• Korean Chemical Engineering Research
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• v.56 no.5
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• pp.694-704
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• 2018

Novel $SnO_2$ mixed biochar composite was prepared from banana peel developed as electrode material for supercapacitor using simple chemical co-precipitation method. The physiochemical and morphological properties of activated composite $SnO_2$ mixed biochar were investigated with XRD, FTIR, UV-vis, FESEM and HRTEM. The composite accounts for outstanding electrochemical behavior such as high specific capacitance, significant rate capability and leading to good cycle retention up to 3500 cycles when used as electrode material for supercapacitors. Highly permeable $SnO_2$ mixed biochar derived from banana peel exhibited maximum specific capacitance of $465F\;g^{-1}$ at a scan rate of $10mV\;s^{-1}$ by cyclic voltammetry (CV) and $476Fg^{-1}$ at current density of $0.15Ag^{-1}$ by charge discharge studies significantly higher about 47% than previously reported identical work on banana peel biochar.

• The Transactions of the Korean Institute of Electrical Engineers B
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• v.49 no.5
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• pp.352-357
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• 2000

This paper presents about an example of circuit design and characteristics of inverter according to the variable capacitance of the DC voltage source separation capacitor used in ZVS-HB type high frequency resonant inverter. The soft switching technology known as ZVS is used to reduce turn off loss at switching. In the event the capacitance of the DC voltage source separation capacitor is varied, the analysis of inverter circuit has generally described by using normalized parameter and operating characteristics have been evaluated in terms of switching frequency and parameters. According to the calculated characteristics value, a method of the circuit designs and operating characteristic of the inverter is also presented in this paper. In addition, this paper proves the validity of theoretical analysis through the experiment. This proposed inverter shows that it can be practically used in future as power source system for the lighting equipment of discharge lamp, DC-DC converter etc.

• Journal of Electrical Engineering and Technology
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• v.7 no.2
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• pp.207-211
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• 2012

Spinel-$Li_4Ti_5O_{12}$ was successfully synthesized by a solid-phase method at 800, 850, and $900^{\circ}C$ according to the $Li_4Ti_5O_{12}$ cubic spinel phase structure. To achieve higher EDLC energy density with the $Li_4Ti_5O_{12}$, the negative electrode of the hybrid supercapacitor was studied in this work. The electrochemical performances of the hybrid supercapacitor and EDLC were characterized by constant current discharge curves, c-rate, and cycle performance testing. The capacitance (1st cycle) of the hybrid supercapacitor and EDLC was 209 and 109 F, respectively, which is higher than EDLC. The capacitance of the hybrid supercapacitor decreases from 209 F to 101 F after 20 cycles when discharged at several specific current densities ranging from 1 to 10 A. In contrast, capacitance of the EDLC hardly decreases after 20 cycles. Results show that hybrid supercapacitor benefits from the high rate capability of supercapacitor and high capacity of the battery. Findings also prove that the hybrid supercapacitor is an energy storage device where the supercapacitor and the Li ion secondary battery coexist in one cell system.

• Journal of the Korean Society for Precision Engineering
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• v.22 no.4
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• pp.52-59
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• 2005

When a micro hole is machined by EDM with a cylindrical electrode, the hole diameter is different at the inlet and the outlet of the micro hole. The taper shape of the micro hole is caused by not only wear of the electrode but the eroded particles. The eroded particles cause secondary discharge during machining the micro hole. As a result, the diameter of the inlet becomes larger than that of the outlet. In this paper, a new method is proposed to reduce the difference in diameter between the inlet and the outlet of the hole. Observed was that the feed depth and machining time affect the formation of taper shape On this experimental basis, ultrasonic vibration was applied to reduce machining time, and capacitance was changed during machining to use the difference in discharging energy of different capacitances. Using the proposed method, a straight micro-hole was fabricated.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.214.1-214.1
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• 2011

In this work, the electrochemical properties of the surface treated multi-walled carbon nanotubes (MWNTs) are investigated for supercapacitors. Nitrogen- and oxygen functional groups containing MWNTs are prepared by nitrogen precursors and acidic treatment, respectively. The surface properties of the MWNTs are confirmed by X-ray photoelectron spectroscopy (XPS) and Zeta-potential measurements. The electrochemical properties of the MWNTs are investigated by cyclic voltammetry, impedance spectra, and charge-discharge cycling performance in 1 M $H_2SO_4$ at room temperature. As a result, these functionalized MWNTs lead to an increase in the specific capacitance as compared with the pristine MWNTs. It proposes that the pyridinic and pyridinic-N-oxides nitrogen species influence on the specific capacitance due to their positive charges, and thus an improved electron transfer at high current loads, since they are the most important functional groups affecting capacitive behaviors.

