• Title/Summary/Keyword: Dispersion Coefficient

검색결과 373건 처리시간 0.031초

이질적 과분산계수가 기대 교통사고건수 추정에 미치는 영향 (Impact of Heterogeneous Dispersion Parameter on the Expected Crash Frequency)

  • 신강원
    • 한국산학기술학회논문지
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    • 제15권9호
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    • pp.5585-5593
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    • 2014
  • 본 연구는 기대 교통사고건수 추정을 위해 사용되는 SPF의 이질적 분산계수의 유의성이 이질적 사전분포에 직접적인 영향을 받는다는 가설을 검증하고, 이질적 사전분포에 대한 모형 오설정이 교통 안전개선 사업의 평가결과에 주는 영향의 특성을 분석하기 위해 수행되었다. 구체적으로 본 연구에서는 이질적 분산계수의 유의성과 이질적 사전분포의 연관성을 검증하기 위해 모의실험을 통해 이질적 사전분포를 발생시킨 후 이를 NB모형과 HNB모형을 이용하여 SPF를 추정하여 이질적 과분산계수가 SPF의 평균함수 및 분산함수에 주는 영향을 분석하였다. 또한 추정된 계수추정치를 이용한 사전분포의 초모수 추정치의 오차특성과 이질적 과분산계수를 고려하지 않았을 경우 발생하는 교통사고감소계수(CRF)의 오차 부호와 크기를 상세 분석하여 제시하였다. 모의실험 자료 분석결과 이질적 분산계수의 오추정은 포아송 사전분포의 평균에는 큰 영향을 주지 않으나 분산의 크기를 변화시켜 궁극적으로는 기대교통사고건수의 추정량인 사후평균의 값에 오차를 발생시킬 수 있으며, 구체적으로 이질적 분산함수를 NB모형으로 오설정할 경우 CRF의 값은 참값에 비해 최대 120%의 오차를 발생시키는 것으로 나타났다.

유한요소법을 이용한 지상 파이프 반사계수 규명 (Identification of Reflection Coefficients for Overground Pipes Using Finite Element Method)

  • 김영환;박경조;강우석
    • 동력기계공학회지
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    • 제15권3호
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    • pp.18-24
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    • 2011
  • In this study, the reflection of the L(0,2), axially symmetric guided elastic wave from defects in pipes above ground is examined using finite element method. Phase and group velocity dispersion curves for the pipe were presented for the selection of the excitation mode. Some simple signal processing was applied to determine the amplitude of each of the reflected waves and to calculate the reflection coefficient. The results show the reflection coefficient of this mode is very close to a linear function of the circumferential extent of the defect. The motivation for the work was the development of a technique for inspecting chemical plant pipelines, but the study addresses the nature of the reflection function and its general applicability.

Ab Initio Dispersion Polymerization of Styrene in the Presence of the Poly(methacrylic acid) Macro-RAFT Agent

  • Wi, Yeon-Hwa;Lee, Kang-Seok;Lee, Byung-Hyung;Choe, Soon-Ja
    • Macromolecular Research
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    • 제17권10호
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    • pp.750-756
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    • 2009
  • Stable, spherical, polystyrene particles were synthesized in ab initio dispersion polymerization by using the poly(methacrylic acid)[PMAA] macro-RAFT agent. The presence of the PMAA macro-RAFT agent on the polystyrene (PS) particles was confirmed by NMR and FTIR spectroscopy. The PS particle size was influenced by the concentration of the RAFT agent and monomer due to the initial nucleation. When the concentration of the PMAA macro-RAFT agent was increased from 2 to 10 wt% relative to the monomer, the average particle size decreased from 2.31 to 1.36 ${\mu}m$, the conversion decreased from 93.3 to 88.9%, the weight-average molecular weight increased from 46,300 to 150,200 g $mol^{-1}$ and the PDI decreased from 2.79 to 1.94, respectively. In particular, the incorporation of 10 wt% of PMAA macro-RAFT agent produced monodisperse PS spheres of 1.36 ${\mu}m$ with a coefficient of variation (CV) of 6.44%. Thus, the PMAA macro-RAFT agent worked as a reactive steric stabilizer providing monodisperse, micron-sized, PS particles.

