• Title/Summary/Keyword: Disperse

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Effect of Denier and Dyestuff Structure on Washing Fastness of Polyester Fabric (섬도와 염료구조가 폴리에스테르 직물의 세탁견뢰도에 미치는 영향)

  • 강연희;백지연;이재웅;김삼수;허만우;이난형
    • Textile Coloration and Finishing
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    • v.13 no.3
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    • pp.180-187
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    • 2001
  • Generally, polyester microfiber has much greater dye uptake than that of regular ones. In spite of high dye up-take visual shade depth of dyed fabric decreases with smaller denier, which results in poor washing fastness of dyed fabric. In this study, in order to investigate the washing fastness, polyester microfiber fabric was dyed by using two type of disperse dyes and treated with 3 different reduction clearing methods. The reduction clearing methods in this study are normal alkaline reduction clearing, $N_2$ gas replacement method, and ultrasonic treatment during reduction clearing. The results were as followings ; The most important factors affecting the washing fastness of polyester artificial suede fabric were found to be the reduction clearing method, the chemical structure of used disperse dyes and the structure and denier of fibers. It was also obtained that the heat treatment of dyed fabric decreased the washing fastness due to the dye migration from inner phase to surface.

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Dyeing of Ultra High Molecular Weight Polyethylene Fibers with Diamino-anthraquinoid Blue Disperse Dyes Having Linear Long Alkyl Substituents (선형의 장쇄 알킬치환기를 가지는 디아미노안트라퀴논계 청색 분산염료에 의한 초고분자량 폴리에틸렌 섬유의 염색)

  • Kwak, Dong-Sup;Kim, Tae-Kyeong
    • Textile Coloration and Finishing
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    • v.24 no.3
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    • pp.180-188
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    • 2012
  • Following the reported study that showed the dyeability of diamino-anthraquinoid blue dyes substituted with relatively shorter alkyl groups, the longer aliphatic substituents than pentyl group were examined in terms of the color strength and fastness properties toward UHMWPE fibers. The color strength was increased up to pentyl group and then gradually decreased. However, the fastness properties were improved continuously to octyl group which was the longest alkyl substituent in this study. The most effective maximum color strength was obtained at $130^{\circ}C$ for 2 hours with 3% owf of dyes. The overall fastnesses to washing, rubbing, and light were good enough for practical uses.

Dyeing Property of Polyester in Byebath Containing Water and Water Miscible Organic Solvents (물/극성유기용매 혼합욕에서 폴리에스테르의 염색)

  • 김은아;유효선
    • Journal of the Korean Society of Clothing and Textiles
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    • v.22 no.1
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    • pp.100-107
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    • 1998
  • Polyester filaments were dyed with disperse dye in dyebath containing water and water miscible organic solvents . acetone, 1,4-dioxane, DMF. In case of Acetone and 1,4-dioxane, the equilibrium dyeuptake was maximun at the volume fraction 0.05. The equilibrium dye uptakes were decreased as volun~e fraction of organic solvents were increased. When the volume fractions of water miscible organic solvents were varied, dye uptake was increased constantly with dyeing time. In dyebath containing water and water miscible organicsolvent, the dyeuptake was increased quickly during initial 40∼ 60 min. and slowly increased there after. The slope of Ct/Coo to t was greater in dyebath containing water and water miscible organic solvents than dyebath containing water. The differences of the slope with volulne fractions of water miscible organic solvent were not shown big.

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Carrier Dyeing of Polyester Fabrics in Alkaline Dyebath (폴리에스테르직물의 알칼리욕에서의 Carrier염색)

  • 조은자;남성우;김인회
    • Textile Coloration and Finishing
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    • v.13 no.6
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    • pp.381-390
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    • 2001
  • The optimum carrier concentrations were obtained by the maxmium exhaustion ratios of polyester fabrics at 8$0^{\circ}C$ . The optimum concentrations of methylsalicylate, acetophenone, anisole, propiophenone, 2-ethyl hexyl alcohol, ethylene glycol and propylene glycol were $3g/\ell,\;12g/\ell,\;7g/\ell,\;5g/\ell,\;3g/\ell,\;35g/\ell,\;and\;40g/\ell$, respectively Azo, anthraquinone, and quinoline disperse dyes were quite stable up to PH 10.3, but nitro disperse dye were severely hydrolyzed in alkaline dyeing. The tensile strength decreased with increasing dyebath pH because the polyester fabrics were easily decomposed by alkali. The reduction cleaning could be canceled in alkaline dyeing because the carriers were solved by alkali during dyeing.

