• 한국산학기술학회논문지
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• 제7권1호
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• pp.12-20
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• 2006

국가차원의 신 재생에너지 활성화 방안에 따라 풍력발전 등의 대규모 분산전원 단지의 도입이 이루어지고 있으나, 이에 대한 기술적인 평가방안이나 해석 방법이 구체적으로 제시되어 있지 않아, 설치자(시도 및 지자체)와 운용자(한전의 배전지사/지점)들은 많은 혼돈과 어려움을 겪고 있는 실정이다. 따라서 본 논문에서는 태양광, 풍력 등의 분산전원이 배전계통에 도입되는 경우, 계통 연계에 대한 기술적인 적합여부를 종합적으로 평가하는 시스템을 개발하였다. 즉, 분산전원을 제작하거나 시공하는 업체와 일반 운용자나 사용자(분산전원을 잘 모르는 비전문가 포함)들이 손쉽게 접근하여, 분산전원의 연계시의 기술적인 문제점과 적합 여부를 판단하는 기술지원 평가 S/W를 제작하였다. 주요 평가 기능으로서는 분산전원의 계통연계 시에 발생할 수 있는 정상, 비정상(사고), 전력품질에 대한 항목으로서, 누구나 동일한 결과를 얻을 수 있는 표준계통에 근거한 평가 알고리즘에 의하여 연계 적합 여부를 판단하는 것이다.

• 한국해양학회지
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• 제26권4호
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• pp.350-357
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• 1991

조간대에 서식하는 고둥류인 좁쌀무늬총알고동, 총알고동, 대수리 등 3종에 대한 유류오염과 유처리제를 이용한 정화작업의 영향을 조사하기 위한 실험을 실시하였다. 라뷰안 원유, 듀바이 원유, 벙커 C유를 실험 생물에 각각 직접 접촉시켰으며, 또한 1 시간 노출시킨 후에 농축형 유처리제로 세척하였다. 원유에 접촉시킨 고동류는 96시간 내에 모두 처사하였으며, 라뷰안 원유가 듀바이 원유보다 높은 독성을 보였다. 벙커 C 유에는 총알고동류가 대수리보다 민감한 반응을 보였으며, 원유 접촉시보다는 서서히 독성효과가 나타났다. 높은 농도의 유처리제를 이용한 전화작업은 고동류에게 치명적 인 영향을 주었으며, 낮은 농도에서도 총알고동류에게 유해한 영향을 주었다. 대수리 는 분산된 유류에 노출될 경우 250 ppm 이하의 농도에서는 도피행동을 보였다. 유류오 염과 유처리제를 이용한 정화작업은 고동류의 흡착기능을 저해하여 물리적인 힘에 의 해 서식지 이탈을 유발시킬 수 있을 것으로 보인다.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2006년도 추계학술대회
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• pp.459-462
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• 2006

Formic acid recently attracted attention as an alternative fuel for direct liquid fuel cells(DLFCs) due to its high theoretical open circuit voltage(1.45V). In this paper, a novel chemical strategy is described for the preparation and characterization of carbon-supported and surface-alloys, which were prepared by using a successive reduction process. After preparing Au colloid nanoparticles, the deposition of Au colloid nanoparticles occurred spontaneously in the carbon black-dispersed aqueous solution. Then nano-scaled Pt layer were formed on the surface of carbon-supported Au nanoparticles. The Au-Pt[x] showed the higher electrocatalytic activity than those of the particle-alloys and commercial one (Johnson-Matthey) for the reaction of formic acid oxidation when the mass-specific currents were compared. The increased electrocatalytic activity might be attributed to the effective surface structure of surface-alloys, which have a high utilization of active materials for the surface reaction of electrode.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2006년도 추계학술대회
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• pp.316-319
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• 2006

There is a worldwide interest in the development and commercialization of Polymer Electrolyte Membrane Fuel Cells (PEMFCs) for vehicular and stationary applications. One of the major objectives is the reduction of loaded electrode materials, which is comprise of the Pt-based noble metals. In this paper, a novel chemical strategy is described for the preparation and characterization of carbon-supported and surface-alloys, which were prepared by using a successive reduction process. After preparing Au colloid nanoparticles, the deposition of Au colloid nanoparticles occurred spontaneously in the carbon black-dispersed aqueous solution. Then nano-scaled active materials were formed on the surface of carbon-supported Au nanoparticles. The structural and electrochemical analyses indicate that the active materials were deposited on the surface of Au nanoparticles selectively and that an at toying process occurred during the successive reducing process The carbon-supported & surface-alloys showed the higher electrocatalytic activity than those of the particle-alloys and commercial one (Johnson-Matthey) for the reaction of methanol and formic acid oxidation. The increased electrocatalytic activity might be attributed to the effective surface structure of surface-alloys, which have a high utilization of active materials for the surface reaction of electrode.