• Journal of Magnetics
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• v.1 no.2
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• pp.94-100
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• 1996

A hysteresis loop tracer using a pulsed high magnetic field of 113.4 kOe, which is suitable for rare earth based permanent magnets, is constructed. The high pulsed magnetic field is generated by discharging a large capacitance charge (5 mF) with a voltage of 600 V into an air solenoid with the inner diameter of 14 mm, outer diameter of 36 mm and the lingth of 34 mm. A computer simulation method is used for the construction of an electromagnet to optimize the many parameters such as the discharge current, generated pulsed magnetic field intensity, thermal dissipation, capacitance, charged voltage, period of damping oscillation and solenoid geometry. By using the hysteresis loop tracer constructed in this work, we are able to measure hystersis loops of several rare earth based permanent magnets with large values of the remanent magnetization, coercvity and energy product.

• Carbon letters
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• v.12 no.4
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• pp.252-255
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• 2011

Carbon-based electric double-layer capacitors are being evaluated as potential energy-storage devices in an expanding number of applications. In this study, samples of carbon black (CB) treated at different temperatures ranging from $650^{\circ}C$ to $1100^{\circ}C$ were used as electrodes to improve the efficiency of a capacitor. The surface properties of the heat-treated CB samples were characterized by X-ray photoelectron spectroscopy and X-ray diffraction. The effect of the heat-treatment temperature on the electrochemical behaviors was investigated by cyclic voltammetry and in galvanostatic charge-discharge experiments. The experimental results showed that the crystallinity of the CBs increased as the heat-treatment temperature increased. In addition, the specific capacitance of the CBs was found to increase with the increase in the heat-treatment temperature. The maximum specific capacitance was 165 $F{\cdot}g-1$ for the CB sample treated at $1000^{\circ}C$.

• Carbon letters
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• v.9 no.2
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• pp.137-144
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• 2008

The commercial activated carbons are typically prepared by activation from coconut shell char or coal char containing lots of inorganic impurities. They also have pore structure and pore size distribution depending on nanostructure of precursor materials. In this study, two types of commercial activated carbons were applied for EDLC electrode by removing impurities with acid treatments, and controlling pore size distribution and contents of functional group with heat treatment. The effect of the surface functional groups on electrochemical performance of the activated carbon electrodes was investigated. The initial gravimetric and volumetric capacitance of coconut based activated carbon electrode which was acid treated by $HNO_3$ and then heat treated at $800^{\circ}C$ were 90 F/g and 42 F/cc respectively showing 94% of charge-discharge efficiency. Such a good electrochemical performance can be possibly applied to the medium capacitance of EDLC.

• 한국정보디스플레이학회:학술대회논문집
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• 2003.07a
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• pp.768-770
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• 2003

In AC PDP, since charges generated by gas discharge are accumulated on the dielectric. The dielectric is a major factor to determine cell capacitance and its memory effect is a play an important role in PDP driving. In this experiment, we have investigated the electro-optical characteristics with dielectric thickness and we have analyzed wall charge and wall voltage by Q-V energy diagram. The dielectric thickness was varied from 20 um to 50 um. As results, according to the dielectric thickness increase,cell capacitance and power consumption is reduced.

• ETRI Journal
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• v.38 no.2
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• pp.252-259
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• 2016

Di(1-aminopyrene)quinone (DAQ) as a quinone-containing conducting additive is synthesized from a solution reaction of 1-aminopyrene and hydroquinone. To utilize the conductive property of DAQ and its compatibility with activated carbon, a composite electrode for a supercapacitor is also prepared by blending activated carbon and DAQ (3:1 w/w), and its supercapacitive properties are characterized based on the cyclic voltammetry and galvanostatic charge/discharge. As a result, the composite electrode adopting DAQ exhibits superior electrochemical properties, such as a higher specific capacitance of up to $160F{\cdot}g^{-1}$ at $100mV{\cdot}s^{-1}$, an excellent high-rate capability of up to $1,000mV{\cdot}s^{-1}$, and a higher cycling stability with a capacitance retention ratio of 82% for the 1,000th cycle.