• 대한수학회지
• /
• 제50권4호
• /
• pp.899-916
• /
• 2013

We develop a version of dipolar conformal field theory in a simply connected domain with the Dirichlet-Neumann boundary condition and central charge one. We prove that all correlation functions of the fields in the OPE family of Gaussian free field with a certain boundary value are martingale-observables for dipolar SLE(4).

• 한국자기공명학회논문지
• /
• 제3권2호
• /
• pp.127-139
• /
• 1999

In this paper we discussed how multiple quantum coherences evolve in the presence of anisotropic distribution of dipolar couplings. The magnitude of dipolar couplings were varied by changing the tile angle of crystal axis. The stronger was dipolar coupling, the higher was frequency of multiple quantum coherence. That is, the order of multiple quantum coherence varies in proportion to the magnitude of dipolar couplings. The theoretical prediction for the multiple quantum coherence at magic angle 54.7$^{\circ}$ in solid NMR spectroscopy was verified in this study. The excitation pattern of n-quantum coherence, which can induce the effective size to characterize spin system, is expected in a larger and more complicated spin system for understanding of the relation of dipolar coupling and multiple quantum coherence.

• 한국응용과학기술학회지
• /
• 제14권3호
• /
• pp.39-46
• /
• 1997

Ultraviolet spectrophotometric investigation has been carried out on the rate constants for 1,3-dipolar cycloaddition of 4-substituted-3-phenyloxadiazole derivatives with dipolarophiles such as phenyl acetylene, propiolic acid methyl ester and dimethylacetylene dicarboxylate. From there, the rate constants for 1,3-dipolar cycloaddition were determined at 80, 100 and $120^{\circ}C$, and the reaction rates were increased with increasing temperature. From these rate constants, the values of the thermodynamic activation parameters were obtained. Some thermodynamic activation parameters such as $E_{\alpha}$, ${\Delta}H^{\ast}$, ${\Delta}S^{\ast}$ and ${\Delta}G^{\ast}$ from Arrhenius equation were also calculated for the electrophilic 1,3-dipolar cycloaddition of 3-phenyloxadiazole derivatives with dipolarophiles. In order to the proposal the mechanism and reactivity of 1,3-dipolar cycloaddition reaction, the effect of substituents having various kinds of electron withdrawing or releasing groups were examinated. Considering the effect of substituents, an electron withdrawing group attached at the 4-carbon position in 3-phenyloxadiazole derivatives decreases the reaction rate because of the lack of electron density in 3-phenyloxadiazole ring.

• 한국자기공명학회논문지
• /
• 제10권1호
• /
• pp.46-58
• /
• 2006

With a simple pulse sequence ($\pi/2$-{gradient, duration T}-acquisition) in solution NMR, detected signal has slowly grown up to percents of the equilibrium magnetization. The source of this unusual resurrection of dephased magnetization after a crushed gradient is cross-correlated effects of radiation damping and the distant dipolar field, which has been demonstrated by a numerical simulation and theoretical analysis.

• 한국자기공명학회논문지
• /
• 제3권2호
• /
• pp.71-83
• /
• 1999

The dynamics of the dipolar demagnetizing field is investigated by numerical simulation. The effects of radiation damping, molecular diffusion, and relaxation processes on the dipolar demagnetizing field are examined in terms of the modulation pattern of the z-magnetization and the signal intensity variation. Simulations for multi-components suggest applications for sensitivity enhancement in favorable conditions.

• Bulletin of the Korean Chemical Society
• /
• 제7권6호
• /
• pp.433-438
• /
• 1986

Two new types of NMR shift reagents, one giving dipolar-only and the other giving contact-only shifts, can be prepared simply by mixing two appropriate $Ln(fod)_3$(Ln = Pr, Nd, Eu, and Yb) reagents in certain ratios. The $^1H$ and $^{13}C$ NMR spectra of pyridine-type substrates, quinoline and isoquinoline, whose paramagnetic shifts are normally a composite of contact and dipolar contributions with single lanthanide shift reagents, show the feasibility of this approach.

• 한국재료학회:학술대회논문집
• /
• 한국재료학회 2003년도 추계학술발표강연 및 논문개요집
• /
• pp.142-142
• /
• 2003

The effects of film thickness on the dipolar relaxation of ferroelectric PbTiO$_3$ films were investigated in the microwave-frequency range. The dielectric constants ($\varepsilon$) and the dielectric losses (tan $\delta$) were successfully measured up to 30 ㎓ using interdigital capacitors. The PbTiO$_3$ thin films were deposited on the quartz substrate at room temperature and postannealed in oxygen atmosphere. As the film thickness increased, its grain size and tetragonality were enhanced. And the dipolar relaxation behavior began to appear in the thin films with approximately 20 nm thickness, since ferroelectric domains could not be formed hi small grains. The observed relaxation frequency (above 10 ㎓) was higher than the previous values reported in bulk ceramics. It can be correlated with the extremely small domain size of the thinfilms as shown by TEM. And, the Rayleigh constant [1] from domain wall motions was alsoinvestigated by LCR meter at 100 KHz.

• 한국군사과학기술학회지
• /
• 제18권6호
• /
• pp.736-742
• /
• 2015

The effect of pressure on 1,3-dipolar cycloaddtion has been studied by means of FT-IR and NMR spectroscopy. Pressure accelerates 1,3-dipolar cycloaddition without solvent or catalyst. This simple and inexpensive method eliminates the need for work-up or purification. The method is expected to be applied to the synthesis of binders for solid rocket propellants.

• Bulletin of the Korean Chemical Society
• /
• 제21권11호
• /
• pp.1077-1084
• /
• 2000

The dipolar effect of neighboring protons that are not directly bonded to the carbon of interest on coupled carbon-13 relaxation in a simple organic molecule has been studied by comparing the relaxation behaviors of labeled carbon-13 in $Br13CH_2COOH$ with those in $BrCH_213COOH.$ Various pulse sequences, such as coupled inversion recovery pulse sequence, J-negative and J-positive pulse sequence, and nonselective and selective proton ${\pi}pulse$ sequence, were employed to perform the required coupled spin relaxation experiments. To gain information on various spectral densities, including that of dipolar-CSA cross correlation, the experiments were performed on two different spectrometers, operating, respectively, at 50.31 and 125.51MHz for 13C. The magnitude of CH dipolar spectral densities for $BrCH_213COOH$ was found to be about 8% of those for $Br13CH_2COOH$, which means the effect due to the protons not directly bonded to the carbon of interest is small but not completely negligible.

• Bulletin of the Korean Chemical Society
• /
• 제26권5호
• /
• pp.717-718
• /
• 2005