• Title/Summary/Keyword: Discharge Properties

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Characterization of Concrete Composites with Mixed Plastic Waste Aggregates (복합 폐플라스틱 골재 치환 콘크리트의 기초 물성 평가)

  • Lee, Jun;Kim, Kyung-Min;Cho, Young-Keun;Kim, Ho-Kyu;Kim, Young-Uk
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.3
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    • pp.317-324
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    • 2020
  • Plastic wastes generated from domestic waste are separated by mixed discharge with foreign substances, and the cost of the separation and screening process increases, so recycling is relatively low. In this study, as a fundamental study for recycling mixed plastic wastes generated from domestic waste into concrete aggregates, changes in concrete properties according to the plastic waste types and the substitution rate were evaluated experimentally. The mixed plastic waste aggregate(MPWA) was found to have a lower density and a higher absorption rate compared to the coarse aggregate with good particle size distribution. On the other hand, the single plastic waste aggregate(SPWA) was composed of particles of uniform size, and both the density and the absorption rate were lower than that of the fin e aggregate. It was found that the MPWA substitution concrete did not cause a material separation phenomenon due to a relatively good particle size distribution even with the largest amount of plastic waste substitution, and the amount of air flow increased little. The compressive strength and flexural strength of the PWA substitution concrete decreased as the amount of substitution of the PWA increased due to the low strength of the PWA, the suppression of the cement hydration reaction due to hydrophobicity, and the low adhesion between the PWA and the cement paste. It was found that the degree of deterioration in compressive strength and flexural strength of concrete substituted with MPWA having good particle size distribution was relatively small.

The Effect of Calcination Temperature on the Layered Li1.05Ni0.9Co0.05Ti0.05O2 for Lithium-ion Battery (리튬이온전지용 층상 Li1.05Ni0.9Co0.05Ti0.05O2에 대한 소성 온도의 영향)

  • Ko, Hyoung Shin;Park, Hyun Woo;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.56 no.5
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    • pp.718-724
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    • 2018
  • In this study, the $Ni_{0.9}Co_{0.05}Ti_{0.05}(OH)_2$ precursor was prepared by the concentration gradient co-precipitation method. In order to overcome the structural change due to oxygen desorption in the cathode active material with high nickel content, the physical and electrochemical analysis of the cathode active material according to the calcination temperature were investigated. Physical properties of $Li_{1.05}Ni_{0.9}Co_{0.05}Ti_{0.05}O_2$ were analyzed by FE-SEM, XRD and TGA. The electrochemical performance of the coin cell using a cathode active material and $LiPF_6$(EC:EMC=1:2 vol%) electrolyte was evaluated by the initial charge/discharge efficiency, cycle retention, and rate capabilities. As a result, the initial capacity and initial efficiency of cathode materials were excellent with 244.5~247.9 mAh/g and 84.2~85.8% at the calcination temperature range of $750{\sim}760^{\circ}C$. Also, the capacity retention exhibited high stability of 97.8~99.1% after 50cycles.

Prediction of a Debris Flow Flooding Caused by Probable Maximum Precipitation (가능 최대강수량에 의한 토석류 범람 예측)

  • Kim, Yeon-Joong;Yoon, Jung-Sung;Kohji, Tanaka;Hur, Dong-Soo
    • Journal of Korea Water Resources Association
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    • v.48 no.2
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    • pp.115-126
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    • 2015
  • In recent years, debris flow disaster has occurred in multiple locations between high and low mountainous areas simultaneously with a flooding disaster in urban areas caused by heavy and torrential rainfall due to the changing global climate and environment. As a result, these disasters frequently lead to large-scale destruction of infrastructures or individual properties and cause psychological harm or human death. In order to mitigate these disasters more effectively, it is necessary to investigate what causes the damage with an integrated model of both disasters at once. The objectives of this study are to analyze the mechanism of debris flow for real basin, to determine the PMP and run-off discharge due to the DAD analysis, and to estimate the influence range of debris flow for fan area according to the scenario. To analyse the characteristics of debris flow at the real basin, the parameters such as the deposition pattern, deposit thickness, approaching velocity, occurrence of sediment volume and travel length are estimated from DAD analysis. As a results, the peak time precipitation is estimated by 135 mm/hr as torrential rainfall and maximum total amount of rainfall is estimated by 544 mm as typhoon related rainfall.

