• Title/Summary/Keyword: Dispersion Effect

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A Study on the Peel Strength of Silane-treated Silicas-filled Epoxy Adhesives (실란처리 되어진 실리카가 첨가된 에폭시 접착제의 접착박리강도에 관한 연구)

  • Choi, Bo-Kyung;Kim, Hong-Gun;Seo, Min-Kang;Park, Soo-Jin
    • Applied Chemistry for Engineering
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    • v.25 no.5
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    • pp.520-525
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    • 2014
  • In this paper, the effect of silane-treated silicas and epoxidized soybean oil (ESBO) addition on adhesion properties of silicas-filled epoxy adhesives was examined. The silicas were treated by ${\gamma}$-methacryloxy propyltrimethoxy silane (MPS), ${\gamma}$-glycidoxy propyl trimethoxy silane (GPS), and ${\gamma}$-mercapto propyl trimethoxy silane (MCPS). Surface and structural properties of the adhesives were determined by using scanning electron microscope (SEM) and Fourier transform infrared spectroscopy (FT-IR). The t-peel strength of the adhesives was estimated using the universal testing machine (UTM). And, the equilibrium spreading pressure, surface free energy, and specific surface area were investigated by BET methods with $N_2$/77 K adsorption. As a result, the peel strength of the adhesives was increased in the presence of silane-treated silicas in the adhesives compared to that of untreated silicas. This result indicated that the silane coupling agent played an important role in improving the dispersion of silicas in epoxy adhesives. And, the adhesives treated by MCPS were superior to the others in adhesion.

Evaluation of Seismic Performance of High Strength Reinforced Concrete Exterior Beam-Column Joints Using High Ductile Fiber-Reinforced Mortar (고인성섬유 복합모르타르를 활용한 고강도 철근콘크리트 외부 보-기둥 접합부의 내진성능평가)

  • Ha, Gee-Joo;Shin, Jong-Hak
    • Journal of the Korea Concrete Institute
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    • v.25 no.4
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    • pp.419-428
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    • 2013
  • In this study, experimental research was carried out to evaluate the constructability and seismic performance of high strength R/C exterior beam-column joints regions, with or without the shear reinforcement, using high ductile fiber-reinforced mortar. Five specimens of retrofitted the exterior beam-column joint regions using high ductile fiber-reinforced mortar are constructed and tested for their retrofit performances. Specimens designed by retrofitting the exterior beam-column joint regions (BCJNSP series) of existing reinforced concrete building showed a stable mode of failure and an increased its maximum load-carrying capacity by 1.09~2.03 times in comparison with specimen of BCJNS due to the effect of enhancing dispersion of crack control at the time of initial loading and bridging of fiber from retrofitting new high ductile materials during testing. Specimens of BCJNSP series attained its maximum load carrying capacity by 0.92~0.96 times and increased its energy dissipation capacity by 1.62 times when compared to standard specimen of BCJC with a displacement ductility of 4.

Performance evaluation of SFRC for tunnel segments based on large beam test (대형보 실험을 통한 TBM 터널 세그먼트용 강섬유보강콘크리트 성능평가)

  • Moon, Do-Young;Roh, Hwasung;Chang, Soo-Ho;Lee, Gyu-Phil;Bae, Gyu-Jin
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.16 no.3
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    • pp.287-298
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    • 2014
  • In order to develop SFRC TBM tunnel segment, evaluating the SFRC mixture was conducted through flexural tests of SFRC beams without ordinary steel reinforcement in this study. Considered variables were compressive strengths of SFRC, aspect and mix ratio of steel fibers and total 16 specimens were fabricated and tested until failure. The load-vertical displacement results demonstrates that the effect of aspect ratio is minor when compared to results form small beam test(Moon et al, 2013). A SFRC beam resists the vertical load until the width of crack reaches to 7 mm due to steel fibers across cracked surfaces. Moreover, it is found that flexural moment estimated by equation of TR No. 63(Concrete Society, 2011) is useful for prediction of nominal strength for SFRC structure. From the investigation of fiber distribution in cracked section, it is found that dispersion improved in actual size beam compared to in standard small beam for evaluation of flexural strength.

