• Journal of the Korean Ceramic Society
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• v.37 no.5
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• pp.466-472
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• 2000

As cathode materials of LiMn2O4-based lithium-ion secondary batteries, Li(Mn1-$\delta$M$\delta$)2O4 (M=Ni and Co, $\delta$=0, 0.05, 0.1 and 0.2) materials which Co and Ni are substituted for Mn, were syntehsized by the solid state reaction at 80$0^{\circ}C$ for 48 hours. No second phases were formed in Li(Mn1-$\delta$M$\delta$)2O4 system with substitution of Co. However, substitution of Ni caued to form a second phase of NiO when its composition exceeded over 0.2 of $\delta$ in Li(Mn1-$\delta$M$\delta$)2O4. As the results of charging-discharging test, the maximum capacity of Li(Mn1-$\delta$M$\delta$)2O4 appeared in $\delta$=0.1 for both Co and Ni. Also, Li(Mn1-$\delta$M$\delta$)2O4 electrode showed higher capacity and better cycle performance than LiMn2O4.

• Korean Chemical Engineering Research
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• v.55 no.4
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• pp.483-489
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• 2017

The loss of the sulfur cathode material through dissolution of the polysulfide into electrolyte causes a significant capacity reduction of the lithium-sulfur cell during the charge-discharge reaction, thereby debilitating the electrochemical performance of the cell. We addressed this problem by using a chemical and physical approach called reduction of polysulfide dissolution through direct coating functional inorganic (graphene oxide) or organic layer (polyethylene oxide) on electrode, since the deposition of external functional layer can chemically interact with polysulfide and physically prevent the leakage of lithium polysulfide out of the electrode. Through this approach, we obtained a composite electrode for a lithium-sulfur battery (sulfur: 60%) coated with uniform and thin external functional layers where the thin external layer was coated on the electrode by solution coating and drying by a subsequent heat treatment at low temperature (${\sim}80^{\circ}C$). The external functional layer, such as inorganic or organic layer, not only alleviates the dissolution of the polysulfide electrolyte during the charging/discharging through physical layer formation, but also makes a chemical interaction between the polysulfide and the functional layer. As-formed lithium-sulfur battery exhibits stable cycling electrochemical performance during charging and discharging at a reversible capacity of 700~1187 mAh/g at 0.1 C (1 C = 1675 mA/g) for 30 cycles or more.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.62 no.1
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• pp.21-28
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• 2013

The paper proposes an optimal sizing method of a customer's battery energy storage system (BESS) which aims at managing the electricity demand of the customer to minimize electricity cost under the time of use(TOU) pricing. Peak load limit of the customer and charging and discharging schedules of the BESS are optimized on annual basis to minimize annual electricity cost, which consists of peak load related basic cost and actual usage cost. The optimal scheduling is used to assess the maximum cost savings for all sets of candidate capacities of BESS. An optimal size of BESS is determined from the cost saving curves via capacity of BESS. Case study uses real data from an apartment-type factory customer and shows how the proposed method can be employed to optimally design the size of BESS for customer demand management.

• Journal of Electrical Engineering and Technology
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• v.13 no.4
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• pp.1759-1768
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• 2018

The energy density, power density and ohm resistance of battery change significantly as results of battery aging, which lead to decrease in the accuracy of the equivalent model. A parameter identification method of the equivale6nt circuit model with 3 R-C branches based on the test database of battery life cycle is proposed in this paper. This database is built on the basis of experiments such as updating of available capacity, charging and discharging tests at different rates and relaxation characteristics tests. It can realize regular update and calibration of key parameters like SOH, so as to ensure the reliability of parameters identified. Taking SOH, SOC and T as independent variables, lookup table method is adopted to set initial value for the parameter matrix. Meanwhile, in order to ensure the validity of the model, the least square method based on variable forgetting factor is adopted for optimizing to complete the identification of equivalent model parameters. By comparing the simulation data with measured data for charging and discharging experiments of Li-ion battery, the effectiveness of the full life cycle database and the model are verified.

• Journal of the Korean institute of surface engineering
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• v.49 no.2
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• pp.191-195
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• 2016

Among the lithium metal oxides for hybrid-capacity, $Li_4Ti_5O_{12}(LTO)$ is an emerging electrode material as zero-stain material in volume change during the with the charging and discharging processes. However, LTO has a limitation of low ionic and electronic conductivity. To enhance the ionic and electronic properties of $Li_4Ti_5O_{12}(LTO)$, we synthesized the spherical LTO/CNT composite by sol-gel process for hybrid capacitors. CNT interconnection networks between CNT-LTO particles enhanced electronic conductivity and electrochemical charging/discharging properties. All of the LTO samples was observed to show the spinel structure and spherical morphology with the diameter of $5{\sim}10{\mu}m$. Especially, spherical LTO/CNT composite of the CNT-3 wt% showed the enhanced capacity from 110 mAh/g to 140 mAh/g at 10 C.