종확산 방정식에 대한 Eulerian-Lagrangian 연산자 분리방법 (Eulerian-Lagrangian Split-Operator Method for the Longitudinal Dispersion Equation)

  • 전경수;이길성
    • 대한토목학회논문집
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    • 제14권1호
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    • pp.131-141
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    • 1994
  • 특성곡선을 고려한 세가지 연산자 분리방법을 오염원의 종확산 문제에 적용하여, 그 결과를 Eulerian 기법들의 계산결과와 비교하였다. 연산자 분리방법의 이송방정식에 대한 수치 기법들로는 generalized upwind, two-point fourth-order 및 sixth-order Holly-Preissmann 기법들을 각각 적용하였으며, 확산 방정식에 대한 수치기법으로는 Crank-Nicholson 기법을 적용하였다. Holly-Preissmann 기법을 사용하는 연산자 분리방법들이 Eulerian 기법들에 비하여 매우 정확한 계산결과를 나타내었다. Eulerian 기법들의 경우에는 이송항의 근사방법으로서 중앙차분을 취하는 기법들은 수치진동을, 후방차분을 취하는 기법들은 수치분산을 각각 보였으며, 이러한 현상들은 종확산계수의 값이 작을수록 더욱 뚜렷하게 나타났다.

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Impacts of C60-Ionic Liquids (ILs) Interactions and IL Alkyl Chain Length on C60 Dispersion Behavior: Insights at the Molecular Level

  • Wang, Zhuang;Tang, Lili;Wang, Degao
    • Bulletin of the Korean Chemical Society
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    • 제35권9호
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    • pp.2679-2683
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    • 2014
  • Mechanisms underlying the impacts of interactions between carbon nanoparticles (CNPs) and ionic liquids (ILs) on the physicochemical behavior of CNPs need to be more full worked out. This manuscript describes a theoretical investigation at multiple levels on the interactions of fullerene $C_{60}$ with 21 imidazolium-based ILs of varying alkyl side chain lengths and anionic types and their impacts on $C_{60}$ dispersion behavior. Results show that ${\pi}$-cation interaction contributed to mechanism of the $C_{60}$-IL interaction more than ${\pi}$-anion interaction. The calculated interaction energy ($E_{INT}$) indicates that $C_{60}$ can form stable complex with each IL molecule. Moreover, the direction of charge transfer occurred from IL to $C_{60}$ during the $C_{60}$-IL interaction. Quantitative models were developed to evaluate the self-diffusion coefficient of $C_{60}$ ($D_{fullerene}$) in bulk ILs. Three interpretative molecular descriptors (heat of formation, $E_{INT}$, and charge) that describe the $C_{60}$-IL interactions and the alkyl side chain length were found to be determinants affecting $D_{fullerene}$.

Jellison Modine 분산식을 이용한 ZnS의 광학상수 결정 (Determination of Optical Constants of ZnS Using Jellison-Modine Dispersion Relation)

  • 박명희
    • 한국안광학회지
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    • 제12권1호
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    • pp.85-90
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    • 2007
  • 안경렌즈의 무반사 코팅물질로 사용되는 황화아연(Zinc Sulphide : ZnS)의 단일박막을 실리콘과 슬라이드 유리 기판위에 스핀코팅방법으로 증착하였다. 박막 증착 후 변입사각분광타원계(VASE : Variable Angle Spectroscopic Ellipsometer)를 사용하여 1.5~5.0 eV 광 에너지 영역에서 타원 각(ellipsometry angle) ${\Delta}$, ${\Psi}$를 측정하였다. 이 측정결과들을 Jellison Modine 분산관계식을 사용하여 최적맞춤하고, 매개변수들을 구하여 박막의 광학상수인 굴절계수 $n({\lambda})$와 소광계수 $k({\lambda})$를 결정하였다.

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하수처리장 방류수에 용존된 무기화학종의 연속계측자료를 이용한 하천유량, 유속 및 방류량 추적

  • 김강주;한찬
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2001년도 총회 및 춘계학술발표회
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    • pp.3-6
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    • 2001
  • Various Parameters such as stream velocities, discharges, and dispersion coefficients of dissolved solutes were estimated by fitting 1-D nonreactive solute transport model to the time-series chemistry data. This study was done for the reaches of Mankyung River lower than the Jeonju Wastewater Treatment Plant (Jeonju WTP). Korea. Concentrations of inorganic chemicals in the stream waters are strongly influenced by mixing with the chemically distinct effluent from Jeonju WTP. Sulfate, EC. and the total major cation were proved to be nearly conservative in the study area front their relationships with chloride, the conservative chemical species. The solute transport model was constrained to the time-series concentrations for these 4 conservative species. The variations of concentration and discharge of Jeonju WTP were used as input parameters, and the stream velocities, dispersion coefficients, and concentrations and discharges of some inflows were optimized. The differences between the observed arid simulated values for alkalinities and nitrates are inversely correlated and show diurnal fluctuations, indicating the photosynthesis. The parameters obtained front this mode] range from 550 to 774 kcmd (stream discharge at the outlet of the study area), from 0.06 to 0.10 m/sec (flow velocity), and from 0.7 to 6.4 m$^2$/sec (dispersion coefficient). The history of Jeonju WTP discharge was well predicted when optimized, indicating the validity of the model results.

