• Title/Summary/Keyword: Dip Coating

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The effect of annealing temperature and solvent on the fabrication of YBCO thin films by MOD-TFA process (MOD-TFA 공정으로 YBCO 박막제조 시 열처리 온도와 용매의 영향)

  • 허순영;유재무;김영국;고재웅;이동철
    • Progress in Superconductivity
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    • v.5 no.1
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    • pp.84-87
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    • 2003
  • $YBa_2$$Cu_3$$O_{7-x}$ (YBCO) thin films were fabricated by MOD-TFA process via dip-coating method on LaAlO$_3$, (LAO) single crystalline substrates. In this study, we investigated effect of annealing temperature and solvent on the microstructure and texture of YBCO thin films. The precursor films were annealed at various temperature to improve surface morphologies and phase purities. It was shown that the films annealed at relatively lower and higher temperature exhibit low phase purity and crystallinity. The effect of various solvents on surface morphologies and second phase has been investigated.

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Humidity Sensitive Properties of $V_2O_5$-added $TiO_2$ Ceramics ($V_2O_5$ 첨가에 따른 $TiO_2$ 세라믹스의 감습특성)

  • Hyun, You-Do
    • Proceedings of the KIEE Conference
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    • 2008.05a
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    • pp.161-163
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    • 2008
  • $TiO_2-V_2O_5$ sol was fabricated using sol-gel method and $TiO_2-V_2O_5$, thin films were fabricated using dip-coating method. $V_2O_5$ sol was added 0.01mole, 0.03mole, 0.05mole into $TiO_2$ sol. Capacitance of thin films decreased with increasing $V_2O_5$ additive and it increased largest at 0.01mole. Because adsorption time and desorption time of thin films was about 2 minutes 40 seconds and about 3 minutes 40 seconds respectively, adsorption time was faster about 1 minutes than desorption time.

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Effects on Properties of $V_2O_5$-added $TiO_2$ Ceramics ($V_2O_5$ 첨가가 $TiO_2$ 세라믹스의 물성에 미치는 효과)

  • You, Do-Hyun
    • Proceedings of the KIEE Conference
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    • 2007.11c
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    • pp.138-140
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    • 2007
  • $TiO_2-V_2O_5$ sol was fabricated using sol-gel method and $TiO_2-V_2O_5$ thin films were fabricated using dip-coating method. $V_2O_5$ sol was added 0.01mo1e, 0.03mo1e, 0.05mo1e into $TiO_2$ sol. Viscosity of sol increased fast from about 1,000 minutes and sol began gelation from about 10,000 minutes. As a results of crystalline properties, $V_2O_5$ peaks were not found despite of $V_2O_5$ addition. Endothermic reaction occurred due to evaporation of solvent and dissociation of OH at $80^{\circ}C$. Exothermic reaction occurred due to combustion and oxidation of solvent at $230^{\circ}C$, occurred to combustion and oxidation of alkyl group at $350^{\circ}C$. Thickness of thin films increased $0.1{\sim}0.25{\mu}m$ every a dipping.

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Variable surface coatings composed of organic-inorganic hybrid polymers

  • Kessler, Daniel;Bahnmuller, Stefan;Theato, Patrick
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.315-315
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    • 2006
  • A variable surface coating with the potential to fulfill the requirements of industry will be presented. Via controlled radical polymerization methods from a functionalized Polymethylsilsesquioxane delivers an inorganic-organic block copolymer, which can be easily modified and tuned for different applications. Spin coated or dip coated on various substrates show promising results. By using different block copolymers the contact angle on a silicon wafer can be varied in a range of $90^{\circ}\;up\;to\;145^{\circ}$ After curing and complete condensation a perfect adhesion on glasses, plastics and metals is achieved.

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Preparation of Inorganic Membrane for H$_2$ Separation by 2-step Silica Sol-Gel method (2단계 실리카 솔-젤법을 이용한 수소분리용 무기재료막의 제조)

  • 소재현;양승만;박승빈
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.10a
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    • pp.55-57
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    • 1996
  • 다공성 무기막은 높은투과도와 뛰어난 내열.내화학성, 그리고 경제성 때문에 기존의 PSA공정이나 증류와 같은 고에너지 분리공정을 대체하는 공정으로 각광을 받고 있다. 무기재료막의 제조하는 방법으로 주로 알콕사이드를 사용하는 솔-젤법(1)과 금속(2) 또는 기상반응(3)을 이용하는 화학증착법이 사용된다. 또한 고온에서 수소를 연속적으로 분리하여 화학평형에 기인한 한계를 극복하여 높은 수율을 얻고자하는 막반응기에 관한 연구가 활발히 진행되고 있다. 본 연구에서는 $\alpha$-알루미나 지지체의 미세한 다공성 구조 내부에서 TEOS(Tetraethylorthosilicate)와 산성의 알코올-물 혼합물을 확산시켜 실리카 솔을 생성시킴과 동시에 젤화시켜 기공의 크기를 감소시켜 막을 제조하였다. 이렇게 제조된 막은 높은 투과도와 낮은 수소선택도(selectivity=3-4)를 보였고, 두번째 단계로 silica sol을 제조하여 진공 하에서 dip-coating을 행하였다. 이렇게 2단계로 기공 구조를 개선시킨 실리카 막은 저압에서 상대적으로 높은 수소의 분리도(selectivity=5-7)를 보였으며 여전히 높은 투과도를 갖는다.

