• Title/Summary/Keyword: Dispersed Phase Method

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Preparations of Polymer Dispersed Liquid Crystals Using the Liquid Crystals with negative dielectric anisotropy

  • Hwang, Sung-Ho;Woo, Sung-Ho;Jeon, Chan-Wook;Yang, Kee-Jeong;Choi, Byeong-Dae;Kim, Byung-Kyu;Kim, Eun-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1394-1397
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    • 2006
  • Polymer Dispersed Liquid Crystal (PDLC) films, of which the liquid crystal has negative dielectric anisotropy, were prepared from the phase separation between MJ001317 and a variety of compositions of resins by common polymerization induced phase separation method. In this work, the effects of resin compositions have been systematically investigated and it was found that the morphology and size of droplet, which is closely related to electro-optic properties, mainly depend on the rate of polymerization and cross-linking density for each resin composition. The reverse mode PDLC films from this newly developed formulation containing TPGDA/EHA/HMPPO showed the good off-state transmittance, contrast ratio (19/1), and relatively low driving voltage(10V).

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Effect of Difference in Mixing Methods of Zirconia on Mechanical Properties of ZTA (ZrO2의 혼합방법 차이가 ZTA의 기계적 물성에 미치는 영향)

  • Sohn, Jeongho
    • Korean Journal of Materials Research
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    • v.23 no.11
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    • pp.625-630
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    • 2013
  • In this study, intermediate-mixed powders were prepared by loading zirconia powders initially in a ball-mill jar and loading alumina powders afterward; the initial-mixed powders were produced by loading zirconia and alumina powders together in the ball-mill jar. The effect of such differences in mixing method on the mechanical properties was investigated. In intermediate-mixed powders, the volume fraction of large particles slightly increased and, simultaneously, zirconia particles formed agglomerates that, due to early ball-mill loading of the zirconia powders only, were more dispersed than were the initial-mixed powders. For the intermediate-mixed powders, zirconia agglomerates were destroyed more quickly than were initial-mixed powders, so the number of dispersed zirconia particles rose and the inhibitory effect of densification due to the addition of a second phase was more obvious. In the microstructure of intermediate-mixed powders, zirconia grains were homogeneously dispersed and grain growth by coalescence was found to occur with increasing sintering temperature. For the initial-mixed powders, large zirconia grains formed by localized early-densification on the inside contacts of some zirconia agglomerates were observed in the early stages of sintering. The intermediate-mixed powders had slightly lower hardness values as a whole but higher fracture toughness compared to that of the initial-mixed powders.

Interconnection of Dispersed Generation Systems considering Load Unbalance and Load Model in Composite Distribution Systems (부하불평형 및 부하모형을 고려한 복합배전계통의 분산형전원의 연계 방안)

  • 이유정;김규호;이상근;유석구
    • The Transactions of the Korean Institute of Electrical Engineers A
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    • v.53 no.5
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    • pp.266-274
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    • 2004
  • This paper presents a scheme for the interconnection of dispersed generator systems(DGs) based on load .unbalance and load model in composite distribution systems. Groups of each individual load model consist of residential, industrial, commercial, official and agricultural load. The unbalance is involved with many single-phase line segment. . Voltage profile improvement and system loss minimization by installation of DGs depend greatly on how they are placed and operated in the distribution systems. So, DGs can reduce distribution real power losses and replace large-scale generators if they are placed appropriately in the distribution systems. The main idea of solving fuzzy goal programming is to transform the original objective function and constraints into the equivalent multi-objectives functions with fuzzy sets to evaluate their imprecise nature for the criterion of power loss minimization, the number or total capacity of DGs and the bus voltage deviation, and then solve the problem using genetic algorithm. The method proposed is applied to IEEE 13 bus and 34 bus test systems to demonstrate its effectiveness.

Electro-Optical Characterization of Polymer Dispersed Liquid Crystals for Various Concentrations of Prepolymer (전폴리머 조성에 따른 고분자 분산형 액정의 전기 광학 특성 평가)

  • Yang, Kee-Jeong;Yoon, Do-Young
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.11
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    • pp.891-895
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    • 2010
  • Polymer dispersed liquid crystal (PDLC) films were prepared by the phase separation method using the liquid crystal (E7) and prepolymers. This work investigated the electro-optical characteristics of various PDLC films. In order to have good contrast ratio, the polymer refractive index must be adjusted to the ordinary refractive index of the liquid crystal. The driving voltage of PDLC films were mainly affected by elastic deformation. E7-Ebecryl810-IOA-TMPTA-HMPPO system had good threshold voltage and driving voltage and E7-Ebecryl810-EHA-PEGDA-HMPPO system had good contrast ratio.

Electro-optic Characteristics of Polymer Dispersed Liquid Crystal Films

  • Yang, Kee-Jeong;Kim, Chang-Geun;Lee, Seung-Chul;Do, Yun-Seon;Kim, Bae-In;Choi, Byeong-Dae
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.902-903
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    • 2009
  • Polymer Dispersed Liquid Crystal (PDLC) films were prepared using the phase separation method with liquid crystal and a newly developed prepolymer. This study investigated the electro-optic characteristics of the PDLC film at various temperatures. It was found that as temperatures increased, the voltage varied, and that the ordinary refractive index of the liquid crystal and the polymer refractive index in the composite had similar dependence at various temperatures.