• Journal of Electrical Engineering and Technology
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• v.13 no.6
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• pp.2227-2235
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• 2018

Under the current policies and compensation rules in South Korea, Photovoltaic (PV) generation supplier can maximize the profit by combining PV generation with Energy Storage System (ESS). However, the existing operational strategy of ESS is not able to maximize the profit due to the limitation of ESS capacity. In this paper, new ESS scheduling algorithm is introduced by utilizing the System Marginal Price (SMP) and PV generation forecasting to maximize the profits of PV generation supplier. The proposed algorithm determines the charging time of ESS by ranking the charging schedule from low to high SMP when PV generation is more than enough to charge ESS. The discharging time of ESS is determined by ranking the discharging schedule from high to low SMP when ESS energy is not enough to maintain the discharging. To compensate forecasting error, the algorithm is updated every hour to apply the up-to-date information. The simulation is performed to verify the effectiveness of the proposed algorithm by using actual PV generation and ESS information.

• Solar Energy
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• v.19 no.4
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• pp.11-20
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• 1999

The study on ice thermal storage system is to improve total system performance and increase the economical efficiency in actual air-conditioning facilities. To obtain the high charging and discharging efficiencies in ice thermal storage system, the improvement of thermal stratification is essential, therefore the process flow must be piston flow in the cylindrical type. In the influence of the inlet port type, the inflowing water in the distributor type diffuses through the whole storage tank more than in the slot type. In case of the flow process in the ice storage tank, the upward flow type in the charging process and the downward flow type in the discharging process make the stratification well, thereby the loss of energy wored be smaller. The influence of the inlet temperature difference and the change of the inlet flow rate is intensive when the temperature difference is larger, the flow rate is smaller in case of charging and the results are opposite in case of discharging with the reason that the good coduction condition. The total effeciency of the ice thermal storge system is 73% on condition that the porosity in the thermal storage tank is 0.55. This result shows that cylinderical ice storage tank has better storage capacity than rectangular type in case of the same porosity.

• Journal of Korean Society of Water and Wastewater
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• v.19 no.5
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• pp.557-564
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• 2005

The objective of this study is to evaluate a criteria of intercepting capacity and a reduction goal of overflow pollution load in combined sewer system. In the current criteria of intercepting capacity in the domestic sewage facility standard, it is known that three times of peak sewage (Q) in dry period or runoff flow by 2mm/hr is not appropriate since the intercepted flow is estimated by runoff and show different result even in the same watershed. Though a reduction goal of overflow pollution load can be determined from 1) same level of storm-water runoff pollution load in separated storm sewer, 2) less than 5% sewage load in dry weather period, by the domestic sewage facility standard, the simulated results from storm-water model show large differences between two criteria. While it is predicted that sewage pollution load standard three time larger than separated storm sewer standard in high population density and urbanized area, it is shown that separate storm sewer standard larger than sewage pollution load standard in middle population density and developing area. Accordingly, it is proposed that more reasonable intercepting flow and reduction goal of overflows pollution load should be established to minimize discharging pollution load in combined sewer systems. For the purpose, a resonable standard has to be amended by pollution load balance considering the characteristics of a watershed for generation, collection, treatment, and discharging flow.

• Analytical Science and Technology
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• v.8 no.4
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• pp.603-610
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• 1995

The charge transfer rate in polypyrrole(PPy) electropolymerized within poly(acrylonitrile-co-butadiene)(PAB) was compared with that in PPy deposited Pt electrodes by using cyclic voltammetry, chronoamperometry, and chronopotentiometry in acetonitrile. For both electrodes anodic and cathodic peak currents were proportional to scan rates below 100 mV/sec, but to square root of scan rates beyond 200 mV/sec. The apparent diffusion coefficient of $ClO{_4}^-$ in the PPy/PAB composite is estimated to be 1.6 times larger than that in PPy. The PPy films composited within PAB layer showed higher anodic and cathodic currents and possessed faster charging-discharging process and larger capacity.

• Journal of Electrical Engineering and Technology
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• v.12 no.5
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• pp.2043-2050
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• 2017

This paper presents two MPC (Model Predictive Control) based charging and discharging algorithms of BESS (Battery Energy Storage System) for capacity firming of wind generation. To deal with the intermittency of the output of wind generation, a single BESS is employed. The proposed algorithms not only make the output of combined systems of wind generation and BESS track the predefined reference, but also keep the SoC (State of Charge) of BESS within its physical limitation. Since the proposed algorithms are both presented in simple if-then statements which are the optimal solutions of related optimization problems, they are both easy to implement in a real-time system. Finally, simulations of the two strategies are done using a realistic wind farm library and a BESS model. The results on both simulations show that the proposed algorithms effectively achieve capacity firming while fulfilling all physical constraints.