• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.9
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• pp.5585-5593
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• 2014

This study tested the hypothesis that the significance of the heterogeneous dispersion parameter in safety performance function (SPF) used to estimate the expected crashes is affected by the endogenous heterogeneous prior distributions, and analyzed the impacts of the mis-specified dispersion parameter on the evaluation results for traffic safety countermeasures. In particular, this study simulated the Poisson means based on the heterogeneous dispersion parameters and estimated the SPFs using both the negative binomial (NB) model and the heterogeneous negative binomial (HNB) model for analyzing the impacts of the model mis-specification on the mean and dispersion functions in SPF. In addition, this study analyzed the characteristics of errors in the crash reduction factors (CRFs) obtained when the two models are used to estimate the posterior means and variances, which are essentially estimated through the estimated hyper-parameters in the heterogeneous prior distributions. The simulation study results showed that a mis-estimation on the heterogeneous dispersion parameters through the NB model does not affect the coefficient of the mean functions, but the variances of the prior distribution are seriously mis-estimated when the NB model is used to develop SPFs without considering the heterogeneity in dispersion. Consequently, when the NB model is used erroneously to estimate the prior distributions with heterogeneous dispersion parameters, the mis-estimated posterior mean can produce large errors in CRFs up to 120%.

• Journal of Power System Engineering
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• v.15 no.3
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• pp.18-24
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• 2011

In this study, the reflection of the L(0,2), axially symmetric guided elastic wave from defects in pipes above ground is examined using finite element method. Phase and group velocity dispersion curves for the pipe were presented for the selection of the excitation mode. Some simple signal processing was applied to determine the amplitude of each of the reflected waves and to calculate the reflection coefficient. The results show the reflection coefficient of this mode is very close to a linear function of the circumferential extent of the defect. The motivation for the work was the development of a technique for inspecting chemical plant pipelines, but the study addresses the nature of the reflection function and its general applicability.

• Macromolecular Research
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• v.17 no.10
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• pp.750-756
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• 2009

Stable, spherical, polystyrene particles were synthesized in ab initio dispersion polymerization by using the poly(methacrylic acid)[PMAA] macro-RAFT agent. The presence of the PMAA macro-RAFT agent on the polystyrene (PS) particles was confirmed by NMR and FTIR spectroscopy. The PS particle size was influenced by the concentration of the RAFT agent and monomer due to the initial nucleation. When the concentration of the PMAA macro-RAFT agent was increased from 2 to 10 wt% relative to the monomer, the average particle size decreased from 2.31 to 1.36 ${\mu}m$, the conversion decreased from 93.3 to 88.9%, the weight-average molecular weight increased from 46,300 to 150,200 g $mol^{-1}$ and the PDI decreased from 2.79 to 1.94, respectively. In particular, the incorporation of 10 wt% of PMAA macro-RAFT agent produced monodisperse PS spheres of 1.36 ${\mu}m$ with a coefficient of variation (CV) of 6.44%. Thus, the PMAA macro-RAFT agent worked as a reactive steric stabilizer providing monodisperse, micron-sized, PS particles.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.14 no.1
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• pp.131-141
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• 1994

Three characteristics-based split-operator methods were applied to a longitudinal pollutant dispersion problem, and the results were compared with those of several Eulerian schemes. The split-operator methods consisted of generalized upwind, two-point fourth-order and sixth-order Holly-Preissmann schemes, respectively, for the advection calculation, and the Crank-Nicholson scheme for the diffusion calculation. Compared with the Eulerian schemes tested, split-operator methods using the Holly-Preissmann schemes gave much more accurate computational results. Eulerian schemes using centered difference approximations for the advection term resulted in numerical oscillations, and those using backward difference resulted in numerical diffusion, both of which were more severe for smaller value of the longitudinal dispersion coefficient.

• Bulletin of the Korean Chemical Society
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• v.35 no.9
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• pp.2679-2683
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• 2014

Mechanisms underlying the impacts of interactions between carbon nanoparticles (CNPs) and ionic liquids (ILs) on the physicochemical behavior of CNPs need to be more full worked out. This manuscript describes a theoretical investigation at multiple levels on the interactions of fullerene $C_{60}$ with 21 imidazolium-based ILs of varying alkyl side chain lengths and anionic types and their impacts on $C_{60}$ dispersion behavior. Results show that ${\pi}$-cation interaction contributed to mechanism of the $C_{60}$-IL interaction more than ${\pi}$-anion interaction. The calculated interaction energy ($E_{INT}$) indicates that $C_{60}$ can form stable complex with each IL molecule. Moreover, the direction of charge transfer occurred from IL to $C_{60}$ during the $C_{60}$-IL interaction. Quantitative models were developed to evaluate the self-diffusion coefficient of $C_{60}$ ($D_{fullerene}$) in bulk ILs. Three interpretative molecular descriptors (heat of formation, $E_{INT}$, and charge) that describe the $C_{60}$-IL interactions and the alkyl side chain length were found to be determinants affecting $D_{fullerene}$.

