• Textile Coloration and Finishing
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• v.21 no.5
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• pp.21-26
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• 2009

In order to analyze numerically the hydrophobicity of the new dyes synthesized for unmodified pure polypropylene fibers, the octanol-water partition coefficient (logP), which is one of molecular descriptors representing hydrophobicity of organic compounds, was obtained by a semi-empirical method using Chem3D software. For the dyes of higher logP than around 5, the affinity of the dyes towards unmodified polypropylene fiber was substantial. In contrast to the new dyes for polypropylene, conventional disperse dyes have logP values lower than 5 and exhibited poor affinity.

• Textile Coloration and Finishing
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• v.10 no.2
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• pp.37-44
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• 1998

In this study, the polyurethane microcapsules containing disperse dye were prepared by in-situ polymerization method using hexamethylene diisocyanate (HDI, aliphatic type) and m-xylene diisocyanate(XDI, aromatic type) with ethylene glycol (EG) And the size, shape, particle size distribution, and breaking behavior of microcapsules prepared were investigated. The size and shape of microcapsule were observed by scanning electron microscope (SEM) . The particle size distribution was analyzed by image analyzer. The breaking behavior of microcapsule was checked by measuring the optical density of solution that the disperse dye was dissolved after the microcapsule was broken by constant pressure. The particle size was inversely proportional to the stirring speed, and the size of microcapsule prepared from HDI and EG was smaller than that of microcapsule prepared from XDI and EG. Aliphatic type microcapsule was broken easily, compared with aromatic type one. It was considered due to the difference of reactivity between HDI and XDI. And the microcapsule prepared by stirring strongly was broken easily.

• Textile Coloration and Finishing
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• v.12 no.5
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• pp.308-314
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• 2000

The dyeability of C. I. Disperse Violet 1 on polyester fiber in alkance including a small amount of water was investigated. Up to 1% of water in alkanes the dye uptakes were increased rapidly. The dyeing transition temperature of the polyester fiber in alkanes with 1% of water was $86.5^\circ{C}$ that is lower by $11^\circ{C}$ than $97.5^\circ{C}$ in alkanes only. This means that water plasticizes the polyester fiber, and that dyes begin to penetrate the polyester fiber at lower temperature. Addition of trichloromethane which is known as a strong plasticizer on polyester fiber, in alkanes, increased the dye uptakes of C. I. Disperse Violet 1 on polyester fiber at $100^\circ{C}$, but the dyeing transition temperature was lower by $3^\circ{C}$ than in alkanes only.

• Textile Coloration and Finishing
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• v.21 no.6
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• pp.12-21
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• 2009

The dyeing property of direct-spinning type and seaisland type 0.2D micro polyester nonwoven fabrics was characterized by three disperse dyes (Dorosperse Red KFFB, Blue KGBR, Yellow KRL) at $120^{\circ}C$ and $130^{\circ}C$. Before and after reduction cleaning, dyeing fastness was evaluated and the thermomigaration after heat setting at $180^{\circ}C$ for 60 min were also evaluated. Direct-spinning type fabric showed better dyeing property, wash fastness, and light fastness, but worse rub fastness than seaisland type fabric. The dyeing property and fastness of direct-spinning type fabric increased at higher dyeing temperature, whereas seaisland type fabric exhibited lower dyeing fastness and the increase of thermomigration at higher dyeing temperature. Non-fixed dye in fiber surface was removed by reduction cleaning process, then dyeing fastness was improved and thermomigration decreased. The higher dye uptake of direct-spinning type non-woven fabric caused the increase of dye molecule migration from fiber internal to fiber surface, so this fabric showed larger thermomigration than seaisland type non-woven fabric.

• Korean Chemical Engineering Research
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• v.53 no.3
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• pp.327-332
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• 2015

A large amount of dye wastewater poses a threat to environmental safety. Disperse blue, an anthraquinone dye that is widely used in textile dyes, is difficult to degrade in wastewater. In this work, one fungus was screened according to the decolorization rate of disperse blue. The fungus was identified and named Aspergillus XJ-2 on the basis of its morphological characteristics and 18s rDNA. Response surface method was used to optimize culture conditions for A. XJ-2. The optimum values of obtained responses were as follows: temperature, $35^{\circ}C$; pH, 5.2; carbon-to-nitrogen ratio, 30:5.5; and rotation ratio, $175r{\cdot}min^{-1}$. Under optimized conditions, the decolorization rate of A. XJ-2 was up to 94.8% in 48 h.