Seed Dispersion and Seedling Spatial Distribution of the Tree of Heaven in Urban Environments (도시환경에서 가중나무 종자의 확산 및 발아 분포)

  • 조치웅;이경재
    • Korean Journal of Environment and Ecology
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    • v.16 no.1
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    • pp.87-93
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    • 2002
  • The tree of heaven naturalized plant grows in the various habitats of the city. The principal reason is that it is reproduced not only through sexual reproduction but through asexual reproduction. By the spreading of sucker and a bud appearance of the seed it forms a group easily inside the city habitat. The distribution of seed and spreading of the seedlings of the tree of heaven were investigated like the followings. As the result of the sexual reproduction by the seed and hangs in cluster farm, 350 individuals are germinated at the Namsan the best environment, and 50 individuals at Toegyewon Rotary These seeds are dispersed by the effect of wind and geographical factor. Because the northwest wind is blowing mainly from late autumn to early spring, it is dispersed in the south. In Toegyewon Rotary, a slant site, is dispersed mainly by down the site. Compared with width of crown, the seedling of a seed germination are distributed outside more than inside the crown and the seed is spreaded until the maximum 7.5 times of crown width at the investigated area. 1 year seedlings appeared as a group at the place of 2-4 times of the crown (in 20m from the crown, 75% distribution). Considering the distribution by the seed scattering of the tree of heaven, there is a possibility of sudden individual increase even in the deteriorated city environment. So this possibility shows that we need to consider the protection of the city soil, and the species variety decrease resulted from the successful competition to the other species.

CO2 Mineral Carbonation Reactor Analysis using Computational Fluid Dynamics: Internal Reactor Design Study for the Efficient Mixing of Solid Reactants in the Solution (전산유체역학을 이용한 이산화탄소 광물 탄산화 반응기 분석: 용액 내 고체 반응물 교반 향상을 위한 내부 구조 설계)

  • Park, Seongeon;Na, Jonggeol;Kim, Minjun;An, Jinjoo;Lee, Chaehee;Han, Chonghun
    • Korean Chemical Engineering Research
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    • v.54 no.5
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    • pp.612-620
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    • 2016
  • Aqueous mineral carbonation process, in which $CO_2$ is captured through the reaction with aqueous calcium oxide (CaO) solution, is one of CCU technology enabling the stable sequestration of $CO_2$ as well as economic value creation from its products. In order to enhance the carbon capture efficiency, it is required to maximize the dissolution rate of solid reactants, CaO. For this purpose, the proper design of a reactor, which can achieve the uniform distribution of solid reactants throughout the whole reactor, is essential. In this paper, the effect of internal reactor designs on the solid dispersion quality is studied by using CFD (computational fluid dynamics) techniques for the pilot-scale reactor which can handle 40 ton of $CO_2$ per day. Various combination cases consisting of different internal design variables, such as types, numbers, diameters, clearances and speed of impellers and length and width of baffles are analyzed for the stirred tank reactor with a fixed tank geometry. By conducting sensitivity analysis, we could distinguish critical variables and their impacts on solid distribution. At the same time, the reactor design which can produce solid distribution profile with a standard deviation value of 0.001 is proposed.

Numerical Study on Atmospheric Dispersion and Fire Possibility in Toluene Leakage (톨루엔 누출 시 대기확산 및 화재가능성에 관한 수치해석 연구)

  • Ko, Jae Sun;Kim, Joo-Seok
    • Fire Science and Engineering
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    • v.31 no.3
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    • pp.1-10
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    • 2017
  • This study examined the risk of accidents when handling hazardous materials in hazardous materials storage facilities without safety facilities. In the case of illegal dangerous cargo containers, the burning rate is very fast in the case of fire, which leads to explosions, that are damaging and difficult to control. In addition, accidents that occur in flammable liquid hazardous materials are caused mostly by accidents that occur in the space due to leakage. Therefore, the variables that affect these accidents were derived and the influence of these variables was investigated. Numerical and computational fluid dynamics programs were used to obtain the following final results. First, when a flammable liquid leaks into a specific space, it is influenced by temperature and relative humidity until a certain concentration (lower limit of combustion) is reached. In the case of temperature, it was found that the reaching time was shorter than the flash point In addition, the effect of variables on pool fire accidents of leakage tanks is somewhat different, but the variables that have the largest influence are the wind speed. Therefore, it is expected that the results of this study will be used as basic data for similar numerical analysis and it will provide useful numerical information about the accidental leakage of hazardous materials under various research conditions.

Biomechanical Evaluation of Trekking Shoes using 3D Bootie Method as Mimics Barefoot Form (맨발 구조를 모사한 3D Bootie 공법을 적용시킨 트레킹화의 생체역학적 특성 평가)

  • Yoo, Chan-Il;Jeon, Keun-Hwan;Won, Yonggwan;Kim, Jung-Ja
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.7
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    • pp.4689-4696
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    • 2015
  • The purpose of this study was to evaluate biomechanical characteristics of trekking shoes using 3D Bootie method as mimics barefoot form of F Co. that provides the best comfort and plantar pressure dispersion. The control group is normal trekking shoes of M Co. and K Co.. 13 healthy males measured the foot pressure, EMG and GRF. Collected data was analyzed using One-way ANOVA in order to investigate the effects of each trekking shoes. The results are as follows: Trekking shoe of F Co. was significantly wider in contact area than others at MF and significantly lower in maximum force, peak pressure than others at RF. In the case of muscle activity, acted in the same way as the effect of barefoot walking. In the case of GRF, effectively absorbed the impact force, so it is possible to efficient walking. As a result of the analysis, trekking shoe using of 3D Bootie method of F Co. can be efficient walking by reducing the load of foot during walking.