• 한국마린엔지니어링학회:학술대회논문집
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• 한국마린엔지니어링학회 2011년도 전기공동학술대회 논문집
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• pp.7-10
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• 2011

According to the requirement of Res.MSC.285(86) for natural gas-fueled engine installations in ships, pump and compressor rooms should be fitted with effective mechanical ventilation system of the under pressure type, providing a ventilation capacity of at least 30 air changes per hour. It generally considered that gas leakage is more likely from a Fueled Gas Supply System(FGS) room as compared to other places, where installed in many kind of machinery or equipments like gas supply high-pressure pipes, valves, flanges and etc. Furthermore, leaked gas may be dispersed in a short time in an enclosed space, especially a FGS room, due to high pressure. However, the present requirement in Res.MSC.285(86) just considers the ventilating capacity of air changes per hour but the capacity of leaked gas. Hence, the current requirements may not meet effectively when enforcing the new propulsion systems as marine fuel. This study is conducted for the purpose of safety evaluation about the dispersion and ventilation efficiency with estimated leakage scenario. Numerical analysis predictions as the result of this paper are explained to know the features of flow pattern and the diffusion of natural gas concentration.

• Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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• 제4권4호
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• pp.201-208
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• 2000

The reduction of NO by hydrocarbons was investigated over Cu/Al$_2$O$_3$catalysts using a stainless steel flow reactor under highly oxidising diesel exhaust conditions(up to 15%). Three different Cu loadings(1,5 and 10wt.%) on an $Al_2$O$_3$support were prepared and characterized using spectroscopic techniques. The catalytic activity tests show that different Cu loadings as well as temperature, oxygen, and hydrocarbon concentration levels significantly influence the NO reduction. Increasing Cu loadings up to 5 and 10wt.% decreases the catalytic activities for NO reduction due to the formation of a bulk crystalline CuO phase, as observed from XRD and SEM images. In particular, the visualization of the copper dispersion on the surface using the SEM-BEI technique provides information on the extent of copper saturation, particle size, and the effects on NO reduction. However, the lower Cu loading(1 wt.%) increases the catalytic activity with a temperature window of 720-810K, thereby favoring the formation of well dispersed isolated Cu species, e.g. Cu(sup)2+ ions, which is related to selective NO reduction. The effects of other reaction parameters, such as oxygen, the hydrocarbon level and type, and byproduct emissions are further discussed.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2006년도 춘계학술대회 논문집
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• pp.547-548
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• 2006

This study focuses on a determination of amount of Pt in the Pt/C for catalysts of polymer electrolyte membrane fuel cells (PEMFC). PEMFC offer low weight and high power density and being considered fur automotive and stationary power applications. The PEMFC behavior is quite complex is influenced by several factors, including catalysts and structure of electrode and membrane type. Catalyst of electrode is important factor for PEMFC. One of the obstacles preventing polymer electrolyte membrane fuel cells from commercialization is the high cost of noble metals to be used as catalyst, such as platinum. To effectively use these metals, they have to be will dispersed to small particles on conductive carbon supports. The optimal amount of Pt in Pt/C was investigated by using polarization curves in single cell with $H_2/O_2$ operation.

• 신재생에너지
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• 제2권4호
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• pp.64-69
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• 2006

There is a worldwide interest in the development and commercialization of polymer electrolyte membrane fuel cells [PEMFCs] for vehicular and stationary applications. One of the major objectives is the reduction of loaded electrode materials, which is comprise of the Pt-based noble metals. In this paper, a novel chemical strategy is described for the preparation and characterization of carbon-supported and surface-alloys, which were prepared by using a successive reduction process. After preparing Au colloid nanoparticles, the supporting of Au colloid nanoparticles occurred spontaneously in the carbon black-dispersed aqueous solution. Then nano-scaled active materials were formed on the surface of carbon-supported Au nanoparticles. The structural and electrochemical analyses indicate that the active materials were deposited on the surface of Au nanoparticles selectively and that an alloying process occurred during the successive reducing process. The carbon-supported & surface-alloys showed the higher electrocatalytic activity than those of the particle-alloys and commercial one [Johnson-Matthey] for the reaction of methanol and formic acid oxidation. The increased electrocatalytic activity might be attributed to the effective surface structure of surface-alloys, which have a high utilization of active materials for the surface reaction of electrode.

• 한국재료학회지
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• 제17권8호
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• pp.397-401
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• 2007

Fe based SOFC(Solid Oxide Fuel Cell) interconnector was fabricated by using the spark plasma sintering process and its microstructure and mechanical properties were investigated in this study. To fabricate the interconnector, the Fe-26Cr powder was mixed with the Ag (5, 10, 20wt.%) particles. In the Fe-26Cr-Ag sintered bodies, the Ag particles were almost dispersed at the grain boundary of the Fe-26Cr. The sintered bodies have the density of 87.2-97.5%, the density increases with increasing Ag content at sintering temperature of $850^{\circ}C$. Also, the compressive yield strength increases with increasing Ag content at the same sintering temperature.

• 한국재료학회지
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• 제18권8호
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• pp.401-405
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• 2008

Pt-loaded carbon black for the catalyst of a PEM fuel cell was synthesized with different molar ratios of polyvinylpyrrolidone and $H_2PtCl_6$ solution to improve the dispersion of Pt nanoparticles on carbon black and decrease the size of Pt nanoparticles. From transmission electron microscopy results, Pt nanoparticles of a size of approximately 2 nm were highly dispersed when the polyvinylpyrrolidone concentration was 10mM. The electrochemical activity of the synthesized Pt/C catalysts was investigated by cyclic voltammetry, showing that the as-synthesized Pt-loaded carbon black catalyst had the best activity at a polyvinylpyrrolidone concentration of 10 mM.