• Journal of the Korean Chemical Society
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• v.22 no.4
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• pp.229-238
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• 1978

Two methods for evaluation of the dipole moment matrix elements are developed, one using the expansion method for spherical harmonics and the other the transformation method of the dipole moment matrix elements into overlap integrals for Mulliken. The numerical values of the dipole moment matrix elements evaluated by two methods are in agreement with each other.

• Bulletin of the Korean Chemical Society
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• v.6 no.3
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• pp.158-162
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• 1985

The dipole moment derivatives of $NH_3$ are reexamined based on our recent intensity data. We have resolved the previous contradiction in the proper signs for the dipole moment derivatives of this molecule.

• Journal of Photoscience
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• v.12 no.2
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• pp.57-61
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• 2005

The ground and excited state dipole moments of Coumarin 450 (C 450) laser dye were measured at room temperature in several solvents of varying dipole moments. The ground state dipole moment (${\mu}_g$) is estimated by using the modified Onsagar model and the excited state dipole moments (${\mu}_e$) were estimated by the method of solvatochromism as well as by utilizing the microscopic solvent polarity parameter ($E^N_T$). Further, the deviation of some of the points from the linearity of the $E^N_T$ versus Stokes shift indicates the existence of specific type of solute-solvent interaction. The excited state dipole moment of C 450 were found to be higher than those of the ground state and is interpreted in terms of the resonance structure of the molecule. A reasonable agreement has been observed between the values obtained by the method of solvatochromism and modified Onsagar model. It is observed that, corresponding to cyclohexane solution, the fluorescence maxima shift towards the red region with increasing the polarity of the solvents, hence the transition involved are of ${\pi}-{\pi}^*$ type.

• Bulletin of the Korean Chemical Society
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• v.5 no.1
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• pp.3-16
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• 1984

The effect of solvent on the dipole moments for (chloromethyl) stannanes has been investigated by applying EHT calculation for the isomers of trigonal bipyramidal Sn(Ⅳ)$Cl_4X$ and $Cl_n$Sn(Ⅳ) $(CH_2Cl)_{4-n}$, octahedral Sn(Ⅳ)$Cl_42X$ and $Cl_nSn$(Ⅳ)$(CH_2Cl)_{4-n}$ 2X type complexes in dioxane and ethylacetate solutions (X: dioxane or ethylacetate). For Sn(Ⅳ)$Cl_4$ in dioxane solution, the calculated dipole moment for the trigonal bipyramidal Sn(Ⅳ)$Cl_4X$ type complex [isomer (b)] is closer to the experimental dipole moment than octahedral Sn(Ⅳ)$Cl_4X$2X type complexes. This calculated dipole moment suggests that Sn(Ⅳ)$Cl_4X$ may have the trigonal bipyramidal structure in dioxane solution. However, the calculated dipole moment for octahedral $Cl_3$Sn(Ⅳ) ($CH_2$Cl)2X type complex [Isomer (d)], ClSn(Ⅳ)(CH2Cl)32X type complex [Isomer(k)] and Cl2Sn(Ⅳ)(CH2Cl)22X type complex [Isomer(h)] are closer to the experimental dipole moments than other isomers for octahedral complexes and trigonal bipyramidal complexes. Such theoretical results indicate that $Cl_3Sn$(Ⅳ )($CH_2Cl$), ClSn(Ⅳ)$(CH_2Cl)_3$ and $Cl2Sn$(Ⅳ)$(CH_2Cl)_2$ complexes may have octahedral structures, Isomer(d), (k) and (h) in ethylacetate solution, respectively.

• Bulletin of the Korean Chemical Society
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• v.7 no.5
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• pp.380-384
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• 1986

The infrared intensities of $CH_{4}$ and $CD_{4}$ are analyzed. The experimental dipole moment derivatives thus obtained are compared with corresponding values from the molecular orbital calculations. The theoretical results are analyzed for the charge-charge flux-overlap(CCFO) electronic contributions to the dipole derivatives.

• Journal of Astronomy and Space Sciences
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• v.36 no.3
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• pp.181-186
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• 2019

The attitude information of spacecraft can be obtained by the sensors attached to it using a star tracker, three-axis magnetometer, three-axis gyroscope, and a global positioning signal receiver. By using these sensors, the spacecraft can be maneuvered by actuators that generate torques. In particular, electromagnetic-torque bars can be used for attitude control and as a momentum-canceling instrument. The spacecraft momentum can be created by the current through the electrical circuits and coils. Thus, the current around the electromagnetic-torque bars is a critical factor for precisely controlling the spacecraft. In connection with these concerns, a solar-cell array can be considered to prevent generation of a magnetic dipole moment because the solar-cell array can introduce a large amount of current through the electrical wires. The maximum value of a magnetic dipole moment that cannot affect precise control is $0.25A{\cdot}m^2$, which takes into account the current that flows through the reaction-wheel assembly and the magnetic-torque current. In this study, we designed a 300-W solar cell array and presented an optimal wire-routing method to minimize the magnetic dipole moment for space applications. We verified our proposed method by simulation.

• The Transactions of the Korean Institute of Electrical Engineers B
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• v.51 no.11
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• pp.616-621
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• 2002

With biological effects by ELF (Extremely Low Frequency) magnetic field generated from power system, the transient magnetic field from electric appliances is a major issue presently. Because the transient magnetic field induces higher current than the power frequency field inside living bodies, transient magnetic field exposure has been much focused. In this paper, it is shown that transient magnetic field from electric home appliances can be characterized as magnetic dipole moment. In this method, the dipole moment vector is assumed by allowing an uncertainty of 6dB in the estimated field. A parameter M that represents biological interaction was applied also. The proposed method was applied to 7 types of appliances (hair drier, heater, VDT, etc.) and their equivalent magnetic dipole moment and harmonic components were estimated. As the results, the useful data for quantifying magnetic field distribution around electric appliances were obtained.

• The Proceeding of the Korean Institute of Electromagnetic Engineering and Science
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• v.1 no.1
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• pp.28-34
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• 1990

In this paper we discussed the theoretical antenna factor of a cylinderical dipole antenna. The Current distribution on a dipole antenna was analyzed by the method of moment, and this solu- tion is used for calculating the effective length and antenna factor of the half-wave dipole in free space.

• Bulletin of the Korean Chemical Society
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• v.8 no.1
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• pp.10-15
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• 1987

The results of an ab initio (6-31G) molecular orbital calculation of the dipole moment derivatives and gas phase IR intensities of difluoromethane are reported. The results are compared with corresponding values obtained from a CNDO calculation. The directions of the dipole derivatives calculated by the two methods agree very well, whereas the intensities differ significantly. The results are also analyzed for the charge-charge flux-overlap electronic contributions to the dipole derivatives.

• Journal of the Korean Institute of Telematics and Electronics
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• v.15 no.2
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• pp.15-18
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• 1978

The impedance step up ratio and variations of input admittances of the folded dipole antenna are calculated by the moment method. The results are compared with those calculated by Guertler's formula. The input admittance of the folded dipole antenna has the maximum value at the frequency somewhat lower than the resonance frequency and its susceptance which has periodic properly is null lot several different frequencies if radius ratio of two elements is not very large. Frequency characteristic of folded dipole antenna is improved when its radius ratio is increased.