• 한국진공학회:학술대회논문집
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• 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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• pp.135-135
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• 2015

Tubes are of extreme importance in industries as for fluid channels or wave guides. Furthermore, some weapon systems such as cannons use the tubes as gun barrels. To increase the service life of such tubes, a protective coating must be applied to the tubes' inner surface. However, the coating methods applicable to the inner surface of the tubes are very limited due to the geometrical restriction. A small-diameter cylindrical magnetron sputtering gun can be used to deposit coating layers on the inner surface of the large-bore tubes. However, for small-bore tubes with the inner diameter of one inch (~25 mm), the magnetron sputtering method can hardly be accommodated due to the space limitation for permanent magnet assembly. In this study, a new approach to coat the inner surface of small-bore tubes with the inside diameter of one inch was developed. Instead of using permanent magnets for magnetron operation, an external electro-magnet assembly was adopted around the tube to confine the plasma and to sustain the discharge. The electro-magnet was operated in pulse mode to provide the strong axial magnetic field for the magnetron operation, which was synchronized with the negative high-voltage pulse applied to the water-cooled coaxial sputtering target installed inside the tube. By moving the electro-magnet assembly along the tube's axial direction, the inner surface of the tube could be uniformly coated. The inner-surface coating system in this study used the tube itself as the vacuum chamber. The SS-304 tube's inner diameter was 22 mm and the length was ~1 m. A water-cooled Cu tube (sputtering target) of the outer diameter of 12 mm was installed inside of the SS tube (substrate) at the axial position. The 50 mm-long electro-magnet assembly was fed by a current pulse of 250 A at the frequency and pulse width of 100 Hz and 100 usec, respectively. The calculated axial magnetic field strength at the center was ~0.6 Tesla. The central Cu tube was synchronously driven by a HiPIMS power supply at the same frequency of 100 Hz as the electro-magnet and the applied pulse voltage was -1200 V with a pulse width of 500 usec. At 150 mTorr of Ar pressure, the Cu deposition rate of ~10 nm/min could be obtained. In this talk, a new method to sputter coat the inner surface of small-bore tubes would be presented and discussed, which might have broad industrial and military application areas.

• 한국환경보건학회지
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• 제46권1호
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• pp.45-64
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• 2020

Objectives: Limited information is available on the presence and associated ecological risks of pharmaceutical residues in aquatic environments near pharmaceutical manufacturing areas in Korea. In this study, we investigated the current state of pharmaceutical contamination and its associated ecological risks in streams near a pharmaceutical manufacturing complex. Methods: Seven pharmaceuticals (acetaminophen, clarithromycin, diclofenac, diphenhydramine, ibuprofen, mefenamic acid and roxithromycin) were measured in water samples collected from the streams near a pharmaceutical manufacturing complex. A predicted no-effect concentration (PNEC) was derived using either the assessment factor method or species sensitivity distribution method. In addition, a hazard quotient for each pharmaceutical was calculated by dividing its measured environmental concentration by its PNEC. Results: Samples collected downstream from the wastewater treatment plant (WWTP) had higher concentrations of pharmaceuticals than those collected from the reference site (upstream). Moreover, pharmaceutical concentrations were greater in ambient water than in the final effluent from the WWTP, which suggested that non-point sources were contributing to the contamination of the ambient water environment. Some of the target pharmaceuticals exhibited a hazard quotient >1, indicating that their potential ecological effects on the aquatic environment near the pharmaceutical industrial area should not be ignored. Conclusion: This study demonstrated that the pharmaceutical manufacturing area was contaminated with residual drugs, and that there was a possible non-point source near the WWTP effluent discharge area. The results of this study will aid in the development of management plans for pharmaceuticals, particularly in hotspots such as pharmaceutical industrial sites and their vicinities.