A Comparative Analysis of Negative Air Ions according to the Planting Structure at School Forests (학교 숲 식재구조에 따른 음이온 발생량 비교 분석)

  • Kim, Jeong-Ho;Oh, Deuk-Kyun;Park, Yong-Gwan;Yoon, Yong-Han
    • Journal of the Korean Institute of Landscape Architecture
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    • v.43 no.5
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    • pp.55-64
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    • 2015
  • In this study, negative air ions, which can increase comfort and positively influence human health, was set as an evaluative factor for school forests. The characteristics, location and microclimate of school forests were examined to determine an effective school forest model for maximum negative air ion generation. It also aimed to provide basic data for the development of urban green fields. The negative air ion concentrations were different according to the green types. The order from the highest to the lowest was: single-layer structure($934ea/cm^3$) > multi-layer structure($794ea/cm^3$) > grass($553ea/cm^3$) > bare ground($529ea/cm^3$). As for the correlation with microclimate, negative air ion concentration was negatively correlated with temperature. The negative air ion concentration was significantly different according to planting type. The negative air ion concentration was higher at single-layer structure sites than at multi-layer structure sites, which appears to indicate that the temperature is higher when the vegetation structure was single-layer compared to multi-layer. Wind speed was higher at the single-layer planted site than at the multi-layer planted site. The vegetation wind shielding effect was lower at single-layer planted sites than at multi-layer planted sites. The single-layer planted site provided more favorable conditions for the generation and dispersion of negative air ions.

Sintered properties of silicon carbide prepared by using the alumina and yttria-coated SiC powder (알루미나 및 이트리아로 코팅된 분말을 사용하여 제조한 탄화규소의 소결물성)

  • Um, Ki-Young;Kim, Hwan;Kang, Hyun-Hee;Lee, Jong-Kook
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.4
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    • pp.645-650
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    • 1998
  • Alumina- and yttria-coated SiC powder was prepared by the surface-induced precipitation method, and sintered properties of silicon carbide prepared from this powder were investigated. After a well dispersion of SiC powders in the aqueous solution of $Al_2(SO_4)_3$ and $Y_2(SO_4)_3$, the mixed precursors of aluminum hydroxide, aluminum carbonate, yttrium hydroxide, and yttrium carbonate were precipitated on the surfaces of SiC particles through the hydrolysis reaction of urea. SiC specimens with alumina and yttria exhibit, 97.8% of theoretical density after the sintering at $1900^{\circ}C$ for 2 hrs. During annealing at $2000^{\circ}C$, $\beta$longrightarrow$\alpha$ phase transformation of SiC had taken place and resulted with a rodlike microstructure. Toughness of sintered SiC was enhanced by crack deflection around the rodlike grains. In case of annealing less than that of 3 hr, the fracture toughness of SiC was slightly improved with increasing the amount of sintering aid. However, annealed specimens for a long time showed constant fracture toughness even though the amount of sintering aid increased. It is resulted that the main factor for toughening in annealed SiC for a long time is the pullout effect of rodlike grains during the propagation of cracks, and the amount of sintering aids is less effective on the fracture toughness of SiC.

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Fabrication of Photocatalytic TiO2 thin Film Using Aerosol Deposition Method and its Filtration Characteristics (에어로졸 증착법을 이용한 광촉매 TiO2 박막 제조 및 박막의 여과 특성)

  • Choi, Wonyoul;Lee, Jinwoo;Kim, Shijun;Kim, Jongoh
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.1
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    • pp.5-11
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    • 2010
  • The objective of this study is to evaluate the effect of operational parameters such as rotation speed and vibrating milling time for the fabrication of photocatalytic $TiO_2$ thin film using aerosol deposition methods. $TiO_2$ powders produced in the range of 1,000-3,000 rpm of rotation speed of centrifugal separator are ineffective on the fabrication of $TiO_2$ thin film by aerosol deposition due to the problem of nozzle powder jam. $TiO_2$ powders controlled by vibrating milling had about 420 nm of average diameter after 2 hr of vibrating milling time. The result of XRD analysis indicated that $TiO_2$ powders had a anatase phase. Vibrating milling methods was considered to be an effective pre-treatment process for $TiO_2$ powder control. Consequently $TiO_2$ photocatalytic thin film with dispersion of anatase crystallites controled by vibrating milling was successfully fabricated by aerosol deposition. The permeation flux of $TiO_2$ photocatalytic thin film with the immobilized $TiO_2$ powder was higher than that of suspended $TiO_2$ powder. Therefore, $TiO_2$ photocatalytic thin film promises to be one of the effective methods for enhancing filtration performance for the treatment of organic pollutants.