• Bulletin of the Korean Chemical Society
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• 제32권8호
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• pp.2765-2770
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• 2011

Organic dye-doped glasses, viz., ruthenium (II) tris(4,7'-diphenyl-1,10'-phenanthroline) $[Ru(dpp)_3]^{2+}$ incorporated into thin silica xerogel films produced by the sol-gel method, were prepared and their $O_2$ quenching properties investigated as a function of the $[Ru(dpp)_3]^{2+}$ concentration (3-400 ${\mu}M$) within the xerogel. The ratio of the luminescence from the $[Ru(dpp)_3]^{2+}$-doped films in the presence of $N_2$ and $O_2$ ($I_{N2}/I_{O2}$) was used to describe the film sensitivity to $O_2$ quenching. ($I_{N2}/I_{O2}$ changed three-fold over the $[Ru(dpp)_3]^{2+}$ concentration range. Time-resolved intensity decay studies showed that there are two discrete $[Ru(dpp)_3]^{2+}$ populations within the xerogels (${\tau}_1$ ~ 300 ns; ${\tau}_2$ ~ 3000 ns) whose relative fraction changes as the $[Ru(dpp)_3]^{2+}$ concentration changes. The increased $O_2$ sensitivity that is observed at the higher $[Ru(dpp)_3]^{2+}$ concentrations is a manifestation of a greater fraction of the 3000 ns $[Ru(dpp)_3]^{2+}$ species (more susceptible to $O_2$ quenching). A model is presented to describe the observed response characteristics resulting from $[Ru(dpp)_3]^{2+}$ distribution within the xerogel.

• 대한화학회지
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• 제63권3호
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• pp.216-219
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• 2019

• 한국인쇄학회지
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• 제13권2호
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• pp.33-45
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• 1995

1, 4-Diketo-3, 6-diphenyl-pyrrolo-[3, 4c]-pyrrole(abbriviated DPP) is a new heterocyclic pigment of red color whose chlorinated derivative is now on the market. DDP was synthesized from benzonitrile and diethylsuccinate. Pariser-parr-pople(PPP) molecular orbital calculations have been carried out on the DPP in other to study spectroscopically the DPP chromophore on deprotonation.

• 센서학회지
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• 제32권2호
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• pp.82-87
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• 2023

This study proposes a pH-dissolved-oxygen monitoring system using 8-HydroxyPyrene-1,3,6-trisulfonic acid Trisodium Salt (HPTS) and tris(4,7-diphenyl-1,10-phenanthroline)Ruthenium(II) chloride (Ru_dpp). Commercial water-quality sensors are electrochemical devices that require frequent calibration and cleaning, are subject to high maintenance costs, and have difficulties conducting measurements in real-time. The proposed pH-dissolved-oxygen monitoring system selects a thin-film sensing layer to measure the change in fluorescence intensity. This change in fluorescence intensity is based on reactions with hydrogen ions in an aqueous solution at a given pH and specific amount of dissolved oxygen. The change in fluorescence intensity is then measured using light-emitting diodes and photodiodes in response to HPTS and Ru_dpp. This method enables the development of a relatively small, inexpensive, and real-time measureable water-quality measurement system.

• 한국인쇄학회지
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• 제21권2호
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• pp.101-108
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• 2003

We synthesised 1,3-Diphenyl-5-pyren-2-yl-4,5-dihydro-1H-pyrazole(DPP) and investigated its optical properties. The structure of DPP was confirmed by GC-Mass and elemental analysis. The absorption and photoluminescent spectra of DPP were measured at both hydrophobic and hydrophilic solvents and by the stokes shifts of DPP Lippert's equation could be applied. The results showed linear relation between $[{\varepsilon}-1/2{\varepsilon}+1)-(n^2-1/2n^2+1)]$ and $({\mu}_g\;-\;{\mu}_2)^2$.

• 한국인쇄학회지
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• 제14권1호
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• pp.1-15
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• 1996

In this paper, the preparation of lead zirconium titanate(PZT) thin film by sol-gel processing was descried. Thin film coated with thickness of 4${\mu}{\textrm}{m}$ on the stainless steel substrates using the multiple spin-coating process. The crystalline phases of PZT powder and film were investigated by X-ray diffraction pattern and PZT thin film has perovskite structure over 600 C annealing temperature. Corona charging characteristics of the ferroelectric PZT thin film at 600 C were investigated by electrophotographic measurement. A difference in the charging characteristics between positive and negative corona charging was found. The charge acceptance depended in the polarity of corona and the poling of film. According to the D-E hysteresis measurment, PZT thin film can be poled by corona charging without use of top electrode. The remnant polarization in the PZT thin film is generally in the order of 48$\mu$C/$\textrm{cm}^2$. From this results, the ferroelectric PZT thin film will be possible to apply for the add-on type imaging formation.

• 폴리머
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• 제29권6호
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• pp.565-570
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• 2005

용융 점도 조절에 의한 나일론6(N6)의 melt impregnation공정에서의 용융가공 특성에 대하여 고찰하여 보았다. N6의 용융 점도를 조절하기 위하여 calcium stearate(CaST)를 윤활제로 사용한 결과, 1 wt$\%$의 윤활제의 첨가에 의하여 용융 점도가 감소함을 알 수 있었다. 아울러 폴리카프로락톤(PCL)을 N6에 반응 용융 블렌딩하여 N6의 용융 점도를 낮출 수 있었으며 phenyl phosphite(PP)와 diphenyl phosphite(DPP)를 첨가하여 블렌딩 시 상호에스테르 교환반응을 증가시켜 추가적인 용융 점도 감소를 확인하였다. 이러한 방법들은 N6의 고온 가공의 문제점으로 지적되는 열안정성 저하를 최소화하면서 melt impregnation 공정에서 필수적인 저점도 가공을 가능하게 할 수 있을 것으로 사료된다.