• 공업화학
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• 제10권1호
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• pp.73-79
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• 1999

초격자 구조의 $Li_{4/3}Ti_{5/3}O_4$를 lithium acetate (LA)와 titanium n-butoxide (TNB)의 혼합 용액을 이용한 졸겔법으로 합성하였다. 이때 얻어진 겔상은 TNB/LA 몰비 5/4에 AA/TNB의 몰비 0.125를 혼합한 clear sol 용액에 $NH_4OH/TNB$ 몰비 0.35와 $H_2O/TNH$ 몰비 3.5를 첨가하여 얻었으며, $Li_{4/3}Ti_{5/3}O_4$는 xerogel을 $600^{\circ}C$에서 30시간 동안 열처리하여 제조하였다. 그리고 합성된 $Li_{4/3}Ti_{5/3}O_4$는 0.5~3.0 V의 전위 영역에서 $0.15mA/cm^2$의 전류밀도로 Li/1M $LiClO_4(in\;PC)/Li_{4/3}Ti_{5/3}O_4$를 구성하여 실험한 결과 174 mAh/g의 초기 용량을 나타냈으며, 25 cycle 동안 27.3%의 용량 감소를 나타냈다.

• 공업화학
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• 제26권5호
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• pp.543-548
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• 2015

리튬이온 전지용 음극소재의 용량 및 사이클 성능을 향상시키기 위해서 Si/C/CNF 합성물의 특성이 조사되었다. 제조과정으로는 SBA-15를 합성하고 볼밀링을 이용한 마그네슘환원을 통해 Si/MgO를 얻은 다음, Phenolic resin과 CNF를 이용해 탄화과정을 거쳐 최종적으로 산처리하여 Si/C/CNF 활물질을 합성하였다. 합성된 Si/C/CNF는 BET, XRD, FE-SEM 그리고 TGA를 이용하여 분석하였다. $50^{\circ}C{\sim}70^{\circ}C$까지 온도에 따라 SBA-15를 합성한 결과 $60^{\circ}C$에서 가장 큰 비표면적을 갖는 결과를 얻었다. 또한 LiPF6 (EC : DMC : EMC = 1 : 1 : 1 vol%) 전해질을 사용하여, 충방전, 사이클, CV와 임피던스 등과 같은 전기화학적 테스트를 수행하여 Si/C/CNF 전극의 이차전지 음극활물질로서 성능을 조사하였다. Si/C/CNF (Si : CNF = 97 : 3 중량비)를 이용한 전지의 용량은 1,947 mAh/g으로 다른 합성물보다 우수한 결과를 보였다. CNF 첨가량이 3 wt%에서 11 wt%로 증가함에 따라 용량 보존율이 84~77%로 안정성이 감소되었다. Si/C/CNF 합성소재 전극이 이차전지의 사이클 성능과 전기전도도를 개선할 수 있다는 것을 알 수 있었다.

• 수산해양기술연구
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• 제33권1호
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• pp.9-26
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• 1997

Stokes drift(SD) and Lagrangian discharge(LD) are important factors for analysis of flushing time, tidal exchange, solute transport and pollutant dispersion. The factors should be calculated using the approached method to flow phenomena. The aim of this paper re-examines the previous procedures for computing the SD and LD, and is to propose the new method approached to stratified flow field in the cross-section of coastal region, e.g. Masan Bay. The intensity of velocity near the bottom boundary layer(BBL) depends on the sea-bed irregularity in the coastal estuaries. So we calculated the depth mean velocity(DMV) considering that of BBL omitted in Kjerfve's calculation method. It revealed that BBL effect resulting in application of the bay acts largely on DMV in half more among 1l stations. The new expression of SD and LD per unit width in the cross-section using the developed DMV and proposed decomposition procedure of current were derived as follow : $$Q=u_0+\frac{1}{2}H_1{U_1cos(\varphi_h-\varphi_u)+U_3cos(\varphi_h-\varphi{ud})} LD ED SD$(Q_{skim}+Q_{sk2}) The third term, $Q_{sk2}$, on the right-hand of the equation is showed newly and arise from vertical oscillatory shear. According to the results applied in 3 cross-sections including 11 stations of the bay, the volume difference between proposed and previous SD was founded to be almost 2 times more at some stations. But their mean transport volumes over all stations are 18% less than the previous SD. Among two terms of SD, the flux of second term, $Q_{skim}$, is larger than third term, $Q_{sk2}$, in the main channel of cross-section, so that $Q_{skim}$ has a strong dependence on the tidal pumping, whereas third term is larger than second in the marginal channel. It means that $Q_{sk2}$ has trapping or shear effect more than tidal pumping phenomena. Maximum range of the fluctuation in LD is 40% as compared with the previous equations, but mean range of it is showed 11% at all stations, namely, small change. It mean that two components of SD interact as compensating flow. Therefore, the computation of SD and LD depend on decomposition procedure of velocity component in obtaining the volume transport of temporal and spacial flow through channels. The calculation of SD and LD proposed here can separate the shear effect from the previous SD component, so can be applied to non-uniform flow condition of cross-section, namely, baroclinic flow field.