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Effect of Intersection Angle of the Flow-focusing Type Droplet Generation Device Channel on Droplet Diameter by using Numerical Simulation Modeling (수치해석 모델링을 이용한 교차 흐름 미세유체 액적 생성 디바이스 채널 교차각이 액적 직경에 미치는 영향)

  • Kim, Shang-Jin;Kang, Hyung-Sub;Yang, Yeong-Seok;Kim, Gi-Beum
    • Journal of Biomedical Engineering Research
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    • v.36 no.3
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    • pp.61-68
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    • 2015
  • In this paper, we studied the effects of intersection angles of the flow-foucusing type droplet generation device inlet channel on droplet diameter using numerical simulation modeling. We modeled different intersection angles with a fixed continuous channel width, dispersed channels width, orifices width, and expansion channels width. Numerical simulations were performed using COMSOL Multiphysics$^{(R)}$ to solve the incompressible Navier-Stokes equations for a two-phase flow in various flow-focusing geometries. Modeling results showed that an increase of the intersection angle causes an increase in the modification of the dispersed flow rate ($v^{\prime}{_d}$), and the increase of the modification of the continuous flow rate ($v^{\prime}{_c}$) obstructs the dispersed phase fluid flow, thereby reducing the droplet diameter. However, the droplet diameter did not decrease, even when the intersection angle increased. The droplet diameter decreased when the intersection angle was less than $90^{\circ}$, increased at an intersection angle of $90^{\circ}$, and decreased when the intersection angle was more than $90^{\circ}$. Furthermore, when the intermediate energy deceased, there was a decrease in the droplet diameter when the intersection angle increased. Therefore, variations in the droplet diameter can be used to change the intersection angle and fluid flow rate.

Characterization of Emulsion Properties for D-limonene (D-리모넨 오일의 유화특성)

  • 하윤식;장윤호;문현수;이정경;서무룡
    • Journal of Environmental Science International
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    • v.7 no.6
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    • pp.875-881
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    • 1998
  • Microemulsion is prepared by the method of phase inversion emulsification with d-limonene that is environmental friendly substance and nontoxic to human body as dispersed phase. Emulsifier used for preparation of microemulsion is nonionic surfactants, polyoxyethylene nonylphenyl ether. Stability of prepared microemulsion was estimated by the various method of ξ-potential, hydrodynamic diameter and electric conductivity. When d-limonene is emulsified by NP series, microemulsion is most stable and narrowly distributed at HLB value of 12.3(either one emulsifier or mixed emulsifiers). Stability of microemulsion is increased as the amount of emulsifiers is increased at same HLB value of 12.3. In the case of using the same amount of emulsifiers, number of produced micelle are relatively large as hydrodynamic diameter is small. Therefore, the state of microemulsion is stable and the electric conductivity is increased. One can determine that higher electric conductivity value means that microemulsion has more micelles and is more stable.

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Numerical Simulation on Flow and Heat Transfer in a Gas Atomizer (가스분무장치에서 열유동 특성에 관한 전산해석)

  • 이성연
    • Journal of Powder Materials
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    • v.4 no.1
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    • pp.55-62
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    • 1997
  • Flow and heat transfer characteristics of gas, and trajectories and cooling characteristics of droplets/particles in a gas atomizer were investigated by a numerical simulation using FLUENT code. Among several kinds of solution method, the k-$\varepsilon$ turbulent model, power-law scheme, SIMPLE algorithm is adopted in this study. Momentum and heat exchange between a continuous phase(gas) and a dispersed phase(particle) were taken into account. Particle trajectories are simulated using the Lagrangian method, and Rosin-Rammler formula is used for the particle size distribution. Streamlines, velocities and pressures of gas, and trajectories, velocities and cooling rates of particles have been investigated for the various gas inlet conditions. Small but very intensive recirculation is found just below the melt orifice, and this recirculation seems to cause the liquid metal to spread radially. Particle trajectory depends on the particle size, the location of particle formation and the turbulent motion of gas. Small particle cools down rapidly, while large diameter particles solidify slowly, and this is mainly due to the differences in thermal inertia.

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Design and Control of Grid-connected Photovoltaic system using the state space Modeling (상태공간 모델링을 이용한 계통연계 태양광발전시스템의 설계 및 제어)

  • Hwang, In-Ho;Kim, Si-Kyeong;Seong, Se-Jin
    • Proceedings of the KIEE Conference
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    • 1996.07a
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    • pp.431-433
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    • 1996
  • It is expected that utility interactive small scale dispersed PV system will be widely diffused in the future. This paper discussed the design and control method of single phase PV inverter system with compensation capability of reactive power including harmonic distortion, based on state space modelling. As the results, compensation effects were suggested by simulation and experiment.

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Synthesis of CuSbS2 and CuSbSe2 Nanocrystals by a Mechanochemical Method (기계화학적 방법에 의한 CuSbS2와 CuSbSe2 나노입자의 합성)

  • Park, Bo-In;Lee, Seung Yong;Lee, Doh-Kwon
    • Current Photovoltaic Research
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    • v.5 no.4
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    • pp.140-144
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    • 2017
  • $CuSbS_2$ (CAS) and $CuSbSe_2$ (CASe) nanocrystals (NCs), which consist of earth-abundant elements, were synthesized by a mechanochemical method. Elemental precursors such as copper, antimony, sulfur, and selenium were used without adding any organic solvents or additives. The NCs were synthesized by milling for a few hours. The sudden phase changes occurred by self-ignition and propagation, as previously observed in other mechanochemical synthetic processes. The XRD, Raman, and TEM analysis were carried out to determine the crystallinity and secondary phase of the as-synthesized CAS and CASe NCs, confirming the phase-pure synthesis of CAS and CASe. Optical properties were investigated by UV-Vis spectroscopy and it was observed that the band gap energies were about 1.1 and 1.5 eV, respectively for CAS and CASe, suggesting the potential for the use as solar cell materials. The NC colloids dispersed in anhydrous ethanol were prepared and coated on Mo substrates by a facile doctor-blade method. The investigation on the solar cell properties of the as-synthesized materials is underway.