Effects of DBD-bio-plasma on the HSP70 of Fibroblasts: A New Approach on Change of Molecular Level by Heat Shock in the Cell (Fibroblasts 세포주의 HSP70에 대한 DBD-bio-plasma의 effects: Cell에서 Heat Shock에 의한 Molecular Level 변화로의 새로운 접근법)

  • Kim, Kyoung-Yeon;Yi, Junyeong;Nam, Min-Kyung;Choi, Eun Ha;Rhim, Hyangshuk
    • KSBB Journal
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    • v.30 no.1
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    • pp.21-26
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    • 2015
  • Plasma is an ionized gas mixture, consisting of neutral particles, positive ions, negative electrons, electronically excited atoms and molecules, radicals, UV photons, and various reactive species. Also, plasma has unique physical properties distinct from gases, liquids, and solids. Until now, non-thermal plasmas have been widely utilized in bio-medical applications (called bio-plasma) and have been developed for the plasma-related devices that are used in the medical field. Although numerous bio-plasma studies have been performed in biomedicine, there is no confirmation of the nonthermal effect induced by bio-plasma. Standardization of the biological application of plasma has not been evaluated at the molecular level in living cells. In this context, we investigated the biological effect of bio-plasma on living cells. Hence, we treated the fibroblasts with Dielectric Bauvier Discharge bio-plasma (DBD), and assessed the characteristic change at the molecular level, one of the typical cellular responses. Heat shock protein 70 (HSP70) regulates its own protein level in response to stimuli. HSP70 responds to heat shock by increasing its own expression at the molecular level in cells. Hence, we confirmed the level of HSP70 after treatment of mouse embryonic fibroblasts (MEFs) with DBD. Interestingly, DBD-plasma induced cell death, but there was no difference in the level of HSP70, which is induced by heat shock stimuli, in DBD-treated MEFs. Our data provide the basic information on the interaction between MEFs and DBD, and can help to design a molecular approach in this field.

Effect of Calcination Temperatures on the Structure and Electrochemical Characterization of Li(Ni0.5Mn0.3Co0.2)O2 as Cathode Material by Supercritical Hydrothermal Synthesis Method (초임계 수열법으로 합성한 Li(Ni0.5Mn0.3Co0.2)O2 양극 활물질의 소성 온도영향에 따른 구조 및 전기화학적 특성)

  • Choo, Soyeon;Beom, YunGyeong;Kim, Sungsu;Han, Kyooseung
    • Journal of the Korean Electrochemical Society
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    • v.16 no.3
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    • pp.151-156
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    • 2013
  • As the cathode material for li-ion battery, $LiNi_{0.5}Mn_{0.3}Co_{0.2}O_2$ were synthesized by supercritical hydrothermal method and calcined $850^{\circ}C$ and $900^{\circ}C$ for 10hrs in air. The effect of temperature in the heat treatment on the powder and its performance were studied of xray diffraction pattern, SEM-image, physical properties and electrochemical behaviors. As a result, calcined at $900^{\circ}C$ material particle size more increase than calcined at $850^{\circ}C$ material, especially shows excellent electrochemical performance with initial reversible specific capacity of 163.84 mAh/g (0.1C/2.0-4.3V), 186.87 mAh/g (0.1C/2.0-4.5V) and good capacity retention of 91.49% (0.2C/2.0-4.3V) and 90.36% (0.2C/2.0-4.5V) after 50th charge/discharge cycle.

Estimation of Groundwater Flow Rate into Jikri Tunnel Using Groundwater Fluctuation Data and Modeling (지하수 변동자료와 모델링을 이용한 직리터널의 지하수 유출량 평가)

  • Lee, Jeong-Hwan;Hamm, Se-Yeong;Cheong, Jae-Yeol;Jeong, Jae-Hyeong;Kim, Nam-Hoon;Kim, Ki-Seok;Jeon, Hang-Tak
    • Journal of Soil and Groundwater Environment
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    • v.14 no.5
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    • pp.29-40
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    • 2009
  • In general, understanding groundwater flow in fractured bedrock is critical during tunnel and underground cavern construction. In that case, borehole data may be useful to examine groundwater flow properties of the fractured bedrock from pre-excavation until completion stages, yet sufficient borehole data is not often available to acquire. This study evaluated groundwater discharge rate into Jikri tunnel in Gyeonggi province using hydraulic parameters, groundwater level data in the later stage of tunneling, national groundwater monitoring network data, and electrical resistivity survey data. Groundwater flow rate into the tunnel by means of analytical method was estimated $7.12-74.4\;m^3/day/m$ while the groundwater flow rate was determined as $64.8\;m^3/day/m$ by means of numerical modeling. The estimated values provided by the numerical modeling may be more logical than those of the analytical method because the numerical modeling could take into account spatial variation of hydraulic parameters that was not possible by using the analytical method. Transient modeling for a period of one year from the tunnel completion resulted in the recovery of pre-excavation groundwater level.

A study for High Efficiency Dewatering of Sludge Contained Fine Particles (미세입자(微細粒子)를 함유(含有)한 슬러지의 고효율(高效率) 탈수(脫水) 연구)

  • Lee, Jung-Eun;Lee, Jae-Keun
    • Resources Recycling
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    • v.15 no.4 s.72
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    • pp.36-43
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    • 2006
  • There was some difficulty dewatering properties due to small porosity diameter of cake, when pigment sludge contained fine particle was formed by cake under the dewatering. It was difficult to dewater the sludge with fine particles with the conventional mechanical dewatering method. This study was to improve the dewatering rate as discharging the water from porosity of cake easily, supplying the low heat to the cake layer. Thermal dewatering equipment of piston type to keep up constant temperature on the cake was set up and relative experiment was conducted for sludge of 200 g with fine pigment particle. As test results. filtration of 176.8 g, cake weight of 19.4 g, cake thickness of 4.2 mm was measured, and it was analyzed that the water content of cake was 47 wt% and dewatering velocity, which moaned the residual d교 sloid amount per dewatering area, was $2.1DS\;m^{2}{\cdot}cycle$. This results showed that filtration increased, cake weight and thickness decreased and dewatering velocity increased against mechanical dewatering method. And water content of cake decreased about 30%, so the result which dewatering rate improved was drew generally. The reason is that the inner vapor pressure working at the cake porosity increased as applying the low heat to the cake layer, which lead to discharge the water from porosity easily. Therefore, this study was estimated by the useful technology for sludge reduction.