• 한국수자원학회논문집
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• 제45권11호
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• pp.1157-1168
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• 2012

본 연구에서는 시간에 따른 수질 변화를 파악하고 원인에 따른 경향을 분석함으로써 적절한 관리대책을 수립하는 것이 필요하다고 생각되어 이 같은 연구를 하게 되었다. 현재 수질오염이 심각한 낙동강 수계를 대상으로 2006~2010년까지 수질변화를 분석하였다. 수계의 803개, 국가하천 13개소, 지방1급 하천은 10개소, 하천에 합류하는 하천은 31개 지점에서 측정한 수은, BOD(Biological Oxygen Demand), TN(Total Nitrogen)과 TP(Total Phosphorus) 등의 월평균 자료결과를 바탕으로 하여 통계적 분석(상관분석, 회귀분석, 분산분석, 시계열분석)을 통한 낙동강 유역의 인근 지역의 계절별로 수질항목을 확인하였으며, 평가지표에 따른 변화를 측정하고자 하였다. 유역의 지질 및 지형의 영향이 주로 작용하는데 지역의 기후조건, 식생, 지형, 토양, 비포화대 매질의 영향을 받기 때문에 여러가지의 변수를 가지고 유출했으며, 이는 방류량의 결정문제, 호소의 부영양화 문제 등이 제기될 수 있겠으며, 좋은 개선방안을 만들어보려고 한다. 따라서 낙동강의 강우기 유량을 증대하는 대책이 병행되는 것이 바람직하며, 물 관리 대책에는 하천유지용수 확보를 구성을 해야하며, 수로 건설사업 완료를 지속적인 관찰이 필요하다. 그러나 지류에는 물이 흐르지 않는 시기가 발생하는 이유는 자연 상태에서 흘러야 하는 하천수 및 공업용수와 농업용수로 취수했기 때문이다. 따라서 이모든 것을 관찰 및 구성을 하기 위해서는 지속적인 연구가 필요로 하며, 다음과 같은 연구의 목적을 두고 연구조사 하였다.

• 한국재료학회지
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• 제14권9호
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• pp.607-613
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• 2004

This study was to investigate the surface properties of electrochemically oxidized Ti-6Al-7Nb alloy by anodic spark discharge technique. Anodizing was performed at current density 30 $mA/cm^2$ up to 300 V in electrolyte solutions containing $DL-{\alpha}$-glycerophosphate disodium salt hydrate($DL-{\alpha}$-GP) and calcium acetate (CA). Hydrothermal treatment was done at $300^{\circ}C$ for 2 hrs to produce a thin outermost layer of hydroxyapatite (HA). The bioactivity was evaluated from HA formation on the surfaces in a Hanks' solution with pH 7.4 at $36.5^{\circ}C$ for 30 days. The size of micropores and the thickness of oxide film increased and complicated multilayer by increasing the spark forming voltage. Needle-like HA crystals were observed on anodic oxide film after the hydrothermal treatment at $300^{\circ}C$ for 2 hrs. When increasing $DL-{\alpha}$-GP in electrolyte composition, the precipitated HA crystals showed the shape of thick and shorter rod. However, when increasing CA, the more fine needle shape HA crystals were appeared. The bioactivity in Hanks' solution was accelerated when the oxide films composed with strong anatase peak with presence of rutile peak. The increase of amount of Ca and P was observed in groups having bioactivity in Hanks' solution. The Ca/P ratio of the precipitated HA layer was equivalent to that of HA crystal and it was closer to 1.67 as increasing the immersion time in Hanks' solution.