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전기저항 측정 방법을 이용한 표면 처리된 탄소 나노튜브와 나노 섬유 강화된 에폭시 복합재료의 비파괴적 감지능 평가 (Nondestructive Sensing Evaluation of Thermal Treated Carbon Nanotube and Nanofiber/Epoxy Composites Using Electrical Resistance Measurement)

  • 정진규;박종만;김대식;김태욱
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2004년도 추계학술발표대회 논문집
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    • pp.15-18
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    • 2004
  • Nondestructive damage sensing and mechanical properties for thermal treated carbon nanotube(CNT) and nanofiber(CNF)/epoxy composites were investigated using electro-micromechanical technique. Carbon black (CB) was used only for the comparison. Electro-micromechanical techniques were applied to obtain the fiber damage and stress transferring effect of carbon nanocomposites with their contents. Thermal treatment and temperature affected on apparent modulus and electrical properties on nanocomposites due to enhanced inherent properties of each CNMs. Coefficient of variation (COV) of volumetric electrical resistance can be used to obtain the dispersion degree indirectly for various CNMs. Dispersion and surface modification are very important parameters to obtain improved mechanical and electrical properties of CNMs for multifunctional applications. Further optimized functionalization and dispersion conditions will be investigated for the following work continuously.

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해양 매립 및 준설토 투기에 따른 부유사 확산의 시.공간적 특성에 관한 연구 (Temporal and Spatial Spreading Characteristic of Drift Soil due to the Reclamation in the Pusan Port)

  • 김용원;김종인;윤한삼;홍도웅
    • 한국해양공학회:학술대회논문집
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    • 한국해양공학회 2000년도 추계학술대회 논문집
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    • pp.196-203
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    • 2000
  • In this study, the evaluation method of diffusion characteristics of Suspended Soli&SS) and the generation limit(source and thick) are investigated, which is significantly affecting on marine examined by construction works such as dredging and reclamation. Dispersion characteristics of SS is examined by hydraulic tests and numerical works in consideration with the Pusan Port. Hydraulic model test was performed in 2-D wave flume to find the limit wave conditon of re-suspension of solid as well as the time dependent characteristics of settlement The results obtainded in the study are as follows; 1) The quantituative evaluation af SS is the basic parameter of marine environmental impact assessment in related with the port development The SS increases as the water content of sea bed solid increases and the density decreases. 2) The sea bed solid in Sinsundai area, Pusan Port has the water content range of 83~157% 3) The ratio of suspension velocity against settlement velocity is about 0.25 and SS concentration converges as the wave heigh. 4) The SS increases 2 time when time step increases 3 time(10 sec to 30 sec) in numerical simulation It means that the effect of the time step should be checked in detail to stable. The diffusion The diffusion coefficient are Affiected senstively in the dispersion process while sea ved friction coefficinet have not strong relation in the simulated area

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Study on Mechanical Properties Modification of Styrene Butadiene Rubber Composites Filling with Graphene and Molybdenum Disulfide

  • Xu, Li Xiang;Sohn, Mi Hyun;Kim, Yu Soo;Jeong, Ye Rin;Cho, Ur Ryong
    • 반도체디스플레이기술학회지
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    • 제18권3호
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    • pp.52-59
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    • 2019
  • Styrene-butadiene rubber (SBR) composites, incorporated with graphene, molybdenum disulfide and their hybrid in different filling ratio, were fabricated by a two roll-mill. The dispersion states of all the samples' matrix were employed by carbon black dispersion tester. The curing properties of the pre-vulcanized rubber composites were investigated, after molding by heating press machine, the tensile strength, storage modulus, friction coefficient, the swelling property had also been tested according to ASTM. The composite G1M10 (filling with 1 phr graphene and 10 phr molybdenum) showed the best mechanical properties and viscoelastic properties in this research with a better filler dispersion state and more compact matrix structure.