• Journal of the Korean Chemical Society
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• v.59 no.5
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• pp.413-422
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• 2015

Proton exchange membrane (PEM), which transfers proton from the anode to the cathode, is the key component of the proton exchange membrane fuel cell (PEMFC). Nafion is widely used as PEM due to its high proton conductivity as well as excellent chemical and physical stabilities. However, its high cost and the environmental hazards limit the commercial application in PEMFCs. To overcome these disadvantages, various alternative polymer electrolytes have been investigated for fuel cell applications. We used densely sulfonated polymers to maximize the ion conductivity of the corresponding membrane. To overcome high swelling, dipole-dipole interaction was used by introducing nitrile groups into the polymer backbone. As a result, physically-crosslinked membranes showed improved swelling ratio despite of high water uptake. All the membranes with different hydrophilic-hydrophobic compositions showed higher conductivity, despite their lower IEC, than that of Nafion-117.

• Korean Journal of Optics and Photonics
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• v.11 no.1
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• pp.1-5
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• 2000

We define the basic minimal coupling Hamiltonian of the atomic systems in the Coulomb guage and show that this Hamiltonian yields the correct equations of motion for the operators of interest. Using the unitary transformation and making the dipole approximation, we calculate the effect of polarization of the dipoles on the interaction Hamiltonian of the system. ystem.

• Applied Chemistry for Engineering
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• v.10 no.3
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• pp.456-460
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• 1999

The YHB radial distribution functions of a linear gas molecule CO were calculated by a computer within the Stockmayer molecular potential molel, which assumed thc CO molecule as a simple dipolar molecule. To examine the validity of the obtained YHB radial distribution of CO gas molecule, the density dependent pressures of CO at several temperatures were also calculated. The calculated pressures showed a good agreement with literially known experimental CO pressure data. The temperatures examined were 273, 298, and 373 K and the densities were up to $0.013/{\AA}^3$ (maximum pressure = 1000 atm). Since the calculated pressures showed a good agreement with the experimental values, the obtained YHB radial distribution functions of CO molecule seemed good enough to obtain and predict various equilibrium physical and chemical quantities of CO molecule sensitive to density such as pressure. It was also found that in CO gas system the dipole-dipole interaction is effective up to approximately 2.5 molecular diameter.

• Transactions of the Korean Society of Mechanical Engineers
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• v.18 no.3
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• pp.584-590
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• 1994

A theoretical model has been developed to analyze the jet-edge interaction and the sound radiation. The edge responding to the sinuous impinging jet is regarded as an array of dipoles and their strength is determined by the boundary condition on the edge surface. The surface pressure distribution and the edgeforce are estimated using these dipoles. Then the pressure amplitude and directivity of the sound field is obtained by summing the radiating sounds from the dipole sources. It is found that the effective source is located a little distance downstream from the edge tip. And the directivity of the sound radiation is cardioid pattern near the edge but dipole pattern far from the edge. The theoretical model is confirmed by comparing the theoretical prediction of the edgeforce and sound pressure level with available experimental data.

• Polymer(Korea)
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• v.24 no.6
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• pp.787-793
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• 2000

The acrylonitrile copolymer/dimethylformamide (DMF) solutions were prepared to investigate the gelation behavior and critical gel concentration (c＊). Gelation is rapidly progressed with the increase of molecular weight of copolymer, but significantly delayed with supercooling temperature and comonomer contents. The c＊ behavior showed contrary trend against gelation behavior. In dynamic viscoelastic test, two glass-transition region were observed in film obtained from gelled solution whereas one glass-transition in film obtained from true solution. This result supports the idea that an ordered junction zone is formed by the dipole-dipole interaction of intermolecularly neighboring stereo-regular parts of atactic acrylonitrile copolymer chains due to a nucleation process in the solution.

• 한국지구과학회:학술대회논문집
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• 2010.04a
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• pp.53-53
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• 2010