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Carrier Dyeing of Polyester Fabrics in Alkaline Dyebath (폴리에스테르직물의 알칼리욕에서의 Carrier염색)

  • Jo, Eun Ja;Nam, Seong U;Kim, In Hoe
    • Textile Coloration and Finishing
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    • v.13 no.6
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    • pp.23-23
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    • 2001
  • The optimum carrier concentrations were obtained by the maxmium exhaustion ratios of polyester fabrics at 80℃. The optimum concentrations of methylsalicylate, acetophenone, anisole, propiophenone, 2-ethyl hexyl alcohol, ethylene glycol and propylene glycol were 3g/ℓ, 12g/ℓ, 7g/ℓ, 5g/ℓ, 3g/ℓ, 35g/ℓ, and 40g/ℓ, respectively. Azo, anthraquinone, and quinoline disperse dyes were quite stable up to pH 10.3, but nitro disperse dye were severely hydrolyzed in alkaline dyeing. The tensile strength decreased with increasing dyebath pH because the polyester fabrics were easily decomposed by alkali. The reduction cleaning could be canceled in alkaline dyeing because the carriers were solved by alkali during dyeing.

The Application of Non-ionic Vat dye to Polyester Fiber : Practical Aspects and Preliminary Studies (비이온성 배트염료의 폴리에스터 섬유에의 응용)

  • 손영아;김태경
    • Textile Coloration and Finishing
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    • v.15 no.1
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    • pp.23-29
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    • 2003
  • Dyeings of the most widely used to the synthetic fibers, namely polyamide and polyester, have been carried out using acid dyes and disperse dyes. The above mentioned dye types, and indeed all dyes onto substrates, rely on the reaction properties between the substrates and dye molecules. In terms of fastness properties, however, especially to washings, the satisfactory levels are not present in the results from acid and disperse dyeings. Thus, vat dyeings leaves a feasibility and are an alternative way to overcome the problem. Although attempts and works have been reported in early years, with little if any commercial achievement and success. In this context, to meet increased demands towards a high level of wash fastness from consumers and retailers, an attempt using vat dyes has been carried out in this work.

Calculation and Analysis of Hydrophobicity of the Dyes Synthesized for Unmodified Polypropylene Fibers Using Molecular Descriptors

  • Kim, Tae-Kyeong;Jang, Kyung-Jin;Jeon, Seon-Hee
    • Textile Coloration and Finishing
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    • v.21 no.5
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    • pp.21-26
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    • 2009
  • In order to analyze numerically the hydrophobicity of the new dyes synthesized for unmodified pure polypropylene fibers, the octanol-water partition coefficient (logP), which is one of molecular descriptors representing hydrophobicity of organic compounds, was obtained by a semi-empirical method using Chem3D software. For the dyes of higher logP than around 5, the affinity of the dyes towards unmodified polypropylene fiber was substantial. In contrast to the new dyes for polypropylene, conventional disperse dyes have logP values lower than 5 and exhibited poor affinity.

Physical Modification of Polypropylene - Preparation of Disperse dyeable Fibers -

  • Lim, Sang-Kyoo;Park, Jun-Ho;Chang, Chul-Min;Kim, Sam-Sue;Son, Tae-Won
    • Proceedings of the Korean Fiber Society Conference
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    • 1998.04a
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    • pp.32-35
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    • 1998
  • Polypropylene fibers are difficult to dye by conventional dyeing techniques due either to lack of dye receptor sites in their molecular structure to with the dye molecules may become attached, or to difficult of penetration of certain types of dye molecules into the structure$^1$. Although the diffusion coefficient of disperse dyes into polypropylene is quite high, the saturation values are very low.(omitted)

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Dyeing and Fastness Properties of Direct Spun Type PET Microfiber Fabrics (직접방사형 PET 극세사 제품의 염색성 및 견뢰도 특성)

  • Koh Joonseok;Park Jong Ho;Lee Kwon Sun;Kim Sung Dong
    • Textile Coloration and Finishing
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    • v.17 no.5 s.84
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    • pp.13-19
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    • 2005
  • Dyeing and fastness properties of direct spun type PET microfiber fabrics have been investigated. The dye uptake of finer microfibers commenced at lower temperatures and showed faster rate of dye uptake. The build-up and wet fastness properties of disperse dyes on finer microfbers were relatively poor since the more dye was needed to achieve a given depth of shade due to the large surface area.

The Preparation of Polyurethane Microcapsule and Its Breaking Behavior (폴리우레탄계 마이크로캡슐의 제조 및 그의 파괴 거동)

  • 박형인;김애경;이웅의;최창남
    • Textile Coloration and Finishing
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    • v.10 no.2
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    • pp.37-44
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    • 1998
  • In this study, the polyurethane microcapsules containing disperse dye were prepared by in-situ polymerization method using hexamethylene diisocyanate (HDI, aliphatic type) and m-xylene diisocyanate(XDI, aromatic type) with ethylene glycol (EG) And the size, shape, particle size distribution, and breaking behavior of microcapsules prepared were investigated. The size and shape of microcapsule were observed by scanning electron microscope (SEM) . The particle size distribution was analyzed by image analyzer. The breaking behavior of microcapsule was checked by measuring the optical density of solution that the disperse dye was dissolved after the microcapsule was broken by constant pressure. The particle size was inversely proportional to the stirring speed, and the size of microcapsule prepared from HDI and EG was smaller than that of microcapsule prepared from XDI and EG. Aliphatic type microcapsule was broken easily, compared with aromatic type one. It was considered due to the difference of reactivity between HDI and XDI. And the microcapsule prepared by stirring strongly was broken easily.

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