• 한국수자원학회논문집
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• 제43권12호
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• pp.1029-1038
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• 2010

우리나라는 기상학적으로 연중 총강수량의 약 2/3가 6~9월에 편중해서 내리고 있고, 지형적으로 국토의 70% 이상이 산지로 구성되어 경사가급해 수해를 입을 가능성이매우 크다. 또한 산업화 및 도시화로인해 불투수층의 증가로 강수량의 대부분이 직접유출로 기여해 강우초기에 노면상의 오염물질을 급속히 하천으로 이동시켜 오염을 가중시키고 있다. 특히 위락시설지역은 도시화에 따른 인구집중으로 지역민들에게 휴식공간 및 공원기능의 제공으로 비점오염원의 이동능력도 증가하여 수질관리가 절실히 필요하다. 따라서 본 연구는 위락시설지역의 비점오염원 유출특성분석을 위해 SOM(Self-Organizing Map) 이론을 도입하여 시험유역에서 측정된 유출 및 BOD, TOC자료에 대해 패턴분류를 수행하여 분할구역별 자료의 특성을 분석하였다. 그 결과 BOD 농도는 4개 TOC 농도는 각각 4개, 6개 분할구역으로 구분되었으며 BOD 농도의 경우 Cluster1과 Cluster2가 TOC 농도의 경우 Cluster4와 Cluster5가 비점오염원 유출 연구에 있어서 매우 중요한 요소인 초기강우 양상을 나타내었다. 또한 유출량 자료 수집과정에서 불가피하게 발생하는 이상치 자료를 정상적으로 측정된 수위와 유출량관계를 통해 추정된 회귀식을 이용하여 보완하여 이상치 자료를 활용하였다.

• 한국산학기술학회논문지
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• 제11권9호
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• pp.3336-3340
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• 2010

2007년1월1일부터 12월 31일까지 퇴원환자조사에서 제외되었던, 100병상미만 의료기관을 조사대상으로 선정하였다. 퇴원환자조사를 위해 조사 기반자료인 의무기록을 토대로 손상퇴원환자의 일반적 특성, 진료비지불방법, 질병 및 수술 양상과 의료이용 실태를 파악하였다. 2007년 한 해 동안 전국 100병상미만의 급성기 의료기관을 퇴원한 추정 환자 수는 총 4,697,095명으로 이는 전체 인구의 9.7%에 해당한다. 인구 10만 명당 퇴원 율은 9,693명이며 평균재원일수는 9.8일이었다. 퇴원후 귀가한 퇴원환자수는 전체 4,538,861명이었고 이중 남성은 1,784,041명, 여성은 2,754,821명이었다. 타병원으로 이송된 환자는 119,378명이었으며 의뢰병원으로 회송된 환자도 8,970명 이었다.이상과 같은 결과는 특정 손상에 대한 고위험군을 파악하고 중재가 필요한 곳을 확인하여 손상을 예방함으로써 공중보건비용을 줄이는 사업계획에 활용할 수 있으며, 지속적으로 수집되는 손상감시자료는 손상예방프로그램의 효율성을 감시 하고 평가하는데도 활용될 수 있다.

• Ocean and Polar Research
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• 제27권3호
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• pp.251-263
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• 2005

In order to study changes in the marine ecosystem of the East China Sea derived by the global warming and construction of the Three Gorges Dam in the middle of the Changjiang, temperature, salinity, nutrients, and chlorophyll-a were studied intensively in the northern part of the East China Sea during the summer of 2003 and spring of 2004. According to the previous studies, the upwelling of the Kuroshio Current and the Changjiang resulted in a major inputs of nutrients in the East China Sea, but these two inputs may not contribute gently to a build up of nutrients in the northern East China Sea. In spring, relatively high concentrations of nitrates and phosphates were observed in the western part of the study area, which resulted from the supply of high concentrations of nutrients showing up in the surface waters as a result of vertical mixing from the ocean bottom. The concentrations of nitrates and phosphates observed in summer were lower than those in spring, since the surface waters were well stratified by the larger discharge of fresh water from the Changjiang in summer. The surface nitrate/phosphate ratios ranged from 1.3 to 16 in spring and from 1.1 to 15 in summer and were lower than the Redfield ratio of 16, indicating that the growth of phytoplankton is limited by nitrogen. This results are contrary to the previous results, in which the growth of phytoplankton was limited by phosphate in the East China Sea. The reason for this contrary result is that most nutrients in the surface waters are supplied by vertical mixing from the bottom waters with low nitrate/phosphate ratios, not directly influenced by the Changjiang with high nitrate/phosphate ratios. The depth-integrated chlorophyll observed in summer was similar to the previous results, but those measured in spring were almost twice as high as those found in previous results. The depth-integrated chlorophyll in spring was higher than that of summer, which results from high concentrations of nitrates and phosphates in the surface waters in spring due to active vertical mixing.