Clincal Effect of Ketotifen in Allergic Rhinitis (알레르기성 비염에 대한 Ketotifen($Zaditen^{(R)}$)의 임상적 효과)

  • Eun, Sun-Jin;Kim, Yang-Dae;Park, Mun-Heum;Suh, Jang-Su;Song, Kei-Won
    • Journal of Yeungnam Medical Science
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    • v.7 no.1
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    • pp.105-112
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    • 1990
  • Ketotifen, a benzocycloheptathiophene, has an orally effective antiallergic as well as antihistaminic properties. In pervious studies, Ketotifen has shown encouraging results in patient with allergic rhinitis, either perennial or seasonal. 39 patients with allergic rhinitis had been treated with Ketotifen 1 mg twice daily for 8 weeks. And we obtained following results. 1) The efficacy rate in sneezing attack was 73.5%, in nasal discharge 71%, in nasal obstruction 58%. 2) Some improvements in at least one of three major symptoms were noted within 1 week in 30.7%, within 2 weeks in 55.8%, within 3 weeks in 66.7%, within 8 weeks in 87.2%. 3) Physical findings such as colour, swelling of turbinate, character of rhinorrhea were not improved significantly. 4) Side effect was observed only in one patient with abdominal pain and diarrhea, which was subsided after interruption of administration. These results suggested that Ketotifen was effective in treatment of allergic rhinitis.

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Synthesis and Characterization of IPA-co-HDO-co-(TPA/MA) Anion-Exchange Membrane for All-Vanadium Redox Flow Battery (전바나듐계 레독스-흐름 전지용 IPA-co-HDO-co-(TPA/MA) 음이온교환막의 합성 및 특성)

  • Jung, Jae-Chul;Kwak, Noh-Seok;Hwang, Taek-Sung
    • Polymer(Korea)
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    • v.35 no.6
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    • pp.593-598
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    • 2011
  • The IPA-co-HDO-co-(TPA/MA) copolymers for all-vanadium redox flow battery were synthesized by melt condensation polymerization using isophthalic acid(IPA), 1,6-hexandiol (HDO), terephthalic acid(TPA) and maleic anhydride(MA). The amination of chloromethylated IPA-co- HDO-co-(TPA/MA)(CIHTM) copolymer was carried out using trimethylamine, and the anion exchange membrane was also prepared by UV crosslinking reaction. The structure and thermal stability of IHTM copolymers were confirmed by FTIR, $^1H$ NMR, and TGA analysis. The anion membrane properties such as water uptake, ion exchange capacity, electric resistance and electrical conductivity, were measured by gravimetry, titration and LCR meter. The efficiency of the all-vanadium redox flow battery was analyzed. The ion exchange capacity, electric resistance and electrical conductivity were 1.10 meq/g, $1.98{\Omega}{\cdot}cm^2$, and 0.009 S/cm, respectively. The efficiency of charge-discharge, voltage, and energy for the allvanadium redox flow battery were 96.5, 74.6, 70.0%, respectively.

Electrochemical Properties of Boron-doped Cathode Materials (LiNi0.90Co0.05Ti0.05O2) for Lithium-ion Batteries (붕소가 도핑된 리튬이온전지용 양극 활물질(LiNi0.90Co0.05Ti0.05O2)의 전기화학적 특성)

  • Kim, Geun Joong;Park, Hyun Woo;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.57 no.6
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    • pp.832-840
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    • 2019
  • To improve the electrochemical performances of the cathode materials, boron-doped $LiNi_{0.90}Co_{0.05}Ti_{0.05}O_2$ were synthesized by using concentration gradient precursor. The characteristics of the prepared cathode materials were analyzed by XRD, SEM, EDS, PSA, ICP-OES and electrical conductivity measurement. The electrochemical performances were investigated by initial charge/discharge capacity, cycle stability, C-rate, cyclic voltammetry and electrochemical impedance spectroscopy. The cathode material with 0.5 mol% boron exhibited a capacity of 187 mAh/g (0.5 C) in a voltage range of 2.7~4.3 V(vs. $Li/Li^+$), and an capacity retention of 94.7% after 50 cycles. In the relatively high voltage range of 2.7~4.5 V(vs. $Li/Li^+$), it showed a high capacity of 200 mAh/g and capacity retention of 80.5% after 50 cycles.