• Textile Coloration and Finishing
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• v.14 no.5
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• pp.268-276
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• 2002

Poly(trimethylene terephthalate)(PTT) and Poly(ethylene terephthalate)(PET) fibers were annealed at various temperatures ranging from $100^\circ{C}$ to $230^\circ{C}$ for 10 min under tension and tension free. Dyeing rates and absorption isotherms of both fibers were obtained with C.I. Disperse Red 60 at 100, 120 and $130^\circ{C}$ in water system. Also X-ray diffraction pattern, moisture regain and water absorption were investigated. The dyeing rate of PTT fiber is faster than PET fiber, and dyeing of PTT fiber begin at lower temperature compared to PET fiber. The absorption isotherms from both fibers with disperse dye we nearly linear up to the saturation dye uptake, which increase with dyeing temperature. Equilibrium dye uptake of PTT fiber annealed under tension above $180^\circ{C}$ was remarkably decreased because of a changes in the fine structure of fiber. The intensities of X-ray diffraction peaks of both annealed fibers were increased with increasing in annealed temperature. The reflections observed at $2\theta$=$15.8^\circ$, $24^\circ$ and $25.2^\circ$ were assigned reflection of crystal at the planes of (010), $(1\bar02,\;\bar112),\;and\;(\bar13,\; \bar113)$ respectively, and the peak became sharp with heat setting temperature.

• Journal of Electrochemical Science and Technology
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• v.12 no.1
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• pp.82-91
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• 2021

This study was conducted to investigate the effect of initial pH, current density, and electrolysis time on process performance in terms of decolorization and chemical oxygen demand (COD) removal from disperse dyebath wastewater (DDW) by mono-polar parallel laboratory scale electrocoagulation (EC) process. COD reduction of 51.3% and decolorization of 92.8% were obtained with operating cost of 0.19 €/㎥ treated wastewater for Al-Al electrode pair, while 90.5% of decolorization and 49.2% of COD reduction were obtained with operating cost of 0.20 €/㎥ treated wastewater for an Fe-Fe electrode pair. The amount of sludge production were highly related to type of the electrode materials. At the optimum conditions, the amount of sludge produced were 0.18 kg/㎥ and 0.28 kg/㎥ for Al-Al and Fe-Fe electrode pairs, respectively. High decolorization can be explained by the hydrophobic nature of the disperse dye, while limited COD removal was observed due to the high dissolved organic matter of the DDW based on auxiliary chemicals. Energy, electrode, and chemical consumptions and sludge handling were considered as major cost items to find a cost-effective and sustainable solution for EC. The contribution of each cost items on operating cost were determined as 10.0%, 51.1%, 30.5% and 8.4% for Al-Al, and they were also determined as 9.0%, 38.0%, 40.5% and 12.5% for Fe-Fe, respectively. COD reduction and decolorization were fitted to first-order kinetic rule.

• Clean Technology
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• v.27 no.2
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• pp.182-189
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• 2021

The adsorption of disperse yellow 3 (DY 3) on granular activated carbon (GAC) was investigated for isothermal adsorption and kinetic and thermodynamic parameters by experimenting with initial concentration, contact time, temperature, and pH of the dye as adsorption parameters. In the pH change experiment, the adsorption percent of DY 3 on activated carbon was highest in the acidic region, pH 3 due to electrostatic attraction between the surface of the activated carbon with positive charge and the anion (OH^-) of DY 3. The adsorption equilibrium data of DY 3 fit the Langmuir isothermal adsorption equation best, and it was found that activated carbon can effectively remove DY 3 from the calculated separation factor (R_L). The heat of adsorption-related constant (B) from the Temkin equation did not exceed 20 J mol^-1, indicating that it is a physical adsorption process. The pseudo second order kinetic model fits well within 10.72% of the error percent in the kinetic experiments. The plots for Weber and Morris intraparticle diffusion model were divided into two straight lines. The intraparticle diffusion rate was slow because the slope of the stage 2 (intraparticle diffusion) was smaller than that of stage 1 (boundary layer diffusion). Therefore, it was confirmed that the intraparticle diffusion was rate controlling step. The free energy change of the DY 3 adsorption by activated carbon showed negative values at 298 ~ 318 K. As the temperature increased, the spontaneity increased. The enthalpy change of the adsorption reaction of DY 3 by activated carbon was 0.65 kJ mol^-1, which was an endothermic reaction, and the entropy change was 2.14 J mol^-1 K^-1.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2008.04a
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• pp.83-85
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• 2008

Dyeing and fastness properties of direct spun type PET microfiber have been compared with those of regular PET fiber and PET-Nylon conjugated microfiber. The dye uptake of finer microfibers commenced at lower temperatures and showed faster rate of dye uptake. The build-up and wash fastness properties of disperse dyes on direct spun type PET microfiber were relatively better than split type PET-Nylon microfiber.

• Journal of the Korean Society of Clothing and Textiles
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• v.26 no.10
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• pp.1401-1411
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• 2002

To Save energy and cost one bath/one step dyeing and finishing on cotton/polyester blends is carried out with disperse dyes in the presence of crosslinking agent. Cotton 100 %, cotton/polyester 70/30, 50/50, 35/65, polyester 100 % fabrics were used. wrinkle recovery angle, tensile strength retention and tearing strength retention were determined in according to the dyebath composition, and also determined while the concentration of DMDHEU, molecular weight and concentration of PEG were varied. Colorfastness to abrasion, washing and light were tested. For cotton and cotton/polyester blends dyed in the presence of DMDHEU/PEG, wrinkle recovery was improved. Tensile strength retention and tearing strength retention were decreased, in compared with dyed fabrics without DMDHEU. Colorfastness to abrasion was good but colorfastness to washing and to light were poor for the fabrics dyed in the presence of DMDHEU/PEG.