissimilar surface property between two materials. Accordingly, the surface modification of the aerogel would be required to obtain compatibilized hybrid coating sols with homogeneous dispersion. In this study, the surface of silica aerogel particles was modified by using both surfactant adsorption and heat treatment methods. Four types of surfactants with different molecular weights and HLB values were used to examine the effect of chain length and hydrophilicity. The surface property of the modified aerogel was evaluated in terms of visible observation for aerogel dispersion in water, water contact angle measurement, and FT-IR analysis. In surface modification using surfactants, the effects of surfactant type and content, and mixing time as process parameter on the degree of hydrophilicity for the modified aerogel. In addition, the temperature condition in modification process via heat treatment was revealed to be significant factor to prepare aerogel with highly hydrophilic property.