지표위의 어떤 지점에서의 지구자기의 수평분력 방향과 진북방향 사이의 각을 편각(Declination)이라고 정의한다. 쉽게 말하면 편각은 나침반의 자침이 가러 키는 방향과 진북방향과의 사이 각을 말한다. 대부분의 사람들은 나침반의 자침이 북자기극(North magnetic pole)을 가러킨다고 잘못알고 있다. 지구 다이나모설(Geodynamo theory)에 의하면 주로 철(약 90%)로 구성된 외핵 속에서 계속 생성 유지되고 있는 복잡한 (각각 나선형(helical)의 회전축에 대체로 평행하거나 평행하지 않은) 대류(Convection currents)에 수반하는 전류가 복잡한 지구자기장을 형성한다. 지표상에서 측정한 지구자기장의 자료를 Spherical harmonic analysis 으로 분석하면 한 개의 커다란 쌍극자(Dipole) (Inclined geocentric dipole 또는 주된 자기장(Main field) 이라고 부름), 적도쌍극자(Equatorial dipole), 4극자 (Quadrupoles), 8극자(Octupoles) 등의 여러 개의 크고 작은 쌍극자들의 총합이 지구자기장의 근원인 것처럼 해석되고 있다. 어떤 지점에서의 지구자기장의 방향은 외핵에서 생성된 천체 자기장에서 Main field를 제거한 나머지 자기장과, 상부 맨틀(upper mantle), 지각 및 지표상에 존재하는 인공 물체 또는 암석 및 광석 등의 잔류자기 및 유도자기 그리고 지형 등의 영향으로 결정된다. 어떤 지점에서의 지구자기장의 방향은 태양풍(Solar wind)과 전리층 사이의 상호작용 등의 외부자장(external field)의 영향도 받는다. 비쌍극자 자장(Non-dipole field)은 지표상에서 측정되는 총자기장에서 외핵에서 생성된 주된 자기장(Main field) 즉, 지구의 회전축에서 약 11.5도 기울어진 쌍극자 자장을 제거하고 남는 자기장을 말한다. 따라서 편각은 비쌍극자자장의 영향을 가장 많이 받는다. 비쌍극자 자장은 정지한 상태의 자장(standing field) 과 매년 서쪽으로 약 0.2도 움직이는 Westward drift하는 자장으로 크게 두 가지로 구분된다. 쌍극자 자장의 방향은 매우 느리게 변하지만 그 세기는 현재 비교적으로 빠르게 약해지고 있다. 비교적으로 매우 빠르게 변하는 비쌍극자 자장의 변화를 영년변화(Secular variation) 이라고 한다.

• Polymer(Korea)
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• v.25 no.5
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• pp.671-678
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• 2001

Sodium and zinc salts of poly(ethyaene-co-methacrylic acid) ionomers consist of three phases, i.e. ionic aggregates, amorphous, and crystalline phases. Dye molecules after soaked from the methanol solution are located near the amorphous phase or ionic aggregates within ionomer films. Depending on the location of the molecules in the ionomer film, they are under influence of dispersion forces (ethylene parts), polar forces (acid parts). and ionic dipole (ionic aggregates) interactions. The UV/Vis absorption peak of Nile Red under the dispersion force is found at near 500 nm, for the dye under the polar force effect 525 nm, and 550 and 610 nm for the dyes under $Na^+$ and $Zn^{2+}$ ionization effects, respectively. Since the divalent $Zn^{2+}$ ion has larger ionic dipole than the monovalent $Na^+$ ion, the larger red-shift of the absorption band due to the ionic dipole interaction is observed for $Zn^{2+}$ counter ion.

• Journal of the Korean Society for Nondestructive Testing
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• v.24 no.3
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• pp.259-267
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• 2004

A finite element method is used to simulate interaction of laser-based ultrasounds with surface breaking tracks in elastic media. The laser line source focused on the surface of semi-infinite medium is modeled as a shear dipole in 2-D plane strain finite elements. The shear dipole-finite clement model is found to give correct directivity patterns for generated longitudinal and shear waves. The interaction of surface waves with surface breaking cracks (2-D machined slot) is considered in two ways. Both the source and receiver are fixed with respect to the cracks in the first case, while the source is moving in another case. It is shown that the crack depth tested in the range of 0.3-5.0mm $({\lambda}_R/d=0.21{\sim}3.45)$ can be measured using the corner reflected waves produced by the fixed laser source. The moving laser source is found to cause a large amplitude change of reflected waves near crack, and the crack whose depth is one order lower than the wavelength ran be detected from this change.

• Journal of KSNVE
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• v.7 no.2
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• pp.215-222
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• 1997

The flow and acoustic fields due to a vortex ring interaction with a rigid sphere are simulated numerically. The flow field is regarded as three-dimensional inviscid and incompressible. The vorticity is assumed to be concentrated inside the finite core of vortex filament. The vortex filament curve, described by parabolic blending curve function, is used to effectively solve the modified Biot-Savart equation. The interaction between a vortex ring and a rigid sphere using the parabolic blending curve is calculated. The trajectory of the vortex ring is obtained with several different initial positions between the ring and the sphere. The force variations acting on the sphere are calculated by using the boundary integral method. Finally, we can also obtain the acoustic signals at the far field observation positions from the force variations acting on the rigid surface. We can find that the dipole axis of the directivity patterns are rotated during the interacting phenomena.

• Nuclear Engineering and Technology
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• v.4 no.4
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• pp.294-300
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• 1972

CNDO/2 and INDO calculations have been carried out on varying geometries of methyl chloro-and fluoro-formates. Results show that the configuration in which halogen atom is trans to methyl group is the most stable. Atomic charges and overlap population show that the trans form is stabilized by conjugation of carbonyl double bend with the unshared pairs of the ether oxygen and by electrostatic attraction of carbonyl oxygen to methyl group. Dipole moments of the trans forms agree reasonably well with the experimental values but showed that any generalizations made with dipole moments from bond moments should be accepted with considerable reservations.