• KSBB Journal
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• 제32권1호
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• pp.35-45
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• 2017

In this work the optical fiber glucose and lactate biosensors were developed by using fluorescent dye and enzyme immobilized on the end tip of an optical fiber. 3-Glycidyloxypropyl)methyldiethoxysilane (GPTMS), (3-Aminopropyl) trimethoxysilane (APTMS) and Methyltrimethoxysilane (MTMS) were used to immobilize glucose oxidase (GOD), lactate oxidase (LOD) and ruthenium(II) complex (tris(4,7-diphenyl-1,10-phenanthroline) ruthenium(II), $Ru(dpp)_3^{2+}$) as oxygen sensitive fluorescent dye. MTMS sol-gel was an excellent supporting material for the immobilization of $Ru(dpp)_3^{2+}$, GOD, and LOD on the optical fiber. Storage stability of the optical fiber glucose sensor was kept constant over 20 days, while the optical fiber lactate sensor had constant storage stability over 17 days. The optical fiber glucose and lactate biosensors also maintained good operational stability for 20 hours and 14 hours, respectively. The activities of the immobilized enzymes were most excellent at pH 7 and at $25^{\circ}C$. On-line monitoring of glucose and lactate in a simulated process was performed with the optical fiber glucose and lactate biosensors. On-line monitoring results were agreed with those of off-line data measured with high performance liquid chromatography (HPLC).

• 한국산학기술학회논문지
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• 제15권1호
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• pp.569-574
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• 2014

오폐수 처리에 있어서 용존산소량을 장기간, 연속측정이 가능한 DO 센서의 개발이 요구되어, 형광검출 특성을 이용한 광학식 DO 센서를 개발하고 특성을 분석하였다 (OS-100, 글로벌광통신주식회사). 형광 센서막은 GA를 이용하여 졸-겔 방법을 이용하여 $Ru(Dpp)_3{^{2+}}$(tris(4,7diphenyl-1, 10-phenanthroline) ruthenium(II)) 형광물질을 제작하였고, 용액과 혼합하여 스프레이 방법으로 석영기판위에 증착하였다. 증착된 형광막은 용존산소 농도 3 mg/L에서 10 mg/L 사이의 넓은 영역에서 ${\pm}1%$ 이하의 오차를 보였다. 제작된 광학식 DO 센서의 성능평가를 위하여 대구염색단지의 오폐수처리장 폐수의 실시간 용존산소를 장기간 측정하였다. 6개월간의 장기간에 걸쳐 실시간 측정된 용존산소의 결과는 염색공단 폐수의 악조건 하에서도 ${\pm}2%$ 이하의 오차를 나타내었다.

• 대한화장품학회지
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• 제36권1호
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• pp.79-87
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• 2010

자외선은 생체 내 활성산소 생성 증가와 내인성 항산화 효소 및 항산화제 감소를 통하여 광노화 과정을 촉진하는 대표적인 외부 환경인자로 알려져 있다. 그러므로 본 연구에서는 12종의 다양한 해양소재 추출물(김, 다시마, 모려, 모자반, 미역, 석결명, 청각, 해룡, 해마, 해삼, 파래, 톳)을 이용하여 기본적인 자유라디칼 소거능 실험을 바탕으로, 자외선 B 조사로 인한 세포독성 및 산화적 사멸을 억제하고 세포 내 항산화 기능을 강화시킬 수 있는 천연 항산화 피부보호소재를 발굴하고자 하였다. 해양소재 추출물의 라디칼 소거능을 1,1-diphenyl-2-picrylhydrazyl (DppH) assay로 비교 측정한 결과 미역, 모자반, 다시마, 해마, 석결명 모려, 해룡의 순으로 항산화력을 나타내었다. 이후 in vitro 세포 실험에서 자외선 B를 섬유아세포주인 HS68 세포에 노출시킨 경우 세포 독성이 유발되어 사멸이 진행되었으며 이는 모자반, 석결명, 청각, 해마 열수 추출물을 처리한 경우 현저히 억제되었다. 특히, 자외선 B로 인한 세포손상은 세포 내 활성산소종의 축적으로 인한 것임을 2',7'-dichlorodihydrofluorescein diacetate (DCF-DA) 형광염색법으로 확인할 수 있었으며, 활성산소종의 생성은 모자반, 석결명, 청각, 해마 열수 추출물을 처리한 경우 유의적으로 감소되었다. 한편, 이러한 항산화 작용은 대표적인 내인성 항산화 효소인 catalase, superoxide dismutase 및 heme oxygenase-1의 발현 증가로 매개되었다. 이상의 결과는 모자만, 석결명, 정각, 해마 풍의 해양소재가 항산화 작용을 통하여 산화적 스트레스가 매개하는 피부손상과 노화과정을 예방 및 보호하는 새로운 화장품 천연소재로의 활용 가능성을 제시한다.