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Dense Ceramic-metal Composite Inorganic Membranes for Oxygen Separation (산소 분리를 위한 무공성 세라믹- 금속 복합 무기막)

  • 김진수
    • Proceedings of the Membrane Society of Korea Conference
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    • 2002.05a
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    • pp.35-41
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    • 2002
  • Dense oxygen ionic conducting materials can be used for oxygen separation membranes at high temperatures. However, they show relatively low permeation flux because of their large resistances. To reduce resistances and improve the oxygen permeation flux, thin dense yttria-stabilized-zirconia (YSZ)/Pd composite dual-phase membranes were fabricated by a new approach that combines the reservoir method and chemical vapor deposition (CVD). A thin porous YSZ layer was coated on a porous alumina support by dip-coating the YSZ suspension. A continuous Pd phase was formed inside pores of the YSZ layer by the reservoir method. The residual pores of the YSZ/Pd layer were plugged with yttria/zirconia by CVD to ensure the gas tightness of the membranes. The oxygen permeation fluxes through these composite membrane were 2.0$\times$10$^{-8}$ mol/cm$^2$.s and 4.8$\times$10$^{-8}$ mol/cm$^2$.s at 105$0^{\circ}C$ when air and oxygen were used as the permeate gases, respectively. These oxygen permeation values are about 1 order of magnitude higher than those of pure YSZ membranes prepared under similar conditions.

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Structure and Properties of Polymer Infiltrated Alumina Thick film via Inkjet Printing Process (잉크젯 프린팅 공정에 의한 유전체 후막의 제조 및 특성)

  • Jang, Hun-Woo;Koo, Eun-Hae;Kim, Ji-Hoon;Kim, Hyo-Tae;Yoon, Young-Joon;Hwang, Hae-Jin;Kim, Jong-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.4
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    • pp.297-302
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    • 2009
  • We have successfully fabricated the alumina thick films using inkjet printing processes without a high temperature sintering process. Alumina suspension as dielectric ink was formulated by combining nano-sized alumina powders with an anionic polymer dispersant in formamide/water as co-solvent. The thickness of the printed alumina thick film was measured at around 5 um by field emission scanning electron microscope. The calculated packing density of 68.5 % from the printed alumina thick film was much higher than the same films fabricated by conventional casting or dip coating processes. Q factor of the dielectrics thick film infiltrated with cyanate ester resin was evaluated by impedance analyzer.

The effect of the initial BSCCO 2212 grain size on the final grain size and the formation of BSCCO 2223

  • Yoo, Jai-Moo;Park, Myoung-Je;Kim, Hai-Doo;Chung, Hyung-Sik;Ko, Jae-Woong
    • 한국초전도학회:학술대회논문집
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    • v.10
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    • pp.285-288
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    • 2000
  • The effect of the initial BSCCO 2212 grain size on the final gain size and the formation of the BSCCO 2223 was studied using a powder precursor synthesized by two-powder method. 2212 and CaCuO$_2$ tapes were prepared by dip coating and joined by pressing and then followed by the repeated thermo mechanical treatment. The samples were characterized by XRD and SEM analysis. The formation and grain size of the BSCCO 2223 depended on the initial BSCCO 2212 grain size.

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Sloshing Flow of Highly-Viscous Fluid in a Rectangular Box (사각용기에서 발생하는 고점성 유체의 슬로싱 유동)

  • park, Jun Sang
    • Journal of the Korean Society of Visualization
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    • v.17 no.3
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    • pp.39-45
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    • 2019
  • A study on the sloshing flow of highly-viscous fluid in a rectangular box was made by both of theoretical approach and experimental visualization method. Assuming a smallness of external forcing to oscillate the container, it was investigated a linear sloshing flow of highly-viscous fluid utilizing asymptotic analysis by Taylor-series expansion as a small parameter Re (≪1) in which Re denotes Reynolds number. The theory predict that, during all cycles of sloshing, a linear shape of free surface will prevail in a bulk zone and it has confirmed in experiment. The relevance of perfect slip boundary condition, adopted in theoretical approach, to the bulk zone flow at the container wall was tested in experiment. It is found that quasi-steady coated thin film, which makes a lubricant layer between bulk flow and solid wall, is generated on the wall and the film makes a role to perfect slip boundary condition.

Effect of Film Thickness on the Tribological Characteristics of Zdol Lubricant on Silicon Surface

  • Kim, Yong-Sik;Yang, Ji-Chul;Kim, Dae-Eun
    • International Journal of Precision Engineering and Manufacturing
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    • v.5 no.1
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    • pp.13-18
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    • 2004
  • In precision mechanical components that experience sliding, it is important to reduce the friction to minimize surface damage. Particularly, new lubrication methods are needed to reduce friction in silicon based micro-systems applications. In this work, the tribological characteristics of PFPE (Perfluoropolyether) Zdol lubricant on silicon were investigated based on the thickness of the film. The lubricant was coated on silicon wafer specimens by the dip coating method. It was shown that the friction coefficient as well as stiction decreased as the thickness of the film increased. The results of this work may be applied to improve the tribological performance of silicon based micro-system components.