• Journal of Korean Ophthalmic Optics Society
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• v.12 no.1
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• pp.85-90
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• 2007

We deposited thin films of ZnS(Zinc Sulphide), in which was used antireflection coating material of glasses-lens on silicon and slide-glass substrates using spin coating method, and measured spectra of ellipsometry angles ${\Delta}$ and ${\Psi}$ in the photon-energy range of 1.5~5.0 eV using a variable angle spectroscopic ellipsometer. The optical constants, refractive index and extinction coefficient, of ZnS were determined via the dispersion parameters extracted from the curve-fitting process based on Jellison-Modine dispersion function.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2001.04a
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• pp.3-6
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• 2001

Various Parameters such as stream velocities, discharges, and dispersion coefficients of dissolved solutes were estimated by fitting 1-D nonreactive solute transport model to the time-series chemistry data. This study was done for the reaches of Mankyung River lower than the Jeonju Wastewater Treatment Plant (Jeonju WTP). Korea. Concentrations of inorganic chemicals in the stream waters are strongly influenced by mixing with the chemically distinct effluent from Jeonju WTP. Sulfate, EC. and the total major cation were proved to be nearly conservative in the study area front their relationships with chloride, the conservative chemical species. The solute transport model was constrained to the time-series concentrations for these 4 conservative species. The variations of concentration and discharge of Jeonju WTP were used as input parameters, and the stream velocities, dispersion coefficients, and concentrations and discharges of some inflows were optimized. The differences between the observed arid simulated values for alkalinities and nitrates are inversely correlated and show diurnal fluctuations, indicating the photosynthesis. The parameters obtained front this mode] range from 550 to 774 kcmd (stream discharge at the outlet of the study area), from 0.06 to 0.10 m/sec (flow velocity), and from 0.7 to 6.4 m$^2$/sec (dispersion coefficient). The history of Jeonju WTP discharge was well predicted when optimized, indicating the validity of the model results.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2004.10a
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• pp.15-18
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• 2004

Nondestructive damage sensing and mechanical properties for thermal treated carbon nanotube(CNT) and nanofiber(CNF)/epoxy composites were investigated using electro-micromechanical technique. Carbon black (CB) was used only for the comparison. Electro-micromechanical techniques were applied to obtain the fiber damage and stress transferring effect of carbon nanocomposites with their contents. Thermal treatment and temperature affected on apparent modulus and electrical properties on nanocomposites due to enhanced inherent properties of each CNMs. Coefficient of variation (COV) of volumetric electrical resistance can be used to obtain the dispersion degree indirectly for various CNMs. Dispersion and surface modification are very important parameters to obtain improved mechanical and electrical properties of CNMs for multifunctional applications. Further optimized functionalization and dispersion conditions will be investigated for the following work continuously.

• Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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• 2000.10a
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• pp.196-203
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• 2000

In this study, the evaluation method of diffusion characteristics of Suspended Soli&SS) and the generation limit(source and thick) are investigated, which is significantly affecting on marine examined by construction works such as dredging and reclamation. Dispersion characteristics of SS is examined by hydraulic tests and numerical works in consideration with the Pusan Port. Hydraulic model test was performed in 2-D wave flume to find the limit wave conditon of re-suspension of solid as well as the time dependent characteristics of settlement The results obtainded in the study are as follows; 1) The quantituative evaluation af SS is the basic parameter of marine environmental impact assessment in related with the port development The SS increases as the water content of sea bed solid increases and the density decreases. 2) The sea bed solid in Sinsundai area, Pusan Port has the water content range of 83~157% 3) The ratio of suspension velocity against settlement velocity is about 0.25 and SS concentration converges as the wave heigh. 4) The SS increases 2 time when time step increases 3 time(10 sec to 30 sec) in numerical simulation It means that the effect of the time step should be checked in detail to stable. The diffusion The diffusion coefficient are Affiected senstively in the dispersion process while sea ved friction coefficinet have not strong relation in the simulated area

• Journal of the Semiconductor & Display Technology
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• v.18 no.3
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• pp.52-59
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• 2019

Styrene-butadiene rubber (SBR) composites, incorporated with graphene, molybdenum disulfide and their hybrid in different filling ratio, were fabricated by a two roll-mill. The dispersion states of all the samples' matrix were employed by carbon black dispersion tester. The curing properties of the pre-vulcanized rubber composites were investigated, after molding by heating press machine, the tensile strength, storage modulus, friction coefficient, the swelling property had also been tested according to ASTM. The composite G1M10 (filling with 1 phr graphene and 10 phr molybdenum) showed the best mechanical properties and viscoelastic properties in this research with a better filler dispersion state and more compact matrix structure.